Characterization of Submillimeter Wave Absorbers from 200–600 GHz

This paper presents measurements of both specular and non-specular scattering from several submillimeter wave absorber materials designed for antenna testing and from low-cost carpet materials. The frequency range is 200–600 GHz in specular scattering, and 300–400 GHz in non-specular scattering measurements. The constructed bistatic test bench allows testing of the full continuous angular range of 0°–90°. The measurement results show large differences in performance of different materials. It is shown that reflectivities below –50 dB over limited angular ranges are possible with a correct alignment of the material. Also, low-cost carpet materials have lower than –15 dB reflectivities in most angles, and may be useful in non-critical parts of the antenna test range. The results can be used to optimise the absorber placement inside an antenna range, concerning both best performance and lowest cost.     

Measurement of the dielectric constant of a shock tube plasma

Measurements of the electrical characteristics of the plasma in waveguide and coaxial shock tubes over the frequency range 200–7300 MHz are reported.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 27–31, February, 1974.     

A study of the infrared spectra of carbon monoxide adsorbed on metals of the copper subgroup and on cobalt,ruthenium, rhodium,and palladium

A study has been made of the infrared spectra of carbon monoxide CO, adsorbed on Cu, Ag, Au, Co, Ru, Rh and Pd at temperatures from –160° C to 200° C and pressures from 10^–5 to 1–10 mm Hg. The spectra of CO adsorbed on Cu, Ag, and Au show one absorption band, characteristic of a surface compound of carbon monoxide, with linear structure. It has been found that in the stable chemosorption of CO on Co, Ru, Rh, and Pd in the range of temperatures and pressures studied, two types of surface compound-linear and bridged-are produced.     

Frequency dependence of propagation time and total losses of magnetoelastic waves in single crystals of yttrium-iron-gallium garnets

The possibility of using single crystals of yttrium-iron-gallium garnets (YIGG) as media for the propagation of magnetoelastic waves in the long-wave region of the uhf range is considered. Frequency dependences are obtained for the total losses and the maximum controllable lag for YIGG single crystals with various levels of saturation magnetization. An empirical formula relating the specific damping of magnetoelastic waves with the saturation magnetization and frequency is proposed. The possibility of choosing a YIGG composition optimal for a given frequency in the range 200–2000 MHz is demonstrated.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 61–65, March, 1977.     

Fine structure of the light absorption spectrum of antiferromagnetic NaMnCl<Subscript>3</Subscript>

A fine structure of the optical absorption spectrum of antiferromagnetic NaMnCl₃ was measured around 23800 cm^–1 at temperatures in the range 1.8–50 K in magnetic fields up to 200 kOe. The fact that the intralayer ferromagnetic interaction in the crystal possessing a layered magnetic structure is stronger than the interlayer antiferromagnetic interaction leads to the formation of intensive hot exciton-magnon absorption bands. The special features of the exciton-magnon band structure in the crystal are connected with the special features of magnon dispersion and density of exciton-magnon states.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 23–28, October, 2004.     

Distinctive features of creep in silicon whiskers

The phenomenon of creep in silicon whiskers has been studied in the temperature range 300–1100°K at stresses (0.1–5)·10⁸ N·m^–2. On the basis of the tests, analysis of the fine structure of the creep curves, and studies on the crystal structure, the conclusion is drawn that the creep observed in silicon whiskers is due to the heterogeneous nucleation of dislocations at stress concentration sites with the participation of thermal fluctuations.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 10, pp. 31–35, October, 1981.     

General intense electron beams by means of a contracted arc discharge

Two types of contracted arc discharge are investigated with a view to generating intense electron beams over a wide pressure range (1–10^–3 Pa). For an arc discharge with a hollow cathode and anode, an electron beam corresponding to a current of up to 300 A and a pulse length of 25 µsec is obtained at a pressure of 1–10^–1 Pa in the accelerating gap with an accelerating voltage of up to 15 kV. At pressures of 10^–2–10^–3 Pa, emitting plasma is created by a low-pressure arc discharge on the basis of a Penning cell. Three discharge systems operating in parallel are used to increase the working life of the cathode and improve the current density distribution of the beam. An electron beam of diameter 200 mm with a current of up to 125 A and a pulse length of 50 µsec is obtained.Institute of High-Power Electronics, Siberian Branch, Russian Academy of Sciences. Translated from Izvestiya Vysshkikh Uchebnykh Zavedenii, Fizika, No. 3, pp. 76–82, March, 1994.     

Compact Atomic-Absorption Graphite-Atomizer Spectrometer

This paper describes the principle of operation and the technical characteristics of the Gelios atomic-absorption spectrometer with a graphite-atomizer. As a pulsed resonance radiation source, hollow-cathode lamps are used. Nonselective noise compensation is performed by a DDS-30 deuterium corrector operating in the pulsed mode as well. The detection limit varies from 10^–6 to 10^–8 and depends on the elements being investigated. The reproducibility is 2–3%. The spectral range is 200–700 nm. The minimum resolvable spectral interval is 0.5 nm.     

The low-frequency spectra of some low-melting organic crystals of randomly disordered structure

Raman spectra at 0–200 cm^–1 are presented for cyclopentane and cyclohexane in different crystalline forms. The spectra in this range are discrete for the modifications of lower symmetry, whereas the higher disordered forms give a continuum, which for cyclopentane bears several maxima. These maxima are assigned from theory to translational motions of the molecule in the lattice, which most probably has space group C _6v ⁴ .     

Synthesis of wurtzite-phase ZnS nanocrystal and its optical properties

The wurtzite phase of ZnS nanocrystal has been prepared by annealing in 200–600 °C temperature range, its cubic phase of 2–3 nm size, prepared through soft chemical method. Results of isochronal experiments of 2 h at different temperatures indicate that visible transformation to wurtzite from cubic ZnS appears at a temperature of 400 °C, which is about three times smaller than that of bulk ZnS phase transition temperature. The phases, nanostructures, and optical absorption characteristics are obtained through X-ray diffraction, transmission electron microscopy, and UV–visible absorption spectroscopy. A stable and green photoluminescence emission peaked at 518 nm is observed from the 600 °C annealed samples, under ultraviolet light excitation.     

Radiation of the Plasma of a Transverse Discharge in a Helium–Krypton–Elegas Mixture

We carried out a spectroscopic investigation of the degradation of the active medium of a pulsed-periodic KrF emitter based on a He/Kr/SF₆ mixture (P = 10–150 kPa) with pumping by a transverse volumetric discharge. The plasma radiation spectra in the range 200–620 nm at different stages of degradation of the working mixture and the dynamics of the radiation of inert gases as well as of the products of decomposition of SF₆ molecules in the plasma are studied. It is shown that since the number of discharge pulses is 10⁴, rather effective formation of excited sulfur molecules is observed which decompose with emission in the spectral range 260–550 nm. This can be employed for developing a wideband lamp based on the system of KrF(B–X; D–X), S₂(B–X), and S₂(f–a) bands.     

Electrical conduction properties of Si δ-doped GaAs grown by MBE

The temperature dependent Hall effect and resistivity measurements of Si δ-doped GaAs are performed in a temperature range of 25–300 K. The temperature dependence of carrier concentration shows a characteristic minimum at about 200 K, which indicates a transition from the conduction band conduction to the impurity band conduction. The temperature dependence of the conductivity results are in agreement with terms due to conduction band conduction and localized state hopping conduction in the impurity band. It is found that the transport properties of Si δ-doped GaAs are mainly governed by the dislocation scattering mechanism at high temperatures. On the other hand, the conductivity follows the Mott variable range hopping conduction (VRH) at low temperatures in the studied structures.     

Theoretical study of effects on lasing characteristics from T1-Ti absorption spectra for coumarins and benzoxazinones

Quantum-chemical methods (PNDO) are used to consider the changes in the triplettriplet absorption spectra on substitution and H-bonding for coumarins and benzoxazinones in the range 200–800 nm. This defines the ways of optimum excitation (lamp or laser) and explains how the excitation technique affects the lasing performance. The results agree well with the few measurements and are correlated with the lasing characteristics.Paper presented at the All-Union Conference on Population Inversion and Lasing on Transitions in Atoms and Molecules, Tomsk, 1986.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 98–103, June, 1988.     

Infrared reflection spectra in contactless nondestructive measurements of the electron density and mobility in indium phosphide

On the basis of numerical calculations and experimental studies we analyze the possibilities of measuring the electrophysical parameters of indium phosphide by means of infrared reflection spectra at wavelengths ranging from 5 to 200 m. We demonstrate that contactless nondestructive measurements of the electron density in the range 10¹⁶–10²⁰ cm^–3 can be made with a relative error not exceeding 15%, and of mobility with a relative error not exceeding 25%. A nomogram method is presented for rapid conversion of data from infrared reflection spectra into the parameters being measured.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 1, pp. 22–27, January, 1988.     

Quantitative analysis of photoacoustic IR spectra

Photoacoustic spectroscopy is a method for directly measuring the absorption properties of gases and condensed matter. We have developed a photoacoustic gas cell for a rapid-scan Fourier spectrometer. With this cell we can extend the spectral range down to 180 cm^–1; more than one octave lower than previously reported useful broadband measurements. The photoacoustic spectrum of a microscope cover glass was measured from 180 ... 200 cm^–1 and normalized with respect to the spectrum of carbon black as a reference material. Starting from the one-dimensional equation of heat conduction we derived an expression for the surface temperature of single and double-layer samples. We calculated the surface temperature of the glass lamella and divided it by the corresponding values for carbon black using the thermal conductivity of carbon black as a fitting parameter. We show that the one-dimensional model calculation reproduces the experimental spectrum over the whole spectral range.     

Thermally Stimulated Electron–Hole and Ionic Processes in Zinc Oxide Crystals

The principal results of the investigation of thermally stimulated electron–hole and ionic processes in hydrothermal and gas-phase ZnO single crystals preexcited at low temperatures, based on simultaneous study of photo-EPR and thermoluminescence (TL), are presented. The nature of the traps determining the TL peaks at 17, 24, 40, 53, 90–110, 140–150, and 160–200 K is discussed. In particular, it has been established that the lithium paramagnetic centers (Li_Zn ⁺–O^I) play the role of hole traps in ZnO giving green and red TL in the temperature range 160–200 K and, in the case of association with small-sized donors, also TL in the temperature range 90–110 K. The other traps are electronic in character, and in the presence of acceptor lithium in the crystals, they form yellow-orange TL. Optical quenching of TL has been evaluated, and it has been found that there is a difference E 0.75 eV between the thermal and optical energies of ionization of lithium acceptors. Irreversible ionic processes associated with the healing of cationic vacancies at T 360–420 K have been revealed.     

The application of ultrasound radiation to the synthesis of nanocrystalline metal oxide in a non-aqueous solvent

Highly crystalline metal oxide nanoparticles of TiO₂, WO₃, and V₂O₅ were synthesized in just a few minutes by reacting transition metal chloride with benzyl alcohol using ultrasonic irradiation under argon atmosphere in a non-aqueous solvent. The sonochemical process was conducted at a relatively low temperature, 363 K. A unique crystallization process of these nanoparticles has been observed and characterized by powder X-ray diffraction (PXRD), high resolution scanning electron microscopy (HRSEM), and BET. The particles’ size and shape measured from HRSEM reveal “quasi” zero-dimensional, spherical TiO₂ particles in the range of 3–7 nm. The V₂O₅ particles have a “quasi” one-dimensional ellipsoidal morphology, with lengths in the range of 150–200 nm and widths varying between 40 and 60 nm. The WO₃ particles were obtained as “quasi” two-dimensional platelets with square shapes having facets ranging from 30 to 50 nm. The thickness of these platelets was between 2 and 7 nm. The mechanism of the reactions leading to these three metal oxide nanoparticles in a non-aqueous system is substantiated by Nuclear Magnetic Resonance (NMR), and Electron Spin Resonance (ESR).     

Absorption of subpicosecond ultraviolet laser pulses in high-density plasma

The absorption of 250 fs KrF laser pulses incident on solid targets of aluminum, copper and gold has been measured for normal incidence as a function of laser intensity in the range of 10¹²–10¹⁴ W cm^–2 and as a function of polarization and angle of incidence for the intensity range of 10¹⁴–2.5×10¹⁵ W cm^–2. As the intensity increases from 10¹² W cm^–2 the reflectivity at normal incidence changes from the low-intensity mirror reflectivity value to values in the range of 0.5–0.61 at 10¹⁴ W cm^–2. For this intensity maximum absorption of 63–80% has been observed for p-polarized radiation at angles of incidence in the range of 54°–57°, increasing with atomic number. The results are compared with the expected Fresnel reflectivity from a sharp vacuum-plasma interface with the refractive index given by the Drude model and also to numerical calculations of reflectivity for various scale length density profiles. Qualitative agreement is found with the Fresnel/Drude model and quantitative agreement is noticed with the numerical calculations of absorption on a steep density profile with normalized collision frequencies, v/, in the range of 0.13–0.15 at critical density and normalized density gradient scale lengths, L/₀, in the range of 0.018–0.053 for a laser intensity of 10¹⁴ W cm^–2.At 2.5×10¹⁵ W cm^–2 a small amount of preplasma is present and maximum absorption of 64–76% has been observed for p-polarized radiation at angles of incidence in the range of 45°–50°.Dedicated to Prof. Dr. Rudolf Wienecke on the occasion of his 65^th birthdayOn leave from: Department of Electrical Engineering, University of Alberta, Edmonton, T6G 2G7, Canada     

Measurement of photon energy and approach angle from an analysis of the tracks of the (e+e−) pair in a multilayer γ-telescope spark chamber

An investigation is made of the problems involved in measuring the characteristics of a photon in the energy range 5–200 MeV with a -telescope whose main recording element is a multilayer spark chamber with an inhomogeneous structure.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 6, pp. 55–58, June, 1979.     

Emission spectroscopy of flame fronts in aluminum suspensions

Spatially resolved emission spectra from Bunsen-type flames stabilized in aluminum suspensions in air and oxygen–argon/helium mixtures were obtained using a mechanical-optical scanning system. A low resolution (1.5 nm) spectrometer was used to acquire the broad spectra over the 350–1000 nm range, and a high-resolution (0.04 nm) instrument was used for observation of AlO molecular bands and non-ionized atomic aluminum. The temperature of condensed phase emitters in the flame was derived using polychromatic fitting of the continuum spectra to Planck’s law. AlO temperature was found by fitting of the theoretically calculated shape of the band to experimental data. Peak temperatures of the condensed emitters were found to be approximately 3250 K in aluminum-air flames and approximately 3350 K for oxygen–argon/helium flames. Temperatures derived from AlO spectra coincide with the temperature of the condensed emitters with measurement accuracy and are only 100–200 °C lower than the computed equilibrium flame temperatures. The radial distribution of the temperature profile of the continuous emitters was found via Abel deconvolution and recovered the double-front structure of the Bunsen flame cone, with the outer flame being attributed to a diffusion flame of the fuel-rich products with ambient air. The observation of atomic aluminum lines seen in emission from the outer flame edge and partial self-absorption from the inner flame confirms the structure associated with the double-front structure. The implications of these results for the regime of particle combustion in a dust flame are discussed.