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Soheila Chitsaz Dieter Fenske Olaf Fuhr 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2006,118(47):8224-8228
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Alexander Lorenz Dieter Fenske 《Angewandte Chemie (Weinheim an der Bergstrasse, Germany)》2001,113(23):4537-4541
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Anke Flemming Martin Köckerling Prof. Dr. 《Angewandte Chemie (International ed. in English)》2009,48(14):2605-2608
Complete exchange : [M6X12] type cluster compounds with an octahedral M6 metal atom arrangement, which is completely surrounded by alcoholato ligands, were unknown until now. The first representatives are prepared containing a [Nb6(OR)12]4+ unit (R=CH3 or C2H5). They are accessible at elevated temperatures from strongly basic alcoholate solutions of [Nb6Cl12]2+‐containing precursors. C gray, H white, K turquoise, Nb blue, O red.
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