CEMS Investigations of Fe-Silicide Phases Formed by the Method of Concentration Controlled Phase Selection

Conversion electron Mössbauer spectroscopy (CEMS) measurements have been made on Fe-silcide samples formed using the method of concentration controlled phase selection. To prepare the samples a 10 nm layer of Fe₃₀M₇₀ (M=Cr, Ni) was evaporated onto Si(100) surfaces, followed by evaporation of a 60 nm Fe layer. Diffusion of the Fe into the Si substrate and the formation of different Fe–Si phases was achieved by subjecting the evaporated samples to a series of heating stages, which consisted of (a) a 10 min anneal at 800°C plus etch of the residual surface layer, (b) a further 3 hr anneal at 800°C, (c) a 60 mJ excimer laser anneal to an energy density of 0.8 J/cm², and (d) a final 3 hr anneal at 800°C. CEMS measurements were used to track the Fe-silicide phases formed. The CEMS spectra consisted of doublets which, based on established hyperfine parameters, could be assigned to - or -FeSi₂ or cubic FeSi. The spectra showed that -FeSi₂ had formed already at the first annealing stage. Excimer laser annealing resulted in the formation of a phase with hyperfine parameters consistent with those of -FeSi₂. A further 3 hr anneal at 800°C resulted in complete reversal to the semiconducting -FeSi₂ phase.     

Influence of Hydrothermal Temperature on Structures and Photovoltaic Properties of SnO2 Nanoparticles

Two SnO₂ nanoparticles were synthesized by hydrothermal method at 170°C and 180°C, respectively. Transmission electron microscope observations reveal that the diameters of both the nanoparticles are around 6nm. At the same time, surface photovoltage spectroscopy measurements show that the nanoparticle synthesized at 180°C has more surface electronic states at 0.3eV below the conduction band than the one synthesized at 170°C. This means that the temperatures chosen in hydrothermal synthesis have significant influence on the surface electronic characteristics of resultant SnO² nanoparticles but the effect on their sizes is not obvious. However, after being calcined at 500°C for 2h, the diameter of the nanoparticle synthesized at 180°C increased to 23nm and that of the nanoparticle synthesized at 170°C increased to 32nm as calculated from X-ray diffraction pattern.     

Electrical properties of GaAs layers irradiated by H4 ions

The quantities(D) and(T) are studied in n- and p-GaAs, irradiated at T = 300°K by H⁺ ions (5 MeV). It is shown that the resistance of lightly doped GaAs specimens increases from original values of ₀ to 10⁹ ·cm upon irradiation by H⁺ ions (5 MeV) to integral fluxes up to D^* – 10¹⁵ H⁺/cm². For D > D^* the layer resistance decreases from 10⁹ ·cm to 1 ·cm at 300°K. It was found that all the GaAs specimens intensely irradiated by H⁺ ions had p-type conductivity near 300°K. Isochronic annealing of radiation defects was studied in the temperature interval 20–700°C.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 39–43, January, 1982.     

Mössbauer Optimization of the Direct Synthesis of β-FeSi2 by Ion Beam Mixing of Fe/Si Bilayers

At present, there is an increasing interest in the iron di-silicide phase -FeSi₂, which is supposed to be a direct band gap semiconductor and one of the most promising materials for silicon-based optoelectronics, e.g., light-emitting devices, solar cells, and photo detectors. But this phase is very difficult to be produced. Here, the successful direct synthesis of this phase by ion beam mixing of Fe/Si bilayers at temperatures in the range of 400 to 600°C is reported. The aim of the experiments was to achieve a complete reaction of the deposited Fe layer with the Si substrate that results in the formation of a pure, single-phased -FeSi₂ surface layer. The obtained silicide layers, their structure and composition are investigated by conversion electron Mössbauer spectroscopy (CEMS), Rutherford backscattering spectrometry (RBS), and X-ray diffraction (XRD). The fraction of the -FeSi₂ formed is determined by CEMS as function of ion species, energy, fluence and temperature. Complete growth and formation of a single-phased -FeSi₂ layer was achieved by 205 keV Xe ion irradiation at a fluence of 2×10¹⁶ ions/cm² at 600°C.     

Wetting transition on grain boundaries in Al contacting with a Sn-rich melt

The contact angle at the intersection of a grain boundary in Al bicrystals with the solid Al/liquid Al–Sn interphase boundary has been measured for two symmetric tilt <011> {001} grain boundaries with tilt angles of 32° and 38.5°. The temperature dependencies (T) present the evidence of the grain boundary wetting phase transition at T_w. The observed hysteresis is consistent with the assumption that the wetting transition is of first order. The determined discontinuity in the temperature derivative of the grain boundary energy is–5.6 J/m²K (T w1=617°C) for the boundary with a low energy (=38.5°) and –17 J/m²K (T w2=604°C) for the grain boundary with a high energy (=32°).     

More on the τ-μ-e problem: The process e+e−→l+l− in the region of the z-resonance

Theoretical and experimental aspects of the study of the e-- problem in effects of neutral weak currents in colliding e⁺e^– beams in the region of the Z resonance are discussed. Quantities that describe the degree of violation of e-- universality are analyzed. In particular, it is shown that by measuring the spin asymmetry for angles 160° it is possible to determine the degree of violation ofl-e universality =g _A ^e g _V ^l –g _V ^e g _A ^l to an accuracy of up to 0.01.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 88-91, May, 1989.     

Spatial Spectrum of Artificial Ionospheric Irregularities Induced by Powerful HF Radiowaves

We present measurement results and spatial-spectrum shapes of the dependence of the relaxation time on the scale across the geomagnetic field for artificial ionospheric irregularities (AIIs) induced in the upper ionosphere by powerful HF radiation of the SURA heating facility. The irregularity diagnostics was based on observing amplitude scintillations of a 243-MHz beacon signal from a quasi-geostationary, solar-synchronous satellite and on measuring field-aligned scattering at frequencies 15 and 20 MHz. The satellite signal was received at the Kazan State University Observatory. The field-aligned scattering signals were received and analyzed by a bistatic HF radar based on the UTR-2 radio telescope located near Kharkov (Ukraine). It is shown that irregularities of the electron density, whose two-dimensional spectrum in the plane perpendicular to the geomagnetic field is the power law æ ^-p with index p2, are developed in the scale range 30–60 l 200–400 m. In this case, the relative fluctuations (N²)^1/2 of the electron density increase with decreasing scale l=2/æ. The estimate N²)^1/2 1–1.5% is obtained for a heating power of 150 MW and irregularity scales l 30–60 m at which the fluctuations are maximum. The measured dependence of the AII relaxation time, defined as the e-folding time of the amplitude-scintillation intensity, has the form _r l . If l 30–60 m, then the index is close to 2, whereas the effective diffusion coefficient D (2–3)· 10^-1 m²/s corresponds to the ambipolar cross-field diffusion coefficient in a magnetized plasma. The time _r for scales l 60–100 m is independent of l and increases with decreasing velocity of regular drift of the plasma. The Doppler-spectrum broadening (²)^1/2 0.6 Hz observed when receiving field-aligned scattered signals can be related to chaotic motions of plasma-density disturbances whose random drift velocities amount to (v²)^1/2 2–3 m/s for scales l 20 m at which the power-law index changes drastically.     

The lanthanideβ″ aluminas

The entire sodium ion content of sodium alumina (Na_1.67Mg_0.67Al_10.33O₁₇) can be replaced with a variety of lanthanide ions by simple diffusion reactions at moderate temperatures (500–700°C). Lanthanide alumina crystals are hard, clear, chemically stable, and have well-defined crystal structures. The fluorescence spectrum of Nd³⁺ in alumina is similar to that in YAG. The lifetime of the⁴ F _3/2 state of Nd³⁺ in completely-exchanged alumina (350s at 10²¹ Nd³⁺ cm^–3) is about 45% longer than in YAG (240s at 10²⁰Nd³⁺ cm^–3). The lanthanide aluminas may be of considerable interest as new phosphor and laser host materials.     

Infrared lattice bands of some pearls

From analysis of anisotropical lattice bands properties of 50 reflection spectra both of the CO stretching and bending bands measured from some pearl (Ca⁺⁺CO ₃ ^–– or Ca⁺⁺HCO ₃ ^–– layer) we discussed following subjects.i) Quantized properties present both in reflectivity and in energy. ii) classifications of the Optical Activity. iii) Polar distributions of the CO₃ oscillators in Ca⁺⁺CO ₃ ^–– surface mono-layer. iv) Force constants of these oscillators. v) Step variation of the dipolemoment and their influences to the degree of Optical Activity. vi) Two types of hysteresis loops of the values of Y_N (M_2Jbend ()/M_1Jstret. ()) derived from the oscillators which are at innert-state, at weak active-state and at active-state.     

Analytic study of power spectra of the tent maps near band-splitting transitions

Successive band-splitting transitions occur in the one-dimensional map x_i+1=g(x_i),i=0, 1, 2,... withg(x)=x, (0 x 1/2) –x +, (1/2 <x 1) as the parameter is changed from 2 to 1. The transition point fromN (=2ⁿ) bands to 2Nbands is given by=(2)^1/N (n=0, 1,2,...). The time-correlation function _i=x_ix₀/(x₀)²,x_i x_i–x_i is studied in terms of the eigenvalues and eigenfunctions of the Frobenius-Perron operator of the map. It is shown that, near the transition point=2, _i–[(10–42)/17] _i,0-[(102-8)/51]_i,1 + [(7 + 42)/17](–1)ⁱe^–yi, where2(–2) is the damping constant and vanishes at=2, representing the critical slowing-down. This critical phenomenon is in strong contrast to the topologically invariant quantities, such as the Lyapunov exponent, which do not exhibit any anomaly at=2. The asymptotic expression for _i has been obtained by deriving an analytic form of _i for a sequence of which accumulates to 2 from the above. Near the transition point=(2)^1/N, the damping constant of _i fori N is given by _N=2(^N-2)/N. Numerical calculation is also carried out for arbitrary a and is shown to be consistent with the analytic results.     

Theory of percolation in fluids of long molecules

We use the reference interaction site model (RISM) integral equation theory to study the percolation behavior of fluids composed of long molecules. We examine the roles of hard core size and of length-to-width ratio on the percolation threshold. The critical density _c is a nonmonotonic function of these parameters exhibiting competition of different effects. Comparisons with Monte Carlo calculations of others are reasonably good. For critical exponents, the theory yields =2=2 for molecules of any noninfinite lengthL. WhenL is very large, the theory yields _cL ^–2. These predictions compare favorably with observations of the conductivity for random assemblies of conductive fibers. The threshold region where asymptotic scaling holds requires the correlation length (/ _c ) ^–v to be much larger thanL. Evidently, the range of densities in this region diminishes asL increases, requiring that density deviations from _c be no larger thanL ^–2. Otherwise, crossover behavior will be observed.     

Spectroscopic factors of9Be,10B and13C from (d,t) reactions

The differential cross sections of tritons from the (d, t) reaction on⁹Be,¹⁰B and¹³C targets have been measured in the angular range of 5° _LAB110° with relatively small errors, 5%. The experimental data were analysed in terms of the standard DWBA using both zero-range and exact finite-range approaches.     

Manifestation of Extracoordination in the Resonance Raman Spectra of Water‐Soluble Cation Co‐Porphyrins

Resonance Raman spectra (RRS) of Co(II) and Co(III)5,10,15,20tetrakis(4Nmethylpyridinium)porphyrin ((Co^II(TmpyP4), and Co^III(TMPyP4)) in aqueous solutions at different pH as well as in organic solvents (methanol, ethanol, DMSO, DMF) are obtained. The increased sensitivity of the oscillation frequencies ₂, ₄, ₈, and ₆ — the markers of the oxidation state of a metal — to the nature of an axial ligand has been revealed. For Co^III(TmpyP4), the shifts of the indicated frequencies in extracoordination have turned out to be twofold larger than those for Co^II(TmpyP4). The spectral effects observed are related to different electron influence of the extraligands on the system of the porphyrin ring. In the case of Co(III)porphyrin, interaction of the d orbitals of the metal and the e _g ^*orbitals of the macrocycle is more efficient since its ionic radius is smaller than for the Co(II)complex. For Co^III(TmpyP4), a linear correlation between the oscillation frequencies ₂, ₄, ₈, and ₆ and the experimental Gutmann parameters characterizing the electronacceptor properties of solvents is found.     

Positron annihilation in ionic media and an optical model of the positron

It is proposed that positron motion in quasiatomic positron + anion systems formed in anionic media can be described by a potential of the form V_eff(r) = Z_eff/r²-/r, where Z_eff is the effective charge of the nucleus, and n is the effective charge of the anion. It is shown that the positron wave function of the ground state of the quasiatomic positron + anion system in the field of such a potential is _X(r) = l/4·A_nx·r^X·e^–ar. Thus the validity of selecting a test variation positron wave function (r) = l/4·A·r·e^–ar is demonstrated for the potential V_eff = at r = 0 and V_eff = –/r for r > 0 (Gol'danskii-Prokop'ev optical positron model, Fiz. Tverd. Tela,8, 515 (1966)), belonging to the class of functions _X(r). Having the wave function _X(r) and Slater wave functions _ns,p(r) of the electrons, annihilation photon angular distribution (APAD) curves are calculated, together with halfwidths of the APAD curves and positron lifetimes _ns,p.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 5, pp. 52–56, May, 1990.     

Magnetic susceptibility and electrical conductivity of the highest chromium germanide

Results are given of measurements over the temperature range 80–1000 ° K of the magnetic susceptibility () and the electrical resistivity () of the highest chromium germanide Cr₁₁Ge₁₉. A ferromagnetic spin ordering is indicated at T < 86 ° K. From the (T) dependence and the values of the resistivity, thermo-emf and Hall constant, it is concluded that the compound studied is a semimetal with p-type conductivity.     

Hall effect in heterogeneous Fe-Ni vacuum condensates

The temperature dependence of the electric conductivity and the Hall and Nernst-Ettinghausen effects of amorphous and microcrystalline Fe-Ni films obtained by ion-plasma sputtering, with a content of technological impurities of about 3 at. %, was studied for the first time. The relationship R_a(T) a²(T), was found between the anomalous Hall constant R_a and . R_a was found to be more sensitive to peculiarities of the complex transformation amorphous, microheterogeneous-crystalline state.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 9, pp. 29–33, September, 1990.     

Unified fields of analytic space-time-energy

An analytic gravitational fieldZ (Z ^y ) is shown to include electromagnetic phenomena. In an almost flat and almost static complex geometryds ² =zdzdz of four complex variables z=t, x, y, x the field equationsR Rz = –(U U – Z ) imply the conventional equations of motion and the conventional electromagnetic field equations to first order if =(Z ^v) and =(z ) are expressed in terms of the conventional mass density function , the conventional charge density function , and a pressurep as follows: v=const=p/c ²–10^–29 gm/cm³.     

Magnetic moments of proton drip-line nuclei13O and9C

The magnetic moments of the proton drip-line nuclei¹³O(I = 3/2^–,T _1/2 = 8.6 ms) and 9C(I = 3/2^–,T _1/2 = 126 ms) have been determined for the first time through the combined techniques of polarized radioactive nuclear beams and-NMR detection. The observed magnetic moments are ¦(¹³O)¦ = 1.3891 ±0.0003 _N and ¦(⁹C)¦ = 1.3914 ±0.0005 _N. Spin expectation values are deduced to be 0.76 and 1.44 for¹³O and⁹C, respectively. While the of¹³O is consistent with the systematics from isospinT= 1/2 mirror pairs, the of⁹C is unusually large, even far larger than the single particle value, = 1.     

Emissivity of CO2-H2O mixtures at temperatures up to 1000° K

The emissivity in the 2.7 m range is examined with a spectrometer having 25 cm^–1 for 2.5, ,7.5 cm·atm,4 8cm·atm, 400T1000° K; 150P730 mm Hg. It is found that relation (1) is obeyed to within /0.1, though the calculated transmission is usually less than the measured value. It is shown that the relation is obeyed on account of the mutual position of the CO₂ and H₂O lines in the band, i.e., one gas may be considered as unselective relative to the other.     

Fast Na+ ion conductivity in glass,intermediate and crystalline phases of Na4UO2(SO4)3

The ac electrical conductivity, DSC calorimetry and density data for pure Na₄UO₂(SO₄)₃ and for compound incorporating guest ions Rb⁺, Cd²⁺, Gd³⁺, SiO ₄ ^4– in the glass, quasi-crystalline intermediate and crystalline phases are reported. The glass phase conductivity data show an increase in Na⁺ conductivity by a factor 10³ relative to pure crystalline Na₂SO₄ in the low temperature (LT) region, i.e. 180°C. There is no onset of phase transition up to 260°C. The distinct conductivity regimes prior to devitrification in the glass suggest that higher energy or excited structural states/configurations can exist in the glass phase. The apparent activation energy Q _c value 76±5 kJ/mole for the glass state of all compositions is in excellent agreement with the Na₂SO₄ III Q _c value. The conductivity regime immediately after devitrification with Q _c of 40±3 kJ/mole represents the stable intermediate phase. The conductivity of the final product of devitrification on cooling resembles crystalline behavior except for (Na_3.5Rb_0.5)UO₂(SO₄)₃. A gradual jump in conductivity accompanies the transition in the crystalline sample. The Q _c value is 75±5 kJ/mole for the (HT) phase conductivity in the heating mode but remains constant at 66±5 kJ/mole for the (LT) phase in the heating mode and for both and phases in the cooling mode.The excellent conductivity-volume, i.e. /V correlation is consistent with the free volume contribution to conductivity enhancement and the percolation-type mechanism of transport.This study received partial support from the Natural Sciences and Engineering Research Council of Canada