Phase transitions in a system of unstable particles

A study is reported of phase separation in a system of particles created at a constant rate and having a finite lifetime. It is shown that (1) phase separation is possible if the particle lifetime exceeds a certain critical value, (2) the particle-density difference between the phases depends on particle lifetime, and (3) the correlation function in the two-phase region oscillates (with damping) as a function of spatial coordinates, which implies correlation between the phase locations. Fiz. Tverd. Tela (St. Petersburg) 40, 741–745 (April 1998)     

Dynamics of transient metastable states in mixtures under coupled phase ordering and chemical demixing

We present theory and simulation of simultaneous chemical demixing and phase ordering in a polymer-liquid crystal mixture in conditions where isotropic-isotropic phase separation is metastable with respect to isotropic-nematic phase transition. In the case the mechanism is nucleation and growth, it is found that mesophase growth proceeds by a transient metastable phase that surround the ordered phase, and whose lifetime is a function of the ratio of diffusional to orientational mobilities. In the case of spinodal decomposition, different dynamic regimes are observed depending on the mobility ratio: metastable phase separation preceding phase ordering, phase ordering preceding phase separation, or simultaneous phase ordering and phase separation. Not only the overall dynamics but also the final structure of the material can be different for each kinetic regime.     

Condensation of electron pancakes in MOS junction

We show that a phase separation similar to the electron hole droplets condensation can exist in the 2-dimension electron gas of a MOS junction: the electrons concentrate in pancakes surrounded by “vacuum” at T = 0. These pancakes have a finite lifetime due to relaxation processes through the depletion layer. It is necessary to have a very thin oxide in order to observe the phenomenon.     

Breakdown of universality in quantum chaotic transport: the two-phase dynamical fluid model

We investigate the transport properties of open quantum chaotic systems in the semiclassical limit. We show how the transmission spectrum, the conductance fluctuations, and their correlations are influenced by the underlying chaotic classical dynamics, and result from the separation of the quantum phase space into a stochastic and a deterministic phase. Consequently, sample-to-sample conductance fluctuations lose their universality, while the persistence of a finite stochastic phase protects the universality of conductance fluctuations under variation of a quantum parameter.     

调制自由载流子吸收测量半导体载流子输运参数的三维理论

推导出用于测量半导体载流子输运特性(载流子寿命、载流子扩散系数和前表面复合速度)的调制自由载流子吸收(modulated free carrier absorption, MFCA)检测技术的三维理论模型,给出了调制自由载流子吸收检测信号与调制频率和抽运-探测光相对距离的关系.定性分析了在不同调制频率时各个载流子输运参数对径向位置扫描曲线(信号与两束光相对距离的关系)的影响,结果表明调制自由载流子吸收检测信号对各个参数的灵敏度随抽运-探测光相对距离的增加而增加.仿真和实验结果表明,通过拟合不同调制频率时调 关键词： 调制自由载流子吸收 载流子输运特性 径向位置扫描     

Nonadiabatic dynamics of the electromagnetic field and charge carriers in high-Q photonic crystal resonators

We address, both experimentally and theoretically, phase and amplitude dynamics of the electromagnetic field in a two-dimensional photonic crystal when femtosecond pulses are injected. We demonstrate that the usual adiabatic approximation underlying the dynamics of field and carriers in a semiconductor resonator is no longer valid, since in general the photon lifetime cannot be neglected with respect to the carrier recombination lifetime. Parameter regions where adiabaticity is broken are shown, and the ubiquity of the observed dynamical scenario in the new generation of active photonic microresonators is predicted.     

大孔径光电导天线产生高功率窄带宽THz辐射特性分析

从大孔径光电导天线产生THz辐射的饱和理论出发,考虑了载流子的瞬变迁移率.分析了脉冲序列激发大孔径光电导天线产生高功率窄带宽THz辐射的特性.对比了单个光脉冲和序列光脉冲激发SI-GaAs和LT-GaAs光电导天线的饱和特性.分析表明,采用序列光脉冲激发载流子寿命小于光脉冲间隔的光电导天线时,可以克服大孔径光电导天线的饱和特性,产生高峰值功率的窄带THz辐射.     

DNA bubble dynamics as a quantum Coulomb problem

We study the dynamics of denaturation bubbles in double-stranded DNA. Demonstrating that the associated Fokker-Planck equation is equivalent to a Coulomb problem, we derive expressions for the bubble survival distribution W(t). Below Tm, W(t) is associated with the continuum of scattering states of the repulsive Coulomb potential. At Tm, the Coulomb potential vanishes and W(t) assumes a power-law tail with nontrivial dynamic exponents: the critical exponent of the entropy loss factor may cause a finite mean lifetime. Above Tm (attractive potential), the long-time dynamics is controlled by the lowest bound state. Correlations and finite size effects are discussed.     

Influence of hydrodynamic interactions on lane formation in oppositely charged driven colloids

The influence of hydrodynamic interactions on lane formation of oppositely charged driven colloidal suspensions is investigated using Brownian dynamics computer simulations performed on the Rotne-Prager level of the mobility tensor. Two cases are considered, namely sedimentation and electrophoresis. In the latter case the Oseen contribution to the mobility tensor is screened due to the opposite motion of counterions. The simulation results are compared to that resulting from simple Brownian dynamics where hydrodynamic interactions are neglected. For sedimentation, we find that hydrodynamic interactions strongly disfavor laning. In the steady state of lanes, a macroscopic phase separation of lanes is observed. This is in marked contrast to the simple Brownian case where a finite size of lanes was obtained in the steady state. For strong Coulomb interactions between the colloidal particles a lateral square lattice of oppositely driven lanes is stable similar to the simple Brownian dynamics. In an electric field, on the other hand, the behavior is found in qualitative and quantitative accordance with the case of neglected hydrodynamics.     

Analysis of free carrier absorption measurement of electronic transport properties of silicon wafers

Sensitivity analysis of electronic transport property measurement of silicon wafers with modulated free carrier absorption (MFCA) technique and multi-parameter fitting procedure is performed. The sensitivity of the multi-parameter estimate employing the dependences of the MFCA amplitude and phase on the pump-probe-beam separation measured at several modulation frequencies covering an appropriate range is theoretically compared with that employing only the dependences of the MFCA amplitude and phase on the modulation frequency. Simulation results show that the dependences of the MFCA amplitude and phase on the pump-probe beam separation are more sensitive to the electronic transport properties of silicon wafers than the frequency dependences. The electronic transport properties of the silicon wafers determined with the two-beam separation dependence are therefore more accurate than that determined with the frequency dependence. Comparative experiments with a silicon wafer are performed and the carrier lifetime, the carrier diffusivity, and the front surface recombination velocity are determined simultaneously and unambiguously with both techniques.     

相分离液体在玻璃转变过程中的动力学性质(英文)

近年来,相分离动力学一直受到大家的关注,人们从技术和理论角度进行了研究.一个二元系统从混溶温度开始进行快速冷却,这个过程驱使两个相的形成和生长.这种自发生长过程遵从幂规律R(t)∝t~n,R(t)是在t时刻的相分离域尺寸大小,增长指数n是一个重要的量,有效的反映了相分离域的增长机制.但是对于相分离液体的玻璃转变过程的研究相对较少.本文采用分子动力学(MD)模拟方法,提出了一个新的模型——相分离液体来研究玻璃转变过程.相分离在玻璃转变过程中,过冷液体分离为两个相.我们主要研究了体系的动力学不均匀性.发现两个相的动力学性质是不均匀的,两个相的玻璃转变温度是不一样的.分析得出,相分离液体在玻璃转变过程中存在着一个动力学奇异点.说明相分离可能是引起玻璃转变系统动力学奇异性的一个原因.     

A Videographic Study of Dynamic Phase Separation for Immiscible Solutions under Acoustic Levitation Condition

The transparent aqueous solutions of succinonitrile(SCN) provide an effective model system to simulate the phase separation process of various advanced materials.Here we report a real-time and in-situ study of phase separation dynamics for the SCN-15%H_2O,SCN-48%H_2O and SCN-70%H_2O solutions implemented by high-speed CCD videography together with acoustic levitation technique.It is found that liquid phase separation induces an unsteady state of drop rotation under levitated conditions.The resultant centrifugal force plays the dominant role in the migration of secondary liquid globules.The most desirable homogeneously dispersive structures can only be derived from the earlier stage of phase separation,whereas three kinds of macrosegregation are always the finally stable structure patterns.The migration velocity of minor liquid phase displays the nonlinear feature owing to the variations of globule location and centrifugal force.The surface tensions and volume fractions of immiscible phases also show a conspicuous influence upon the evolution dynamics of separation morphology.     

Strong phase separation in a model of sedimenting lattices

We study the steady state resulting from instabilities in crystals driven through a dissipative medium, for instance, a colloidal crystal which is steadily sedimenting through a viscous fluid. The problem involves two coupled fields, the density and the tilt; the latter describes the orientation of the mass tensor with respect to the driving field. We map the problem to a one-dimensional lattice model with two coupled species of spins evolving through conserved dynamics. In the steady state of this model each of the two species shows macroscopic phase separation. This phase separation is robust and survives at all temperatures or noise levels- hence the term strong phase separation. This sort of phase separation can be understood in terms of barriers to remixing which grow with system size and result in a logarithmically slow approach to the steady state. In a particular symmetric limit, it is shown that the condition of detailed balance holds with a Hamiltonian which has infinite-ranged interactions, even though the initial model has only local dynamics. The long-ranged character of the interactions is responsible for phase separation, and for the fact that it persists at all temperatures. Possible experimental tests of the phenomenon are discussed.     

Transients in semiconductor diodes at high injection levels

A theoretical calculation is presented of the duration of the first phase of the switching process from forward to reverse direction for a diode with a finite base, allowing for the finite surface-recombination velocity at the back contact at high injection levels. Formulas are obtained suitable for practical calculation of minority-carrier lifetime and surface recombination rate for junction diodes.     

Raman scattering by wavevector dependent coupled plasmon - LO phonons of n - GaAs

We show that Raman scattering by coupled plasmon-LO phonons of n-GaAs can be used to study the wavevector- and frequency-dependent dielectric function of the charge carriers. It is found that Landau-damping is induced by finite temperatures and carrier lifetime effects. When Landau-damping effects are negligible the results are well described, to the lowest order in wavevector, by the random phase approximation.     

Spinodal decomposition of polymer solutions: molecular dynamics simulations of the two-dimensional case

As a generic model system for phase separation in polymer solutions, a coarse-grained model for hexadecane/carbon dioxide mixtures has been studied in two-dimensional geometry. Both the phase diagram in equilibrium (obtained from a finite size scaling analysis of Monte Carlo data) and the kinetics of state changes caused by pressure jumps (studied by large scale molecular dynamics simulations) are presented. The results are compared to previous work where the same model was studied in three-dimensional geometry and under confinement in slit geometry. For deep quenches the characteristic length scale ?(t) of the formed domains grows with time t according to a power law close to [Formula: see text]. Since in this problem both the polymer density ρ(p) and the solvent density ρ(s) matter, the time evolution of the density distribution P(L)(ρ(p),ρ(s),t) in L × L subboxes of the system is also analyzed. It is found that in the first stage of phase separation the system separates locally into low density carbon dioxide regions that contain no polymers and regions of high density polymer melt that are supersaturated with this solvent. The further coarsening proceeds via the growth of domains of rather irregular shapes. A brief comparison of our findings with results of other models is given.     

Study of the surface and far fields of terahertz radiation generated by large-aperture photoconductive antennas

We have studied analytically the temporal characteristics of terahertz radiation emitted from a biased largeaperture photoconductive antenna triggered by an ultrashort optical pulse. We have included the effects of the finite lifetime and transient mobility dynamics of photogenerated carriers in the analysis. Succinct explicit expressions are obtained for the emitted radiation in the surface field and in the far field. The dependence of the waveforms of the radiated field on the fluence and duration of triggering optical pulse, carrier relaxation time and carrier lifetime are discussed in detail using the obtained expressions.     

Spin dynamics of Rashba-Dresselhaus two-dimensional electron systems with electron-electron interactions

Spin dynamics of Rashba-Dresselhaus two-dimensional electron systems is studied by taking account of electron-electron interactions under the D’yakonov-Perel’ mechanism. The diffusion equations for charge and spin densities are obtained through decoupling of the interactions using the auxiliary Bose field. We show that the electron-electron interaction has no effect on the infinite spin lifetime when the Rashba and Dresselhaus coupling constants satisfy the condition α = ±β. If the general condition α≠±β is satisfied, the spin lifetime is finite and enhanced by the electron-electron interaction with the increment of the temperature in the ballistic regime. The increasing amplitude of the spin lifetime depends on the ratio of the temperature to the Fermi temperature.     

Coarsening and self-organization in dilute diblock copolymer melts and mixtures

This paper explores the evolution of a sharp interface model for phase separation of copolymers in the limit of low volume fraction. Particles both exchange material as in usual Ostwald ripening, and migrate because of an effectively repulsive nonlocal energetic term. Coarsening via mass diffusion only occurs while particle radii are small, and they eventually approach a finite equilibrium size. Migration, on the other hand, is responsible for producing self-organized patterns.We construct approximations based upon an ansatz of spherical particles similar to the classical LSW theory to derive finite dimensional dynamics for particle positions and radii. For large systems, kinetic-type equations which describe the evolution of a probability density are constructed. For systems larger than the screening length, we obtain an analog of the homogenization result of Niethammer & Otto [B. Niethammer, F. Otto, Ostwald ripening: The screening length revisited, Calc. Var. Partial Differential Equations 13-1 (2001) 33-68]. A separation of timescales between particle growth and migration allows for a variational characterization of spatially inhomogeneous quasi-equilibrium states.     

高压作用下相分离液体玻璃转变的分子动力学研究

采用分子动力学模拟方法,研究了二元混合液体在不同外压作用下的相分离与玻璃转变过程,计算了相分离液体在玻璃转变过程中的结构和动力学特征.研究发现,外压会促进相分离的产生,并提高玻璃转变温度,会使β弛豫出现的温度更高、存在的时间更长,导致系统扩散性降低.同时还发现,相分离液体的玻璃转变过程存在微观不均匀现象. 关键词： 相分离 玻璃转变 分子动力学模拟 外压影响