High energy x-ray satellites ofL 2,3 emission bands of Na,Mg, Al,and Si

The x-ray satellites found on the high energy sides of theL _2,3 emission bands of Na, Mg, Al, and Si have previously been attributed to the radiative decay of double ionization states. However, in some recent papers it has been proposed that the satellites in Al and Si may arise from the simultaneous radiative decay of a core ionization state and a volume plasmon. A detailed investigation of the high energy satellites of theL _2,3 x-ray emission bands of Na, Mg, Al, and Si have been made for incident electron energies from 500 eV to 5 keV and the results compared with the double ionization theory. Plasmon involvement is also considered. The present results lend additional support to the first interpretation; namely, that the satellites arise from the radiative decay of atoms with a double vacancy in theL _2,3 (2p) shell and not from the plasma phenomenon.     

L-subshell fluorescence and coster-kronig yields atZ=92 and the decay of235Np

TheK andL x-rays emitted in the decay of²³⁵Np have been studied with high resolution Ge(HP) and Si(Li) detectors in coincidence, in order to obtain theL ₂ andL ₃ subshell fluorescence and Coster-Kronig yields atZ=92. The results are:v ₂=0.630±0.036, ω₂=0.560±0.033,f ₂₃=0.147±0.010, and ω₃=0.481±0.029. Results for theL ₁ subshell were derived from singles spectra, by assuming a value off ₁₃ of 0.67, and are:v ₁=0.54±0.04, ω₁=0.21±0.04, andf ₁₂<0.07. With the same assumption, theL ₁/K electron capture ratio and decay energyQ _ec for²³⁵Np were found to be 29.0±3.6 and 123.6±0.7 keV, respectively. RelativeL x-ray intensities forZ=92 also were measured and are compared with the theory of Scofield and with recent diffraction experiments. Electron ejection from theL shell during²³⁵Np decay has been studied byL x-ray-L x-ray coincidences and found to occur with a probability of (1.3±1.0) × 10^?4 per disintegration.     

TheL 1 subshell fluorescence and Coster-Kronig yields forZ=96

High resolution Si(Li)-Si(Li) and Si(Li)-Ge(Li) detector arrangements have been used to studyL x-ray spectra in coincidence withL-shell internal conversion electrons, gamma rays, andK x-rays emitted in²⁴⁹Cf decay. TheL ₁ subshell fluorescence and Coster-Kronig yields determined forZ=96 from these spectra are ω₁=0.25±0.06,f ₁₂≦0.10, andf ₁₃=0.69 ±0.08. The presence of theL ₁-L ₃ radiative transition is also further confirmed in this work.     

L 1 subshell yields atZ=73 from the electron capture decay of181W

The TaL x ray spectrum from the electron capture decay of¹⁸¹W is analyzed into components characteristic of the threeL-subshells and theL ₁ subshell yields atZ=73 are determined to beΩ ₁=0.15±0.02,f ₁₂=0.23±0.05 andf ₁₃=0.32±0.02. A revised decay scheme for the decay of¹⁸¹W is proposed from measurements of x-ray and gamma intensities. A value of 0.97±0.08 for theK-conversion coefficient of the 153 keV transition is obtained and itsE ₂/M ₁ multipolarity mixing ratio,δ ²(0.25) is deduced.     

Fine structure of LiI (n=4–7)d 2 D-terms by beam-foil quantum-beat spectroscopy

L-subshell fluorescence yields of lead are determined in a series of experiments where lead atoms in lead tetraethyl, Pb(C₂H₅)₄, in a small admixture to the propane in proportional counter are ionized in theL-shell by a beam of monochromatic X-rays. The technique of selective photoexcitation of consecutive subshells is applied and fluorescence events are resolved into subshell contributions. The subshell fluorescence yields are determined asω _LI=0.16±0.04,ω _LII=0.407±0.010 andω _LIII=0.347±0.005.     

X-ray production by 1.5–11 MeV protons

K-shell ionization andL x-ray production cross-sections by proton impact have been determined from measurements ofK x-ray yields from thin targets of Ti, Fe, Co, Cu, Ni and Ag and ofL x-ray yields from Au and Pb. The proton energies varied from 1.5 to 11 MeV. A Si(Li) semiconductor detector recorded the x-rays. The total error in the measured cross-sections is mostly less than 5%.K _β /K _α ratios andL _l,β,γ /L _α ratios have been determined. Ionization cross-sections have been compared with predictions of the plane-wave Born approximation (PWBA) and the binary-encounter approximation (BEA). Both theories describe the ionization quite well: PWBA is, however, better for higher proton energies whereas BEA is superior for lower energies. An empirical formula for ionization cross-sections is derived.     

L X-ray energy shifts and intensity ratios in tantalum with C and N ions — multiple vacancies in M, N and O shells

The energy shifts and intensity ratios of different L X-ray components in tantalum element due to 10 MeV carbon and 12 MeV nitrogen ions are estimated. From the observed energy shifts, the possible number of simultaneous vacancies in M shell are estimated. A comparison of L _α /L _β2.15, L _β1/L _γ1 and L _γ2.3/L _γ4.4 with the ratios due to Scofield theoretical transition rates indicate that the number of multiple vacancies in N shell are higher than the vacancies in M and O shell. Employing Larkin’s statistical scaling procedure, the number of possible multiple vacancies in N and O shells are estimated quantitatively.     

X-Ray Fluorescence Determination of the Composition of Chalcogenide Glasses

A procedure of x-ray spectroscopic fluorescence determination of the composition of chalcogenide glasses As _x S_100–x is developed, and its metrological characteristics are established. The magnitude of relative standard deviation in determining the content of the components does not exceed 0.003, and the results of x-ray spectroscopic fluorescence analysis (RSFA) agree well with the data of a gravimetric method.     

L-shell ionization of atoms by relativistic electrons

A theoretical study of theL-shell ionization of atoms by relativistic electrons is made for atomic numbers in the range 47 to 92. A new potential model recently proposed by Das and Chakraborty dealing with atomic screening effect in a better way has been used. The results are in satisfactory agreement when compared with some available experimental results and also with the theoretical results of Scofield.     

Lorentz ionization of atoms in a strong magnetic field

Lorentz ionization emerges due to the motion of atoms or ions in a strong magnetic field. We use the semiclassical approximation to calculate the probability w _L of Lorentz ionization. We also find the stabilization factor S, which takes into account the reduction by the magnetic field of the probability of ionization decay of the bound s state. We estimate the probabilities w _L in magnetic-cumulation experiments and in astrophysics. We also qualitatively examine the dynamics of the magnetic cumulation process with allowance for the conductivity of the shell. Finally, we discuss a paradox related to the use of the quasistationary solution at the shell expansion stage. Zh. éksp. Teor. Fiz. 115, 1642–1663 (May 1999)     

L 2 andL 3 subshell fluorescence and Coster-Kronig yields forZ=96 from the decay of249Cf

TheL ₂ andL ₃ subshell fluorescence and Coster-Kronig yields forZ=96 have been measured by theK-L x-ray coincidence method with high resolution Si(Li) and Ge(Li) x-ray detectors. The results ν₂=0.650±0.036, ω₂=0.552±0.032, ω₃=0.515±0.034, andf ₂₃=0.188±0.019 agree fairly well with theory. New measurements of theL x-ray singles spectra of²⁴⁴Cm and²³⁸Pu with a high resolution Si(Li) detector permitted reevaluation of the values of ω₂ andf ₂₃ forZ=92 and 94 reported by Byrneet al. The revised values atZ=92 are ω₂=0.529±0.035 andf ₂₃=0.23±0.12, and atZ=94, ω₂=0.523±0.023 andf ₂₃=0.24±0.08. These revised values are in much better agreement with theory and with current experiments.     

Elastic scattering of a photon by an atom with an open shell

In the nonrelativistic approximation, the absolute values and the forms of the differential cross sections of the anomalous elastic scattering of a linearly polarized x-ray photon by manganese and copper atoms in the energy region of the ionization threshold of the 1s shell are calculated for the wave functions of one-electron states. We take into account the multiparticle effects of relaxation of atomic shells in the field of core vacancies, multiplet splitting, the configuration interaction, and Auger and radiative decays of vacancies, as well as the processes of double excitation/ionization of the ground state of the atom. The calculation results are in good agreement with the synchrotron experiment.     

L-subshell ionization cross sections for Au,Pb, and Bi by 60–600 keV electron impact

TheL ₁-,L ₂- andL ₃-subshell ionization cross sections of Au, Pb and Bi by 60–600 keV electron impact have been determined from the measured x-ray production cross sections. The experimental results have been compared with the relativistic PWBA, the Binary Encounter Approximation (BEA) and the Kolbenstvedt Approximation (KA) calculations. These calculations, especially the relativistic PWBA, give good agreement with the experimental data for theL ₃-subshell. For theL ₁- andL ₂-subshells there are some deviations and these can explain the disagreement observed for theL _α/L _χ- andL _γ/L _χ intensity ratios.     

Local geometry and electronic structure of free NaCl clusters

Experimental x-ray spectra of the Cl L _{2, 3} absorption edge for free NaCl clusters of various sizes are presented. X-ray absorption spectra of the Na₄Cl₄ cluster have been theoretically calculated by the total multiple scattering method. A distorted cube is determined as the most probable geometric structure of the Na₄Cl₄ cluster. Curves of the partial densities of states are obtained for the cluster.     

Electron capture decay of181W: L subshell fluorescence and Coster-Kronig yields in Ta

The TaL x-ray spectrum from the 140 d electron capture decay of¹⁸¹W was studied with high resolution semiconductor detectors and fast coincidence techniques. Measurement ofL x-ray-K x-ray andL x-ray—γ-ray coincidence rates yielded the followingL shell fluorescence and Coster-Kronig yields and radiative decay branching ratios: ω₂=0.250±0.013, ω₃=0.228±0.013 (corrected for angular correlation effects),f ₂₃=0.180±0.007,v ₁=O.218±0.016,s ₃=0.205+-0.010,s ₂=0.215+-0.010,f ₁₃+f ₁₂ f ₂₃=0.36+-0.02, and ω₁+f ₁₂ω₂=0.14±0.02, from which upper limits were obtained off ₁₃<0.36 and ω₁<0.14.     

Gas-phase synthesis of nitrogen-containing carbon nanotubes and their electronic properties

Nitrogen-containing carbon nanotubes are synthesized using a gas-phase reaction. The synthesis of nitrogen-doped carbon nanotubes from 100 to 500 Å in diameter is accomplished through pyrolysis of acetonitrile (CH₃CN) at a temperature of 800°C. Cobalt and nickel metallic particles formed upon thermal decomposition of a mixture of maleate salts are used as catalysts. The materials synthesized are investigated by scanning and transmission electron microscopy. Analysis of the x-ray photoelectron spectra demonstrates that the content of nitrogen atoms in three nonequivalent charge states is approximately equal to 3%. A comparison of the CK _α x-ray fluorescence spectrum of the carbon nanotubes synthesized through electric-arc evaporation of graphite and the x-ray fluorescence spectrum of the nitrogen-containing carbon nanotubes prepared by catalytic decomposition of acetonitrile indicates that, in the latter case, the spectrum contains a certain contribution from the sp ³ states of carbon atoms. The temperature dependences of the electrical conductivity for different types of multi-walled carbon nanotubes are compared. The difference observed in the temperature dependences of the electrical conductivity is associated with the presence of additional scattering centers in nitrogen-containing carbon nanotubes.     

TG/DTA evidence of fluorine incorporation into YBa2Cu3O6⋅+δ

TG/DAT evidence to support incorporation of fluorine into superconducting orthorhombic lattice in YBa₂Cu₃O_6⋅+δ is presented. It is inferred that the F atom goes substitutionally in place of O atom in the lattice. Replacement of two oxygen atoms by four fluorine atoms did not alter theT _cof the product. By a similar replacement of two of its oxygens by fluorine atoms, the tetragonal modification of the oxide yields a product that remains non-superconducting down to 30 K.     

Experimental investigation of angular dependence of photon induced L-shell X-ray emission intensity

The angular dependence of emission intensity of L shell X-rays induced by 59.57 keV photons in Pb and U is investigated by measuring the normalized intensities of the resolved L X-ray peaks at different angles varying from 40° to 120°. It is observed that while L _l and L_α X-ray peaks (originating fromJ = 3/2 state) show some anisotropic angular distribution, the emission of L_β and L_γ X-ray peaks is isotropic. The present results contradict the calculations of Co-oper and Zare (1969) that after photoionization of inner shell, the vacancy state has equal population of magnetic substates and the subsequent X-ray emission is isotropic but confirm the predictions of Fluggeet al (1972) that the atomic inner shell vacancies produced after photoionization are aligned and the x-ray emission from the filling of vacancies in state withJ ⩾ 3/2 is anisotropic.     

X-Ray Luminescence of Defects in Spinel Single Crystals

The flareup of x-ray luminescence in spinel single crystals (MgAl₂O₄) depending on the time of x-ray irradiation and the decay of fluorescence depending on the time elapsed after the termination of irradiation have been investigated. These dependences were measured at different powers of the irradiation dose (power of the x-ray tube) and at different temperatures of the samples. The experimental results suggest the existence of large-size complexes of defects, which include antisite defects and impurity ions, the exchange of charge carriers between which during and after irradiation leads to luminescence of the impurity ions. Transfer of charge carriers between isolated elements of the pairs of antisite defects (not interacting with the impurity ions) leads to the formation of a competing channel of recombination luminescence in the UV region of the spectra. The decay of fluorescence attributable to transitions in the Mn²⁺ and Cr³⁺ ions depending on the time elapsed after the termination of x-ray irradiation points to the existence of various combinations of antisite defects in the surroundings of these ions.     

Transition metal oxide perovskites by photoelectron and x-ray absorption spectroscopy

X-ray and ultraviolet photoelectron spectroscopy as well as x-ray absorption spectroscopy have been employed to investigate transition metal oxide perovskites of the general formula ABO₃ (A = La or rare-earth ion, B=trivalent transition metal ion). Systematics in the core levels and in the valence bands in the series of LaBO₃ compounds have been discussed. Lanthanum chemical shifts in the x-ray absorption spectra in this series show interesting trends. Photoelectron spectra of the solid solutions, LaNi_1−x Co _x O₃, LaNi_1−x Fe _x O₃ and LaFe_1−x Co _x O₃ show that the rigid band model is applicable to these systems. It is shown that x-ray photoelectron spectroscopy can be employed to identify multiple oxidation states of transition metal ions in oxide perovskites. Communication No. 30 from the Solid State and Structural Chemistry Unit. An erratum to this article is available at .