Layered model of electrorheological fluid under flow

We present a theoretical model of the behavior of a concentrated electrorheological fluid (ERF) which explicitly takes into account the effects of conductivity. The increase in shear viscosity under an electric field is due to a layered structure between the electrodes, made up of the remnants of particle chains adhering to the electrodes by electrostatic image forces, and a freely flowing liquid layer where all the shear flow is concentrated. This layered model can explain the variation of electric current with shear rate, as well as the rheological response of a dynamic yield stress proportional to the square of the applied electric field.     

Suspension of layered particles: an optimum electrorheological fluid for d.c. applications

 A comparison is made between two types of solid particles used in electrorheological fluids: particles with homogeneous electrical properties versus layered particles with a semi-conducting core surrounded by an outer layer of lower conductivity. Rheological measurements of these suspensions under steady shear and d.c. electric field show that the layered particle system produces the same yield stress but with a substantially reduced electric current. X-ray spectroscopic analysis confirms that these particles have a thin layer of SiO_x on the outer surface which causes the reduction in conductivity. Measurement of the dielectric permittivity followed by analysis using the Maxwell-Wagner model of polarization indicates that the conductivity of the outer layer is about 0.62 times that of the core region. Received: 13 January 1999 Accepted: 26 July 1999     

Maximising the electrorheological effect for bidisperse nanofluids from the electrostatic force between two particles

A multipole re-expansion solution for two nonidentical dielectric spheres in a parallel electric field is used to determine the critical ratio of particle radii which leads to the strongest force of attraction between the spheres at various interstices and under varying dielectric properties. These critical ratios provide genuine optimal dimensions, in the sense that the force of attraction decreases for both increasing and decreasing ratios. Numerical results are compared with experimental results from the literature and discussed from the perspective of the impact on the design of electrorheological nanofluids.     

Exponential shear flow of branched polymer melts

  The behavior of a low-density polyethylene melt in exponential shear strain histories is examined and compared to its behavior in constant rate planar elongation. A new set of shear stress and first normal stress difference data in exponential shear are presented and used in several different material functions that have been previously proposed. Viscosities composed of principal stress differences for the two flows showed no correspondence suggesting that, contrary to previous assertions, exponential shear and constant rate planar elongation flows are fundamentally different. It is further suggested that the presence of vorticity makes exponential shear a weak, rather than strong, flow. Received: 5 March 1999/Accepted: 1 September 1999     

Computer simulation of polymer brushes under shear

 Recently two different methods were used to simulate the stationary properties of polymer brushes under strong shear: stochastic dynamics of a multi-chain brush model, and self-consistent Brownian dynamics of a one-chain model. The former explicitly describes volume interactions (VI) between polymer segments but does not take into account hydrodynamic interactions (HI) inside the brush. In the latter the self-consistent molecular field method has been chosen to calculate VI, and HI were accounted for using the Brinkman equation. Despite a significant difference between models a collapse of the brush under shear was observed in both studies. In particular, the density profile changes from parabolic to step-like and the free ends of the chains become concentrated in a narrow region at the periphery of the brush. However, when HI are taken into account much higher shear rates are necessary to attain the same brush deformation because the shear flow only slightly penetrates into the brush in contrast to the free-draining case. The inner brush structure is also found to be different for the two models. In the first model all chains are inclined approximately at the same angle when shear is applied. In the second model chains with the free ends found in the inner sublayer of the brush do not feel the flow at all whereas those in the upper sublayer are stretched and inclined by the flow. Received: 24 June 1999 Accepted: 8 February 2000     

Field dependence of the response of a magnetorheological suspension under steady shear flow and squeezing flow

A comparison was made of the behaviour of a magnetorheological suspension under steady shear flow and constant velocity squeezing flow. The strain rates and sample dimensions were chosen to be comparable in the two deformation modes, and the dependence of the mechanical properties on the magnetic flux density B was investigated. The measurements found that the mechanical response under squeezing flow scaled as B^0.91, whereas the response under shearing scaled as B^1.4, close to theoretical predictions. This difference of the field dependence between the shearing and squeezing flows was possibly due to the different microstructural rearrangement processes which occur in the two deformation modes.     

Influence of long-chain branches in polyethylenes on linear viscoelastic flow properties in shear

 This contribution presents a survey on the influence of long-chain branching on the linear viscoelastic properties zero shear-rate viscosity and steady-state recoverable compliance of polyethylene melts. The materials chosen are linear and slightly long-chain branched metallocene-catalyzed polyethylenes of narrow molecular mass distribution as well as linear and highly long-chain branched polyethylenes of broad molecular mass distribution. The linear viscoelastic flow properties are determined in shear creep and recovery experiments by means of a magnetic bearing torsional creep apparatus. The analysis of the molecular structure of the polyethylenes is performed by a coupled size exclusion chromatography and multi-angle laser light scattering device. Polyethylenes with a slight degree of long-chain branching exhibit a surprisingly high zero shear-rate viscosity in comparison to linear polyethylenes whereas the highly branched polyethylenes have a much lower viscosity compared to linear samples. Slightly branched polyethylenes have got a higher steady-state compliance in comparison to linear products of similar polydispersity, whereas the highly branched polyethylenes of broad molecular mass distribution exhibit a surprisingly low elasticity in comparison to linear polyethylenes of broad molecular mass distribution. In addition sparse levels of long-chain branching cause a different time dependence in comparison to linear polyethylenes. The experimental findings are interpreted by comparison with rheological results from literature on model branched polymers of different molecular topography and chemical composition. Received: 12 July 2001 Accepted: 30 October 2001     

Time dependent flow in equimolar micellar solutions: transient behaviour of the shear stress and first normal stress difference in shear induced structures coupled with flow instabilities

Recently we studied time dependent structural changes that are coupled with flow instabilities (Fischer 1998; Wheeler 1998; Fischer 2000). Within a stability analysis, a classification scheme for the feedback circuit of coupled shear-induced structure and flow instabilities was derived by Schmitt et al. (1995) and applied to our samples. Here, inhomogeneous flow layers of different concentration and viscosity are generated by shear-induced diffusion (spinodal demixing) and, as consequence, one no longer observes a homogeneous solution but a type of shear banding that is seen here for the first time. In this paper we present the behaviour of the first normal stress difference observed in the critical shear-rate regime where transient shear-induced structure is coupled with flow instability. Similar to the oscillations of the shear stresses (strain-controlled rheometer) one observes oscillations in the first normal stress difference. This behaviour indicates that elastic structures are built up and destroyed while the shear-induced structures occur and that the induced phase is more elastic than the initial one. Oscillations of shear stress and first normal stress difference are in phase and indicate that both phenomena are caused by the same mechanism. Received: 30 June 1999/Accepted: 14 December 1999     

The effect of parallel combined steady and oscillatory shear flows on blood and polymer solutions

Human blood at physiological volume concentration exhibits non-Newtonian and thixotropic properties. The blood flow in the microcirculation is pulsatile, initiated from the heart pulse and can be considered as superposition of two partial flows: a) a steady shear, and b) an oscillatory shear. Until now steady and viscoelastic behavior were separately investigated. Here we present the response to the combination of steady and oscillatory shear for human blood, a high molecular weight aqueous polymer solution (polyacrylamide AP 273E) and an aqueous xanthan gum solution. The polyacrylamide and xanthan solutions are fluids that model the rheological properties of human blood. In general, parameters describing blood viscoelasticity became less pronounced as superimposed steady shear increased, especially at low shear region and by elasticity, associated with reduction in RBC aggregation. The response of polymer solutions to superposition shows qualitative similarities with blood by elasticity, but their quantitative response differed from that of blood. By viscosity another behavior was observed. The superposition effect on viscous component was described by a modified Carreau equation and for the elastic component by an exponential equation.Paper in part presented at the Symposium on Rheology and Computational Fluid Mechanics dedicated to the memory of Prof. A. C. Papanastasiou, University of Cyprus, Nicosia, July 4–5, 1996     

Boundary-layer flow of a micropolar fluid due to a stretching wall

Summary  A Theoretical analysis is carried out to study the boundary-layer flow over a continuously moving surface through an otherwise quiescent micropolar fluid. The transformed boundary-layer equations are solved numerically for a power-law surface velocity using the Keller-box method. The effects of the micropolar K and exponent m parameters on the velocity and microrotation field as well as on the skin-friction group are discussed in a detailed manner. It is shown that there is a near-similarity solution of this problem. The accuracy of the present solution is also discussed. Accepted for publication 1 April 1996     

Effect of drop size distribution on the flow behavior of oil-in-water emulsions

The effect of drop size distribution on the viscosity was experimentally examined for oil-in-water emulsions at volume fractions of = 0.5, 0.63 and 0.8. At = 0.5, the hydrodynamic forces during drop collisions govern the viscosity behavior. The viscosity versus shear rate curve is scaled on the root-mean-cube diameter which is related to the number of drops per unit volume. At = 0.8, the resistance to flow arises from the deformation and rearrangement of thin liquid films between drops. The viscosity at a given shear rate is inversely proportional to the volume-surface mean diameter which is related to the total interfacial area per unit volume. However, since the drops come into contact and the liquid film separating adjacent drops is generated without drop deformation at = 0.63, the viscosity curve is not scaled on the mean diameter. The flow behavior near the critical volume fraction strongly depends not only on the mean drop size, but also on the width of the distribution.     

The shear wave diffraction on tunnel cavities in an elastic layer and a half-layer

Summary  The antiplane steady dynamic problem of the theory of elasticity for an isotropic layer and a half-layer weakened by tunnel cavities of arbitrary cross section is investigated. A radiating monochromatic shear wave (SH-wave) is considered as loading. Using the constructed Green's functions for a layer and a half- layer, the corresponding boundary problems are reduced to the Fredholm's integral equations of the second kind. The obtained algorithm is realized numerically by the quadrature method. Results specifying the influence of the openings configuration, their number and relative position, types of edge conditions and inertia effects on tangential stress concentration are given. Received 13 July 1999; accepted for publication 20 July 2000     

Generalized thermoelastic analysis of the stress-focusing effect in a solid cylinder under rotationally asymmetrical instantaneous thermal loading

Summary  This paper investigates the stress-focusing effect in an infinitely long cylinder under rotationally asymmetrical instantaneous thermal loading on the basis of the generalized thermoelastic Lord–Shulman (L-S) and Green–Lindsay (G-L) theories. Combined forms of the governing equations of both theories are given in a cylindrical coordinate system. The two-dimensional generalized thermoelastic problems are solved by numerical inversion of Laplace transform. Calculations have been performed to find distributions of thermal stresses on the basis of the L-S theory. Stress-focusing phenomena under different heating conditions are presented. The effects of thermomechanical coupling and relaxation time on the stress-focusing phenomena as well as the singularity of stresses are discussed. Received 15 November 2000; accepted for publication 15 November 2001     

Large-strain response of isotropic-hardening elastoplasticity with logarithmic rate: Swift effect in torsion

Summary  Recently, a new Eulerian rate-type isotropic-hardening elastoplasticity model has been established by utilizing the newly discovered logarithmic rate. It has been proved that this model is unique among all isotropic hardening elastoplastic models with all possible objective corotational stress rates and other known objective stress rates by virtue of the self-consistency criterion: the hypoelastic formulation intended for elastic behaviour must be exactly integrable to deliver a hyperelastic relation. The simple shear response of this model has been studied and shown to be reasonable for both the shear and normal stress components. The objective of this work is to further study the large deformation response of this model, in particular, the second-order effects, including the well-known Swift effect, in torsion of thin-walled cylindrical tubes with free ends. An analytical perturbation solution is derived, and numerical results are presented by means of the Runge–Kutta method. It is shown that the prediction of this model for the shear stress is in good accord with experimental data, but the predicted axial length change is negligibly small and much less than experimental data. This suggests that the strain-induced anisotropy may be the main cause of the Swift effect. Received 10 December 1999; accepted for publication 20 July 2000     

On the elastic properties of model suspensions as investigated by creep recovery measurements in shear

 The elastic properties of model suspensions with spherical monodisperse hydrophilic glass spheres that were dispersed in a Newtonian liquid were determined in creep and creep recovery measurements in shear with a magnetic bearing torsional creep rheometer. The creep and creep recovery measurements were performed depending on the applied level of shear stresses ranging from 0.19 Pa to 200 Pa. Since the recoverable creep compliances of the chosen suspending medium (i.e. a low molecular weight polyisobutylene) were far below the lower limit of the resolution of the creep rheometer it can be considered to behave as purely viscous. By applying a large shear stress in the creep tests the investigated suspensions with a volume fraction of Φ _t =0.35 behave as Newtonian liquids, too. For these suspensions no significant recoverable creep compliances could be detected, as well. In contrast to the Newtonian state of suspensions at high shear stresses, where a shear induced ordering of the particles can be expected, a non-Newtonian behaviour arises by applying a very low shear stress in the creep test. In this state large recoverable creep compliances were detected for the suspensions. The magnitude of the recoverable creep compliances of the suspensions exceeded the largest creep compliances of polymer melts that are reported in the literature by more than two decades. From the results obtained by creep recovery measurements with a magnetic bearing torsional creep rheometer it can clearly be concluded that the particle structure present in the chosen model suspension gives rise to a pronounced elasticity. Received: 21 November 2000 Accepted: 12 July 2001     

Effects of shear thinning on migration of neutrally buoyant particles in pressure driven flow of Newtonian and viscoelastic fluids

The pattern of cross stream migration of neutrally buoyant particles in a pressure driven flow depends strongly on the properties of the suspending fluid. These migration effects have been studied by direct numerical simulation in planar flow. Shear thinning has a large effect when the inertia or elasticity is large, but only a small effect when they are small. At moderate Reynolds numbers, shear thinning causes particles to migrate away from the centerline, creating a particle-free zone in the core of the channel, which increases with the amount of shear thinning. In a viscoelastic fluid with shear thinning, particles migrate either toward the centerline or toward the walls, creating an annular particle-free zone at intermediate radii. The simulations also give rise to precise determination of slip velocity distributions in the various cases studied.     

Effect of particle size distribution on micro- and macromechanical response of granular packings under compression

The role of particle size heterogeneity on micro- and macromechanical properties of assemblies of spherical particles was studied using DEM simulations. The response to an imposed load of a granular material composed of non-uniformly sized spheres subjected to uniaxial confined compression was investigated. A range of geometrical and micro-mechanical properties of granular packings (e.g., void fraction, contact force distribution, average coordination number and degree of mobilisation of friction at contacts between particles) were examined, and provided a more accurate interpretation of the macroscopic behaviour of mixtures than has previously been available. The macromechanical study included stress transmission, stiffness and angle of internal friction of the granular assemblies.The degree of polydispersity showed slight effect on both, the void fraction and the elastic properties of the system. The tendency for increase in the lateral-to-vertical pressure ratios was observed with an increasing degree of particle size heterogeneity; however, the different pressure ratios calculated for samples with various degrees of polydispersity lay within the range of data scatter.