Interconnected polyaniline nanofibers with diameters in the range of 30–60 nm and lengths up to several micrometers have been synthesized by chemical oxidative polymerization of aniline in catanionic solution by mixing cetyltrimethylammonium bromide and sodium dodecylbenzenesulfonate. The product was characterized by field‐emission scanning electron microscopy, transmission electron microscopy, UV‐vis spectroscopy, and Fourier transform infrared spectroscopy. The effects of the molar fraction of cetyltrimethylammonium bromide on the morphologies of polyaniline have been investigated. 相似文献
We prepared PANI/tetradecanol/MWNTs composites via in-situ polymerization. DSC results indicated that the composites are good
form-stable phase change materials (PCMs) with large phase change enthalpy of 115 J g−1. The MWNTs were randomly dispersed in the composites and significantly enhanced the thermal conductivity of the PCMs from
0.33 to 0.43 W m−1 K−1. The form-stable PCMs won’t liquefy even it is heated at 80°C, so that the MWNTs were fixed in the composite and the phase
separation of the MWNTs from PANI/tetradecanol/MWNTs composites won’t occur. 相似文献
Summary: This work evaluated the influence of the synthesis temperature on the polyaniline (PANI) properties obtained by in-situ polymerization onto a poly (terephthalate) (PET) substrate. The residual mass of these syntheses was dried under vacuum, obtaining PANI powders for each temperature investigated. PANI/PET thin films and PANI powders were characterized by atomic force microscopy (AFM), field emission scanning electron microscopy (FEG-SEM), X-ray diffraction (XRD), ultraviolet-visible spectroscopy (UV-Vis) and four-point probe techniques. The UV-Vis results showed that the synthesized PANI presents the emeraldine oxidation state. By means of XRD technique, it was possible to verify that the PANI powders present crystalline form. The AFM and FEG-SEM techniques showed that the decrease in PANI/PET and PANI powders electrical conductivity with increasing of the synthesis temperature is related to the polymeric aggregates morphology. 相似文献
We present the first fast and facile microwave assisted synthesis of polyaniline (PANI) nanofibers (“MWA synthesis”). Under conventional synthesis (CS), the polymer was produced with 79.7% yield after 5 h at ambient temperature. However, under microwave irradiation, the nanofibers were produced with yield of 76.2% after only 5 min, i.e., with 78.8% after 20 min at ambient temperature. The FTIR and Raman spectra show the PANI structure in all samples either synthesized conventionally or in the microwave. SEM and TEM confirm the nanofibrillar morphology.
In a 0.010 m HCl solution, we successfully transformed irregular polyaniline (PANI) agglomerates into uniform PANI nanofibers with a diameter of 46–145 nm and a characteristic length on the order of several microns by the addition of superparamagnetic Fe3O4 microspheres in a magnetic field. The PANI morphological evolution showed that the PANI nanofibers stemmed from the PANI coating shell synthesized on the surface of the Fe3O4 microsphere chains. It was found that the magnetic field could optimize the PANI nanofibers with a narrow diameter size distribution, and effectively suppressed secondary growth. When compared with other microspheres (like silica and polystyrene), only the use of superparamagnetic Fe3O4 microspheres resulted in the appearance of PANI nanofibers. Attempts to form these high‐quality PANI nanofibers in other concentrations of HCl solution were unsuccessful. This deficiency was largely attributed to the inappropriate quantity of aniline cations. 相似文献
Electrospun polyaniline nanofibers are one of the most promising materials for cardiac tissue engineering due to their tunable electroactive properties. Moreover, the biocompatibility of polyaniline nanofibes can be improved by grafting of adhesive peptides during the synthesis. In this paper, we describe the biocompatible properties and cardiomyocytes proliferation on polyaniline electrospun nanofibers modified by hyperbranched poly-L-lysine dendrimers (HPLys). The microstructure characterization of the HPLys/polyaniline nanofibers was carried out by scanning electron microscopy (SEM). It was observed that the application of electrical current stimulates the differentiation of cardiac cells cultured on the nanofiber scaffolds. Both electroactivity and biocompatibility of the HPLys based nanofibers suggest the use this material for culture of cardiac cells and opens the possibility of using this material as a biocompatible electroactive 3-D matrix in cardiac tissue engineering. 相似文献
Summary: Polyaniline (PANI)/Au composite nanotubes and nanofibers are synthesized through a self‐assembly process in the presence of camphorsulfonic acid and hydrochloric acid, as dopants, respectively. The PANI/Au composites are characterized by FT‐IR, UV‐vis, and thermogravimetric analysis to verify the incorporation of the Au nanoparticles and determine the Au content. Structural characterization is performed using SEM, TEM and X‐ray diffraction. The presence of the Au nanoparticles results in an increased conductivity and improved crystallinity of the PANI. The self‐assembly method employed here is a simple and inexpensive route to synthesize multifunctional nanotubes and nanofibers and could be extended to prepare other inorganic nanoparticle/PANI composites.
In this work, we demonstrate for the first time a template free approach to synthesize aligned polyaniline nanofiber (PN) array on a passivated gold (Au) substrate via a facile wet chemical process. The Au surface was first modified using 4‐aminothiophenol (4‐ATP) to afford the surface functionality, followed subsequently by an oxidation polymerization of aniline (AN) monomer in an aqueous medium using ammonium persulfate as the oxidant and tartaric acid as the doping agent. The results show that a vertically aligned PANI nanofiber array with individual fiber diameters of ca. 100 nm, heights of ca. 600 nm and a packing density of ca. 40 pieces·µm−2, was synthesized.
下载免费PDF全文