共查询到17条相似文献,搜索用时 78 毫秒
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采用紧密结合的分子动力学模型,对Na(n)(5<=n<=10)小团簇的键长涨落、势能、热容量等熔化性质在50K到1500K温区进行了模拟研究,结果表明:它们发生两次相变,一种在230K到300K的温度范围内,依次有块体玻璃态转变;一种在550K到870K温度段,依次经历了熔化相变.同时也得到随着团簇体系的减小,势能由下向上排列的曲线,即体系的势能由低变高. 相似文献
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钠原子团簇的碰撞动力学 总被引:1,自引:1,他引:0
采用紧密结合的分子动力学模型,对第一个满壳附近(n=8)钠原子团簇碰撞Nan+Nan的动力学性质进行了系统性研究。对有限温度下的多次模拟事件,在各种碰撞参数与不同轰击能量时,双团簇(Nan)2的稳定性进行了研究。并发现,当质心系单原子能量为0.025eV时,对中心碰撞,(Na8)2能够存在3000fs,而对周边碰撞,(Na8)2能够存在10000fs;不管对中心碰撞还是对周边碰撞,在较低的轰击能量下,这种暂态双团簇结构具有较长的寿命;在相同的单原子轰击能量和相同的碰撞参数,(Na8)2和(Na9)2的动力学寿命没有差别,只是(Na8)2比(Na9)2的温度更低。 相似文献
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发展了一个与距离相关的紧密结合分子动力学模型来系统研究钠原子团簇Nan的结构、热力学和碰撞动力学性质.计算结果能够很好地符合从头计算法(abinition)的计算结果和实验结果.同时也探讨了这种有限数目团簇随温度升高可能发生的从类固相到类液相的相变和在碰撞过程中形成双团簇(Nan)2的动力学稳定性. Based on the tight binding molecular dynamics, the structural, thermodynamical and collision properties are systematically studied for Nan. Present claculations are successful in reproducing some of the experimental data and in agreement very well with some other ab initio calculations. We also investigate the transition from solid like phase to liquid like phase with increasing temperature for this finite system and the stability of dimer (Nan)2 formed in cluster collisions. 相似文献
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采用紧束缚的分子动力学模型,对Nan(5≤n≤10)小团簇的键长涨落、势能、热容量等熔化性质在50 K~1500 K温区进行了模拟研究,结果表明:它们发生两次相变,一种在230 K~300 K的温度范围内,依次有块体玻璃态转变;一种在550 K~870 K温度段,依次经历了熔化相变.同时也得到随着团簇体系的减小,势能由下向上排列的曲线,即体系的势能由低变高. 相似文献
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运用距离相关紧密结合的分子动力学模型,通过无量纲的形变参数S1对简单金属原子团簇Na4、Na8、Na14和Na20相变时的多极形变特征进行了分析,发现S1可以用作表征团簇形变的灵敏探针. 相似文献
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采用紧密结合分子动力学模型,对Na9+Na9碰撞系统在质心系中单原子的轰击能量为Ecm/n=0.0063eV的对心碰撞进行了研究。从动力学的观战对双团簇分子(Na9)2的形成给预了证明,结合所谓“「突然冷却”技术,鉴别出所形成的(Na9)2,并给出了其结构性质。 相似文献
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许雪松 《原子与分子物理学报》2006,23(1):137-142
应用密度泛函B3LYP/6—31+G(d,p)方法对C8H80-(H2O)n(n=1~5)团簇这种弱相互作用体系进行垒自由度能量梯度优化,得到该系列团簇的稳定蛄构.计算结果表明。在该系列二元团簇中,一方面水分子数目的多少对苯基丙酮分子的结构影响很小,另一方面由于苯基丙酮分子的存在,破坏了团簇中水分子的对称性结构,在团簇内部极力形成O—H—O这样弯曲的有方向性的氢键.对苯基丙酮-水这样结构复杂的团簇,指认光谱的难度非常大,本文只讨论了与C=O有关的振动峰和水分子的对称伸缩振动的最强峰. 相似文献
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采用紧密结合分子动力学模型 ,对Na9+Na9碰撞系统在质心系中单原子的轰击能量为Ecm/n =0 .0 0 63eV的对心碰撞进行了研究。从动力学的观点对双团簇分子 (Na9) 2 的形成给予了证明 ,结合所谓“突然冷却”技术 ,鉴别出了所形成的 (Na9) 2 ,并给出了其结构性质。 相似文献
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采用密度泛函理论中的局域自旋密度近似和广义梯度近似对(CoMn)n(n=1~5)团簇的几何构型进行优化、能量、频率和磁性计算,确定了团簇的基态,对其基态的磁性和电子结构进行了系统研究,并与相对应的一元团簇进行了结构和磁性比较.研究表明,两种方法确定的基态构型基本一致,当n=1~4时,等比CoMn二元合金团簇的几何形状仍与一元团簇相同;(CoMn)3和(CoMn)4团簇出现了磁性双稳态,显示铁磁性和反铁磁性耦合;二元CoMn合金团簇中Co、Mn原子磁性仍能保持一元Co、Mn团簇基态的磁性. 相似文献
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本文使用分子轨道从头算方法,在HF/6—31G和MP2/6—31G“水平下,计算了小硅化物SiXm的平衡几何和谐振子振动频率。理论值和实验值的比较表明,对于SiHm分子,实验的键长位于HF键长和MP2键长之间,而MP2振动频率更接近于实验的振动;率。对于SiClm分子,无论是键长还是振动频率HF值和MP2值都比较接近。对于SiFm分子,处于这两类的中间情况。关联作用随着X原子的原子序数的增加而减弱。 相似文献
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E. M. Fernández G. Borstel J. M. Soler L. C. Balbás 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2003,24(1-3):245-248
The ionic and electronic structure of
(Al2O3)n(Ox)
clusters with n
16 and x
= 0,
1, 2 is studied by means of first principles density functional
calculations, norm-conserving pseudopotentials and a numerical
atomic basis set. The equilibrium geometries have been
determined by total energy minimization, starting with several
initial geometries for each cluster size. The trends obtained
for the atomic arrangements (structural isomers, coordination
numbers, disordered versus
ordered structures, etc.) and the electronic properties
(binding energies, Homo-Lumo gap and dipole moments) are
discussed. For most of the oxidized clusters studied here we
find that the Homo-Lumo gap and the magnitude of dipole moment
of isomeric species can vary drastically. 相似文献
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Z.F. Liu W.L. Yim J.S. Tse J. Hafner 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2000,10(1):105-114
Ab initio Molecular Dynamics (MD) method, based on density functional theory (DFT) with planewaves and pseudopotentials, was used to
study the stability and internal motion in silver cluster Agn, with n
=4-6. Calculations on the neutral, cationic and anionic silver dimer Ag2 show that the bond distance and vibrational frequency calculated by DFT are of good quality. Simulations of Ag4, Ag5, and Ag6 in canonical ensemble reveal distinct characteristics and isomerization paths for each cluster. At a temperature of 800 K,
an Ag4 has no definite structure due to internal motion, while for Ag5 and Ag6the clusters maintain the planar structure, with atomic rearrangement observed for Ag5 but not for Ag6. At a temperature of 200 K, Ag4 can exist in two planar structures whilst Ag5 is found to be stable only in the planar form. In contrast Ag6 is stable in both planar trigonal and 3D pentagonal structures. Micro-canonical MD simulation was performed for all three
clusters to obtain the vibrational density of states (DOS).
Received 5 May 1999 and Received in final form 20 August 1999 相似文献
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Xiaozhen ZhengYonghong Zhang Shiping Huang Hui LiuPeng Wang Huiping Tian 《Applied Surface Science》2011,257(15):6410-6417
The geometrical, electronic and vibrational properties of pure (Al2O3)n (n = 9, 10, 12, 15) clusters and Ni-doped (Al2O3)9-10 clusters are investigated by density functional theory. There are four different Ni-doped (Al2O3)9 clusters and one Ni-doped (Al2O3)10 cluster taken into account. Compared with the pure clusters, the Ni-doped (Al2O3)9-10 clusters have narrower HOMO-LUMO energy gaps. The results indicate that the impurity of Ni atom is mainly responsible for the reduction of the HOMO-LUMO energy gap. One characteristic vibration band at about 1030 cm−1 is found in the vibrational frequencies of the Ni-doped (Al2O3)9-10 clusters, which is caused by the asymmetric Al-O-Al stretching vibration. Another band at around 826 cm−1 involving the characteristic vibration of Ni-O bond is in good agreement with experimental results. 相似文献