共查询到20条相似文献,搜索用时 0 毫秒
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Furman GB Goren SD Panich AM Shames AI Nakajima T 《Solid state nuclear magnetic resonance》2010,38(4):84-89
Spin diffusion and spin-lattice relaxation in solids containing paramagnetic impurities under influence of a multiple-pulse spin-locking radio-frequency sequence are studied theoretically and experimentally. The diffusion equation obtained provides a clue for determination of the time dependent magnetization. The spin-lattice relaxation time is calculated as a function of the correlation time and multiple-pulse field parameters. From the experimental data the spin diffusion coefficient, the radius of the spin diffusion barrier, and the correlation time for very slow molecular motion in polycrystalline (C(2)F)(n) system are estimated and found to be D~7.1×10(-12)cm(2)/s, r(c)~4.8×10(-10)m, and τ(c)~10.2μs, respectively. 相似文献
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Charagundla SR Borthakur A Leigh JS Reddy R 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,162(1):113-121
Significant artifacts arise in T(1rho)-weighted imaging when nutation angles suffer small deviations from their expected values. These artifacts vary with spin-locking time and amplitude, severely limiting attempts to perform quantitative imaging or measurement of T(1rho) relaxation times. A theoretical model explaining the origin of these artifacts is presented in the context of a T(1rho)-prepared fast spin-echo imaging sequence. Experimentally obtained artifacts are compared to those predicted by theory and related to B(1) inhomogeneity. Finally, a "self-compensating" spin-locking preparatory pulse cluster is presented, in which the second half of the spin-locking pulse is phase-shifted by 180 degrees. Use of this pulse sequence maintains relatively uniform signal intensity despite large variations in flip angle, greatly reducing artifacts in T(1rho)-weighted imaging. 相似文献
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The behavior of nuclear quadrupole resonance (NQR) signals between RF pulses of the strong off-resonance comb (SORC) as well as the spin-locking spin-echo (SLSE) pulse sequences was studied as for 14N NQR line ν ?+? of dimethylnitramine (CH3)2NNO2 at 77 K. The periodic variation of the signal amplitude observed by using SORC pulse sequence could be reasonably explained by the theoretical expression reported in the literature. 相似文献
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The non-markovian behaviour of coupled nuclear spins in the spin-locking experiment is investigated both experimentally and theoretically. 相似文献
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The nuclear quadrupole resonance (NQR) method has been applied to Heroin Base (HB) to find an optimised multi-pulse technique for effective detection of HB. Experimental results of applying the proposed spin-locking multi-pulse (SLMP) technique to nitrogen-14 NQR in this sample are presented and convincingly demonstrate as a path towards efficient detection. A detection using a sequence of this character could be achieved over real-world scan volumes for screening of goods. All experiments were carried out at room temperature. 相似文献
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Kaikkonen A Kowalewski J 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2000,146(2):297-310
A relaxation network has been calculated for multipolar AMX systems under application of a spin-locking RF field. Systems of this type are of interest in the study of proteins with fractional 2H enrichment. All possible auto- and cross-correlation terms involving dipolar, quadrupolar, and CSA interactions have been taken into account. The results show the presence of spectral densities at zero frequency for interactions associated with the locked nuclei, which are nonvanishing in the absence of fast motions. In addition, the application of a spin-locking field blocks certain cross-correlation interactions, thereby considerably simplifying the relaxation network. 相似文献
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In the interests of NQR tomography, theoretical formulas for calculating the concentration and spin-spin and spin-lattice relaxation times of local volumes containing quadrupole nuclei are derived from expressions for NQR echo-signals. 相似文献
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The polarizations of spins in the local field hz? S(hz, t) (the layer polarization) are calculated. In terms of layer polarizations, the solid-echo formation mechanism and the transfer processes in multi-pulse NMR spin-locking are explained. 相似文献
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V. L. Ermakov R. H. Kurbanov D. Ya. Osokin V. A. Shagalov 《Applied magnetic resonance》1992,3(6):975-980
NQR imaging based on spin precession in toggling reference frame and radio frequency field encoding is proposed. The profile of a NaNO2 monocrystalline phantom obtained using the method proposed is demonstrated. The application of the method in remote NQR detection and NMR surface coil techniques is suggested. 相似文献
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V. S. Grechishkin 《Russian Physics Journal》1992,35(7):637-640
Kaliningrad State University. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 62–65, July, 1992. 相似文献
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Kozhan T. M. Kuznetsova V. V. Sergeev I. I. Khomenko V. S. 《Journal of Applied Spectroscopy》1984,41(6):1341-1344
Journal of Applied Spectroscopy - 相似文献
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The application of multiple-pulse sequences consisting of two-transition composite pulses for remote nuclear quadrupole resonance
detection of explosives and narcotics is discussed. The pulse sequence for obtaining these pulses is described and it is shown
that these pulses are equivalent to the pulse applied at the third (nonirradiated) transition. The loss of the signal intensity
in this case is absent. 相似文献
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The present paper reports the achievement of the rotating-frame analog of spin-locking and its application to the precise measurements of the spin-lattice relaxation time T(1DR) in the doubly rotating frame. After the magnetization is aligned along the resonant RF field H(1), a pulse sequence of a low-frequency oscillating magnetic field at exact resonance is applied perpendicular to H(1). We have overcome several technical difficulties arising from the fact that the rotating-wave approximation is not valid for the low-frequency field. We have theoretically derived an expression of T(-1)(1DR) due to fluctuating magnetic dipole interactions in the weak collision case and found an important relation among the spin-lattice relaxation rates T(-1)(1), T(-1)(1rho), and T(-1)(1DR). This relation can be used to ascertain whether the relaxation is only due to the fluctuating magnetic dipole interactions between like spins. The experiment was carried out on (1)H nuclei in tetramethylammonium iodide (CH(3))(4)NI and the temperature dependence of T(-1)(1DR) was measured together with that of T(-1)(1) and T(-1)(1rho). The activation energies and the preexponential factors of Arrhenius expressions of the correlation times are newly determined. 相似文献