Chemiluminescence of Si + N2O flames

Spectra of the chemiluminescent flame produced by the reaction of silicon vapor with N₂O have shown strong emission from the A¹Π-X¹Σ⁺, b³Π-X¹Σ⁺, and a³Σ⁺-X¹Σ⁺ systems of SiO with preferential excitation into the b³Π state. Bandhead measurements of 33 bands of the b-X system yielded the following constants for the b³Π state:

$T_e=33947.0\pm 1.9c{m}^{?1};{\omega }_e=1013.8\pm 1.1c{m}^{?1};{\omega }_e{x}_e=7.57\pm 0.12c{m}^{?1}$

. From partially resolved rotational structure in the a-X bands, an approximate value of B = 0.59 ± 0.01cm^?1 was obtained for the a³Σ⁺ state. The effect of adding active nitrogen and CO to the flame was investigated and the results were shown to be consistent with assigning the a and b states as triplets. The photon yield of the Si + N₂O reaction was measured and found to be small.     

Triangle for the entropic index q of non-extensive statistical mechanics observed by Voyager 1 in the distant heliosphere

Tsallis [Physica A 340 (2004) 1) identified a set of numbers, the “q-triplet” ≡ {q_stat, q_sen, q_rel}, for a system described by non-extensive statistical mechanics. The deviation of the q's from unity is a measure of the departure from thermodynamic equilibrium. We present observations of the q-triplets derived from two sets of daily averages of the magnetic field strength B observed by Voyager 1 in the solar wind near 40 A.U. during 1989 and near 85 A.U. during 2002, respectively. The results for 1989 do not differ significantly from those for 2002. We find $q_{\mathrm{stat}}=1.75\pm 0.06$, $q_{\mathrm{sen}}=-0.6\pm 0.2$, and $q_{\mathrm{rel}}=3.8\pm 0.3$.     

Thermoelectric and topological properties of half-Heusler compounds ZrIrX(As,Sb, Bi)

The strain dependent electronic structures, thermoelectric and topological properties of the half-Heusler compounds ZrIrX(X=As, Sb, Bi) are investigated by the first-principle calculations. At the equilibrium lattice constants, all the three compounds are trivial insulators and good thermoelectric materials with the Seebeck coefficient S and the power factor over relaxation time $S^2\sigma /\tau$ as large as 1180 (μV/K) and 4.1 (${10}^{11}W{m}^{?1}{K}^{?2}{s}^{?1}$), respectively. The compressive strain enhances the band gap, while the tensile strain decreases the band gap. At some specific tensile strains, the compounds become Dirac-semimetals, with the s-type band ${\mathrm{\Gamma }}_6$ below p-type band ${\mathrm{\Gamma }}_8$, in the cubic phase. When we compress the a(b)-axis and elongate the c-axis of the compounds, they become the type-I Weyl semimetals. For ZrIrAs, the eight Weyl-Points (WPS) locate at (± K_x, 0, ± K_z), (0, ± K_y, ± K_z), ${\mathrm{K}}_x={\mathrm{K}}_y=0.008{\mathrm{\AA }}^{?1}$, ${\mathrm{K}}_z=0.043{\mathrm{\AA }}^{?1}$.     

p(x) and Tc(x) characteristics in the Y 1−b(Ca)bBa2Cu3O6+x cuprate family

A model has been proposed to calculate the $p\left(x\right)$ and $T_c\left(x\right)$ dependences in the Y _1?b(Ca)_bBa₂Cu₃O_6+x high-$T_c$ cuprate family and applied to $b=0$, $b=0.1$, and $b=0.2$ cases, for which experimental data exist in the literature. The results obtained imply that the Ca efficiency to provide holes is independent of the basal plane oxygen concentration, which is consistent with a view that electrons from CuO₂ layers would go primarily to Ca since it is twice closer than oxygen (in addition, the chain oxygen is screened by a layer made up of Ba and O(4) ions). It is shown that, in fully oxygenized compounds ($x=1$) the average efficiency, $\chi$, of a chain oxygen to attract an electron from the two nearby layers is reduced by the Ca insertion, though not because the charge transfer mechanism is in itself weakened by Ca, but because a part of electrons that are otherwise available in CuO${}_2$ layers has already been removed by the substitution of Y ³⁺ with Ca²⁺. It has been found that the $b$-dependence of the average oxygen doping efficiency can be fairly accurately described by the following relation: $\chi \left(b\right)=0.39\times (1?0.78b)$. The calculated $p\left(x\right)$ and $T_c\left(x\right)$ dependences are in very good agreement with the available experimental data.     

On the non-integrability of a generalized Darboux Halphen system

In this paper we study a generalized Darboux Halphen system given by ${\dot{x}}_1=x_2{x}_3-x_1(x_2+x_3)+{\tau }^2({\alpha }_1,{\alpha }_2,{\alpha }_3,x_1,x_2,x_3)\text{,}$${\dot{x}}_2=x_3{x}_1-x_2(x_3+x_1)+{\tau }^2({\alpha }_1,{\alpha }_2,{\alpha }_3,x_1,x_2,x_3)\text{,}$${\dot{x}}_3=x_1{x}_2-x_3(x_1+x_2)+{\tau }^2({\alpha }_1,{\alpha }_2,{\alpha }_3,x_1,x_2,x_3)\text{,}$ where $x_1$, $x_2$, $x_3$ are real variables, ${\alpha }_1,{\alpha }_2,{\alpha }_3$ are real constants and ${\tau }^2({\alpha }_1,{\alpha }_2,{\alpha }_3,x_1,x_2,x_3)={\alpha }_1^2(x_1-x_2)(x_3-x_1)+{\alpha }_2^2(x_2-x_3)(x_1-x_2)+{\alpha }_3^2(x_3-x_1)(x_2-x_3)\text{.}$ We prove that, for any $({\alpha }_1,{\alpha }_2,{\alpha }_3)\in {\mathbb{R}}^3\setminus \left\{(0,0,0)\right\}$, this system does not admit any non-constant global first integral that can be described by a formal power series. Furthermore, restricting the values of $({\alpha }_1,{\alpha }_2,{\alpha }_3)$ to a full Lebesgue measure set, we prove that this system does not admit any non-constant rational or Darbouxian global first integral. This is a first step toward proving that this system is chaotic.     

Numerically anticanonical divisors on Kato surfaces

The compact curves of an intermediate Kato surface $S$ form a basis of $H^2(S,\mathbb{Q})$. We present a way to compute the associated rational coefficients of the first Chern class $c_1\left(S\right)$. We get in particular a simple geometric obstruction for $c_1\left(S\right)$ to be an integral class, or equivalently index $\left(S\right)=1$. In the final part we discuss relations with some recent work of Dloussky (2011) and Oeljeklaus and Toma (2009).     

Disorder dependence electron phonon scattering rate of V82Pd18 − xFex alloys at low temperature

We have systematically investigated the disorder dependence electron phonon scattering rate in three dimensional disordered V₈₂Pd_18 ? xFe_x alloys. A minimum in temperature dependence resistivity curve has been observed at low temperature $T=T_{\mathrm{m}}$. In the temperature range $5\text{ K}\le T\le T_{\mathrm{m}}$ the resistivity correction follows ${{\rho }_{\mathrm{o}}}^{5/2}{T}^{1/2}$ law. The dephasing scattering time has been calculated from analysis of magnetoresistivity by weak localization theory. The electron dephasing time is dominated by electron–phonon scattering and follows anomalous temperature (T) and disorder $({\rho }_0)$ dependence behaviour like ${\tau }_{\mathrm{e}\text{-}\mathrm{ph}}^{?1}\propto T^2/{\rho }_0$, where ${\rho }_0$ is the impurity resistivity. The magnitude of the saturated dephasing scattering time $({\tau }_0)$ at zero temperature decreases with increasing disorder of the samples. Such anomalous behaviour of dephasing scattering rate is still unresolved.     

A fresh look into m¯c,b(m¯c,b) and precise fD(s),B(s) from heavy–light QCD spectral sum rules

Using recent values of the QCD (non-)perturbative parameters given in Table 1 and an estimate of the N3LO QCD perturbative contributions based on the geometric growth of the PT series, we re-use QCD spectral sum rules (QSSR) known to N2LO PT series and including all dimension-six NP condensate contributions in the full QCD theory, for improving the existing estimates of ${\overline{m}}_{c,b}$ and $f_{D_{(s)},B_{(s)}}$ from the open charm and beauty systems. We especially study the effects of the subtraction point on “different QSSR data” and use (for the first time) the Renormalization Group Invariant (RGI) scale-independent quark masses in the analysis. The estimates [rigourous model-independent upper bounds within the SVZ framework] reported in Table 8: $f_D/f_{\pi }=1.56(5)$ $[?1.68(1)]$, $f_B/f_{\pi }=1.58(5)$ $[?1.80(3)]$ and $f_{D_s}/f_K=1.58(4)$ $[?1.63(1)]$, $f_{B_s}/f_K=1.50(3)$ $[?1.61(3.5)]$, which improve previous QSSR estimates, are in perfect agreement (in values and precisions) with some of the experimental data on $f_{D,D_s}$ and on recent lattice simulations within dynamical quarks. These remarkable agreements confirm both the success of the QSSR semi-approximate approach based on the OPE in terms of the quark and gluon condensates and of the Minimal Duality Ansatz (MDA) for parametrizing the hadronic spectral function which we have tested from the complete data of the $J/\psi$ and ? systems. The values of the running quark masses ${\overline{m}}_c(m_c)=1286(66)\text{MeV}$ and ${\overline{m}}_b(m_b)=4236(69)\text{MeV}$ from $M_{D,B}$ are in good agreement though less accurate than the ones from recent $J/\psi$ and ? sum rules.