共查询到20条相似文献,搜索用时 15 毫秒
1.
Yang C Kim JY Cho S Lee JK Heeger AJ Wudl F 《Journal of the American Chemical Society》2008,130(20):6444-6450
The synthesis of two well-solubilized [60]methanofullerene derivatives ( p- EHO-PCBM and p- EHO-PCBA) is presented for usage in organic solar cells and in field-effect transistors. The para position of the PCBM's phenyl ring was substituted with a branched alkoxy side chain, which contributes to higher solubility, facilitating synthesis, purification, and processing. We find a small change of the open-circuit voltage ( V oc) as a slight improvement in performance upon application in P3HT/[60]methanofullerene bulk-heterojunction-photovoltaic cells, when compared to PCBM, because of the electron donation of the alkoxy group. In the case of the devices with a TiO x layer, the best power conversion efficiencies (PCE, eta e) is observed in a layered structure of P3HT/ p- EHO-PCBA/TiO x (eta e = 2.6%), which slightly exceeds that of P3HT/PCBM/TiO x (eta e = 2.3%) under conditions reported here. This can be attributed, in part, to the carboxylic acid group in p- EHO-PCBA that leads to an effective interface interaction between the active layer and TiO x phase. In addition, n-channel organic field-effect transistor (OFET) devices were fabricated with thin films of p- EHO-PCBM and p- EHO-PCBA, respectively cast from solution on SiO 2/Si substrates. The values of field-effect mobility (mu) for p- EHO-PCBM and p- EHO-PCBA are 1 x 10 (-2) and 1.6 x 10 (-3) cm (2)/V.s, respectively. The results in this paper demonstrate the effects of a carboxylic acid group and an electron-donating substituent in [60]methanofullerenes as n-type materials with respect to organic solar cells and OFET applications. 相似文献
2.
3.
Two structural isomers of six-fused-ring sulfur-containing molecules were synthesized as active materials for p-type organic field-effect transistors, and their optical and electrochemical properties were characterized. Field-effect transistors based on these compounds were fabricated to investigate the relationships between structures and semiconductor properties. 相似文献
4.
LIU Ying YU Gui & LIU YunQi Beijing National Laboratory for Molecular Sciences Key Laboratory of Organic Solids 《中国科学:化学》2010,(4)
Fused thiophenes refer to oligothienoacenes in which several thiophenes are coupled together via twoor multi-positions and their derivatives. The synthesized organic semiconductors based on fused thiophenes exhibit excellent field effect properties due to their efficient intermolecular S…S interactions and π…π stacking. The performances of organic field-effect transistors (OFETs) depend not only on the materials but also on the devices. Such factors which influence the device performances as device structur... 相似文献
5.
The multi-level microstructure of conjugated polymers is the most critical parameter determining the charge transport property in field-effect transistors (FETs). However, controlling the hierarchical microstructures and the structural evolution remains a significant challenge. In this perspective, we discuss the key aspects of multi-level microstructures of conjugated polymers towards high-performance FETs. We highlight the recent progress in the molecular structures, solution-state aggregation, and polymer crystal structures, representing the multi-level microstructures of conjugated polymers. By tuning polymer hierarchical microstructures, we attempt to provide several guidelines for developing high-performance polymer FETs and polymer electronics.The multi-level microstructures of conjugated polymers, including solution-state aggregation and crystal structures, are reviewed due to their influence on charge transport in polymer field-effect transistors. 相似文献
6.
Organic semiconductor materials, especially donor–acceptor (D–A) polymers, have been increasingly applied in organic optoelectronic devices, such as organic field-effect transistors (OFETs) and organic solar cells (OSCs). Plenty of high-performance OFETs and OSCs have been achieved based on varieties of structurally modified D–A polymers. As the basic building block of D–A polymers, acceptor moieties have drawn much attention. Among the numerous types, lactam- and imide-functionalized electron-deficient building blocks have been widely investigated. In this review, the structural evolution of lactam- or imide-containing acceptors (for instance, diketopyrrolopyrrole, isoindigo, naphthalene diimide, and perylene diimide) is covered and their representative polymers applied in OFETs and OSCs are also discussed, with a focus on the effect of varied structurally modified acceptor moieties on the physicochemical and photoelectrical properties of polymers. Additionally, this review discusses the current issues that need to be settled down and the further development of new types of acceptors. It is hoped that this review could help design new electron-deficient building blocks, find a more valid method to modify already reported acceptor units, and achieve high-performance semiconductor materials eventually.This review highlights the recent structural evolution of lactam- and imide-functionalized polymers applied in organic field-effect transistors and organic solar cells. 相似文献
7.
Alkenyl tosylates of the type RCHCH(CH2)nOTs [RH, n=9; RH, n=7; and RCH3(CH2)7, n=8] undergo metathesis using a WCl6-Me3SnCl catalyst system, producing difunctionalised alkenes of the type TsO(CH2)nCHCH(CH2)nOTs (n=7,8, and 9); examples of the use of these products in synthesis are presented. 相似文献
8.
Jin-Long Wang Xue-Qiang Chen Xiang Yao Si-Cheng Wu Li-Na Liu Wen-Jing Xiao Hongyu Wang Jingjing Li Zhengquan Lu Wei-Shi Li 《Tetrahedron letters》2017,58(28):2695-2699
The continuous microstructure evolution occurring in active layers of polymer-fullerene solar cells is one of the main causes for their device instability. With aim to tackle it, this work developed a new polymerizable fullerene acceptor, [6,6]-phenyl-C61-butyl acrylate (PC61BA). It was found that PC61BA has similar light-absorption properties and HOMO and LUMO energy levels as [6,6]-phenyl-C61-butyric acid methyl ester (PC61BM), and can be converted into insoluble oligomers upon heating at 150 °C. Polymer-fullerene solar cells using poly(3-hexylthiophene) (P3HT) as donor and PC61BA as acceptor exhibited an optimized efficiency of 3.54%, the performance comparable to P3HT/PC61BM cells (optimized efficiency: 3.70%). But, the former possess much better thermal stability than the latter owing to aggregation suppression by the polymerized PC61BA. These results indicate that PC61BA, unlike most previous reported, is a unique polymerizable fullerene derivative that can be used alone as acceptor to achieve both efficient and thermally stable polymer solar cells. 相似文献
9.
An efficient synthetic approach to a series of aceno[2,1,3]thiadiazole derivatives is described. 2-TIPS and 2-TES molecules exhibited different crystal packings, and 2-TIPS show good device performances with hole mobility up to 0.4 cm(2) V(-1) s(-1) and an average mobility of 0.15 cm(2) V(-1) s(-1) as the active material for organic field-effect transistors. All of the results demonstrate these aceno[2,1,3]thiadiazole derivatives as promising materials for optoelectronic devices. 相似文献
10.
Jun Ho Kwon Ji‐Young An Hanmae Jang Solji Choi Dae Sung Chung Min‐Jung Lee Hyo‐Jung Cha Jin‐Hee Park Chan‐Eon Park Yun‐Hi Kim 《Journal of polymer science. Part A, Polymer chemistry》2011,49(5):1119-1128
A new semiconducting polymer, poly((5,5‐E‐α‐((2‐thienyl)methylene)‐2‐thiopheneacetonitrile)‐alt‐2,6‐[(1,5‐didecyloxy)naphthalene])) (PBTADN), an alternating copolymer of 2,3‐bis‐(thiophene‐2‐yl)‐acrylronitrile and didecyloxy naphthalene, is synthesized and used as an active material for organic thin film transistors (OTFTs) and organic solar cells. The incorporation of 2,3‐bis‐(thiophene‐2‐yl)‐acrylronitrile as an electron deficient group and didecyloxy naphthalene as an electron rich group resulted in a relatively low bandgap, high charge carrier mobility, and finally good photovoltaic performances of PBTADN solar cells. Because of the excellent miscibility of PBTADN and PC71BM, as confirmed by Grazing Incident X‐ray Scattering (GIXS) measurements and Transmission Electron Microscopy (TEM), homogeneous film morphology was achieved. The maximum power conversion efficiency of the PBTADN:PC71BM solar cell reached 2.9% with a Voc of 0.88 V, a short circuit current density (Jsc) of 5.6 mA/cm2, and a fill factor of 59.1%. The solution processed thin film transistor with PBTADN revealed a highest saturation mobility of 0.025 cm2/Vs with an on/off ratio of 104. The molecular weight dependence of the morphology, charge carrier mobility, and finally the photovoltaic performances were also studied and it was found that high molecular weight PBTADN has better self assembly characteristics, showing enhanced performance. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
11.
This Review describes the application of nitroxides to synthesis and polymer chemistry. The synthesis and physical properties of nitroxides are discussed first. The largest section focuses on their application as stoichiometric and catalytic oxidants in organic synthesis. The oxidation of alcohols and carbanions, as well as oxidative C-C bond-forming reactions are presented along with other typical oxidative transformations. A section is also dedicated to the extensive use of nitroxides as trapping reagents for C-centered radicals in radical chemistry. Alkoxyamines derived from nitroxides are shown to be highly useful precursors of C-centered radicals in synthesis and also in polymer chemistry. The last section discusses the basics of nitroxide-mediated radical polymerization (NMP) and also highlights new developments in the synthesis of complex polymer architectures. 相似文献
12.
Kim C Wang Z Choi HJ Ha YG Facchetti A Marks TJ 《Journal of the American Chemical Society》2008,130(21):6867-6878
We report here the synthesis and dielectric properties of optimized, cross-linked polymer blend (CPB) dielectrics for application in organic field-effect transistors (OFETs). Novel silane cross-linking reagents enable the synthesis of CPB films having excellent quality and tunable thickness (from 10 to approximately 500 nm), fabricated both by spin-coating and gravure-printing. Silane reagents of the formula X 3Si-R-SiX 3 (R = -C 6H 12- and X = Cl, OAc, NMe 2, OMe, or R = -C 2H 4-O-C 2H 4- and X = OAc) exhibit tunable reactivity with hydroxyl-containing substrates. Dielectric films fabricated by blending X 3Si-R-SiX 3 with poly(4-vinyl)phenol (PVP) require very low-curing temperatures ( approximately 110 degrees C) and adhere tenaciously to a variety of FET gate contact materials such as n (+)-Si, ITO, and Al. The CPB dielectrics exhibit excellent insulating properties (leakage current densities of 10 (-7) approximately 10 (-8) A cm (-2) at 2.0 MV/cm) and tunable capacitance values (from 5 to approximately 350 nF cm (-2)). CPB film quality is correlated with the PVP-cross-linking reagent reactivity. OFETs are fabricated with both p- and n-type organic semiconductors using the CPB dielectrics function at low operating voltages. The morphology and microstructure of representative semiconductor films grown on the CPB dielectrics is also investigated and is correlated with OFET device performance. 相似文献
13.
Shinamura S Osaka I Miyazaki E Nakao A Yamagishi M Takeya J Takimiya K 《Journal of the American Chemical Society》2011,133(13):5024-5035
A straightforward synthetic approach that exploits linear- and angular-shaped naphthodithiophenes (NDTs) being potential as new core structures for organic semiconductors is described. The newly established synthetic procedure involves two important steps; one is the chemoselective Sonogashira coupling reaction on the trifluoromethanesulfonyloxy site over the bromine site enabling selective formation of o-bromoethynylbenzene substructures on the naphthalene core, and the other is a facile ring closing reaction of fused-thiophene rings from the o-bromoethynylbenzene substructures. As a result, three isomeric NDTs, naphtho[2,3-b:6,7-b']dithiophene, naphtho[2,3-b:7,6-b']dithiophenes, and naphtho[2,1-b:6,5-b']dithiophene, are selectively synthesized. Electrochemical and optical measurements of the parent NDTs indicated that the shape of the molecules plays an important role in determining the electronic structure of the compounds; the linear-shaped NDTs formally isoelectronic with naphthacene have lower oxidation potentials and more red-shifted absorption bands than those of the angular-shaped NDTs isoelectronic with chrysene. On the contrary, the performance of the thin-film-based field-effect transistors (FETs) using the dioctyl or diphenyl derivatives were much influenced by the symmetry of the molecules; centrosymmetric derivatives tend to give higher mobility (up to 1.5 cm(2) V(-1) s(-1)) than axisymmetric ones (~0.06 cm(2) V(-1) s(-1)), implying that the intermolecular orbital overlap in the solid state is influenced by the symmetry of the molecules. These results indicate that the present NDT cores, in particular the linear-shaped, centrosymmetric naphtho[2,3-b:6,7-b']dithiophene, are promising building blocks for the development of organic semiconducting materials. 相似文献
14.
Two tetrabrominated intermediates obtained by bromination of naphthodithiophene in different solvents were used to construct novel highly π-extended butterfly-shaped heteroarenes 1-6, containing either an 8- or 10-fused ring. The solution-processed organic field-effect transistors based on compound 1 exhibited promising device performance with a hole mobility of 0.072 cm(2) V(-1) s(-1) and a current on/off ratio of 10(6) under ambient atmosphere. 相似文献
15.
Waghadkar Yogesh Shinde Manish Ballal Reshma Rane Sunit Gosavi Suresh Chauhan Ratna 《Journal of Solid State Electrochemistry》2017,21(6):1797-1804
Journal of Solid State Electrochemistry - Hierarchically nano-structured ZnO microspheres have been synthesized solvothermally at variable reaction times (6, 12, 36, and 48 h) by using... 相似文献
16.
A series of crosslinkable maleimide conjugated polymers with different vinyl group contents as side‐chain crosslinking sites have been synthesized by the Suzuki coupling reaction. Polymer solar cells (PSCs) were fabricated based on an interpenetrating network of the crosslinkable maleimide polymers as the electron donor, and a fullerene derivative, (6,6)‐phenyl‐C61‐butyric acid methyl ester (PCBM), as the electron acceptor. The crosslinkable maleimide polymers underwent crosslinking reaction at the side‐chain vinyl groups upon the thermal treatment with or without the addition of initiator, azobisisobutyronitrile (AIBN). Better photovoltaic (PV) performances were obtained for the PSCs based on the polymer crosslinking without using initiator, whereas poorer PV performances were observed for the PSCs based on the polymer crosslinking with the AIBN initiator. In addition, higher operational stability was observed for the crosslinked polymer based solar cell as compared to the solar cell based on the un‐crosslinked polymer. The photo‐physical and PV properties of the cross‐linked maleimide polymers/PCBM based PSCs are discussed in detail as the morphology and crosslinking density of the polymers are taken into account. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
17.
T. M. Wijendra Jayalath Bandara Piyasiri Ekanayake M. A. K. Lakshman Dissanayake Ingvar Albinsson Bengt-Erik Mellander 《Journal of Solid State Electrochemistry》2010,14(7):1221-1226
Various iodide ion conducting polymer electrolytes have been studied as candidate materials for fabricating photoelectrochemical
(PEC) solar cells and energy storage devices. In this study, enhanced ionic conductivity values were obtained for the ionic
liquid tetrahexylammonium iodide containing polyethylene oxide (PEO)-based plasticized electrolytes. The analysis of thermal
properties revealed the existence of two phases in the electrolyte, and the conductivity measurements showed a marked conductivity
enhancement during the melting of the plasticizer-rich phase of the electrolyte. Annealed electrolyte samples showed better
conductivity than nonannealed samples, revealing the existence of hysteresis. The optimum conductivity was shown for the electrolytes
with PEO:salt = 100:15 mass ratio, and this sample exhibited the minimum glass transition temperature of 72.2 °C. For this
optimum PEO to salt ratio, the conductivity of nonannealed electrolyte was 4.4 × 10−4 S cm−1 and that of the annealed sample was 4.6 × 10−4 S cm−1 at 30 °C. An all solid PEC solar cell was fabricated using this annealed electrolyte. The short circuit current density (I
SC), the open circuit voltage (V
OC), and the power conversion efficiency of the cell are 0.63 mA cm−2, 0.76 V, and 0.47% under the irradiation of 600 W m−2 light. 相似文献
18.
Singh K Sharma A Zhang J Xu W Zhu D 《Chemical communications (Cambridge, England)》2011,47(3):905-907
New, neutral, meso-substituted tetrathia[22]annulene[2,1,2,1] aromatic macrocyclic architectures display p-type semiconductor behaviour and constitute efficacious molecular field-effect transistors with reproducible bulk-like carrier mobility (as high as 0.63 cm(2) V(-1) S(-1)) on highly crystalline thin films deposited on octadecyltrichlorosilane modified SiO(2). 相似文献
19.
Sang Kyu Lee In‐Nam Kang Jong‐Cheol Lee Won Suk Shin Won‐Wook So Sang‐Jin Moon 《Journal of polymer science. Part A, Polymer chemistry》2011,49(14):3129-3137
A novel series of thiazolothiazole (Tz)‐based copolymers, poly[9,9‐didecylfluorene‐2,7‐diyl‐alt‐2,5‐bis‐(3‐hexylthiophene‐2‐yl)thiazolo[5,4‐d]thiazole] (P1), poly[9,9‐dioctyldibenzosilole‐2,7‐diyl‐alt‐2,5‐bis‐(3‐hexylthiophene‐2‐yl)thiazolo[5,4‐d]thiazole] (P2), and poly[4,4′‐bis(2‐ethylhexyl)‐dithieno[3,2‐b:2′,3′‐d]silole‐alt‐2,5‐bis‐(3‐hexylthiophene‐2‐yl)thiazolo[5,4‐d]thiazole] (P3), were synthesized for the use as donor materials in polymer solar cells (PSCs). The field‐effect carrier mobilities and the optical, electrochemical, and photovoltaic properties of the copolymers were investigated. The results suggest that the donor units in the copolymers significantly influenced the band gap, electronic energy levels, carrier mobilities, and photovoltaic properties of the copolymers. The band gaps of the copolymers were in the range of 1.80–2.14 eV. Under optimized conditions, the Tz‐based polymers showed power conversion efficiencies (PCEs) for the PSCs in the range of 2.23–2.75% under AM 1.5 illumination (100 mW/cm2). Among the three copolymers, P1, which contained a fluorene donor unit, showed a PCE of 2.75% with a short‐circuit current of 8.12 mA/cm2, open circuit voltage of 0.86 V, and a fill factor (FF) of 0.39, under AM 1.5 illumination (100 mW/cm2). © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
20.
Jinsheng Song Chi Zhang Cuihong Li Weiwei Li Ruiping Qin Binsong Li Zhengping Liu Zhishan Bo 《Journal of polymer science. Part A, Polymer chemistry》2010,48(12):2571-2578
A series of main chain donor‐acceptor low‐bandgap conjugated polymers were designed, synthesized, and used for the fabrication of polymer solar cells. The absorption spectra of low‐bandgap conjugated polymers were tuned by the ratio of three copolymerization monomers. The polymers in films exhibited broad absorption ranging from 300 to 1000 nm with optical bandgaps of around 1.40 eV. All of the polymers have been investigated as an electron donor in photovoltaic cells blending with PCBM ([6, 6]‐phenyl C61‐butyric acid methyl ester) as an electron acceptor and power conversion efficiencies (PCEs) of 1.32–1.8% have been obtained. As for P1 , PCE increases from 1.67 to 2.44% after adding 1,8‐diiodooctance as an additive. The higher PCEs are probably because of better phase separation of blend films. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 2571–2578, 2010 相似文献