Intergranular Stress Corrosion Cracking of Pure Copper 〈111〉 Tilt Bicrystals

Behaviour of stress corrosion cracking (SCC) in a series of pure copper bicrystals with a symmetrical 111-tilt boundary has been investigated. Tests were performed by the slow strain rate technique (SSRT) in 1M NaNO₂ solutions. The small-angle tilt bicrystals fractured in both intergranular and transgranular manners accompanied by a large amount of plastic strain to fracture while the large-angle bicrystals fractured in almost intergranular manner with a smaller plastic strain. Susceptibility of SCC increases with increasing misorientation and becomes relatively constant in large-angle grain boundaries. The local minima appeared at the 7(321) and 3(211) boundaries, suggesting that the susceptibility was partially affected by grain boundary energy. Stress concentration generated by the pile-up of trapped dislocations at the grain boundary could account for the high susceptibility of the intergranular SCC in large-angle grain boundaries.     

Characteristics of Fe2O3 Nanoparticles from Doped Low-pressure H2/O2/Ar Flames

A burner stabilized premixed low-pressure flame has been used to generate iron-oxide (Fe₂O₃) nanoparticles with sizes in the range 7–20nm. The H₂/O₂/Ar flames were doped with different amounts of iron-pentacarbonyl (Fe(CO)₅) with concentrations in the range 524–2096ppm. The influence of precursor concentration on composition, structure, morphology, and size have been studied utilizing transmission electron microscopy (TEM), X-ray powder diffraction (XRD), measurements of the specific surface area (BET), and infrared spectroscopy (FT-IR). The product particles consist of both, the - and the -phase of Fe₂O₃. Average particle sizes were measured in the range 7.4–16nm depending on precursor concentration and flame conditions.     

Some critical exponent inequalities for percolation

For a large class of independent (site or bond, short- or long-range) percolation models, we show the following: (1) If the percolation densityP (p) is discontinuous atp _c , then the critical exponent (defined by the divergence of expected cluster size, nP _n (p) (P _c –P)^– asp p _c ) must satisfy 2. (2) or (defined analogously to, but asp p _c ) and [P _n (p _c ) (n ^–1–1/) asn ] must satisfy, 2(1 – 1/). These inequalities for improve the previously known bound 1(Aizenman and Newman), since 2 (Aizenman and Barsky). Additionally, result 1may be useful, in standardd-dimensional percolation, for proving rigorously (ind>2) that, as expected,P _x has no discontinuity atp _c .     

Stochastic Schrödinger operators and Jacobi matrices on the strip

We discuss stochastic Schrödinger operators and Jacobi matrices with wave functions, taking values in ^l so there are 2l Lyaponov exponents ₁..._l0 _l+1..._2l =–₁. Our results include the fact that if ₁=0 on a set positive measure, thenV is deterministic and one that says that {E|exactly 2j 's are zero} is the essential support of the a.c. spectrum of multiplicity 2j.Research partially supported by USNSF under grant DMS-8416049     

Twin boundaries with 9R zone in Cu and Ag studied by quantitative HRTEM

When highly inclined against the {111} plane of the coherent twin boundary, 3 110 tilt boundaries in Cu or Ag have a complex structure. As the boundary plane approaches the symmetrical {211} orientation, the grain boundaries decompose into two phase boundaries. Between these phase boundaries the metal adopts a rhombohedral crystal structure, denoted as 9R. Not the {211}-oriented boundary, but a boundary inclined by 8° against {211} has the minimum energy in this family of grain boundaries with 9R zone. Using high resolution transmission electron microscopy, we have studied the atomistic structure of this special boundary. An iterative structure refinement based on quantitative image analysis reveals the atomistic structure of the grain boundary at a well-defined level of confidence. Comparing the refined grain boundary structure with a model obtained by molecular statics calculations exposes small, but significant discrepancies. These probably arise because in the model the stacking fault energy is too small and the short distance repulsion is too weak. Grain boundaries of equivalent geometry in Ag and Al exhibit different widths of the 9R zone. Experimental observations support a theory relating the equilibrium width of the 9R slab to the stacking fault energy and the elastic properties of the material.Presented at the Workshop on High-Voltage and High Resolution Electron Microscopy, February 21–24, 1994, Stuttgart, Germany.     

Percolation and electrical resistivity in the YBa2Cu3O7−Ag composite system

We have measured the resistivity of the YBa₂Cu₃O₇–Ag composite system with Ag volume fraction,p _Ag ranging from 0–100%. The percolation behavior and the normal-state resistivity are studied. We find a three-dimensional threshold for the Ag matrix occurring atp _Ag 20% and a threshold for the superconducting matrix occurring at 1–p _Ag30%. The electrical resistivity is interpreted in terms of a resistivity model for granular YBa₂Cu₃O₇ proposed by Halbritter et al. [Z. Phys. B —Condensed Matter71, 411 (1988)]. Based on this model, we show that the resistivities between the YBa₂Cu₃O₇ grains and flaws in the grains are greatly diminished in the samples, indicating significantly improved grain growth behavior of the YBa₂Cu₃O₇ phase resulting from the addition of Ag. With the diminishing of the grain boundary resistivities, an intrinsic value for the temperature coefficient of resistivity, (1/gr)(d/dT), can be inferred, which is 3.3×10^–3/K at 300 K. This value is very close to that observed in the Cu–O₂ planes in single crystals and epitaxial films of YBa₂Cu₃O₇.     

Local energy flux and the refined similarity hypothesis

In this paper we demonstrate the locality of energy transport for incompressible Euler equations both in space and in scale. The key to the proof is the proper definition of a local subscale flux, _t (r), which is supposed to be a measure of energy transfer to length scales <l at the space point r. Kraichnan suggested that for such a quantity the refined similarity hypothesis will hold, which Kolmogorov originally assumed to hold instead for volume-averaged dissipation. We derive a local energy-balance relation for the large-scale motions which yields a natural definition of such a subscale flux. For this definition a precise form of the refined similarity hypothesis is rigorously proved as a big-O bound. The established estimate is _t (r)=O(l _3h-1) in terms of the local Hölder exponenth at the point r, which is also the estimate assumed in the Parisi-Frisch multifractal model. Our method not only establishes locality of energy transfer, but it also clarifies the physical reason that convection effects, which naively violate locality, do not contribute to the subscale flux. In fact, we show that, as a consequence of incompressibility, such effects enter into the local energy balance only as the divergence of a spatial current. Therefore, they describe motion of energy in space and cancel in the integration over volume. We also discuss theorems of Onsager, Eyink, and Constantinet al. on energy conservation for Euler dynamics, particularly to explain their relation with the Parisi-Frisch model. The Constantinet al. proof may be interpreted as giving a bound on the total flux, _t =d ^d r _t (r), of the form _t (r)=O(l _z3h-1), wherez ₃ is the third-order scaling exponent (or Besov index), in agreement with the multifractal model. Finally, we discuss how the local estimates are related to the results of Caffarelli-Kohn-Nirenberg on partial regularity for solutions of Navier-Stokes equations. They provide some heuristic support to a scenario proposed recently by Pumir and Siggia for singularities in the solutions of Navier-Stokes with small enough viscosity.     

Hyperbolic initial-boundary-value problem for magnetic flux compression by plane liners

Based on the (relativistic) Maxwell equations with displacement current E/t, the initial-boundary-value problem for the compression of an initially homogeneous magnetic fieldB={0,B(x,t),0} between a fixed liner atx=0 and a detonation-driven liner atx=s(t) is solved analytically. By homogenizing the boundary conditions at the moving boundary, the transient electromagnetic fields are shown to be a superposition of quasistatic elliptic (E/t=0) and hyperbolic (E/t0) wave solutions. The wave equation is solved by a Fourier expansion in time-dependent eigenfunctionsf _n =f _n [nx/s(t)] for the variable region 0xs(t), where the Fourier amplitudes _n (t) are determined by coupled differential equations of second order. It is concluded that the conventional elliptic flux compression theories (E/t=0) hold approximately for nonrelativistic liner speeds , whereas the hyperbolic theory (E/t0) is valid for arbitrary liner speeds .     

Real-space renormalization group for directed percolation system

We use the recently proposed real-space renormalization group method to study the critical behavior of directed percolation system in two dimensions. The correlation length exponents and are found to be 1.76 and 1.15. These results are in good agreements with the best known values.     

Application of151Eu Mössbauer spectroscopy to studies of electric field gradients in high-temperature superconductors

The rare-earth site of samples having the compositions (Fe,Cu)Sr₂(Eu,Ce) _n Cu₂O_4+2n+z (n=2 and 3) were studied by¹⁵¹Eu Mössbauer spectroscopy. The results obtained are compared with measurements of EuBa₂Cu₃O_7– (123) and Bi₂Sr₂(Ca_1–yEu_y)Cu₂O_8+E (2212) samples. The full quadrupole Hamiltonian of the 21.5-keV -transition was applied in analyzing the measured spectra. Simultaneous fitting of spectra recorded from crystallites oriented in various directions was used to determine the hyperfine parameters of then= 2 and 3 samples. Two different electric field gradients, not discernible in simple random crystallite measurements, were obtained for then=3 series.     

Differential calculus on quantum spheres

Three-dimensional differential calculus on quantum spheres S _infc ^sup2 ,]–1, 1[{0}, c[0, ], is introduced and investigated. Spectra of generalized Laplacians are found. These operators are expressed by generalized directional derivatives. Classical limits of these objects are obtained and a simple approach to quantum mechanics on a quantum sphere is presented.     

On classical models of Spin

We discuss two classical situations that lead to probabilities characteristic for systems with spin-1/2. (a) Pitowsky model: It is demonstrated that the definition of spin functions does not imply which circle (a parallel or a great circle) on the sphere should be taken as a probability space in calculation of conditional probabilities. Pitowsky's choice of parallels must be formulated as an assumption about the model. It is shown that the model explicitly avoiding this difficulty is possible and no contradiction with the Bell Theorem is found. The modification is based on a new pathological decomposition of the sphere and belongs to a class of hidden variable theories with undetected signals. (b) Aerts model: We show the importance of the polarization effect of the measurements for the sake of obtaining a non-Kolmogorovian probability model. It is also shown that the conditioning by a change of state leads in general to the non-Kolmogorovian probability calculus.2. For example, let _{Cw,z xCw,z}µ_c ({y C _w,z S ₊|(x,y) /2})=µ _c(C _w,z S ₊)= 1/2µ _c(C _w,z). Pitowsky spheres with white points distributed onC _w,z in this way exist. The proof is exactly analogous to this of Theorem 1 in [1]. Then (**) = 1 -/, if one takesC _w,z as the probability space. This example seems very instructive.3. If the chargeq falls down on some point then it clearly has not fallen down on another one. Having given a result of a measurement we cannot, within the model with polarization, talk in a sensible way about its alternative: We can think either aboutsuccessive measurements (then the Bell inequality is not derivable) or ask What would have happened if..., but then we deal with a different problem (in Aerts' terminology [2b] this is anobservation) and obtain again Eq. (8) (there is no complementarity but there is no model of spin either).     

Anisotropy of the low temperature resistivity of hexagonal single crystalline spin glass systems

The impurity contribution to the resistivity in zero field (T) of dilute hexagonal single crystals of ZnMn, CdMn and MgMn has been studied in the mK range on samples cut parallel () and perpendicular () to thec-axis, using a SQUID technique for the measurements. Typical spin glass behavior is found in (T) as well as (T) for all alloys, with Kondo like logarithmic increases at higher temperatures and maxima atT _m at lower temperatures, indicating the influence of impurity interactions. The differences in the corresponding isotropic resistivity _poly(T) between the three systems can qualitatively be understood within the framework of a theoretical model by Larsen, describing (T) as a function of universal quantitiesT/T _K and _RKKY/T _K , where _RKKY is the RKKY-interaction strength andT _K the Kondo temperature. With respect to the two lattice directions studied, the behavior of (T and (T is anisotropic in the Kondo regime as well as in the range where ordering becomes important. While the anisotropy in the Kondo slope can be understood by an anisotropic unitarity limit, the understanding of the anisotropy in region where impurity interactions are important remains problematic.Dedicated to Prof. Dr. S. Methfessel on the occasion of his 60th birthday     

UV cavity enhanced absorption spectroscopy of the hydroxyl radical

We present the application of a continuous-wave ultra-violet tuneable light source for detection of the hydroxyl radical (OH) using cavity-enhanced absorption spectroscopy of the Q₁₁(2) and Q₂₁(2) absorption lines in the A²⁺(v=0)²_3/2(v=0) band at ca. 308 nm. A tuneable infra-red diode laser operating at 835 nm and either an Ar⁺ laser or a single frequency continuous-wave intracavity frequency-doubled diode laser, both operating at ca. 488 nm, were used to produce 0.1–0.5 W of tuneable radiation at ca. 308 nm by sum frequency generation in a BaB₂O₄ crystal. Cavity enhanced absorption spectroscopy was used to detect OH generated by UV photolysis of water vapour in argon, nitrogen, neon and helium at atmospheric pressure. A noise-equivalent (1) absorption sensitivity of 2.1×10^-7 cm^-1Hz^-1/2 measured over 128 scans in a time of 1.16 s was demonstrated with mirrors of reflectivity 0.9963 in a cavity of length 58.5 cm for a 2 cm^-1 scanning range at a UV power of 0.5 W. An OH detection limit (1) of 3.84×10⁹ moleculecm^-3 was estimated in argon at atmospheric pressure. OH collisional broadening in humidified N₂, Ar, Ne and He was determined at atmospheric pressure . PACS 39.30.+w; 42.55.Px; 42.62.Fi; 42.68.Ca     

Continuity of type-I intermittency from a measure-theoretical point of view

We study a simple dynamical system which displays a so-called type-I intermittency bifurcation. We determine the Bowen-Ruelle measure and prove that the expectation (g) of any continuous functiong and the Kolmogoroff-Sinai entropyh() are continuous functions of the bifurcation parameter. Therefore the transition is continuous from a measure-theoretical point of view. Those results could be generalized to any similar dynamical system.     

Superplasticity in single-phase Zn-0·25 wt. % Cd alloy

A single-phase Zn-0·25 wt. % Cd alloy was prepared with the mean grain sized¯ 1m. Superplastic characteristics (A _max=320% andm _max>0·4) were established at room temperature at the strain rates.10^–4s^–1. Because of the absence of any second phase particles the fine-grained structure was not stable and an intense grain coarsening was observed both during the long-term ageing and during straining at room temperature. The increasing temperature accelerated this grain coarsening and suppressed the superplastic behaviour. Nevertheless, the stress relaxation tests suggested that the superplastic behaviour might be expected at higher temperatures in coarser grained specimens, too, but at substantially lower strain rates.     

Mixing properties,differentiability of the free energy and the central limit theorem for a pure phase in the Ising model at low temperature

For the Ising model with nearest neighbour interaction it is shown that the spin correlations _{A B} - _{A B} decrease exponentially asd(A, B) in a pure phase when the temperature is well belowT _c. This is used to prove that the free energyF(,h) is infinitely differentiable in and has one sided derivatives inh of all orders forh=0. The bounds are also used to prove that the central limit theorem holds for several variables such as e.g. the total energy and the total magnetization of the system, the limit distribution being gaussian with variances determined by the second derivatives ofF(,h).     

Calculation of characteristics of benzene derivatives

The C₆H₅X compounds are considered as regards the energy and wave function _x as functions of within limits of –3 and +3, and also as functions of _cx within limits of 0. 5 and 1. 5. Convenient numerical tables are compiled.We are indebted to N.A. Prilezhaev and V.I. Danilov for extensive collaboration in this work.     

On the theory of amplification of meso-ultrasound in anisotropic monopolar semiconductors

The electronic absorption coefficient (_e) of meso-ultrasound (_p ^–1 _en, _t, _ee; ql 1, where _p, _en, _t are the times of pulse relaxation, energy, and current carrier traps; _ee ^–1 is the frequency of intraelectron collisions; , q are the frequency and wave vector of sound; l is the carrier mean free path) in the presence of a permanent external field E₀ e ₀ ^–1 q₀T is calculated for anisotropic single-valley semiconductors with piezoelectrical and potential-deformation acoustoelectronic interaction. Considered arbitrary are: 1) the anisotropy of the tensors * and _p (and other crystal parameters); 2) the degree of Fermi degeneration of the carriers; 3) the dependence of _p on the carrier energy . The acoustoheat nonlinearity is neglected. The possibility of meso-ultrasound amplification by the transverse field (E₀ - q) is predicted. By changing the orientation of the vector q relative to the crystal axes, the transverse threshold field (E ^thr ) can be controlled smoothly and within broad limits, This permits the production of a mechanical sound-amplification regulator or a modulator of its intensity. The ratio between E ^thr and E ^thr yields a measure of the relative anisotropy of the mobility.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 2, pp. 87–92, February, 1977.     

Kinetic equation in the kinetic region of the dilute and nonuniform electron plasma

Mori's scaling method is used to derive the kinetic equation for a dilute, nonuniform electron plasma in the kinetic region where the space-time cutoff (b, t _c) satisfies _Dbl _f , _D t _{c f} , with _D the Debye length, _D ^–1= _p the plasma frequency, andl _f and _f the mean free path and time, respectively. The kinetic equation takes account of the nonuniformity of the order ofl _f and _D for the single-and the two-particle distribution function, respectively. Thus the Vlasov term associated with the two-particle distribution function is retained. This kinetic equation is deduced from the kinetic equation in the coherent region obtained by Morita, Mori, and Tokuyama, where the space-time cutoff of the coherent region satisfies _Dbr ₀, _Dt _{c 0}, withr ₀ the Landau length and ₀ the corresponding time scale.