Characteristics of laser supersonic heating method for producing micro metallic particles

In this article, the authors analyzed the process characteristics of laser supersonic heating method for producing metallic particles and predicted the in-flight tracks and shapes of micro-particles. A pulse Nd–YAG laser was used to heat the carbon steel target placed within an air nozzle. The high-pressure air with supersonic velocity was used to carry out carbon steel particles in the nozzle. The shock wave structures at the nozzle exit were visualized by the shadowgraph method. The carbon steel particles produced by laser supersonic heating method were grabbed and the spraying angles of the particle tracks were visualized. The velocity of the in-flight particles was measured by a photodiode sensor and compared with the numerical result. The solidification of carbon steel particles with diameters of 1–50 μm in compressible flow fields were investigated. The result shows that there is no significant difference in the dimension of solid carbon steel particles produced at shock wave fields under various entrance pressures (3–7 bar) with a constant laser energy radiation.     

Reactor laser using a mixture of xenon with uranium hexafluoride

The possibility is considered of developing a reactor laser based on a mixture of xenon, uranium hexafluoride, and a buffer gas. The kinetic scheme of populating the xenon monofluoride exciplex is analyzed. The conditions for the possibility of less stringent requirements on the nuclear pumping intensity are investigated. The conditions that ensure the necessary heat dissipation under various reactor-laser operating conditions are considered. It is shown that in principle supersonic flow of the working gas can ensure energy output in the form of laser radiation.Translated from Trudy Fizicheskogo Instituta im. P. N. Lebedeva, Vol. 120, pp. 43–50, 1980.     

Prediction of particle sticking efficiency for fly ash deposition at high temperatures

The tendency of ash particles to stick under high temperatures is dictated by the ash chemistry, particle physical properties, deposit surface properties and furnace operation conditions. A model has been developed in order to predict the particle sticking efficiency for fly ash deposition at high temperatures. The model incorporates the particle properties relevant to the ash chemistry, particle kinetic energy and furnace operation conditions and takes into consideration the partial sticking behaviour and the deposit layer. To test the model, the sticking behaviours of synthetic ash in a drop tube furnace are evaluated and the slagging formation from coal combustion in a down-fired furnace is modelled. Compared with the measurements, the proposed model presents reasonable prediction performance on the particle sticking behaviour and the ash deposition formation. Through a sensitivity analysis, furnace operation conditions (velocity and temperature), contact angle and particle size have been found to be the significant factors in controlling the sticking behaviours for the synthetic ash particles. The ash chemistry and furnace temperature dictate the wetting potential of the ash particles and the melting ability of the deposit surface; particle size and density not only control the particle kinetic energy, but also affect the particle temperature. The furnace velocity condition has been identified as being able to influence the selective deposition behaviour, where the maximum deposition efficiency moves to smaller particles when increasing the gas velocity. In addition, the thermophoresis effect on the arrival rate of the particles reduces with increasing the gas velocity. Further, increasing the melting degree of the deposit layer could greatly enhance the predicted deposition formation, in particular for the high furnace velocity condition.     

The Effect of Boundary Conditions on Gas-phase Synthesised Silver Nanoparticles

We have prepared spherical non-agglomerated silver nanoparticles by an evaporation–condensation–dilution/cooling technique. Silver was evaporated from a crucible in a tubular flow reactor. A porous tube diluter was used to quench the carrier gas at the outlet of the reactor to enhance the formation of small particles and to suppress agglomeration and other particle growth mechanisms. The number size distribution of the prepared particles was measured with a differential mobility analyser–condensation nucleus counter combination and the size and the shape of the particles were analysed with transmission electron microscope. The system was modelled using a sectional aerosol dynamics computer code to estimate the importance of different aerosol processes. In all conditions the particles obtained were non-agglomerated and spherical. The mean particle diameter varied from 4 to 10-nm depending on boundary conditions. From the modelling studies it can be concluded that the nucleation rate is the most important parameter controlling the final particle size.     

Preparation of WO3 nanoparticles and application to NO2 sensor

WO₃ nanoparticles were prepared by evaporating tungsten filament under a low pressure of oxygen gas, namely, by a gas evaporation method. The crystal structure, morphology, and NO₂ gas sensing properties of WO₃ nanoparticles deposited under various oxygen pressures and annealed at different temperatures were investigated. The particles obtained were identified as monoclinic WO₃. The particle size increased with increasing oxygen pressure and with increasing annealing temperature. The sensitivity increased with decreasing particle size, irrespective of the oxygen pressure during deposition and annealing temperature. The highest sensitivity of 4700 to NO₂ at 1 ppm observed in this study was measured at a relatively low operating temperature of 50 °C; this sensitivity was observed for a sensor made of particles as small as 36 nm.     

A new technique for the measurement of the product CO/CO2 ratio at the surface of char particles burning in a fluidized bed

A new experimental technique is proposed to measure the product CO/CO₂ ratio at the surface of spherical char particles during fluidized bed combustion. It is based on the measurement of the burning rate of a single char particle under low oxygen concentration conditions and on the use of an accurate prediction of the particle Sherwood number. This technique was applied to spherical char particles obtained from a bituminous coal which is characterized by a low attrition and fragmentation propensity. The product CO/CO₂ ratio was measured at a bed temperature of 850 °C and at a fluidization velocity of 0.3 m/s in a lab-scale apparatus operated with a bed of 0.5–0.6 mm sand. The char particle size was varied between 2 and 7 mm and the inlet oxygen concentration between 0.1% and 2.0%. Results showed that under the experimental conditions investigated carbon was mostly oxidized to CO₂ within the particle boundary layer, with a maximum fraction of carbon escaping as CO of 10–20% at the lowest oxygen concentrations and largest particle sizes.     

High-order non-uniform grid schemes for numerical simulation of hypersonic boundary-layer stability and transition

The direct numerical simulation of receptivity, instability and transition of hypersonic boundary layers requires high-order accurate schemes because lower-order schemes do not have an adequate accuracy level to compute the large range of time and length scales in such flow fields. The main limiting factor in the application of high-order schemes to practical boundary-layer flow problems is the numerical instability of high-order boundary closure schemes on the wall. This paper presents a family of high-order non-uniform grid finite difference schemes with stable boundary closures for the direct numerical simulation of hypersonic boundary-layer transition. By using an appropriate grid stretching, and clustering grid points near the boundary, high-order schemes with stable boundary closures can be obtained. The order of the schemes ranges from first-order at the lowest, to the global spectral collocation method at the highest. The accuracy and stability of the new high-order numerical schemes is tested by numerical simulations of the linear wave equation and two-dimensional incompressible flat plate boundary layer flows. The high-order non-uniform-grid schemes (up to the 11th-order) are subsequently applied for the simulation of the receptivity of a hypersonic boundary layer to free stream disturbances over a blunt leading edge. The steady and unsteady results show that the new high-order schemes are stable and are able to produce high accuracy for computations of the nonlinear two-dimensional Navier–Stokes equations for the wall bounded supersonic flow.     

Kr-PLIF for scalar imaging in supersonic flows

Experiments were performed to explore the use of two-photon planar laser-induced fluorescence (PLIF) of krypton gas for applications of scalar imaging in supersonic flows. Experiments were performed in an underexpanded jet of krypton, which exhibited a wide range of conditions, from subsonic to hypersonic. Excellent signal-to-noise ratios were obtained, showing the technique is suitable for single-shot imaging. The data were used to infer the distribution of gas density and temperature by correcting the fluorescence signal for quenching effects and using isentropic relations. The centerline variation of the density and temperature from the experiments agree very well with those predicted with an empirical correlation and a CFD simulation (FLUENT). Overall, the high signal levels and quantifiable measurements indicate that Kr-PLIF could be an effective scalar marker for use in supersonic and hypersonic flow applications.     

On the outflow conditions for spectral solution of the viscous blunt-body problem

The purpose of this paper is to study and identify suitable outflow boundary conditions for the numerical simulation of viscous supersonic/hypersonic flow over blunt bodies, governed by the compressible Navier–Stokes equations, with an emphasis motivated primarily by the use of spectral methods without any filtering. The subsonic/supersonic composition of the outflow boundary requires a dual boundary treatment for well-posedness. All compatibility relations, modified to undertake the hyperbolic/parabolic behaviour of the governing equations, are used for the supersonic part of the outflow. Regarding the unknown downstream information in the subsonic region, different subsonic outflow conditions in the sense of the viscous blunt-body problem are examined. A verification procedure is conducted to make out the distinctive effect of each outflow condition on the solution. Detailed comparisons are performed to examine the accuracy and performance of the outflow conditions considered for two model geometries of different surface curvature variations. Numerical simulations indicate a noticeable influence of pressure from subsonic portion to supersonic portion of the boundary layer. It is demonstrated that two approaches for imposing subsonic outflow conditions namely (1) extrapolating all flow variables and (2) extrapolation of pressure along with using proper compatibility relations are more suitable than the others for accurate numerical simulation of viscous high-speed flows over blunt bodies using spectral collocation methods.     

Characteristics of conjugate heat and mass transfer in the flow of supersonic and hypersonic streams over blunt bodies

Problems associated with the formulation and solution of problems of conjugate heat and mass transfer in the supersonic and hypersonic motion of bodies are considered. The influence of the blunting geometry in streamline flow at different angles of attack, with gas injection into the shock layer, on the aerodynamic characteristics and the characteristics of heat and mass transfer is analyzed.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 82–95, August, 1992.     

Correction factors for a total scatter/backscatter nephelometer

Total aerosol scattering and backscattering atmospheric values are typically obtained with an integrating nephelometer. Due to design limitations, measurements do not cover the full (0°–180°) angular range, and correction factors are necessary. The effect of angle cutoff is examined for a number of particle size distributions and refractive indices. Scattering data for sub-micron particles can be corrected by the use of a modified Anderson approximation, while data for larger particle distributions can be approximated by a function of the effective size parameter. Correction factors for the hemispheric backscatter ratio are found to be small if nonsphericity is assumed. Such approximations will help more accurate corrections for angle range, particularly at large size parameter values.     

Shape Memory Effect and Superelasticity in Ti–Ni and Fe–Ni–Co–Ti Single Crystals

The dependence of shape memory effect and superelasticity on the crystal orientation, size, and particle volume fraction is studied for Ti–Ni and Fe–Ni–Co–Ti single crystals. The shape memory effect and superelasticity are shown to decrease with increase in the particle volume fraction and depend on the number of crystallographic variants of particles that can vary due to aging under loading. The influence of disperse particles undergoing no martensite transformations on the martensitic crystal growth and their fine structure is examined.     

The improvement of turbulence modeling for the aerothermal computation of hypersonic turbulent boundary layers

The engineering computation of turbulent flows is mainly based on turbulence modeling,however,accurate aerothermal computation of hypersonic turbulent boundary layers is still a not well-solved problem. Aerothermal computation for turbulent boundary layers on a supersonic or hypersonic blunt cone with small bluntness is done firstly by using both direct numerical simulation and BL model,and seven different cases are investigated. Then the results obtained by the two methods are compared,and the reason causi...     

Numerical simulation of modes of combustion and detonation of hydrogen-air mixtures in porous medium in the framework of the mechanics of two-phase reaction mediums

Numerical simulation is carried out for combustion and detonation waves propagating through a motionless gas mixture in a porous inert charge. Computations are performed in a one-dimensional approximation by means of an EFAE computer program that was developed in the framework of the mechanics of multiphase reaction mediums. The chemical conversion of gas is modeled by a one-stage reaction of the Arrhenius type with constants selected based on existing experimental data on the ignition lags behind the reflected shock waves. Computations are performed for hydrogen-air mixtures with 35 and 15% hydrogen and compared with literature experimental data in which the initial pressure and the diameter of charged particles are varied. All three combustion modes (slow, fast, and supersonic) observed in the experiment and combustion failure under conditions lower than threshold are followed by numerical simulation. In addition, the computations qualitatively reproduced experimental data on the change of the combustion mode in the case of transfer from stoichiometric to a lean mixture and data on the combustion wave velocity and limiting conditions of combustion mode transition and failure of flame as a function of the initial pressure and the charged particle size. It is shown that supersonic waves propagating with a velocity of lower than 1100 m/s do not have a Chapman-Jouguet surface in the end of the reaction zone and it is evident that they can be related to detonation, as in the cited literature.     

Conical separation zone formation at impingement of supersonic jet on obstacle under cold spraying

Impingement of supersonic jet upon substrate surface, in front of which conical separation zone is created artificially with the aid of a spike or particle under conditions typical of cold spraying on geometric and dynamic parameters, is considered. Numerical simulation is carried out. Simulation results are in qualitative agreement with experimental observation data. Preliminary analysis of obtained pattern of supersonic jet impingement shows that in local ring area, creation of more favorable conditions for cold spraying of fine particles sized 1 micron or less is possible comparing to typical conditions.     

Evolution of the Structure and Carbon Atom Transfer in the Zone of Fatigue Crack Growth in Ferrite-Pearlite Steel

Structure and phase transformations in Fe–0.6C–1Mn–2Si steel subjected to multicyclic fatigue tests under normal conditions and with intermediate electrostimulation are investigated by the methods of metallography of etched microsections and scanning and transmission electron diffraction microscopy of thin foils and carbon replicas. It is demonstrated that fatigue failure under normal loading is preceded by complete dissolution of initial cementite particles with carbon localized on structural defects (dislocations, subboundaries, and boundaries), micropores, and microcracks. Electrostimulation, promoting the relaxation of stress concentrators through dissolution of particles localized on the grain boundaries and the state change of the interphase boundaries between the matrix and second-phase particle, causes the mean and maximum subcritical crack length to increase together with the thickness of the sample layer involved in the strain of the material and the zone of fatigue crack growth. This is accompanied by a significant increase in the operating lifetime of the material.     

Comparison of electrostatic fine powder coating and coarse powder coating by numerical simulations

Powder coating has several key advantages over liquid coating, and fine powder coating makes the surface finish quality comparable with liquid coating. This work reports on the numerical simulation of a fine powder-coating process in comparison with coarse powder coating, using a commercial computational fluid dynamic code, Fluent v6.1. The purpose of the study is to understand the gas and particle flow fields inside the coating booth for various operating conditions and the effect of reducing particle size on the coating process. The air and powder particle flows in a coating booth were modeled as a three-dimensional turbulent continuous gas flow with solid particles as a discrete phase. The continuous gas flow was calculated by solving the Navier–Stokes equations, including the standard k–ε turbulence model with non-equilibrium wall function. The discrete phase was modeled based on the Lagrangian approach. In addition to drag force and gravity, the electrostatic force including the effect of space charge due to free ions was considered in the equation of motion and implemented using user-defined scalars and user-defined functions. The governing equations were solved using a second-order upwind scheme. This study demonstrates that the use of finer particles of size 15 μm or lower can give a very smooth and uniform surface finish, which may serve the requirement of automotive top-clear coating. This also provides useful information about optimum operating conditions such as the airflow rate, the applied external voltage and the powder-spray rate. The numerical model can also be used to optimize the gun-booth design for a better coating efficiency.     

Measurement of particle velocity and characterization of deposition in aluminum alloy kinetic spraying process

Particle velocity is a very important parameter in kinetic spraying (or cold gas dynamic spraying). It is difficult to measure the velocity of a particle with supersonic speed at low temperature (lower than 500 °C). Thus, in many investigations only estimated values are used for evaluating coating processes. In this paper, the modeling of particle acceleration was reviewed, and the measurement of in-flight particle velocity in a kinetic spraying process was performed. Particle velocity and flux distributions from different process gas temperatures and pressures were investigated. The influences of process gas temperature and pressure on particle velocity were discussed. Characteristic of Al-Si feedstock deposition onto a mild steel substrate was described by comparing coatings structures with the in-flight particle conditions. The deposition behavior showed two critical particle velocities for Al-Si powder deposition onto a substrate and for particle-particle bonding.     

Rigorous bounds on the radiative interaction between real gases and scattering particles

The radiative interaction due to the simultaneous presence of a real (non-gray) gas and isotropically scattering particles is examined rigorously for an isothermal plane layer, allowing completely general, frequency-dependent gas and particle radiative properties. A correction factor is defined to characterize the effects of interaction on the total hemispherical emittance of the layer, and rigorous bounds on the correction factor are determined, using the exact normal mode expansion technique of Case. It is shown that, under certain conditions for high albedo particles, interaction effects may lead to a slight enhancement of the total hemispherical emittance of the gas/particle mixture, compared to the sum of the emittances for the gas and particles considered separately, with the maximum enhancement possible being 3.2%. Under most conditions, however, the presence of the particles would be expected to shield the gas emittance. These rigorous bounds on the extent of the interaction effects are in contrast to the results of a previous numerical study, which predicted strong enhancement effects (nearly 100% enhancement for some cases) due to gas/particle radiative interaction.     

气载放射性微粒在真实人体上呼吸道模型内沉积特性的研究

基于人体医学CT扫描,重建得到"鼻腔-咽喉主气管-六级支气管"三维几何模型;采用大涡模拟和离散相模型的描述颗粒运动,并在拉格朗日框架下跟踪颗粒。考察了四种气载放射性微粒在典型呼吸强度下的运动和沉积。结果表明:在各工况下,气载放射性颗粒在呼吸道内运动受流道变化、缩放效应、呼吸强度和阻流面等影响较大,均呈现出明显的积聚性和沉积的高度不均匀性,易形成局部沉积热点。在4个弯曲面、2个缩放管结构区域以及支管分叉面出现大量颗粒沉积。气载放射性颗粒的沉积热点区域将导致人体组织细胞的应激反应,造成组织和器官的辐射损伤。颗粒的沉积率随粒径和呼吸强度的增加而增加,但粒径小于0.5μm后,沉积率呈相反趋势。大颗粒在呼吸道内受流道变化、呼吸强度和阻流效应等影响较大,小颗粒受布朗运动和斯坦夫升力影响更显著。