共查询到19条相似文献,搜索用时 140 毫秒
1.
2.
流动注射在线萃取荧光法测定痕量阴离子表面活性剂 总被引:9,自引:0,他引:9
报道了痕量阴离子表面活性剂的流动注射在线萃取荧光分析方法.该方法测定的线性范围为 0.01~0. 20 mg/L;进样频率为 20样/h.应用本法测定了水样中痕量阴离子表面活性剂,得到了满意的结果. 相似文献
3.
研究了罗丹明123(RDM123)与阴离子表面活性剂(AS)的荧光反应,建立了荧光光度法测定环境水中阴离子表面活性剂。在稀H2SO4溶液中,罗丹明123与阴离子表面活性剂形成黄色荧光缔合物,激发波长为500 nm,发射波长为538 nm。通过含时密度泛函计算结果得:罗丹明123化合物激发波长主要是π→π*电子跃迁产生。阴离子表面活性剂十二烷基苯磺酸钠(DBOSO3Na)、十二烷基硫酸钠(DSO4Na)浓度分别在0~56和0~115μg/m L范围与ΔF呈良好的线性关系,检出限分别为0.0576和0.0843μg/m L,方法用于环境水中阴离子表面活性剂的测定。 相似文献
4.
5.
6.
废水中的阴离子表面活性剂的测定 总被引:15,自引:0,他引:15
十六烷基三甲基溴化铵 ( CTMAB)、溴甲酚紫 ( BCP)和阴离子表面活性剂三者在 p H 7.0 0的条件下可形成有色离子缔合物 ,据此建立了 CTMAB- BCP分光光度法测定阴离子表面活性剂的方法。在 75μg CTMAB存在下 ,十二烷基硫酸钠 ( SDS)在 0~ 5 0 μg范围内符合比耳定律 ,其表观摩尔吸光系数是 2 .74× 1 0 4 L· mol- 1·cm- 1,并用标准加入法和主成分回归法不分离干扰可直接测定。应用此方法测定了河水、池塘水和生活污水中的阴离子表面活性剂 (以 SDS计 )并与亚甲蓝法进行比较 ,结果满意 相似文献
7.
8.
9.
10.
阴离子表面活性剂在有机合成中的催化作用 总被引:2,自引:0,他引:2
从亲电取代、亲核取代、亲核加成、酯水解、氧化、还原、聚合等八个方面概述了阴离子表面活性剂在有机合成中的催化作用及其催化机理 相似文献
11.
P. S. Niranjan 《Journal of Dispersion Science and Technology》2013,34(1):109-113
The interaction of polyacrylamide (PAM) with conventional anionic (sodium lauryl sulphate, NaLS) and gemini anionic (sodium salt of bis(1-dodecenyl succinimic acid), represented as NaBDS) surfactants has been studied in alkaline medium by electrical conductance and surface-tension measurements at 350C in order to compare the behavior of two surfactants toward the polymer. The surface parameters and thermodynamic parameters have been evaluated and compared. The results indicate more readily interaction of anionic gemini surfactant with the polymer (PAM). 相似文献
12.
在pH 2.36的B-R介质中,一定量的3种阴离子表面活性剂十二烷基苯磺酸钠(SD-BS)、十二烷基硫酸钠(SDS)和十二烷基磺酸钠(SLS)可与1.0×10-4 mol·L-1硫堇溶液1.0mL在总体积10mL中反应生成离子缔合物,产生共振瑞利散射光谱,在其最大共振光散射峰655nm波长处测定共振瑞利散射强度IRRS。SDBS、SDS和SLS的质量浓度分别在0.05~3.0,0.5~3.0,1.0~5.0mg·L-1范围内与样品及空白溶液的IRRS值之差ΔIRRS呈线性关系,方法的检出限(3S/N)分别为0.017,0.166,0.571mg·L-1。方法用于两个标准样品和两个环境水样中SDBS的测定,测定结果与认定值和亚甲蓝光度法测得结果相符。 相似文献
13.
《Analytical letters》2012,45(13-14):2791-2802
Abstract An anionic surfactant ion selective electrode has been developed by coating the Ru?i?ka Selectrode with plasticised polyvinyl chloride containing hyaminedodecylsulfate active substance. The electrode responds to dodecylsulfate, in the range 10?2 ? 10?2 mol dm?3 and has been used for potentiometric titration of micromolar amounts of dodecylsulfate with an accuracy of 0.3%. The influence of several organic and inorganic anions has been investigated. 相似文献
14.
酚藏花红与DNA作用的共振光散射特征及微量DNA的光散射测定 总被引:17,自引:0,他引:17
研究了酚藏花红与脱氧核糖核酸在近中性条件下作用中的共振光散射特征,并以此建立起纳克级核酸的分析方法。考察了影响因素和最佳反映条件,建立了用RLS光谱测定纳克级DNA的新方法。 相似文献
15.
以国标方法 GB 7494-1987为依据,采用直线模组自动控制系统和基于多通阀的复杂管路切换技术,实现对阴离子表面活性剂的在线、连续、多样品萃取分析.结果表明,阴离子洗涤剂在线萃取分析系统在0.1~2.0 mg/L质量浓度范围内,标准曲线的线性相关系数为0.999 9,检出限为0.035 mg/L,实际样品加标回收率为80%~115%,相对标准偏差在0.57%~5.73%之间,每个样品的实际检测周期为25 min,样品最大检测位数为20位.全自动萃取分析系统整个萃取过程完全密闭,且可恒温恒湿,操作过程试验人员不会接触三氯甲烷试剂,整个萃取分析流程较手动萃取快速高效,完全满足水样批量分析及实时监测的要求. 相似文献
16.
17.
Bianca Schweitzer Arlindo C. Felippe Alexandre Dal Bó Edson Minatti Dino Zanette 《Macromolecular Symposia》2005,229(1):208-216
Summary: In this study sodium cholate (NaC) was used as a representative bile salt for the competitive binding between NaC and sodium dodecyl sulfate (SDS) in bovine serum albumin (BSA), in 0.02 M tris-HCl buffer solution at pH 7.50 and 25 °C. The NaC and SDS associations with BSA were monitored at low surfactant concentrations where only this specific binding process can develop. The applied method to monitor the binding was based on the analysis of the effect of SDS and NaC concentrations and their mixtures upon the fluorescence intensity of the BSA tryptophan residues. This consists of the measurement of the surfactant monomer partitioning between the dispersion medium and the microaggregates on the protein molecule where the binding is indicated by the quenching of the fluorescence chromophores. Experimentally, varying the protein concentration, the surfactant concentration needed to reach a given Io/I ratio (Io and I are the intensities with and without protein, respectively) was measured. The analyses, based on the average number of surfactant molecules bound on the protein, indicated that the SDS is a more efficient quencher than the bile salt. The need for 4–6 NaC bound molecules to give the same protein quenching efficiency by a single molecule of SDS was estimated. We concluded that the differences in the competitive binding on the protein are exclusively related to the quenching efficiency in the formation of the nonfluorescent fluorophore-quencher complex via a physical contact and static quenching process. 相似文献
18.
以酚藏花红为指示剂催化荧光法测定痕量亚硝酸根的研究 总被引:18,自引:5,他引:18
基于稀磷酸介质中,亚硝酸根对溴酸钾氧化酚藏花红反应的催化作用,建立了催化荧光法测定痕量亚硝酸根的新方法。反应在55℃水浴中进行8min,线性范围为0.27~7.3μg/L,其回归方程为ΔF=0.40+10.93c,r=0.9994。用于水样中痕量亚硝酸根的测定,结果良好。 相似文献
19.
采用在线微孔膜双萃取-流动注射光度法测定了水中的阴离子表面活性剂.方法基于亚甲基蓝与阴离子表面活性剂作用生成的盐类(λ_(max)=650 nm),可被氯仿萃取,采用在线双微孔膜液液萃取相分离器,优化了流路参数、萃取模块的流路尺寸和微孔膜的孔径.方法的线性范围为25~1000 μg/L,线性相关系数r≥0.999;检出限为4.3 μg/L;不同浓度的相对标准偏差(n=7)为0.7%~6.0%;实际水样的加标回收率为96%~110%;样品测定频率为18样/h.利用本方法分别测定了2个实际水样和2个国家标准参考物质中的阴离子表面活性剂,结果令人满意. 相似文献