Double quantum transitions in free radicals

The observation of double quantum transitions on three kinds of free radicals (DPPH, DPANO, ultramarine) at temperatures of liquid nitrogen is described. Signals having an absorption and emission character were observed in the 12-5 MHz–18 MHz frequency band in the direction parallel to the external magnetic fieldH ₀ and their dependence on different parameters was studied.Bloch equations were solved for two mutually perpendicular high-frequency fields and expressions were found for the components of dynamic susceptibility in theH ₀ direction. The experiments agree with theory.The possibility of using double quantum transitions for measuring relaxation times is discussed.

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(DPPH, DPANO, ) . 12,5MHz–18MHz H ₀, ; . H ₀. . .

     

On the approximate formulation of the orthogonalized plane-wave method

An approximate method, analogical to the orthogonalized plane-wave method, is used to calculate the energy at a number of points in the Brillouin zone of lithium and the results are compared with the energy values calculated by the OPW method. Some of the general properties of the matrix elements of the repulsive potential are discussed and correlation with other methods carried out.

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, , , . .

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In conclusion the author thanks Dr. Glasser for communicating the numerical values of the wave function and K. Trnková for carrying out the numerical calculations.     

The influence of magnetic after-effect on the rectangularity of the hysteresis loop of MgMn ferrites

The influence of the magnetic after-effect on the rectangularity of the hysteresis loop of MgMn ferrites in two different compositions was studied; it was found that this influence is so small that it cannot be the actual cause of a rectangular hysteresis loop of such materials.

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-

- . , , .

     

Hard gamma radiation in the decay of Lu176m

Gamma lines 1·05 MeV(4 × 10^–6 quanta/decay) and 1·14 MeV (9 × 10^–6 quanta/decay), giving evidence of the existence of a new level in Hf¹⁷⁶ with an energy of 1·14 MeV, were found in the decay of Lu^176m with a half-life of 3·7 hours, using the scintillation method. The component of the beta spectrum, exciting this level, has a maximum energy of 0·17 MeV and logft=8·3. The spin of this level proved to be equal to one. The level was interpreted as a single-particle neutron level withn ₀: 5/2^– (512),n ₁: 7/2^– (514);I=1⁺.

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- Lu^176m

Lu^176m 3,7 - 1,05 MeV (4.10^–6 /) 1,14 MeV (9.10^–6 / /), Hf¹⁷⁶ 1,14 MeV. -, , 0,17 MeV logft = =8,3. . cn ₀: 5/2^– (512),n ₁: 7/2^– (514);I = 1⁺h

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The authors thank L. K. Peker from the Leningrad State University for a helpful discussion of their results.     

Equilibrium state of toroidal electron beam

The paper deals with the collective behaviour of electrons which rotate in a magnetic field used in a betatron. It is shown experimentally that there exists strong interaction between the electrons, which leads to the rapid formation of the equilibrium state with characteristic distribution of the charge density in the cross-section of the toroidal beam. The corresponding relaxation time is of the order of 1 sec. A statistical theory of the equilibrium beam is elaborated. Its main result is that the effective radius of the beam is a function of two parameters, one of which is proportional to the thermal energy of the electrons and the other to the perveance of the beam. The charge contained in a toroidal beam of given effective cross-section is equal to the product of the charge the beam would contain at zero temperature and a coefficient, which is a function of the temperature of the beam. Its value is unity at zero temperature and rapidly decreases with increasing temperature. The cause of cooling of the beam is shown.

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, . , , . 1S. . , , — I/(E₀/q)^3/2 (I — , ₀ — q ). , , , , , . . .

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Now Institute of Vacuum Electronics, Czechosl. Acad. Sci., Prague.

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In conclusion the author thanks J. Luká and L. Hyttych for invaluable help in the experiments, A. Rajský for constructing the electronic apparatus and J. Sokol for preparing the miniature probe.     

Anti-parallel ferroelectric domains in surface space-charge layers of BaTiO3

It is shown on simplified models of a surface space-charge layer of a single crystal of BaTiO ₃ that in the surface region, in which the direction of the electric field is opposite to the direction of spontaneous polarization inside the crystal, anti-parallel domains can exist. The dimensions of these domains are determined. The use of the results obtained is proposed for interpreting the microrelief of the etch figures and for explaining the different phases of the polarization reversal process of a single-domain single crystal of BaTiO ₃.

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BatiO₃

BaTiO₃ , , , . . BaTiO₃.

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The author would like to thank J. Kaczer, Z. Málek and V. Dvoák of the Institute of Physics, Czechoslovak Academy of Sciences, for valuable remarks on this paper and H. Havlíková for carefully carrying out the numerical calculations.     

Magnetic anisotropy in thin ferromagnetic films

The magnetic properties of thin ferromagnetic films are studied taking into account the magnetic anisotropy term in the Hamiltonian. In the second approximation equations are obtained for the magnetization of the monatomic layers parallel to the surface of the thin film. From these equations one obtains the Curie temperature, which depends on the thickness of the thin film and the ratio a between the anisotropy constant and the exchange energy between two neighbours. A value can be chosen for such that the thin film becomes ferromagnetic only for a thickness greater than a definite value and in this manner the theoretical results can be fitted to the experimental data. The situation in cobalt thin films is dealt with in particular.

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. , . , . , , - , . , , .

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The author extends his thanks to the research workers of CIFA 1 as well as to Dr. L. Valenta for information on the same subject.     

An interpretation of the conditions for the existence of Shockley surface states

A study is made of the Shockley surface states in a linear chain of equal atoms, joined by alternately strong bonds. If the simple MO LCAO method is used, which considers the exchange integrals between nearest neighbours and next nearest neighbours, we get the surface states for a semi-infinite chain if the stronger bond is interrupted. The connection between Shockley and Tamm surface states is shown and the hypothesis is put forward that the condition for the existence of Shockley surface states has a generally simple physical interpretation, the validity of which is proved on the models of a semi-infinite crystal studied up to now.

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, . MO LCAO, , , . , , , .

     

ВЛИЯНИЕ ПРЕДВАРИТЕЛ ЬНОГО ОСВЕЩЕНИЯ ha ХАРАКТЕРИСТИКИ МЕДН ОЗАКИСНЫХ ВЫПРЯМИТЕ ЛЕЙ

, 150° , . - . -. . ( ).     

Der Exzitonenzerfall im elektrostatischen Felde der Störstellen von Ionenkristallen

Zusammenfassung Es wird theoretisch der Prozeß des Exzitonenzerfalls mit Hilfe der Ionisation durch das elektrostatische Feld der Störstelle untersucht. Die Wirkungsquerschnitte werden in zwei Grenzfällen bestimmt: bei einer kleinen und einer großen mittleren freien Bahn des Exzitons, die durch dessen Wechselwirkung mit den Phononen bedingt ist. Die Ergebnisse werden zum Studium des Exzitonenzerfalls an einer Vakanz nach einem Kupferion in Cu₂O-Kristallen mit einem stöchiometrischen Sauerstoffüberschuß verwendet.

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. : , . Cu₂0 .

     

Der Einfluss der Plastischen Verformung durch Kaltwalzen auf die Koerzitivkraft

Zusammenfassung Es werden die Ergebnisse der Messungen der Koerzitivkraft von Eisen, Nickel und einiger Fe-Ni-Legierungen in Abhängigkeit von der plastischen Verformung durch Kaltwalzen angegeben. Gemessen wurde in Richtung parallel und senkrecht zur Walzrichtung. Die Ergebnisse werden insbesondere vom Gesichtspunkt des Einflusses der Versetzungen und der einachsigen induzierten Anisotropie diskutiert.

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, - , . . .

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Für die wertvollen Diskussionen und das Durchlesen der Arbeit danken wir den Kollegen J. Kaczér und V. Janovec, für die wirkungsvolle Hilfe bei den Messungen Koll. J. Grolmus.     

ИЗЛУЧЕНИЕ ЧЕРЕНКОВА ПРОСТРАНСТВЕННОГО З АРЯДА В ВОЛНОВОДАХ И В НЕОГР АНИЧЕННОЙ СРЕДЕ

, - e . -. , .     

к ВОпРОсУ О БЕтАтРОННых кОлЕБАНИьх В УскОРИтЕлЕ с ОБОБЩЕННыМ пОлЕМ

, , [1], [2]. .

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A remark on betatron oscillations in an accelerator with a generalized field

The paper discusses the stability region for a canonical system of equations of motion describing the behaviour of a particle in an accelerator with a generalized field, defined on the general rotation surface [1], [2], The stability region is determined in the plane of two invariants.

     

Two-barrier detector

The paper describes the principle of a detector with two opposite surface barriers and the experimental verification of its functioning. The detector permits double the effective depth to be attained on the material with a given bias voltage. The principle of opposite barriers also permits a reduction in the system of dE/dx andE detectors to one detector.

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. . dE/dx E .

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The authors thank A. Irra for carefully preparing the plates, K. Putz and J. imková for very effective help in measuring on the cyclotron and the members of of the cyclotron staff for their cooperation.     

The formation of dislocations by a spark discharge

The arrangement of dislocations formed in a single crystal of the alloy Fe-4·2% Si by a spark discharge in air is studied. The dislocations are made visible by etching on the surfaces perpendicular and parallel to the axis of the crater. The results of the observations are explained on the basis of microphysical conceptions of plastic deformation.

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, Fe— 4,2% Si . , . .

     

Optical and magneto-optical effects in semi-conductor crystals

The complicated line structure of the fundamental absorption edge and the effect of magneto-optical oscillations (which are general properties of crystals) open up good possibilities for the study of band structure and exciton states.From a survey of the facts observed lately it follows that the real existence of the exciton is almost certain although no experiment has yet been performed, which would provide direct experimental proof of its motion in the crystal. The evidence of the motion of excitons in the crystal can be determined from effects based on spatial dispersion effects. The observed optical anisotropy of absorption in a Cu₂O cubic crystal (due to spatial dispersion) and the quadrupole character of the exciton linen=1 confirm the motion of exciton through the crystal.The fine structure of the spectral curve for photoconductivity (an effect that is also common to all crystals), which is directly connected with the exciton absorption structure, also testifies to the motion of excitons.The exciton structure of the absorption edge and also the connected effect of edge emission enable the band structure and its splitting to be studied.The determination of the splitting of the exciton lines and edge of continuous absorption under the influence of oriented elastic deformation and the study of the state of polarization of the split components provides a new method for the study of band structure.The study of the Zeeman effect for lines of exciton, absorption in crystals can supply data on the exciton motion and on the complicated band structure in crystals. Special detailed data on the band structure can be obtained from studies in polarized light. From the effect of magneto-optical oscillations we can decide with great exactness the band width of the forbidden zone and obtain data which are in good agreement with those obtained by other methods.

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- , , . , , , , . , . — —, , n=1 . — , , — , . , - . () , . , , , , . - . . , , .

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Address delivered at International Conference on Semi-conductor Physics, Prague, Czechoslovakia, September 1960.     

The quantum theory of the spontaneous magnetization of ferrimagnetics,anti-ferromagnetics and thin films with arbitrary spin at high temperatures

Using Van Vleck's modification of the Heisenberg theory of ferro-magnetism for substances with arbitrary spin per atom, a generalization of the theory is given for the case of ferrimagnetics, anti-ferromagnetics and thin films with an arbitrary number of sub-lattices and with arbitrary spin per atom. The exchange part of the energy operator is formulated by means of rotated spin operators. The theory contains the quantum-mechanical generalization of non-quantum theories given by Néel and later generalized by Yafet and Kittel. It also contains the theory of thin films proposed recently by the author. The magnetization laws are completely analogous to the relations derived from the theory of molecular fields. The constants of the molecular fields are interpreted by means of exchange integrals. For the special case of spin S=1/2the theory agrees with the results of the work of Vlasov and Imuchametov for ferrimagnetics and anti-ferromagnetics and with the author's for thin films.

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, , , . . - , . , . , . . S=1/2 .

     

On the energy balance in the optics of metals

On the basis of the boundary conditions of the electromagnetic theory an explicit calculation of the absorption in a thin metallic film was carried out with the result that transport and interference components were found to exist. By applying the method to a simple metal-dielectric boundary the physical interpretation was given of the energy balance, which had hitherto been regarded as unclear. It was also explained why the reversibility principle fails when applied to a metal-dielectric boundary.

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, . - , . , - .

     

ИспОльжОВАНИЕ ФлУОР ЕсцЕНтНОгО РЕНтгЕНО ВскОгО ИжлУЧЕНИь Дль кОНтАк тНОИ МИкРОРАДИОгРАФ ИИ

( )K- Fe, Ti Ca . , , , . , , , K- , .

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The use of fluorescent X-rays for contact microradiography

The possibilities of using fluorescentK-radiation of the elements Fe, Ti and Ca for contact microradiography of thin, little absorbing samples were studied and a simple set-up for carrying out this method, which uses a common type of microstructural X-ray tube as a source of the exciting radiation, was proposed. The experiments performed showed that if large magnifications are not required secondary-excitedK-radiation of the above-mentioned elements can be advantageously used for contact microradiography without the exposure times becoming impracticably long.

     

Thermostimulierte Exoemission und Lumineszenz von MgO und CaO

Ohne Zusammenfassung

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MgO CaO

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Ich danke bestens Frau K. Listoová für die sorgfältige Durchführung der Versuchsreihen und Ing. S. urovi und Dr. A. Bergstein für das liebenswürdige Überlassen der Präparate.