低密度EPS不同角度及厚度情况下火蔓延特性研究

本文采用小尺寸实验的方法探究了低密度EPS火蔓延及其熄灭特性,分析了密度、厚度以及角度综合因素对EPS火蔓延及熄灭的影响。研究发现:密度为6 kg/m^3的EPS,由于密度很小,材料厚度以及放置角度受到密度影响的抑制,EPS均无法被火源点燃进而进行火蔓延;而当密度为10 kg/m^3的EPS,随着材料厚度以及放置角度的增加,试样经历了从不能点燃,到短距离不稳定火蔓延,正常蔓延,以及蔓延过程中收缩性熄灭等过程。研究发现,密度为10 kg/m^3,厚度为4 cm的EPS试样,当放置角度为0°、10°、20°和30°时,能够正常蔓延,而当角度增加至40°、50°时,EPS火蔓延过程中出现了收缩性熄灭的现象.通过分析火蔓延过程收缩性熄灭机理,发现火蔓延速度与预热区的长度之间的相互竞争机制,是导致熄灭现象产生的主要原因。实验结果表明,收缩性熄灭对火蔓延速度,池火区长度以及表面火焰区火焰形态等都产生了相应的影响。     

基于光谱分析的油料池火内部传热特性研究

油料池火焰内部分为不同燃烧区域,目前对油池火内部传热特性研究较少。针对油池火内部传热特性研究不足的现状,构建了红外火焰光谱测试系统,研究分析了92#汽油、95#汽油及润滑油池火焰红外光谱特性,对油池火焰不同燃烧区域的光谱信息进行了提取分析,结果表明：三种油料池火焰光谱特征相似,存在多个CO₂,H₂O及炭黑颗粒等燃烧产物的特征发射波段,3.4 μm处C—H伸缩振动峰明显;火焰烟气区主要光谱特征为4～4.5 μm波段范围内高温CO₂发射峰,该区域火焰与空气换热剧烈,温度变化不稳定,火焰脉动频率较高;火焰间歇区的光谱特征是4～4.5 μm波段范围内高温CO₂发射峰,与烟气区相比,火焰间歇区脉动频率相对较低;与烟气区及间歇区相比,火焰连续区燃烧较为稳定,该区域的光谱特征明显,在2.5～3 μm波段范围内炭黑粒子发射光谱强度较高,且在3.4 μm处存在C—H伸缩振动峰,表明油料池火焰光谱3.4 μm处的特征峰由高温油蒸汽产生。油池火焰不同燃烧区域光谱特征分析表明,油池火焰液态油表面的“富燃料层”吸收火焰传热,引起3.4 μm附近油蒸汽分子能级的改变。油池火焰不同燃烧区域发射光谱强度计算表明,火焰连续区的强度最大,其次为间歇区,火焰烟气区与空气对流强烈,测得的发射光谱强度最低。研究结果为火焰—油料传热模型的修正提供了参考。     

The burning rate’s effect on the flame length of weak fire whirls

This paper discusses why the visibly-determined flame length of a weak fire whirl increases as compared with the corresponding pool fire without spin. Here, a fire whirl is called weak when the pure aerodynamic effect of flow circulation has a negligible influence on the flame length. Split cylinders were used to apply a flow circulation to a 3-cm-diameter methane burner flame and a 3-cm-diameter ethanol pool fire. After applying the flow circulation, the flame length of the ethanol pool fire increased about three times, while little change was observed in the flame length of the methane burner flame. The difference is explained by the fact that the burning rate of the methane burner flame was fixed constant, whereas that of the ethanol pool fire increased due to the increased heat input to the fuel surface caused by a change in flame shape pushed toward the fuel surface. The experimental observations thus demonstrate that the burning-rate effect can significantly increase the flame length even under a weak circulation condition. Computational fluid dynamics (CFD) simulations were conducted to understand the detailed flow structure of a fire whirl. An analytical model was then developed based on the experimental observations and CFD calculations; the predicted relationship between the flame height and the burning rate agreed with experimental data.     

不同重力下窄通道内薄材料表面的火焰传播

在常重力下模拟微重力燃烧对载人航天器的火灾安全具有重要意义.窄通道就是这样一种可以有效限制自然对流的模拟设施.但是,不同重力下火焰传播的相似性仍然是有待研究的问题.本文用实验和数值模拟的方法,比较了不同重力下有限空间内热薄材料表面的逆风传播火焰.不同重力下火焰形状和火焰传播速度的比较表明,1cm高的水平窄通道可以有效地限制自然对流,在常重力下用这种通道能够模拟微重力下相同几何尺寸的通道中的火焰传播.因此,在地面上首先利用水平窄通道,模拟相同环境中的微重力火焰传播,然后考虑通道尺寸变化对火焰传播的影响,有可能成为地面模拟其他尺寸的空间中的微重力燃烧的方法.     

Hydrodynamic and chemical scaling for blow-off dynamics of lean premixed flames stabilized on a meso-scale bluff-body

Direct numerical simulations were conducted to investigate the effect of two parameters, density ratio and laminar flame speed, on the conditions of the onset of local extinction and blow-off of lean premixed flames, stabilized on a meso-scale bluff-body in hydrogen-air and syngas–air mixtures. A total of six simulation cases were considered as isolated comparison of the two parametric effects of the fluid dynamic instability and flame time scale. For all cases under study, the general flame development towards the blow-off limit showed a sequence of five distinct modes, with possible cyclic patterns among the different modes for a range of velocity conditions. The onset of local extinction was observed during the asymmetric vortex shedding and vortex street mode. As the density ratio is decreased, the flow inunder reviewstability is promoted through the increased sinuous mode, and such behavior was properly scaled by the Strouhal number. Although the blow-off velocity is altered by the fluid dynamic effects, the condition for the onset of local extinction and blow-off was mainly dictated by the competition between flow residence time associated with the lateral flame motion and ignition delay of the local mixtures. Time scale analysis supported the validity of the findings across all the cases investigated.     

Experimental comparison of opposed and concurrent flame spread in a forced convective microgravity environment

Flame spread experiments in both concurrent and opposed flow have been carried out in a 5.18-s drop tower with a thin cellulose fuel. Flame spread rate and flame length have been measured over a range of 0–30 cm/s forced flow (in both directions), 3.6–14.7 psia, and oxygen mole fractions 0.24–0.85 in nitrogen. Results are presented for each of the three variables independently to elucidate their individual effects, with special emphasis on pressure/oxygen combinations that result in earth-equivalent oxygen partial pressures (normoxic conditions). Correlations using all three variables combined into a single parameter to predict flame spread rate are presented. The correlations are used to demonstrate that opposed flow flames in typical spacecraft ventilation flows (5–20 cm/s) spread faster than concurrent flow flames under otherwise similar conditions (pressure, oxygen concentration) in nearly all spacecraft atmospheres. This indicates that in the event of an actual fire aboard a spacecraft, the fire is likely to grow most quickly in the opposed mode as the upstream flame spreads faster and the downstream flame is inhibited by the vitiated atmosphere produced by the upstream flame. Additionally, an interesting phenomenon was observed at intermediate values of concurrent forced flow velocity where flow/flame interactions produced a recirculation downstream of the flame, which allowed an opposed flow leading edge to form there.     

Radiative properties of extruded polystyrene foams: Predictive model and experimental results

The radiative properties of extruded polystyrene foams (XPS) were predicted using morphological data and optical properties of bulk medium. A particular attention was paid on the modelling of the radiative properties of struts, which are located at the junctions between cell walls. The radiative properties of XPS foams were determined by adding the contributions of each particle (walls and struts) using the independent scattering hypothesis. Hemispherical reflectance and transmittance measurements were made in addition to total thermal conductivity measurements. Comparisons were made between theoretical and experimental results and some improvements were suggested to better improve modelling of foam radiative properties.     

Numerical modelling of methanol liquid pool fires

The focus of this paper is on numerical modelling of methanol liquid pool fires. A mathematical model is first developed to describe the evaporation and burning of a two-dimensional or axisymmetric pool containing pure liquid methanol. Then, the complete set of unsteady, compressible Navier-Stokes equations for reactive flows are solved in the gas phase to describe the convection of the fuel gases away from the pool surface, diffusion of the gases into the surrounding air and the oxidation of the fuel into product species. Heat transfer into the liquid pool and the metal container through conduction, convection and radiation are modelled by solving a modified form of the energy equation. Clausius–Clapeyron relationships are invoked to model the evaporation rate of a two-dimensional pool of pure liquid methanol. The governing equations along with appropriate boundary and interface conditions are solved using the flux-corrected transport algorithm. Numerical results exhibit a flame structure that compares well with experimental observations. Temperature profiles and burning rates were found to compare favourably with experimental data from single- and three-compartment laboratory burners. The model predicts a puffing frequency of approximately 12 Hz for a 1 cm diameter methanol pool in the absence of any air co-flow. It is also observed that increasing the air co-flow velocity helps in stabilizing the diffusion flame, by pushing the vortical structures away from the flame region.     

Experimental research on combustion dynamics of medium-scale fire whirl

The medium-scale fire whirl was extensively investigated by experimental means, in order to establish correlations of the burning rate, flame height and flame temperature of fire whirl, and to clarify the difference between fire whirls and general pool fires. Experimental observations and data confirmed that a free burning fire whirl is a highly stable burning phenomenon with large quasi-steady periods. Burning rates of fire whirls depend on pool diameter similarly to those of general pool fires; however the transition turbulent burning occurs sooner as the pool diameter increases. The lip height seems to have little effect on the burning rate of fire whirls. The correlation was proposed to couple the height of fire whirl to the fire release rate and ambient circulation. It correlates the data from both this work and the literature. Radial temperature profiles in the continuous region of the fire whirl were confirmed to be hump-type, implying the existence of fuel-rich inner core. The pool diameter and heat release rate do not significantly affect the radial temperature profiles in non-dimensional radial coordinates. It was found that the fire plume of fire whirl involves three distinct zones just like that of pool fire, but with different normalized ranges. Fire whirls maintain a higher ratio of continuous flame height to the overall flame height, and also higher maximum centerline excess temperature in continuous flame region, as compared to general pool fires. It was further demonstrated that the fire whirl plume at its origin behaves like a turbulent jet with moderate swirling, and then tends to become buoyancy dominated downstream, with slight swirling. With an increase in dimensionless height adjusted by the plume origin, the plume centerline excess temperature decays rapidly and approaches the theoretical value of −5/3 for free buoyancy plume.     

Effects of the initial fuel temperature on burning behavior of crude oil pool fire in ice cavities

The influence of the initial fuel temperature on the burning behavior of crude oil pool fire in ice cavities was experimentally studied in this paper. The Bohai crude oil with initial fuel temperatures of 283, 293, and 303 K was burned in an initial ice cavity diameter of 6–8 cm. The mass loss rate exhibits three stages: the initial decrease stage, growth stage, and decay stage. The initial fuel temperature plays a significant role in the initial decrease stage. A heat transfer model is established to predict the mass loss rate, which agrees well with the experimental value.     

浮力扩散火焰对低频外加声场的响应特性

本文通过实验研究了浮力扩散火焰在外加声场作用下的响应行为和熄火机理.实验发现,声场中的气体燃料火焰熄火时,火焰处的声压与声频呈正相关.但该正比关系受火焰和环境等因素影响,无法精确判断熄火的临界条件.因此,本文基于火焰在声场中的偏移量脉动,为声场的临界灭火条件构造了数值判据.研究结果表明,该判据对目标火焰的依赖性较低,且...     

An experimental study on flame geometry and radiation flux of line-source fire over inclined surface

An experimental study was performed on line-source fire over an inclined surface (ground) to simulate downhill fire spread behavior. The flame geometry and the thermal radiation to both far-field surroundings and near-field inclined surface were investigated. As a basic configuration for wildland fire over a slope, the buoyancy induced natural convection flow along the inclined surface and the constraint of air entrainment by the inclined surface change the flame geometry as well as its radiation emission. Various surface (ground) inclination angles (from 0°-80°), fire source heat release rates and fuels were considered comprehensively with a total of 126 test conditions. Results showed that the flame perpendicular height decreased, while both the flame parallel length and base drag length along the inclined surface increased, with the increased inclination angle. A dimensional analysis was then performed based on the controlling mechanisms, with the dimensionless heat release rate, the density ratio of fuel vapor to air, along with sinα and cosα involved to represent the components in the parallel and perpendicular directions. The flame geometry parameters were well represented by the proposed dimensional analysis. Both the radiation fluxes to far-field surroundings and to near-field inclined surface decreased with the increased inclination angle. The far-field radiation was found to be well characterized by a model based on the soot volume fraction analysis according to single point source model. Concerning the near-field radiation to inclined surface, an inclined cuboid radiative modeling was developed. The predicting results by the proposed model and the experimental values showed good agreement. The present study has explained the controlling physics and proposed non-dimensional functions for flame geometry and modeling the downslope radiation of the line-source fire over the inclined surface, which facilitates the understanding of the wildland fire spread behavior over a slopping ground in the downhill direction.     

Opposed flow flame spread over an array of thin solid fuel sheets in a microgravity environment

In this work a numerical study has been carried out to gain physical insight into the phenomena of opposed flow flame spread over an array of thin solid fuel sheets in a microgravity environment. The two-dimensional (2D) simulations show that the flame spread rates for the multiple-fuel configuration are higher than those for the flame spreading over a single fuel sheet. This is due to reduced radiation losses from the flame and increased heat feedback to the solid fuel. The flame spread rate exhibits a non-monotonic variation with decrease in the interspace distance between the fuel sheets. Higher radiation heat feedback primarily as gas/flame radiation was found to be responsible for the increase in the flame spread rate with the reduction of the interspace distance. It was noted that as the interspace distance between the fuel sheets was reduced below a certain value, no steady solution could be obtained. However, at very small interspace distances, steady state spread rates were obtained. Here, due to oxygen starvation the flame spread rate decreased and eventually at some interspace distance the flame extinguished. With fuel emittance (equal to absorptance) reduced to ‘0’ the flame spread rate was nearly independent of the interspace distance, except at very small distances where the flame spread rate dropped due to oxygen starvation. A flame extinction plot with the extinction oxygen level was constructed for the multiple-fuel configuration at various interspace distances. The default fuel with an emittance of 0.92 was found to be more flammable in the multiple-fuel configuration than in a single fuel sheet configuration. For a fuel emittance equal to zero, the extinction oxygen limit decreases for both the single and the multiple fuel sheet configurations. However, the two flammability curves cross over at a certain fuel separation distance. The multiple-fuel configurations become less flammable compared to the single fuel sheet configuration below a certain separation distance.     

Experimental study and large eddy simulation of effect of terrain slope on marginal burning in shrub fuel beds

This paper presents a combined study of laboratory scale fire spread experiments and a three-dimensional large eddy simulation (LES) to analyze the effect of terrain slope on marginal burning behavior in live chaparral shrub fuel beds. Line fire was initiated in single species fuel beds of four common chaparral plants under various fuel bed configurations and ambient conditions. An LES approach was developed to model fire spreading through a fuel bed with a subgrid scale turbulent combustion model based on a flame surface density concept. By examining two fuel bed slope configurations, it was found that upslope fire spread depends not only on the increased radiant heat transfer but also on the aerodynamic effect created by the interaction of the flame with the inclined surface. Under certain conditions, the convective heat transfer induced by this interaction becomes the dominant mechanism in determining fire spread success. Seventy-three (or 42%) of 173 experimental fires successfully propagated for slopes ranging from −70% to 70%. It was found there exists a critical slope above which fire spread in these live fuel beds was successful, and below which fire spread was unsuccessful. This critical slope for marginal burning varied widely with fuel moisture content and fuel loading. A stepwise logistic regression model was developed from experimental data to predict the probability of successful fire spread. It is expected that this model may be helpful in providing guidelines for prescribed fire application.     

Experimental research on flame revolution and precession of fire whirls

This paper presents the first experimental effort to explore the large scale 3-D flame instabilities of fire whirls, including the inclined flame revolution during the transition from a general pool fire to fire whirl, and the swirling flame precession in a quasi-steady fire whirl. The experimental medium-scale fire whirls were produced by a fixed-frame facility. Experimental observations indicate that flame revolution is an important flame instability during the formation of fire whirl, showing that the entire flame is inclined and revolves around the geometrical axis of symmetry with increasing angular velocity until the critical point, without the self-rotation of the flame. It is found that the inlet velocity fluctuates synchronously with the flame revolution. As soon as the fire whirl forms, the erect swirling flame starts to precess around the geometrical axis of symmetry. Analysis indicates that during flame precession the periodic fluctuations of inlet velocity disappear and a local annular external recirculation zone (ERZ) is produced outside the flame (vortex core), while the flow is upward inside. It is found that the inlet velocities are nearly constant within the continuous flame in order to maintain a stable generating eddy. A good linear correlation exists between the average inlet velocities and average ambient circulations for all fuel pan sizes. The precession frequency is relatively stable during one test. The frequencies of flame revolution and precession are both proportional to the average inlet velocity, and the corresponding Strouhal numbers are constants of 0.42 and 0.80, respectively. The flame revolves and precesses in the same direction as the self-rotation of the fire whirl flame in all tests. The flame revolution is related to the periodical fluctuations of inlet flow, while the flame precession is considered to be linked to the occurrence of ERZ in fire whirls.     

Heterogeneous nucleation and growth of silver nanoparticles on unmodified polystyrene spheres by in situ reduction

The in situ reduction growth of Ag nanoparticles (NPs) on unmodified polystyrene (PS) spheres is investigated via controlling Ag nucleation and growth rates by continuous dripping addition of reductant solution in the absence of surfactants. The sub-micro PS spheres were coated by a uniform coverage of Ag NPs with several shapes like elongated islands, spherical particles, and particle aggregates. The reaction temperature and reductant concentration are demonstrated to influence the crystal structure, distribution, and stability of the Ag NPs on the PS substrates. The heterogeneous nucleation and growth of Ag NPs on PS spheres are found to depend on the inhibition of in-solution reduction and homogeneous nucleation.     

Thermal radiative properties of phenolic foam insulation

Thermal insulation has long been an important subject in engineering. Foam insulations have become the most widely used insulations due to their low cost and ease of procesing. In recent years, phenolic foams find increasing applications because of their fire retardation. This paper presents experimental results of thermal radiative properties of phenolic foams, with or without activated carbon. Transmittance spectra were first taken using FTIR for samples of various densities. Extinction coefficient spectra were then obtained by applying Beer's law. Finally, by using the diffusion approximation, the Rosseland mean extinction coefficients and radiative thermal conductivities were obtained for various temperatures. Results show that the extinction coefficient increases with sample density. The addition of activated carbon increases the extinction coefficient slightly.     

沟渠内杨木三合板架空燃烧的火灾行为的研究

建立了缩尺寸沟渠火灾试验模型,测量了沟渠以及平台入口附近的温度分布,研究了沟渠内杨木三合板架空燃烧的位置和沟渠的倾斜角度对火蔓延行为的影响,分析了火焰传播特征和火蔓延速率.试验结果表明:在沟渠效应和烟囱效应的综合作用下,火焰先从杨木三合板与沟渠底板之间的狭长空间传播到沟渠顶部,在入口处形成喷射状火焰;狭长空间内的温度先...     

Large-scale protein/antibody patterning with limiting unspecific adsorption

A simple synthetic route based on nanosphere lithography has been developed in order to design a large-scale nanoarray for specific control of protein anchoring. This technique based on two-dimensional (2D) colloidal crystals composed of polystyrene spheres allows the easy and inexpensive fabrication of large arrays (up to several centimeters) by reducing the cost. A silicon wafer coated with a thin adhesion layer of chromium (15 nm) and a layer of gold (50 nm) is used as a substrate. PS spheres are deposited on the gold surface using the floating-transferring technique. The PS spheres were then functionalized with PEG-biotin and the defects by self-assembly monolayer (SAM) PEG to prevent unspecific adsorption. Using epifluorescence microscopy, we show that after immersion of sample on target protein (avidin and anti-avidin) solution, the latter are specifically located on polystyrene spheres. Thus, these results are meaningful for exploration of devices based on a large-scale nanoarray of PS spheres and can be used for detection of target proteins or simply to pattern a surface with specific proteins.     

Propagation and extinction of an unsteady spherical spray flame front

Experimental evidence seems to indicate that the life of a laminar spherical flame front propagating through a fresh mixture of air and liquid fuel droplets can be roughly split into three stages: (1) ignition, (2) radial propagation with a smooth flame front and (3) propagation with flame front cellularization and/or pulsation. In this work, the second stage is analysed using the slowly varying flame approach, for a fuel rich flame. The droplets are presumed to vaporize in a sharp front ahead of the reaction front. Evolution equations for the flame and evaporation fronts are derived. For the former the combined effect of heat loss due to droplet vaporization and radiation plays a dominant explicit role. In addition, the structure of the evaporation front is deduced using asymptotics based on a large parameter associated with spray vaporization. Numerical calculations based on the analysis point to the way in which the spray modifies conditions for flame front extinction. Within the framework of the present simplified model the main relevant parameters turn out to be the initial liquid fuel load in the fresh mixture and/or the latent heat of vaporization of the fuel.