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1.
Ming Zhu Guanyao Wang Xing Liu Bingkun Guo Gang Xu Zhongyi Huang Minghong Wu Hua‐Kun Liu Shi‐Xue Dou Chao Wu 《Angewandte Chemie (International ed. in English)》2020,59(16):6596-6600
Sodium metal is an ideal anode material for metal rechargeable batteries, owing to its high theoretical capacity (1166 mAh g?1), low cost, and earth‐abundance. However, the dendritic growth upon Na plating, stemming from unstable solid electrolyte interphase (SEI) film, is a major and most notable problem. Here, a sodium benzenedithiolate (PhS2Na2)‐rich protection layer is synthesized in situ on sodium by a facile method that effectively prevents dendrite growth in the carbonate electrolyte, leading to stabilized sodium metal electrodeposition for 400 cycles (800 h) of repeated plating/stripping at a current density of 1 mA cm?2. The organic salt, PhS2Na2, is found to be a critical component in the protection layer. This finding opens up a new and promising avenue, based on organic sodium slats, to stabilize sodium metals with a protection layer. 相似文献
2.
Dr. Yuxi Xu Zhaoyang Lin Dr. Xing Zhong Ben Papandrea Prof. Yu Huang Xiangfeng Duan 《Angewandte Chemie (International ed. in English)》2015,54(18):5345-5350
A solvent‐exchange approach for the preparation of solvated graphene frameworks as high‐performance anode materials for lithium‐ion batteries is reported. The mechanically strong graphene frameworks exhibit unique hierarchical solvated porous networks and can be directly used as electrodes with a significantly improved electrochemical performance compared to unsolvated graphene frameworks, including very high reversible capacities, excellent rate capabilities, and superior cycling stabilities. 相似文献
3.
Dr. Nian‐Wu Li Yang Shi Dr. Ya‐Xia Yin Dr. Xian‐Xiang Zeng Jin‐Yi Li Prof. Cong‐Ju Li Prof. Li‐Jun Wan Prof. Rui Wen Prof. Yu‐Guo Guo 《Angewandte Chemie (International ed. in English)》2018,57(6):1505-1509
Lithium (Li) metal is a promising anode material for high‐energy density batteries. However, the unstable and static solid electrolyte interphase (SEI) can be destroyed by the dynamic Li plating/stripping behavior on the Li anode surface, leading to side reactions and Li dendrites growth. Herein, we design a smart Li polyacrylic acid (LiPAA) SEI layer high elasticity to address the dynamic Li plating/stripping processes by self‐adapting interface regulation, which is demonstrated by in situ AFM. With the high binding ability and excellent stability of the LiPAA polymer, the smart SEI can significantly reduce the side reactions and improve battery safety markedly. Stable cycling of 700 h is achieved in the LiPAA‐Li/LiPAA‐Li symmetrical cell. The innovative strategy of self‐adapting SEI design is broadly applicable, providing opportunities for use in Li metal anodes 相似文献
4.
A High‐Energy‐Density Potassium Battery with a Polymer‐Gel Electrolyte and a Polyaniline Cathode 下载免费PDF全文
Dr. Hongcai Gao Dr. Leigang Xue Dr. Sen Xin Prof. John B. Goodenough 《Angewandte Chemie (International ed. in English)》2018,57(19):5449-5453
A safe, rechargeable potassium battery of high energy density and excellent cycling stability has been developed. The anion component of the electrolyte salt is inserted into a polyaniline cathode upon charging and extracted from it during discharging while the K+ ion of the KPF6 salt is plated/stripped on the potassium‐metal anode. The use of a p‐type polymer cathode increases the cell voltage. By replacing the organic‐liquid electrolyte in a glass‐fiber separator with a polymer‐gel electrolyte of cross‐linked poly(methyl methacrylate), a dendrite‐free potassium anode can be plated/stripped, and the electrode/electrolyte interface is stabilized. The potassium anode wets the polymer, and the cross‐linked architecture provides small pores of adjustable sizes to stabilize a solid‐electrolyte interphase formed at the anode/electrolyte interface. This alternative electrolyte/cathode strategy offers a promising new approach to low‐cost potassium batteries for the stationary storage of electric power. 相似文献
5.
Facile Stabilization of the Sodium Metal Anode with Additives: Unexpected Key Role of Sodium Polysulfide and Adverse Effect of Sodium Nitrate 下载免费PDF全文
Dr. Huan Wang Chuanlong Wang Edward Matios Prof. Weiyang Li 《Angewandte Chemie (International ed. in English)》2018,57(26):7734-7737
Sodium metal is an attractive anode for next‐generation energy storage systems owing to its high specific capacity, low cost, and high abundance. Nevertheless, uncontrolled Na dendrite growth caused by the formation of unstable solid electrolyte interphase (SEI) leads to poor cycling performance and severe safety concerns. Sodium polysulfide (Na2S6) alone is revealed to serve as a positive additive or pre‐passivation agent in ether electrolyte to improve the long‐term stability and reversibility of the Na anode, while Na2S6‐NaNO3 as co‐additive has an adverse effect, contrary to the prior findings in the lithium anode system. A superior cycling behavior of Na anode is first demonstrated at a current density up to 10 mA cm?2 and a capacity up to 5 mAh cm?2 over 100 cycles. As a proof of concept, a high‐capacity Na‐S battery was prepared by pre‐passivating the Na anode with Na2S6. This study gives insights into understanding the differences between Li and Na systems. 相似文献
6.
Dong‐Joo Yoo Sungyun Yang Ki Jae Kim Jang Wook Choi 《Angewandte Chemie (International ed. in English)》2020,59(35):14869-14876
In lithium metal batteries, electrolytes containing a high concentration of salts have demonstrated promising cyclability, but their practicality with respect to the cost of materials is yet to be proved. Here we report a fluorinated aromatic compound, namely 1,2‐difluorobenzene, for use as a diluent solvent in the electrolyte to realize the “high‐concentration effect”. The low energy level of the lowest unoccupied molecular orbital (LUMO), weak binding affinity for lithium ions, and high fluorine‐donating power of 1,2‐difluorobenzene jointly give rise to the high‐concentration effect at a bulk salt concentration near 2 m , while modifying the composition of the solid‐electrolyte‐interphase (SEI) layer to be rich in lithium fluoride (LiF). The employment of triple salts to prevent corrosion of the aluminum current collector further improves cycling performance. This study offers a design principle for achieving a local high‐concentration effect with reasonably low bulk concentrations of salts. 相似文献
7.
Zhiliang Liu Shaolei Yang Bingxue Sun Piaoping Yang Jie Zheng Xingguo Li 《Angewandte Chemie (International ed. in English)》2020,59(5):1975-1979
Phosphorus‐rich metal phosphides have very high lithium storage capacities, but they are difficult to prepare. A low‐temperature phosphorization method based on Mg reducing PCl3 in ZnCl2 molten salt at 300 °C is developed to synthesize phosphorus‐rich CuP2@C from a Cu‐MOF derived Cu@C composite. Abnormal oxidation of Cu by Zn2+ in the molten salt is observed, which leads to the porous honeycomb nanostructure and homogeneously distributed ultrafine CuP2 nanocrystals. The honeycomb CuP2@C exhibits excellent lithium storage performance with high reversible capacity (1146 mAh g?1 at 0.2 A g?1) and superior cycling stability (720 mAh g?1 after 600 cycles at 1.0 A g?1), showing the promising application of P‐rich metal phosphides in lithium ion batteries. 相似文献
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9.
Ming Zhu Dr. Guanyao Wang Dr. Xing Liu Prof. Bingkun Guo Prof. Gang Xu Zhongyi Huang Prof. Minghong Wu Prof. Hua-Kun Liu Prof. Shi-Xue Dou Dr. Chao Wu 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2020,132(16):6658-6662
Sodium metal is an ideal anode material for metal rechargeable batteries, owing to its high theoretical capacity (1166 mAh g−1), low cost, and earth-abundance. However, the dendritic growth upon Na plating, stemming from unstable solid electrolyte interphase (SEI) film, is a major and most notable problem. Here, a sodium benzenedithiolate (PhS2Na2)-rich protection layer is synthesized in situ on sodium by a facile method that effectively prevents dendrite growth in the carbonate electrolyte, leading to stabilized sodium metal electrodeposition for 400 cycles (800 h) of repeated plating/stripping at a current density of 1 mA cm−2. The organic salt, PhS2Na2, is found to be a critical component in the protection layer. This finding opens up a new and promising avenue, based on organic sodium slats, to stabilize sodium metals with a protection layer. 相似文献
10.
Yiren Zhong Yujun Xie Sooyeon Hwang Qian Wang Judy J. Cha Dong Su Hailiang Wang 《Angewandte Chemie (International ed. in English)》2020,59(33):14003-14008
The energetic chemical reaction between Zn(NO3)2 and Li is used to create a solid‐state interface between Li metal and Li6.4La3Zr1.4Ta0.6O12 (LLZTO) electrolyte. This interlayer, composed of Zn, ZnLix alloy, Li3N, Li2O, and other species, possesses strong affinities with both Li metal and LLZTO and affords highly efficient conductive pathways for Li+ transport through the interface. The unique structure and properties of the interlayer lead to Li metal anodes with longer cycle life, higher efficiency, and better safety compared to the current best Li metal electrodes operating in liquid electrolytes while retaining comparable capacity, rate, and overpotential. All‐solid‐state Li||Li cells can operate at very demanding current–capacity conditions of 4 mA cm?2–8 mAh cm?2. Thousands of hours of continuous cycling are achieved at Coulombic efficiency >99.5 % without dendrite formation or side reactions with the electrolyte. 相似文献
11.
Yulin Jie Xiaojing Liu Zhanwu Lei Shiyang Wang Yawei Chen Fanyang Huang Ruiguo Cao Genqiang Zhang Shuhong Jiao 《Angewandte Chemie (International ed. in English)》2020,59(9):3505-3510
Lithium metal is an ideal electrode material for future rechargeable lithium metal batteries. However, the widespread deployment of metallic lithium anode is significantly hindered by its dendritic growth and low Coulombic efficiency, especially in ester solvents. Herein, by rationally manipulating the electrolyte solvation structure with a high donor number solvent, enhancement of the solubility of lithium nitrate in an ester‐based electrolyte is successfully demonstrated, which enables high‐voltage lithium metal batteries. Remarkably, the electrolyte with a high concentration of LiNO3 additive presents an excellent Coulombic efficiency up to 98.8 % during stable galvanostatic lithium plating/stripping cycles. A full‐cell lithium metal battery with a lithium nickel manganese cobalt oxide cathode exhibits a stable cycling performance showing limited capacity decay. This approach provides an effective electrolyte manipulation strategy to develop high‐voltage lithium metal batteries. 相似文献
12.
An O3‐type Oxide with Low Sodium Content as the Phase‐Transition‐Free Anode for Sodium‐Ion Batteries 下载免费PDF全文
Chenglong Zhao Dr. Maxim Avdeev Prof. Liquan Chen Prof. Yong‐Sheng Hu 《Angewandte Chemie (International ed. in English)》2018,57(24):7056-7060
Layered transition metal oxides NaxMO2 (M=transition metal) with P2 or O3 structure have attracted attention in sodium‐ion batteries (NIBs). A universal law is found to distinguish structural competition between P2 and O3 types based on the ratio of interlayer distances of the alkali metal layer d(O‐Na‐O) and transition‐metal layer d(O‐M‐O). The ratio of about 1.62 can be used as an indicator. O3‐type Na0.66Mg0.34Ti0.66O2 oxide is prepared as a stable anode for NIBs, in which the low Na‐content (ca. 0.66) usually undergoes a P2‐type structure with respect to NaxMO2. This material delivers an available capacity of about 98 mAh g?1 within a voltage range of 0.4–2.0 V and exhibits a better cycling stability (ca. 94.2 % of capacity retention after 128 cycles). In situ X‐ray diffraction reveals a single‐phase reaction in the discharge–charge process, which is different from the common phase transitions reported in O3‐type electrodes, ensuring long‐term cycling stability. 相似文献
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14.
MoS2 Nanoflowers with Expanded Interlayers as High‐Performance Anodes for Sodium‐Ion Batteries 下载免费PDF全文
Zhe Hu Lixiu Wang Dr. Kai Zhang Dr. Jianbin Wang Prof. Fangyi Cheng Prof. Zhanliang Tao Prof. Jun Chen 《Angewandte Chemie (International ed. in English)》2014,53(47):12794-12798
MoS2 nanoflowers with expanded interlayer spacing of the (002) plane were synthesized and used as high‐performance anode in Na‐ion batteries. By controlling the cut‐off voltage to the range of 0.4–3 V, an intercalation mechanism rather than a conversion reaction is taking place. The MoS2 nanoflower electrode shows high discharge capacities of 350 mAh g?1 at 0.05 A g?1, 300 mAh g?1 at 1 A g?1, and 195 mAh g?1 at 10 A g?1. An initial capacity increase with cycling is caused by peeling off MoS2 layers, which produces more active sites for Na+ storage. The stripping of MoS2 layers occurring in charge/discharge cycling contributes to the enhanced kinetics and low energy barrier for the intercalation of Na+ ions. The electrochemical reaction is mainly controlled by the capacitive process, which facilitates the high‐rate capability. Therefore, MoS2 nanoflowers with expanded interlayers hold promise for rechargeable Na‐ion batteries. 相似文献
15.
Qi Zhang Jingyi Luan Yougen Tang Xiaobo Ji Haiyan Wang 《Angewandte Chemie (International ed. in English)》2020,59(32):13180-13191
Aqueous zinc‐ion batteries have rapidly developed recently as promising energy storage devices in large‐scale energy storage systems owing to their low cost and high safety. Research on suppressing zinc dendrite growth has meanwhile attracted widespread attention to improve the lifespan and reversibility of batteries. Herein, design methods for dendrite‐free zinc anodes and their internal mechanisms are reviewed from the perspective of optimizing the host–zinc interface and the zinc–electrolyte interface. Furthermore, a design strategy is proposed to homogenize zinc deposition by regulating the interfacial electric field and ion distribution during zinc nucleation and growth. This Minireview can offer potential directions for the rational design of dendrite‐free zinc anodes employed in aqueous zinc‐ion batteries. 相似文献
16.
Dr. Yang Xu Dr. Min Zhou Xin Wang Dr. Chengliang Wang Liying Liang Fabian Grote Dr. Minghong Wu Yan Mi Prof. Yong Lei 《Angewandte Chemie (International ed. in English)》2015,54(30):8768-8771
The utilization of oxygen vacancies (OVs) in sodium ion batteries (SIBs) is expected to enhance performance, but as yet it has rarely been reported. Taking the MoO3?x nanosheet anode as an example, for the first time we demonstrate the benefits of OVs on SIB performance. Moreover, the benefits at deep‐discharge conditions can be further promoted by an ultrathin Al2O3 coating. A series of measurements show that the OVs increase the electric conductivity and Na‐ion diffusion coefficient, and the promotion from ultrathin coating lies in the effective reduction of cycling‐induced solid‐electrolyte interphase. The coated nanosheets exhibited high reversible capacity and great rate capability with the capacities of 283.9 (50 mA g?1) and 179.3 mAh g?1 (1 A g?1) after 100 cycles. This work may not only arouse future attention on OVs for sodium energy storage, but also open up new possibilities for designing strategies to utilize defects in other energy storage systems. 相似文献
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18.
Inside Cover: A Flexible Solid Electrolyte Interphase Layer for Long‐Life Lithium Metal Anodes (Angew. Chem. Int. Ed. 6/2018) 下载免费PDF全文
Dr. Nian‐Wu Li Yang Shi Dr. Ya‐Xia Yin Dr. Xian‐Xiang Zeng Jin‐Yi Li Prof. Cong‐Ju Li Prof. Li‐Jun Wan Prof. Rui Wen Prof. Yu‐Guo Guo 《Angewandte Chemie (International ed. in English)》2018,57(6):1422-1422
19.
A large‐scale hierarchical assembly route is reported for the formation of SnO2 on the nanoscale that contains rigid and robust spheres with irregular channels for rapid access of Li ions into the hierarchically structured interiors. Large volume changes during the process of Li insertion and extraction are accommodated by the SnO2 nanoflake spheres’ internal porosity. The hierarchical SnO2 nanoflake spheres exhibit good lithium storage properties with high capacity and long‐lasting performance when used as lithium‐ion anodes. A reversible capacity of 517 mA h g?1, still greater than the theoretical capacity of graphite (372 mA h g?1), after 50 charge–discharge cycles is attained. Meanwhile, the synthesis process is simple, inexpensive, safe, and broadly applicable, providing new avenues for the rational engineering of electrode materials with enhanced conductivity and power. 相似文献
20.
Ting Jin Peng‐Fei Wang Qin‐Chao Wang Kunjie Zhu Tao Deng Jiaxun Zhang Wei Zhang Xiao‐Qing Yang Lifang Jiao Chunsheng Wang 《Angewandte Chemie (International ed. in English)》2020,59(34):14511-14516
P2‐type layered oxides suffer from an ordered Na+/vacancy arrangement and P2→O2/OP4 phase transitions, leading them to exhibit multiple voltage plateaus upon Na+ extraction/insertion. The deficient sodium in the P2‐type cathode easily induces the bad structural stability at deep desodiation states and limited reversible capacity during Na+ de/insertion. These drawbacks cause poor rate capability and fast capacity decay in most P2‐type layered oxides. To address these challenges, a novel high sodium content (0.85) and plateau‐free P2‐type cathode‐Na0.85Li0.12Ni0.22Mn0.66O2 (P2‐NLNMO) was developed. The complete solid‐solution reaction over a wide voltage range ensures both fast Na+ mobility (10?11 to 10?10 cm2 s?1) and small volume variation (1.7 %). The high sodium content P2‐NLNMO exhibits a higher reversible capacity of 123.4 mA h g?1, superior rate capability of 79.3 mA h g?1 at 20 C, and 85.4 % capacity retention after 500 cycles at 5 C. The sufficient Na and complete solid‐solution reaction are critical to realizing high‐performance P2‐type cathodes for sodium‐ion batteries. 相似文献