动载荷下金属板表面的微物质喷射

 用石英晶体传感器技术，测量了冲击波作用下铝合金（Ly-12）和纯铅样品自由表面的微物质喷射量。在冲击压力为32 GPa时，测得光洁度为3.2、0.4、0.1 μm的铝合金的微物质喷射量分别为1.53～3.28 g/m²，0.2～0.3 g/m²和0.053～0.096 g/m²，对光洁度为3.2 μm的纯铅样品，在压力为13 GPa和47 GPa时，微物质喷射量分别微26.4～42.4 g/m²和183～328 g/m²。在最高冲击压力约为20 GPa时，做了多次冲击下的微物质喷射量测量，发现比单次冲击加载下的喷射量有很大的减少。结果表明，微物质喷射量与自由表面的加工条件、局部熔化和加载方式等因素有关。     

THE HIGH-PRESSURE CRYSTALLIZATION AND ANNEALING BEHAVIORS OF POLYETHYLENE TEREPHTHALATE OLIGOMER

Polyethylene terephthalate (PET) oligomer samples crystallized and annealed at high pressure were investigated with differential scanning calorimetry (DSC) and scanning electron microscopy (SEM). The results showed that better crystals were obtained through high-pressure crystallization from the melt than annealing under the same conditions. The difference of the effects of crystallization and annealing on the morphology of crystals reduced with the increase of crystallization time. The melting temperature was determined by the lamellar thickness when it was shorter than the length of the molecular chains, while the main factor governing the melting temperature changed from lamellar thickness to density of chain-end defects when the lamellar thickness was much longer than the molecular length. PET oligomer extended-chain crystals with thickness up 100 μm were obtained.     

Detonation in an aluminum-Teflon mixture

Detonation in an aluminum-fluoroplastic-4 (Teflon) mixture is studied experimentally. To increase reactivity, the initial mixture is pretreated in a mechanochemical activator. As a result, a mechanically activated composite is obtained in the form of thin aluminum layers in a Teflon matrix. The action of a shock wave on a composite sample initiates the steady detonation regime, in which the initial and final substances are in the condensed state. Depending on the percentage composition and density of the mixture, the detonation velocity varies from 700 to 1300 m/s for the speed of sound below 100 m/s in the initial composition. The steady detonation velocity changes insignificantly when sample pores are filled with helium instead of air. The results prove that it is possible in principle to reach the steady detonation regime in reactive condensed mixtures forming final reaction products in the solid state.     

碳纤维-泡沫铝夹芯板低速冲击响应

为研究夹芯结构的低速冲击响应,以碳纤维(T700)/环氧树脂复合材料层合板为上下面板,以闭孔泡沫铝为芯层,模拟夹芯板落锤冲击时的损伤演化过程。复合材料层合板采用三维实体单元建模,基于有限元软件ABAQUS中的用户子程序VUMAT,引入三维Hashin失效准则模拟复合材料的损伤破坏;采用二次应力准则,Cohesive单元模拟黏结层的层间失效;闭孔泡沫铝芯层采用3D Voronoi细观模型建模。分析复合材料夹芯结构在落锤冲击下的损伤起始、损伤扩展和最终破坏模式,通过锤头的接触力、位移、夹芯板的内能、后面板的最大位移研究夹层结构的能量吸收情况及抗冲击特性,得出了在质量保持不变的情况下,5种芯层相对密度和厚度的耦合关系中的最优设计是芯层相对密度15.0%,厚度为10 mm,为满足实际工程中的需求提供了设计依据。     

Deflagration-to-detonation transition in mixtures of finely divided ammonium perchlorate with submicron aluminum powder

Deflagration-to-detonation transition in binary mixtures of fine ammonium perchlorate (20-μm grains) with submicron ALEX-L aluminum powder (0.2-μm particles) is studied using high-speed photography and pressure recording with quartz crystal sensors. The test mixtures were loaded in thin-walled quartz tubes of inner diameter 10 mm. The charges had a porosity of ~50%. It has been shown that, even under very mild conditions (low-strength shell and a weak source of initiation), the deflagration mode of mixture combustion easily transforms into the detonation mode. The shortest length of the region of transition from deflagration to normal detonation (not more than 30 mm) was observed for a lean mixture, with an aluminum content of ~5%. The mechanism of transition to detonation involves the stage of convective combustion, resulting in the formation of a brightly luminescent crescent-shaped area behind the primary flame front, which, in turn, generates a forward (in the direction of propagation) and a backward wave. The forward wave gives rise to low-speed detonation, which later transforms into normal detonation. The pressure profile within the region of low speed detonation is measured. A comparison with similar experiments in which ALEX-L alu- minum powder was replaced by ASD-4 aluminum (4 μm particles) shows that ALEX-L sensitizes the mixture, resulting in a dramatic reduction of the length of the transition region, making it possible to produce normal detonation in low-strength shells.     

Effect of the initial temperature on the threshold of laser initiation of pentaerythritol tetranitrate seeded with aluminum nanoparticles

The effect of temperature on the threshold of explosive decomposition of pentaerythritol tetranitrate samples with a density of ρ = 1.73 g/cm³ containing 0.1 wt % 100- to 120-nm aluminum particles under the action of laser pulses (λ = 1.06 μm, τ = 20 ns) is examined. A model capable of describing the experimental results is proposed, according to which the explosive decomposition of the samples is associated with the absorption of laser radiation by structural defects of pentaerythritol tetranitrate and aluminum nanoparticles. It is demonstrated that, at 300 K, explosion initiation is largely determined by the heating of aluminum nanoparticles with the formation of chemical decomposition kernels nearby.     

脉冲激光作用下铝靶的层裂

 本文报导波长为1.06 μm脉宽（FWHM）约4 ns的强脉冲激光辐照下，铝靶发生层裂的实验结果。当入射功率密度在2.0×10¹¹~5×10¹¹ W/cm²范围的激光束作用下，厚度为0.1 mm、0.2 mm的靶在超临界条件下发生层裂，层裂厚度分别在(17±6) μm及(35±5) μm范围。文中使用一种简化模型对阈值条件下不同厚度的靶发生层裂时的层裂片厚度作了近似估算，并与已有的实验结果较好地符合。     

Microstructure of contact layers formed by the contact melting of copper and aluminum

The contact melting of copper and aluminum is performed in the nonsteady-state diffusion mode at a temperature of 570°C. Fragments of a spherical phase, presumably CuAl₂, 10–15 μm in size and a lamellar phase 70–200 μm in length and 10 μm in width are found on the cleaved facets of the contact layer formed.     

Blast waves in a cylindrical channel generated by the nonideal detonation of aluminum-Teflon-RDX high-density formulations

The pressure at the front and the pressure impulse of blast waves generated in a cylindrical tube by the expanding products of the nonideal detonation of low-porosity charges prepared by pressing of fine-grained powders of aluminum, Teflon, and RDX were measured. The measured parameters are compared to the same parameters of blast waves produced by the detonation of TNT charges of identical mass. The relative quantities were used to evaluate the effectiveness of blast waves with respect to those generated by TNT. Mixed compositions differing in the shape (brand) of the aluminum powder particles and the ratio between the components at 30% RDX are studied. It is shown that, for the investigated compositions, the pressure at the leading front of the wave exceeds the pressure achieved during TNT explosion on average by 10–30%, almost independently of the distance traveled along the tube in the range from 0.8 to 3.8 m. The dependence of the wave amplitude on the particle shape and aluminum content was weak. In the same range of distances, the relative pulse pressure increases strongly, from 0.5 to 2.1 and higher, mainly due to an increase in the width of the wave. This result is of interest from the point of view of achieving a high pressure impulse of the blast wave in an area remote from the charge. The obtained data suggest that RDX mainly reacts in the detonation wave, with the chemical transformation of Teflon and aluminum in the detonation wave and near-to-charge zone occurring, if at all, to a small extent. On the contrary, as the blast wave front moves through the channel, the burning of aluminum in the fluoride formed during the decomposition of Teflon provides an appreciable support to the blast wave, causing a significant increase in the pressure impulse.     

Mechanisms of fracture of the free surface of shock-compressed metals

The mechanisms of the ejection of aluminum and copper microparticles from the free surfaces of these metals have been studied under conditions of the escape of a moderate-intensity shock wave from a sample. The free surfaces of samples contained 0.7–0.9 mm deep artificial wells and protrusions simulating (on a greater scale of 10: 1) the natural surface roughness retained upon mechanical processing. The pressure in a shock-wave pulse at the base of a protrusion was controlled within P = 5–20 GPa (i.e., below the melting region), and the variable duration of pressure pulses was 0.02, 0.2, and 1 μs. Analysis of the free surfaces of postloaded samples showed that, for certain loading and roughness parameters, the ejection of metal from vertices of protruding ridges or pyramids (as a result of the longitudinal fracture) was about ten times greater than the amount of metal ejected in the form of cumulative jets from wells. The amount of ejected metal and the size distribution of metal microparticles were quantitatively characterized using “soft collecting targets” and by measuring mass losses of samples upon fracture.     

用金刚石车削技术制备EOS实验用铝薄膜和铜薄膜

 具有材料理论密度的金属薄膜对于材料高压状态方程(EOS)研究而言具有重要的意义。本文提出采用金刚石车削技术,利用超精密金刚石车床、金刚石圆弧刀具及真空吸附夹持技术,对纯铝和无氧铜进行端面车削,完成了EOS实验用铝薄膜和铜薄膜的车削加工,实现了薄膜密度接近材料理论密度。精加工工艺参数为：进给量0.001 mm/r,主轴转速3000 r/min,切削深度1 μm。采用Form Talysurf series 2型触针式轮廓仪进行测量,结果表明：铝薄膜、铜薄膜厚度可以达到小于10 μm水平,表面均方根粗糙度小于5 nm,原始最大轮廓峰-谷高度小于50 nm,厚度一致性好于99%。     

高压下尼龙1010-单壁碳纳米管复合材料的结晶行为

 采用XKY-6×1200MN型六面顶压机,在不同温度、压力条件下处理30 min后制备了尼龙1010(PA1010)-单壁碳纳米管（SWCNT）复合材料的高压结晶样品,通过X射线衍射（XRD）、差热分析仪（DSC）、扫描电子显微镜（SEM）、透射电子显微镜（TEM）,研究了高压处理样品的结晶行为、结构变化及形貌特征。结果表明：在1.0~2.5 GPa压力下,属于高压熔体结晶;在3.0和4.5 GPa压力下属于高压退火处理;高压结晶或高压退火均有助于聚合物片层晶体的增厚,并且高压熔体结晶的增厚效果优于高压退火处理。XRD结果表明,PA1010的三斜晶型在高压处理后保持不变,高压熔体结晶或高压退火都可以使(100)晶面和(010)晶面间距减小,即高压处理致使聚合物分子链紧密堆积。DSC结果表明：在高压熔体结晶过程中,升高压力和温度可以得到片层厚度较大的PA1010晶体;在2.0 GPa、350 ℃下获得的高压结晶样品的熔点和结晶度最高,分别达到208.5 ℃和64.6%。SEM和TEM结果表明：与常压结晶样品相比,高压结晶样品内部出现c轴厚度超过150 μm的大尺寸晶体;SWCNT与PA1010基体之间形成相互穿插的网络结构,刚性的SWCNT作为高压成核剂促进PA1010晶体生长和增厚。     

Effect of static pressure on acoustic energy radiated by cavitation bubbles in viscous liquids under ultrasound

The effect of static pressure on acoustic emissions including shock-wave emissions from cavitation bubbles in viscous liquids under ultrasound has been studied by numerical simulations in order to investigate the effect of static pressure on dispersion of nano-particles in liquids by ultrasound. The results of the numerical simulations for bubbles of 5 μm in equilibrium radius at 20 kHz have indicated that the optimal static pressure which maximizes the energy of acoustic waves radiated by a bubble per acoustic cycle increases as the acoustic pressure amplitude increases or the viscosity of the solution decreases. It qualitatively agrees with the experimental results by Sauter et al. [Ultrason. Sonochem. 15, 517 (2008)]. In liquids with relatively high viscosity (～200 mPa s), a bubble collapses more violently than in pure water when the acoustic pressure amplitude is relatively large (～20 bar). In a mixture of bubbles of different equilibrium radius (3 and 5 μm), the acoustic energy radiated by a 5 μm bubble is much larger than that by a 3 μm bubble due to the interaction with bubbles of different equilibrium radius. The acoustic energy radiated by a 5 μm bubble is substantially increased by the interaction with 3 μm bubbles.     

0.35 μm激光驱动冲击波的实验测量

 采用波长为0.35 μm的高功率激光脉冲聚焦辐照楔形铝靶,用光学条纹相机观测靶背面冲击波加热发光的特性。并对冲击波压力的定标关系和楔形样品冲击波速度的计算方法进行了介绍,对实验结果进行了简要的分析。结果表明：实验测量的冲击压力与定标公式的结果较为接近。     

强激光加载下锡材料微喷颗粒与气体混合回收实验研究及颗粒度分析

冲击波在金属材料自由面卸载时,材料表面会形成微颗粒向外喷射,这是材料表面一种特殊的破坏形态.在内爆压缩和高压工程领域的相关物理过程中,微喷射颗粒是引起界面混合现象的重要来源,会直接影响后期的混合状态和压缩过程.而微颗粒的尺寸、形态、运动速度等是开展微喷混合过程理论和数值模拟研究的重要参数.由于实验中动态诊断的难度较大,目前已获取的微喷颗粒尺寸及分布数据十分有限.基于神光Ⅲ原型激光装置,本文设计并开展了强激光驱动冲击加载,锡材料微喷颗粒经过气体区混合后,低密度泡沫材料对微颗粒进行回收分析的实验研究.通过对微喷颗粒回收样品的X光电子计算机断层扫描分析和图像重建,获得了两个典型加载压强条件下与气体混合后微喷颗粒的三维图像,通过与真空实验条件下回收微喷颗粒图像的对比分析,对混合后的微喷颗粒分布形态有了初步的认识;测量统计了回收颗粒尺寸与数目,并通过分析,给出了微喷颗粒尺寸的双指数分布规律.     

Crevice corrosion of copper alloys by optical interferometry

In the present investigation, an optical corrosion-meter has been developed for testing of materials and evaluation of different corrosion phenomena. The idea of the optical corrosion-meter was established based on principles of 3D-holographic interferometry for measuring microsurface dissolution, i.e. mass loss, and on those of electrochemistry for measuring the bulk electronic current, i.e. corrosion current of metallic samples in aqueous solutions. In the present work, an early stage of crevice corrosion of an aluminium brass and a pure copper sample in seawater and tap water, respectively, was monitored in situ by the optical corrosion-meter during the cyclic polarization test. The observations of crevice corrosion were basically interferometric perturbations detected on the surface of both alloys underneath a crevice assembly, made of a Teflon bolt, a Teflon nut, and a Teflon washer. The crevice assembly was used on all tested samples to create a differential aeration cell between the surface of the sample and areas underneath the crevice assembly in seawater. Each Teflon washer contained radial grooves and had 20 plateaus which formed crevices (shield areas) when pressed against the surface of the sample. The interferometric perturbations were interpreted as a localized corrosion in the form of an early crevice corrosion of depth ranging between 0.3 μm and several micrometers. Consequently, results of the present work indicate that holographic interferometry is a very usefull technique as a 3D-interferometric microscope for monitoring crevice corrosion at the initiation stage of the phenomenon for different metallic samples in aqueous solutions.     

High-Velocity Interaction of Teflon-Containing Impactors with Targets Made of Titanium and Aluminum Alloys

The results of an experimental and theoretical study of the high-velocity (600–1000 m/s) interaction of impactors filled with Teflon with semiinfinite and finite-thickness titanium and aluminum targets are presented. The effects of the physicomechanical and physicochemical properties of the filler on the parameters of the caverns produced in targets of various thicknesses made of the indicated materials are assessed.     

Influence of particle size on the breaking of aluminum particle shells

Rupturing the alumina shell (shell-breaking) is a prerequisite for releasing energy from aluminum powder. Thermal stress overload in a high-temperature environment is an important factor in the rupture of the alumina shell. COMSOL Multiphysics was used to simulate and analyze the shell-breaking response of micron-scale aluminum particles with different particle sizes at 650 ℃ in vacuum. The simulation results show that the thermal stability time and shell-breaking response time of 10 μm-100 μm aluminum particles are 0.15 μs-11.44 μs and 0.08 μs-3.94 μs, respectively. They also reveal the direct causes of shell breaking for aluminum particles with different particle sizes. When the particle size is less than 80 μm, the shell-breaking response is a direct result of compressive stress overload. When the particle size is between 80 μm and 100 μm, the shell-breaking response is a direct result of tensile stress overload. This article provides useful guidance for research into the energy release of aluminum powder.     

Flame propagation of nano/micron-sized aluminum particles and ice (ALICE) mixtures

Flame propagation of aluminum–ice (ALICE) mixtures is studied theoretically and experimentally. Both a mono distribution of nano aluminum particles and a bimodal distribution of nano- and micron-sized aluminum particles are considered over a pressure range of 1–10 MPa. A multi-zone theoretical framework is established to predict the burning rate and temperature distribution by solving the energy equation in each zone and matching the temperature and heat flux at the interfacial boundaries. The burning rates are measured experimentally by burning aluminum–ice strands in a constant-volume vessel. For stoichiometric ALICE mixtures with 80 nm particles, the burning rate shows a pressure dependence of r_b = aPⁿ, with an exponent of 0.33. If a portion of 80 nm particles is replaced with 5 and 20 μm particles, the burning rate is not significantly affected for a loading density up to 15–25% and decreases significantly beyond this value. The flame thickness of a bimodal-particle mixture is greater than its counterpart of a mono-dispersed particle mixture. The theoretical and experimental results support the hypothesis that the combustion of aluminum–ice mixtures is controlled by diffusion processes across the oxide layers of particles.     

Targets for studying the dynamic and radiative properties of material with laser facilities

The technology of target preparation for direct and indirect laser irradiation is developed to study the shock compressibility of materials on the Sokol-2 and Iskra-5 laser facilities. Copper and aluminum films with a density close to that of the bulk materials are prepared by ion-beam deposition. The difference in the densities of the film and bulk materials is 0.8–1.7%, and the accuracy of density measurement is 0.4–1.5%. Processes for the preparation of porous materials (aluminum, copper, nickel, gold, etc.) are also devised. Porous cop-per samples of thickness 10–50 μm, pore size 0.1–5.0 μm, mean density 0.065–0.4 g/cm³, and porosity 20–140 are obtained. The preparation of freely suspended film targets 0.1–0.2 μm thick that are irradiated by picosecondlaser shots on the Progress-P and élas-PS facilities is described.