Angle-resolved investigation of Auger electrons from Cu and Au adsorbed on W(110)

The angular distribution of Cu M_2,3VV and Au N_6,7VV Auger electrons from Cu and Au mono- and double layers on W(110) is measured with the goal of obtaining information on the contribution of the backscattered wave on the angular distribution of Auger electrons from adsorbed atoms.     

Magnetism of ultrathin Fe(110) films

Application of conversion electron Mössbauer spectroscopy (CEMS) to structural and magnetic analysis of ultrathin films and their interfaces is reviewed. Fe(110) films were prepared on W(110) under UHV conditions and analyzed in situ. CEMS provides detailed information on the mode of growth and film structure and on magnetic hyperfine fields, B _hf. Local structure of B _hf across the film is discussed in relation to modifications of magnetic order caused by the finite (including monolayer) film thickness and by the electronic structure of the interface.     

Size effects in ultrathin Mg/W(110) films: Quantum electronic states

Quantum-size effects were studied in thin Mg films of submonolayer and monolayer thicknesses during their deposition on a W(110) single-crystal surface by angle-resolved photoelectron spectroscopy using synchrotron radiation. In the Mg/W(110) system, quantum electronic states were detected located within the allowed energy bands of the Mg(0001) structure. The quantum states are shifted toward the band boundaries as the Mg layer thickness increases. The energies of the quantum electronic states are analyzed using two approaches, namely, the general phase model and an extended phase model. It is established that both the models are in satisfactory agreement with experiment. However, the extended phase model is preferable for ultrathin adsorbate layers. Original Russian Text ? N.A. Vinogradov, D.E. Marchenko, A.M. Shikin, V.K. Adamchuk, O. Rader, 2009, published in Fizika Tverdogo Tela, 2009, Vol. 51, No. 1, pp. 168–177.     

Spin polarization in low-energy electron diffraction from Au(110): Theory and experiment

A special LEED system has been constructed, in which the gun is movable in front of the grids and diffracted beams can be extracted through a probe hole in the screen. The polarization is subsequently measured by means of Mott scattering. The Au(110) surface is of particular interest, because it shows a reversible structure transition, which manifests itself in LEED intensities as a change from a (1 × 2) pattern at low temperatures to a (1 × 1) pattern at higher temperatures. For the (1 × 1) structure, spin polarization was measured, with values up to 70%, and calculated for a number of beams as a function of energy and scattering angle. Theoretical and experimental results are in reasonable agreement. In particular, the polarization is found to depend sensitively on geometrical, electronic and vibronic properties of the surface.The experimental work was sponsored by the Deutsche Forschungsgemeinschaft, Sonderforschungsbereich 128     

Periodic lattice distortions in epitaxial films of Fe(110) on W(110)

The epitaxial growth of Fe(110) on W(110) at 500 K is analyzed using LEED and AES. Frank-van der Merwe growth is established by AES. According to LEED, pseudomorphism occurs up to θ = 1.64, where every W atom of two topmost W layers is just covered by exactly one Fe atom. For 2?θ?9, characteristic reflection-multiplets are observed, symmetric about the basic Fe(110) reflections, which are interpreted in terms of periodic lattice distortions. The latter are caused by interaction with the misfitting W substrate.     

Radiation from silver films bombarded by low-energy electrons

Emission spectra from Ag films irradiated by low energy electrons (20–1500 eV) have been measured, and the results compared with theory. For relatively smooth films, two peaks in the spectra are resolved. One at 3.73 eV, the volume plasmon energy, is attributed to transition radiation and/or bremsstrahlung. The second, at about 3.60 eV, is very sensitive to surface roughness in both position and magnitude and is produced by roughness-coupled radiation from surface plasmons. For rough films, the roughness-coupled radiation dominates the emission. In addition to spectral shapes, the polarization of the radiation and its intensity as a function of electron energy were measured. The experimental results are compared with new calculations of roughness-coupled emission which account for most of our observations. They indicate that high wavevector roughness components play the dominant role in the emission process.     

The interaction of ultrathin films of Ni and Pd with W(110): an XPS study

The interaction of ultrathin films of Ni and Pd with W(110) has been examined using X-ray photoelectron spectroscopy (XPS) and the effects of annealing temperature and adsorbate coverage (film thickness) are investigated. The XPS data show that the atoms in a monolayer of Pd or Ni supported on W(110) are electronically perturbed with respect to the surface atoms of Pd(100) and Ni(100). The magnitude of the electronic perturbations is larger for Pd than for Ni adatoms. Our results indicate that the difference in Pd(3d_5/2) XPS binding energies between a pseudomorphic monolayer of Pd on W(110) and the surface atoms of Pd(100) correlates with the variations observed for the desorption temperature of CO (i.e., the strength of the Pd---CO bond) on these surfaces. A similar correlation is seen for the Ni(2p_3/2) XPS binding energies of Ni/W(110) and Ni(100) and the CO desorption temperatures from the surfaces. The shifts in XPS binding energies and CO desorption temperatures can be explained in terms of: (1) variations that occur in the Ni---Ni and Pd---Pd interactions when Ni and Pd adopt the lattice parameters of W(110) in a pseudomorphic adlayer; and (2) transfer of electron density from the metal overlayer to the W(110) substrate upon adsorption. Measurements of the Pd(3d_5/2) XP binding energy of Pd/W(110) as a function of film thickness indicate that the Pd---W interaction affects the electronic properties of several layers of Pd atoms.     

Elastic scattering of low-energy electrons by NO

We report elastic integral, momentum transfer and differential cross sections for electron scattering by N₂O for energies up to 50 eV. These results were obtained at the static-exchange approximation with the Schwinger Multichannel Method with Pseudopotentials [M.H.F. Bettega, L.G. Ferreira and M.A.P. Lima, Phys. Rev. A 47, 1111 (1993)]. In general our results show good agreement with experimental data and with other theoretical results but some discrepancies are found. We have also found a shape resonance around 4 eV in agreement with previous calculations using the R-matrix Method of Sarpal et al. [J. Phys. B 29, 857 (1996)]. On the other hand, the existence of a resonance at about 13 eV, clearly seen by the Schwinger Variational Iterative Method [Michelin et al., J. Phys. B 29, 2115 (1996)], can not be confirmed by our calculations. At this energy, our cross sections show a broad bump with no clear resonant behavior given by the eigenphase sum. Received: 13 November 1997 / Revised: 13 March 1998 / Accepted: 9 April 1998     

Transmission of low-energy (< 10 eV) O ions through Au films on TiO2(110)

In an attempt to identify the fundamental processes that influence ion transport through metallic surface layers, we have studied the transmission of O⁺ ions through discontinuous Au films adsorbed on TiO₂(110). A low energy (< 10 eV) O⁺ ion beam is generated via electron stimulated desorption when an Au-dosed TiO₂(110) substrate is bombarded with a focused 250 eV electron beam. Low energy ion scattering data indicate that Au evaporated under ultrahigh vacuum conditions at 300 K forms three-dimensional clusters on TiO₂(110). As the Au coverage increases, the formation of Au clusters on TiO₂(110) blocks a fraction of the TiO₂ surface and the O⁺ yield is attenuated. However, for high coverages (≥30% Au covered substrate) the O⁺ signal decreases at a faster rate than the TiO₂ open area fraction. We attribute the attenuation of the O⁺ yield for high Au coverages mainly to blocking of O⁺ by Au clusters, to deflection of trajectories by the image force between ions and Au clusters, and to charge transfer between desorbing O⁺ and neighboring Au clusters.     

Surface electronic structure of Gd(0001) films on W(110)

Received: 1 September 1996/Accepted: 6 January 1997     

Elastic scattering of low-energy electrons by cadmium atoms

Experimental results on the differential cross sections of 180° elastic electron scattering and the total cross section of electron scattering by cadmium atoms in the energy range 0–6 eV are reported for the first time. Distinct shape resonances with the (5s ²5p)² P ⁰ and 5s5p ² configurations are revealed in the near-threshold range and at E≈4 eV. In the range 3.0–3.7 eV, the differential cross section exhibits extra singularities that are probably related to the d-wave shape resonance. The resonance contribution to the backscattering cross section near 4 eV is found to be about 20%.