Spectrum and structure of the He2 molecule: Characterization of the singlet and triplet states associated with the UAO's 4s, 4dσ, 4dπ, and 4dδ

The emission spectrum of the He₂ molecule has been rephotographed in the ～4000–～5700 Å region and the $\text{4d(}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{,}{}^3\text{Π}{}_{\mathrm{u}}\text{,}{}^3\text{Δ}{}_{\mathrm{u}}\text{) → 2pπ}{}^3\text{Π}{}_{\mathrm{g}}$, $\text{4d(}{}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{,}{}^1\text{Π}{}_{\mathrm{u}}\text{,}{}^1\text{Δ}{}_{\mathrm{u}}\text{) → 2pπ}{}^1\text{Π}{}_{\mathrm{g}}$, $\text{4s}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{→ 2pπ}{}^3\text{Π}{}_{\mathrm{g}}$ and $\text{4s}{}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{→ 2pπ}{}^1\text{Π}{}_{\mathrm{g}}$ transitions analyzed. The 4dδj³Δ_u, 4dπj³Π_u, $\text{4dσj}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ and $\text{4sh}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ states have been characterized through v = 2 and the 4dδJ¹Δ_u, 4dπJ¹Π_u, $\text{4dσJ}{}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$, and $\text{4sH}{}^1\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ states for v = 0. The term levels for these perturbed and l-uncoupled states have been confirmed (a) by analyses of bands with common levels from Δv = 0, ±1 sequences and (b) by analyses of the transitions between the above states from 4d and 4s and the $\text{c}{}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ and $\text{C}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ states associated with 3pσ. Molecular constants are reported which have been partially corrected for the effects of l-uncoupling and the homogeneous perturbations between the state pairs J, H and j, h.     

Predissociation and Λ-doubling in the even-parity Rydberg states of the nitrogen molecule

Predissociations in the y¹Π_g and $\text{x}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ Rydberg states of N₂ (configurations $\text{1π}{}_{\mathrm{u}}{}^{\mathrm{?1}}\text{4pσ}$ and $\text{1π}{}_{\mathrm{u}}{}^{\mathrm{?1}}\text{3pπ}$, respectively) and their likely causes, are discussed. Peaking of rotational intensity at unusually low J values, without sharp breaking off, is interpreted as due to case c^? or case cⁱ predissociation. Λ doubling in the y state, attributed to interactions with the $\text{x}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ state and with another, ¹Σ⁺, state of the same electron configuration as x, is analyzed. From this analysis the location of the (unobserved) ${}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ state, here labeled x′, is obtained. It is concluded that the predissociation in the Π⁺ levels of the y state is an indirect one mediated by the interaction with x′ coupled with predissociation of x′ by a ${}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ state dissociating to ${}^4\text{S +}{}^2\text{P}$ atoms: combined, however, with perturbation of the y state by the k¹Π_g Rydberg state (configuration $\text{3σ}{}_{\mathrm{g}}{}^{\mathrm{?1}}\text{4dπ}$), whose Π⁺ levels are completely predissociated.     

3Σu−-3Σu+ coupling in the O2B3Σu− predissociation

The role of $\text{B}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}\text{-2}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ spin-orbit mixing in the O₂ Schumann-Runge predissociation is investigated. The $\text{2}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ state is found to cross the $\text{B}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}$ state near 2.0 Å with an interaction matrix element of approximately 55 cm^?1. This state contributes to the widths of the Bv ≥ 6 levels, but introduces only small level shift perturbations. When the partial widths due to the ${}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}\text{-}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ interaction are added to the previously calculated widths due to the ⁵Π_u, ³Π_u, and ¹Π_u states, reasonable agreement is obtained with experimental measurements on O¹⁶O¹⁶ and O¹⁸O¹⁸. The possibility of non-Lorentzian line profiles and the dependence of the width on rotational quantum number is investigated. The approximation of the spin-orbit matrix element by its value at the crossing point is shown to be a good approximation for calculating the second difference perturbations.     

A multipole analysis of pion photoproduction in the first resonance region

An energy-independent multipole analysis of pion photoproduction in the first resonance region has been performed in which special care has been taken in the selection and normalization of the data. The results obtained are a significant improvement on those of earlier analyses. Three features are of particular interest: a zero in the $\text{E}{}_{\mathrm{1+}}{}^{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ multipole at resonance; a smooth $\text{M}{}_{\mathrm{1?}}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ multipole showing the onset of the P₁₁(1470) resonance; and evidence for the position of the Δ⁺ resonance being different from those of the Δ⁺⁺ and Δ^o resonances. A comparison is made with the recent energy-dependent analyses, indicating agreement in the gross features of the multipoles but showing significant differences in essential details.     

Thermochemistry of azide salts and the azide ion using direct minimisation equations to obtain the lattice energy of the univalent azide salts

The opportunity to test a new equation for the computation of the lattice energy and at the same time examine a disparity in the literature data for the enthalpy of formation of the azide ion, $\text{ΔH}{}^{\mathrm{\theta }}{}_{\mathrm{?}}\text{(}\text{N}{}_3{}^{\mathrm{?}}\text{) (}\text{g}\text{)}$ was the motivation for this study. The results confirm our earlier calculation and show the new equation to be reliable. Thermodynamic data produced in the study take values: $\text{ΔH}{}^{\mathrm{\theta }}{}_{\mathrm{?}}\text{(}\text{N}{}_3{}^{\mathrm{?}}\text{)(}\text{g}\text{) = 144}\text{kJ mor}{}^{\mathrm{?1}}$ΔH^θ_hyd(N₃^?) = ?315 KJ mol^?1 or ΔH^θ_hyd(N₃^?) = ?295 KJ mol^?1U_POT(NaN₃) = 732 kJ mol^?1U_POT(KN₃) = 659 kJ mol^?1U_POT(RbN₃) = 637 kJ mol^?1U_POT(CsN₃) = 612 kJ mol^?1U_POT(TIN₃) = 689 kJ mol^?1. The lattice energies of azides whose enthalpies of formation are documented have been calculated as well as the enthalpy of formation of the azide radical.     

Double resonance production and the equal-phase hypothesis

If all the helicity amplitudes for the reaction

$\text{0}{}^{\mathrm{?}}\text{+}\text{1}\text{2}{}^{\mathrm{+}}\text{→ J}{}_1\text{+ J}{}_2\text{, J}{}_2\text{?}\text{3}\text{2}$

have the same phase, it follows that certain bilinear forms in the statistical tensors t_L1L2^M₁M₂, with L₁ and L₂ even, vanish. An intuitive discussion is given of how these tests of the equal-phase hypothesis arise, their relation to positivity constraints on the joint-density-matrix is studied, and their behavior in the limit of forward production is examined. In order to illustrate the sensitivity of these tests, calculations of helicity amplitudes and the corresponding bilinear forms were made, using reggeized absorption-model calculations for πp → ?Δ. Some of the available data on πp → ?Δ, πp → ωΔ and $\text{K}{}^{\mathrm{+}}\text{p}\text{→}\text{K}{}^1\text{Δ}$ are studied using our tests. Some recent high statistics data on ?Δ indicate that the equal-phase hypothesis is incorrect for this reaction.A by-product of the investigation is the interesting result that if all the helicity amplitudes are in phase, and the absence of a polarized target, one arbitrarily chosen helicity amplitude can be taken to be zero at an arbitrary value of the kinematic variables, without affecting any observable results.     

Self-adjointness of the minimal Schrödinger operator with potential belonging to L1, loc

Let $\text{0 ?q(x) ∈L}{}_{\mathrm{1,loc}}\text{(}\text{R}{}^{\mathrm{m}}\text{)}$,m? 1.Consider the operatorT₀ = ?Δ+q with domain consisting of all bounded measurable functions $\text{u(x), x ∈}\text{R}{}^{\mathrm{m}}$, having bounded support, for which the distribution ?Δu+qu belongs to $\text{L}{}_2\text{(}\text{R}{}^{\mathrm{m}}\text{)}$. The main result of the paper is essential self-adjointness of $\text{T}{}_0\text{in L}{}_2\text{(}\text{R}{}^{\mathrm{m}}\text{)}$. The proof is independent of a method due to Kato who recently established the self-adjointness of a maximal Schrödinger operator corresponding to such potential.     

The spectrum of HeNe+

Discharges through mixtures of helium and neon show two band groups near 4250 and 4100 Å as first observed by Druyvesteyn. These bands, assigned to the HeNe⁺ ion by Tanaka, Yoshino, and Freeman, have been studied under high resolution and have been fairly completely analyzed. The upper state of the transition is a very weakly bound state resulting from $\text{He}{}^{\mathrm{+}}\text{(}{}^2\text{S) +}\text{Ne}\text{(}{}^1\text{S}{}_0\text{)}$. There are two lower states resulting from the two components of $\text{Ne}{}^{\mathrm{+}}\text{(}{}^2\text{P) +}\text{He}\text{(}{}^1\text{S}{}_0\text{)}$. The upper of these two (${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$) is also very weakly bound while the lower of the two, the ²Σ⁺ ground state, has a dissociation energy of 0.69 eV and an r_e value of 1.30 Å. All bands in both band groups show four branches designated R_ff, Q_ef, Q_fe, and P_ee. From their analysis the rotational constants in the various vibrational levels of the three electronic states have been determined. While no spin splitting in the B²Σ⁺ state has been found the ground state X²Σ shows a very large spin splitting and the $\text{A}{}_2{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ state a very large $\text{Ω-type}$ doubling. The vibrational numberings in all these states were established by the study of the spectrum of ³HeNe⁺. At the same time the hyperfine structure observed in all lines of ³HeNe⁺ confirmed the nature of the upper state B²Σ⁺ as resulting from He⁺ + Ne, i.e., by charge exchange from the ground state. The ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ component of the ²Π state has not been observed, presumably because of low intensity.     

Laser-excited phosphorescence spectrum of C3S2 in an Ar matrix

The phosphorescence spectrum of C₃S₂ was observed in a low-temperature Ar matrix with excitation of an Ar⁺ laser. The spectrum consists of a very strong 0-0 band at 18 287 cm^?1 and well-resolved progressions in the ν₂, ν₅, ν₆, and ν₇ vibrations. Side bands were found on the high-energy sides of some transitions. The separation between the main and side bands is 23 cm^?1. Polarization analysis suggests that C₃S₂ is linear symmetric in the Phosphorescent state as in the ground electronic state. On the basis of symmetry considerations and a qualitative evaluation of spin-orbit coupling, the phosphorescent state is assigned to ³Σ_u^? with Σ_u⁺ and Π_u components split by spin-spin interaction. The Σ_u⁺ level is lower than the Π_u one by 23 cm^?1 and the main and side band emissions start from the Σ_u⁺ and Π_u levels, respectively. The Σ_u⁺ component seems to acquire allowed character from a ¹Σ_u⁺ state by spin-orbit coupling and from bent ${}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}\text{(}{}^1\text{B}{}_2\text{)}$ and ${}^1\text{Δ}{}_{\mathrm{g}}\text{(}{}^1\text{A}{}_1\text{+}{}^1\text{B}{}_2\text{)}$ states by ν₅ vibronic coupling. Mixing of the Σ_u⁺ and Π_u components through ν₅ is responsible for most of the side bands. The ν₅ frequency is estimated to be 160 ± 20 cm^?1 in the ³Σ_u^? state from the intensities of ν₅ progression bands and from the ground-state frequency, 411 cm^?1.     

Observed and calculated interactions between valence states of the NO molecule

No perturbation between two valence states of NO has ever been identified, although many valence-Rydberg and several Rydberg-Rydberg perturbations have been extensively studied. The first valence-valence crossing to be experimentally documented for NO is reported here and occurs between the ¹⁵N¹⁸O B²Π (v = 18) and B′²Δ (v = 1) levels. No level shifts larger than the detection limit of 0.1 cm^?1 are observed at the crossings near $\text{J = 6.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_2\text{)]}$ and $\text{J = 12.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_1\text{)]}$; two crossings involving higher rotational levels could not be examined. Semi-empirical calculations of spin-orbit and Coriolis perturbation matrix elements indicate that although the electronic part of the $\text{B}{}^2\text{Π}\text{～ B′}{}^2\text{Δ}$ interaction is large, a small vibrational factor renders the ¹⁵N¹⁸O B (v = 18) ? B′ (v = 1) perturbation unobservable. Semi-empirical estimates are given for all perturbation matrix elements of the operators $\text{Σ}{}_{\mathrm{i}}\text{a}\text{?}{}_{\mathrm{i}}\text{l}{}_{\mathrm{i}}\text{·s}{}_{\mathrm{i}}$ and $\text{B(L}{}_{\mathrm{\pm }}\text{S}{}_{\mathrm{?}}\text{? J}{}_{\mathrm{\pm }}\text{L}{}_{\mathrm{?}}\text{)}$ which connect states belonging to the configurations $\text{(σ2p)}{}^2\text{(π2p)}{}^4\text{(π}{}^1\text{2p)}$, $\text{(σ2p)(π2p)}{}^4\text{(π}{}^1\text{2p)}{}^2$, and $\text{(σ2p)}{}^2\text{(π2p)}{}^3\text{(π}{}^1\text{2p)}{}^2$.     

The reactions K−p → K1− + nucleon at 3.13 and 3.3 GeV/c

Results are presented of a 12 event/μb bubble-chamber experiment; the reactions discussed in detail are $\text{K}{}^{\mathrm{?}}\text{p}\text{→}\text{K}{}^1\text{(890)}{}^{\mathrm{?}}\text{p, K}{}^1\text{(1420)}{}^{\mathrm{?}}\text{p and K}{}^1\text{(890)}{}^{\mathrm{?}}\text{Δ}{}^{\mathrm{+}}$.The K¹ (890)^?p channel is dominated by the forward peak. The suggestion of flattering at cos θ = 1 is more pronounced in $\text{(?}{}_{11}\text{+ ?}{}_{\mathrm{1?1}}\text{)}\text{d}\text{σ}\text{d}\text{t}$; which is mainly natural-parity exchange. Pseudoscalar exchange contributes to $\text{?}{}_{00}{}^{\mathrm{J}}\text{d}\text{σ}\text{d}\text{t}$; this is more sharply peaked in t. The value of $\text{(?}{}_{11}\text{? ?}{}_{\mathrm{1?1}}\text{)}\text{d}\text{σ}\text{d}\text{t}$ is somewhat larger than the upper limit from the dominant natural-parity exchange. There is significant structure in $\text{?}{}_{00}{}^{\mathrm{H}}\text{d}\text{σ}\text{d}\text{t}\text{at}\text{t ≈ ?0.6 (}\text{GeV}\text{/c)}{}^2$.The K¹ (1420)^?p channel is much more pronounced at 3.3 GeV/c than at 3.13 GeV/c, but is not markedly peripheral. The width of the K¹ (1420) in the 3.3 GeV/c data is 42 ± 12 MeV/c².The cross section for $\text{K}{}^{\mathrm{1?}}\text{Δ}{}^{\mathrm{+}}$ agrees with that expected from $\text{K}{}^{\mathrm{+}}\text{p}\text{→}\text{K}{}^1\text{Δ}$, assuming a single t-channel exchange. Our measured density matrix elements are consistent with a strong pseudoscalar exchange.     

Light-cone expansions,the parton model and virtual γγ scattering

It is shown that it is sufficient to use the light-cone algebra of currents and the algebra of bilocal operators to find the asymptotic behaviour of the γγ scattering amplitude when one (or two) of the photon masses q_1,2² is large, and for an arbitrary value of the energy squared s = (q₁+q₂)². A general form of this asymptotic behaviour is obtained. The box-diagram is dominant over the wide region in $\text{s(μ}{}^2\text{« s « q}{}_1{}^2\text{q}{}_2{}^2\text{/μ}{}^2\text{,μ ～ 1}\text{GeV}\text{)}$ and so the asymptotic amplitude is known completely. It is shown that the parton model of the type of ref.[8] gives the same predictions for the asymptotic behaviour of the γγ amplitude.     

Electromagnetic mass differences of the old and the charmed mesons

We predict for M_?⁺?M_?⁰ the values -3.4 ± 0.8 MeV using the ?-ω mixing and the quark model, respectively. The extracted parameters indicate the necessity of a relativistic treatment of the old mesons. The problem of extrapolating these parameters to the charmed mesons is discussed. Under conservative assumptions, we predict 1.7 ? M_D⁰ ? 2.2 MeV and .     

The emission spectra of H35Cl+, H37Cl+, D35Cl+, and D37Cl+ in the region 2700–4100 Å

The $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}\text{-X}{}^2\text{Π}$ emission spectrum of HCl⁺ has been measured and analyzed for four isotopic combinations. These analyses extend previous work and provide rotational constants for the v = 0–2 levels of the ground state and for the v = 0–9 levels of the excited state. RKR potentials have been determined for both states, although the upper state could not be fitted precisely to such a model. Calculated relative intensities based on these potentials demonstrated that the electronic transition moment must change rapidly with lower state vibrational quantum number. Although considerable caution should be exercised in applying the concept of equilibrium constants to the $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}$ state, the following are the best estimates of these constants (in cm^?1) for the $\text{X}{}^2\text{Π}$ state of H³⁵Cl⁺: B_e = 9.9406, ω_e = 2673.7, A_e = ? 643.7, and $\text{r}{}_{\mathrm{e}}\text{= 1.315}\text{A}\text{?}$. For the $\text{A}{}^2\text{Σ}{}^{\mathrm{+}}$ state of H³⁵Cl: T_e = 28 628.08, B_e ～ 7.505, ω_e ～ 1606.5, and $\text{r}{}_{\mathrm{e}}\text{= 1.514}\text{A}\text{?}$.     

Evidence for double dissociation in K-p interactions at 14.3 GeV/c

We have studied the reaction K^-p → K^-π⁺π^-π⁺π^-p at 14.3 GeV/c to search for evidence of the double dissociation process $\text{K}{}^{\mathrm{-}}\text{p}\text{→}\text{QN}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}{}^1$. In the channel $\text{K}{}^{\mathrm{-}}\text{p}\text{→}\text{K}{}^{10}\text{(890)}$π₁^-π₂^-Δ⁺⁺ (1236) there is evidence for simultaneous production of low-mass enhancements in the $\text{K}{}^{10}\text{π}{}_1{}^{\mathrm{-}}$ and Δ⁺⁺(1236)π₂^- subsystems which correspond to the $\text{Q}\text{→}\text{K}{}^1\text{(890)π}$ and $\text{N}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}{}^1\text{→ Δπ}$ decay modes. In this particular final state the double fragmentation system is produced with a cross section of the order of a few microbarns. Our data are consistent with the factorizable pomeron exchange model of double diffractive dissociation.     

QED distributions for hard photon emission in e+e− → μ+μ−γ

The hard photon emission in e⁺e^? → μ⁺μ^?γ is investigated to order α³. Formulas for a number of distributions are obtained, when neglecting terms of order (m_e/?)² and (m_μ/?)². Both charge-even and charge-odd contributions are calculated. The total contribution to the charge asymmetry parameter

$\text{? =}\text{[}\text{d}\text{σ(θ)}\text{d}\text{O}{}_{\mathrm{\mu }}{}^{\mathrm{+}}\text{?}\text{d}\text{Oσ(π?θ)}\text{d}\text{O}{}_{\mathrm{\mu }}{}^{\mathrm{+}}\text{]}\text{[}\text{d}\text{σ(θ)}\text{d}\text{O}{}_{\mathrm{\mu }}{}^{\mathrm{+}}\text{+}\text{d}\text{σ(π ? σ)}\text{d}\text{O}{}_{\mathrm{\mu }}{}^{\mathrm{+}}\text{]}$

does not exceed 5% for the c.m.s. energy 2? = 3 GeV.     

The laser magnetic resonance spectrum of the NCO radical at 5.2 μm

Lines in the ν₃ (“antisymmetric” stretch) fundamental of the NCO radical in the $\text{X}\text{?}{}^2\text{Π}$ state were studied by CO laser magnetic resonance. The observations were assigned to P and R lines in the vibration-rotation band and lead to a precise determination of the vibrational interval and the anharmonic correction to the rotational constant: ν₃ = 1920.60645(19) cm^?1, α₃ = 0.003338(21) cm^?1. A single transition in the hot band (011)-(010), ${}^2\text{Δ}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{-}{}^2\text{Δ}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ was detected. This observation is used to determine the origin of the hot band as 1907.11892(20) cm^?1, i.e., the anharmonicity parameter x₂₃ = ?13.48753(28) cm^?1.     

Polarization spectroscopy of the E0g+-B0u+ band system of Br2

The E-B (0_g⁺-0_u⁺) band system of Br₂ has been investigated at Doppler-limited resolution using polarization labeling spectroscopy. Merged E state data for the three naturally occurring isotopes in the range v_E = 0–16, expressed in terms of the constants for ⁷⁹Br₂, are (in cm^?1) Y_0,0 = 49 777.962(54), Y_1,0 = 150.834(22), Y_2,0 = ?0.4182(28), Y_3,0 = 6.6(11) × 10^?4, Y_0,1 = 4.1876(28) × 10^?2, Y_1,1 = ?1.607(16) × 10^?4, and Y_0,2 = 1.39(39) × 10^?8. The bond distance is $\text{r}{}_{\mathrm{<mtext>e</mtext>}}\text{= 3.194}\text{A}\text{?}$, and the diabatic dissociation energy to $\text{Br}{}^{\mathrm{+}}\text{(}{}^3\text{P}{}_2\text{) +}\text{Br}{}^{\mathrm{?}}\text{(}{}^1\text{S}{}_0\text{)}\text{is 34 700 cm}{}^{\mathrm{?1}}$.     

The infrared part of the C2 Phillips system (2.3–0.9 μm)

Line positions and molecular constants for the 0-0, 1-0, 2-0, 0-1, 2-1, 3-1, 0-2, 1-2, and 4-2 bands of the C₂ Phillips system ($\text{A}{}^1\text{Π}{}_{\mathrm{u}}\text{-X}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$) are reported. Among them, five bands have not been reported previously. Rotational perturbations have been observed in the previously unobserved v = 1 level of the $\text{A}{}^1\text{Π}{}_{\mathrm{u}}$ state. This state is perturbed by the $\text{c}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ state which was discovered by Ballik and Ramsay. These observations provide new information regarding the perturbing state. In particular, the minimum of the potential energy for the $\text{c}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ state has been found to be at 9227.4 cm^?1 instead of 13 310 cm^?1, which was the previous T_e value for this electronic state.