首页 | 本学科首页   官方微博 | 高级检索  
相似文献
 共查询到20条相似文献,搜索用时 50 毫秒
1.
研究了制样过程对聚β-羟基丁酸酯(PHB)/聚醋酸乙烯酯(PVAc)共混体系的相容性和结晶行为的影响,DSC、SAXS、POM等实验结果表明,PHB/PVAc共混物经溶液成膜后处于分相的状态,PVAc对PHB的结晶能力影响不大,而经熔融处理后,PHB/PVAc共混物则处于相容的均相状态,随PVAc在共混物中含量的增加,PHB的冷结晶温度升高,球晶增长速率下降,织态结构变得不规整。当PVAc的含量高于80%时,PHB失去结晶能力。  相似文献   

2.
热致液晶PEI与PES—C共混物的研究   总被引:2,自引:0,他引:2  
通过熔融共混,制备不同配比(2.5/97.5-75/25)的PEI/PES-C共混物,使用WAXD、DSC、锥板流变仪、力学性能测试、SEM等方法对共混物进行了研究。共混后强度、模量均有提高,在高剪切速率下,共混物的粘度有所降低。扫描电镜照片显示,共混物具有“皮芯”结构。  相似文献   

3.
PEO/EVA共混物的结构研究   总被引:1,自引:0,他引:1  
PEO以分散相形式存在于PEO/EVA共混物中,且具有部分相容性。X-射线衍射谱表明EVA含有较强的PE衍射峰;PEO/EVA共混物既表现出PE的衍射峰也含有PEO的晶面反射。随着PEO的Mn的增加,PEO/EVA的Wc、x增大且于时获得最大值:PE0/EVA的Wc、x值比纯PEO的Wc、x明显降低。  相似文献   

4.
弹性体型聚氨酯和聚碳酸酯共混物的形态结构   总被引:1,自引:0,他引:1  
阎荣江  李光 《应用化学》1994,11(3):62-65
用DSC、WAXD和SAXS研究了溶液共混的弹性体型聚氨酯(PU)/聚碳酸酯(PC)共混物的结构。结果表明,PU/PC为部分相容体系;共混过程中,溶剂DMF的诱导作用使PC形成结晶,其长周期与PU硬段形成微相的长周期相近  相似文献   

5.
研究了制样过程聚β-羟基丁酸酯/聚醋酸乙烯酯共混体系的相容性和结晶行为的影响。DSC、SAXS、POM等实验结果表明,PHB/PVAc共混物经溶液成膜后处于分相的状态,PVAc对PHB的结晶能力影响不大;而经融处理后,PHB/PVAc共混物则处于相容的均相状态,随PVAc的含量含量的增加。  相似文献   

6.
以DSC,POM,WAXD实验方法研究了聚β-羟基丁酸酯/聚醋酸乙稀酯(PHB/PVAc)共混体系的结晶行为。结果表明:随共混物中非晶组份PVAc含量的增加,PHB结晶的活化能增大。用Avrami方程处理实验数据,结果表明PVAc的加入对PHB结晶的生长方式影响不大,但结晶速率却明显下降。WAXD实验表明,PVAc的加入不影响PHB的结晶结构,但微晶尺寸和结晶度却明显变小。偏光显微镜观察结果与DSC实验结果基本一致。  相似文献   

7.
聚β—羟基丁酸酯/聚醋酸乙烯酯共温物结晶行为的研究   总被引:2,自引:0,他引:2  
以DSC,POM,WAXD实验方法研究了聚β-羟基丁酸酯/聚醋酯乙稀酯(PHB/PVAc)共混体系的结晶行为。结果表明:随共混物中非晶组份PVAc含量的增加,PHB结晶的活化能增大。用Avrami方程处理实验数据,结果表明PVAc的加入对PBH结晶的生长方式影响不大,但结晶速率却明显下降。WAXD实验表明,PVAc的加入入不影响PHB的结晶结构,但微晶尺寸和结晶度却明显变小。偏光显微镜观察结果与D  相似文献   

8.
EVA增容PP/HDPE共混体系的形态结构与性能   总被引:4,自引:0,他引:4  
采用乙烯-醋酸乙烯酯共聚物(EVA)作为聚丙烯(PP)/高密度聚乙烯(HDPE)共混体系的增容剂,通过冲击实验、拉伸实验、示差量热扫描仪(DSC)和扫描电镜(SEM),系统地研究了共混体系的性能与其形态结构之间的。结果表明,EVA是PP/HDPE共混物较好物增容剂,EVA可以使PP、HDPE的晶相结构受到一定程度的破坏,增加PP和HDPE的相容性,同时共混物的冲击韧性明显提高。  相似文献   

9.
通过测定醋酸纤维素(CDA)和聚乙烯基吡咯烷酮(PVP)共混物溶液的绝对粘度和特性粘数,发现CDA和PVP分子链段间有缔合现象.用富里哀变换红外光谱(FTIR)研究了共混物的吸收光谱,发现共混物中CDA的羟基吸收峰和PVP的羰基吸收峰均向低频方向迁移,证明了CDA的羟基和PVP的羰基之间有氢键形成.研究结果表明CDA和PVP的相容性及其特殊相互作用来源于不同分子链段间的氢键相互作用.  相似文献   

10.
通过测定醋酸纤维素(CDA)和聚乙烯基吡咯烷酮(PVP)共混物溶液的绝对粘度和特性粘数,发现CDA和PVP分子链段间有缔合现象,用富里哀变换红光谱(FTIR)研究了共混物的吸收光谱,发现共混物中CDA的羟基吸收峰和PVP的羰基吸收峰均向低频方向迁移,证明了CDA的羟基和PVP的羧基之间有氢键形成,研究结果表明CDA和PVP的相容性及其特殊相互作用来源于不同分子链段间的氢键相互作用。  相似文献   

11.
用溶胶-凝胶法以磷钼酸(MPA)的镍盐溶液水解钛酸四丁酯制备了NiPMo/TiO2催化剂.使用ICP、 XRD、 TG-DTA、 IR、 TPD-MS和微反应技术研究了催化剂的化学组成、热稳定性、化学吸附性质和催化反应性能.杂多钼酸盐与TiO2通过O2-在TiO2表面发生了键合.在623 K下,杂多阴离子仍保持原有的Keggin结构.CO2在Lewis酸位Ni(Ⅱ)和Lewis碱位Ni-O-Mo的桥氧协同作用下生成CO2卧式吸附态Ni(Ⅱ)←O-(CO)←(O--Ni).丙烯有多种吸附态在催化剂上吸附.在563 K、 1 MPa和空速1500 h-1的反应条件下,丙烯的摩尔转化率为3.2%,产物MAA选择性为95%.  相似文献   

12.
Different approaches for the synthesis of 1-benzyloxypyrazin-2(1H)-one derivatives from simple amino acids have been investigated. A library of 33 precursors for the preparation of N-hydroxy pyrazinones was obtained in moderate to good yields.  相似文献   

13.
In the context of the preparation of camptothecin and luotonin A analogs, the synthesis of some key keto-precursors and their use in Friedländer condensation are described. This paper also focuses on the stability of these keto intermediates and emphasizes the major differences between indolizinones and pyrroloquinazolinones series. Noteworthy is also the report of some original structures isolated as by-products of some experiments.  相似文献   

14.
The Langevin paramagnetic theory can’t describe the relation between magnetization of ferrofluids and applied magnetic field. The structuralization of ferrofluids, which is considered the main influence factor of the magnetization, is regarded. The part of magnetization works is deposited when the structure is forming. This action influences the magnetization of ferrofluids directly or indirectly. On the base of the “compressing” model, the Langevin function that usually describes the magnetization of ferrofluid is modified, and a well-fitted curve is obtained. An equation of the relation between the equivalent volume fraction after being “compressed” and the intensity of magnetic field is discovered, which approximately describes the process of magnetization. The relation between the approximate initial susceptibility and the volume fraction can be obtained from modified formula.  相似文献   

15.
The highly regioselective Buchwald–Hartwig amination at C-2 of the cheap and readily accessible reagent, 2,4-dichloropyridine with a range of anilines and heterocyclic amines is described. This new methodology is robust and provides a facile access to 4-chloro-N-phenylpyridin-2-amines on 0.25 mol scale. These intermediates undergo a further Buchwald–Hartwig amination at higher temperature to enable rapid exploration of the chemical space at C-4 and to provide a library of 2,4-bisaminopyridines.  相似文献   

16.
KMnO4-mediated oxidative CN bond cleavage of tertiary amines producing secondary amine was introduced, which was trapped by electrophiles (acyl chloride and sulfonyl chloride) to form amides and sulfonamides. The reaction could take place at mild condition, tolerating a wide range of function groups and affording products in moderate to excellent yields.  相似文献   

17.
The review contains a concise historical account and information on the most significant researches undertaken by the staff at the A. E. Favorsky Irkutsk Institute of Chemistry, Siberian Branch of the Russian Academy of Sciences on the Chemistry of Heterocyclic Compounds. Dedicated to Academician of the Russian Academy of Sciences B. A. Trofimov on his 70th jubilee. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 10, pp. 1443–1502, October, 2008.  相似文献   

18.
A general synthesis of previously unknown semicarbazone-based α-amidoalkylating reagents, 4-(tosylmethyl)semicarbazones, has been developed. The synthesis involved three-component condensation of semicarbazones of aliphatic or aromatic aldehydes with the same or other aldehydes and p-toluenesulfinic acid. The scope and limitations of this reaction were investigated. The compounds obtained were demonstrated to be an efficient α-(4-semicarbazono)alkylating agents. They were reacted with H- (sodium borohydride), O- (sodium methylate), S- (sodium phenylthiolate), N- (pyrrolidine, sodium succinimide), P- (trialkyl phosphites), and C-nucleophiles (sodium diethyl malonate) to give the corresponding products of the tosyl group substitution, 4-substituted semicarbazones, including analogues of nitrofurazone. Among the prepared compounds tested in vitro for antibacterial and antifungal activity, three nitrofuryl-containing semicarbazones exhibited high biological activities with minimum inhibitory concentration (MIC) values of 8–32 μg/mL.  相似文献   

19.
Zhanhui Yang  Shiyi Yang  Jiaxi Xu 《Tetrahedron》2017,73(23):3240-3248
Regiospecific and direct imidation of the methyl C(sp3)–H bond of thioanisoles is realized under mild and metal-free conditions with N-fluorobis(benzenesulfonyl)imide as an oxidant and nitrogen source. Proposed mechanism suggests that thionium ion intermediates and a Pummerer-type reaction are involved. The imidation has advantages such as high step-economy, excellent functionality tolerance, and regiospecificity, giving structurally diverse imidation products.  相似文献   

20.
A small library of new chiral bidentate hydroxyalkyl-imidazolium salts 1 is conveniently synthesized on multi-gram scale from inexpensive and commercially available chiral pool amino acids. The corresponding carbenes, generated by deprotonation of imidazolium salts 1, in combination with palladium(II) chloride were tested in the Mizoroki–Heck coupling reaction. The most significant results in terms of yields and reactivities were achieved with low catalyst loading. The catalytic activities of these imidazolium salts were also investigated in the asymmetric addition of diethylzinc to benzaldehyde. The use of MgO nanoparticles as an additive in conjunction with these ligands played a crucial role in increasing the efficiency of these reactions.  相似文献   

设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号