Orienting properties of discotic nematic liquid crystals in Jeffrey-Hamel flows

The orienting properties of incompressible discotic nematic liquid crystals for creeping flows between converging and diverging planar walls (Jeffrey-Hamel) are analyzed using the Leslie-Ericksen theory. The dependence of director orientation on the reactive parameter and the flow kinematics is presented. Closed form stationary solutions for the director orientation are found when elastic effects are neglected. Stationary numerical solutions for the velocity and director fields using the full Leslie-Ericksen theory are presented. The director field in converging flow is characterized by azimuthal (radial) centerline orientation, by being asymmetric with respect to the azimuthal (radial) direction, and by having an allowed orientation range that spans two half-quadrants (full quadrants). In the limiting case of perfectly flat disk ( –) the flow-induced director orientation in converging flow is the azimuthal direction, while in diverging flow the director rotates by a full n radians. By reducing the vertex angle between the walls to vanishingly small values, converging flow solutions properly reduce to those of flow between parallel plates, but diverging flows are expected to lead to a new instability.     

On an inversion theorem for conical regions in elasticity theory

Summary Two-dimensional stress singularities in wedges have already drawn attention since a long time. An inverse square-root stress singularity (in a 360° wedge) plays an important role in fracture mechanics.Recently some similar three-dimensional singularities in conical regions have been investigated, from which one may be also important in fracture mechanics.Spherical coordinates are r, , . The conical region occupied by the elastic homogeneous body (and possible anisotropic) has its vertex at r=0. The mantle of the cone is described by an arbitrary function f(, )=0. The displacement components be u. For special values of (eigenvalues) there exist states of displacements (eigenstates) % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqef0uAJj3BZ9Mz0bYu% H52CGmvzYLMzaerbd9wDYLwzYbItLDharqqr1ngBPrgifHhDYfgasa% acOqpw0xe9v8qqaqFD0xXdHaVhbbf9v8qqaqFr0xc9pk0xbba9q8Wq% Ffea0-yr0RYxir-Jbba9q8aq0-yq-He9q8qqQ8frFve9Fve9Ff0dme% GabaqaaiGacaGaamqadaabaeaafiaakabbaaa6daaahjxzL5gapeqa% aiaadwhadaWgaaWcbaGaeqOVdGhabeaakiabg2da9iaadkhadaahaa% WcbeqaaiabeU7aSbaakiaadAgadaWgaaWcbaGaeqOVdGhabeaakiaa% cIcacqaH7oaBcaGGSaGaeqiUdeNaaiilaiabfA6agjaacMcaaaa!582B!\[u_\xi = r^\lambda f_\xi (\lambda ,\theta ,\Phi )\],which may satisfy rather arbitrary homogeneous boundary conditions along the generators.The paper brings a theorem which expresses that if is an eigenvalue, then also-1- is an eigenvalue. Though the theorem is related to a known theorem in Potential Theory (Kelvin's theorem), the proof has to be given along quite another line.

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Zusammenfassung Zwei-dimensionale Spannungssingularitäten in keilförmigen Gebieten sind schon längere Zeit untersucht worden und neuerdings auch ähnliche drei-dimensionale Singularitäten in konischen Gebieten.Kugelkoordinaten sind r, , . Das konische Gebiet hat seine Spitze in r=0. Der Mantel des Kegels lässt sich beschreiben mittels einer willkürlichen Funktion f(, )=0. Die Verschiebungskomponenten seien u. Für spezielle Werte von (Eigenwerte) bestehen Verschiebunszustände % MathType!MTEF!2!1!+-% feaafiart1ev1aaatCvAUfeBSjuyZL2yd9gzLbvyNv2CaerbuLwBLn% hiov2DGi1BTfMBaeXafv3ySLgzGmvETj2BSbqef0uAJj3BZ9Mz0bYu% H52CGmvzYLMzaerbd9wDYLwzYbItLDharqqr1ngBPrgifHhDYfgasa% acOqpw0xe9v8qqaqFD0xXdHaVhbbf9v8qqaqFr0xc9pk0xbba9q8Wq% Ffea0-yr0RYxir-Jbba9q8aq0-yq-He9q8qqQ8frFve9Fve9Ff0dme% GabaqaaiGacaGaamqadaabaeaafiaakabbaaa6daaahjxzL5gapeqa% aiaadwhadaWgaaWcbaGaeqOVdGhabeaakiabg2da9iaadkhadaahaa% WcbeqaaiabeU7aSbaakiaadAgadaWgaaWcbaGaeqOVdGhabeaakiaa% cIcacqaH7oaBcaGGSaGaeqiUdeNaaiilaiabfA6agjaacMcaaaa!582B!\[u_\xi = r^\lambda f_\xi (\lambda ,\theta ,\Phi )\],welche homogene Randwerte der Beschreibenden des Kegels entlang genügen.Das Bericht bringt ein Theorem, welches aussagt, das und =–1– beide Eigenwerte sind.

     

An experimental study on the two-dimensional opposed wall jet in a turbulent boundary layer: Change in the flow pattern with velocity ratio

Results of the measurement of flow properties in a two-dimensional turbulent wall jet which is injected into the turbulent boundary layer in the direction opposite to that of the boundary layer flow are presented by varying the ratio of the jet issuing velocity to the mainstream velocity . This flow includes the flow separation and the recirculating flow, and so it requires the magnitude and direction of instantaneous velocity be measured. In the present work, a tandem hot-wire probe is manufactured and its characteristics are examined experimentally. With the use of this probe the change in the penetration length of the jet with the velocity ratio is investigated. It is clarified that two regimes of flow patterns exist: in the low velocity ratio the penetration length of the jet changes little with , and in the high velocity ratio it goes far from the nozzle with increasing . Streamlines, turbulence intensity contours and static pressure contours are presented in the two typical velocity ratios corresponding to each of two flow patterns, and they are compared.List of symbols b ₀ nozzle width (Fig. 1) - , e mean and fluctuating output voltages of hot-wire anemometer - p, p mean static pressure, p = p – p _o - p ₀ static pressure in undisturbed mainstream - p _w , p _w mean wall pressure, p _w = p _w – p _o - U ₀ mainstream velocity - U _j jet velocity at the nozzle exit - , u mean and fluctuating velocity components in x-direction - u _e effective cooling velocity - x distance along the wall from nozzle exit - x _pmax, x _pmin positions where the wall pressure has maximum and minimum values respectively - x _s penetration length of jet - y distance from the wall - forward flow fraction - ₁, ₂ yaw and pitch angles of flow direction (Fig. 4) - velocity ratio, = U _j /U _o - density of the fluid - nondimensional stream function The authors wish to express their appreciation to Prof. Toshio Tanaka of Gifu University for his advice in the course of the experiment. They also would like to thank the Research Foundation for the Electrotechnology of Chubu which partly supported this work.     

Robustness of Exponential Dichotomies in Infinite-Dimensional Dynamical Systems

In this paper we examine the issue of the robustness, or stability, of an exponential dichotomy, or an exponential trichotomy, in a dynamical system on an Banach space W. These two hyperbolic structures describe long-time dynamical properties of the associated time-varying linearized equation _t +A=B(t) , where the linear operator B(t) is the evaluation of a suitable Fréchet derivative along a given solution in the set K in W. Our main objective is to show, under reasonable conditions, that if B(t)=B(, t) depends continuously on a parameter and there is an exponential dichotomy, or exponential trichotomy, at a value ₀, then there is an exponential dichotomy, or exponential trichotomy, for all near ₀.We present several illustrations indicating the significance of this robustness property.     

The self-preservation of homogeneous shear flow turbulence

An analysis of the equations governing homogeneous shear flow shows the possibility of solutions which are self-preserving at all scales of motion, and that these solutions are dependent on the initial conditions. The appropriate velocity scale is the one obtained from the turbulence kinetic energy, q ²/2, while the length scale is the Taylor microscale, . Two cases of self-preserving flow are identified: one corresponding to constant mean shear, the other to a mean shear which is inversely proportional to time. For the first case (the only one considered in detail) the principal results of the postulated similarity are that is constant, while q ² varies exponentially with time. The ratio of the turbulence energy production rate to its dissipation rate remains constant. It is also shown that the energy spectra scale over all wavenumbers with q ² and , and that they have shapes determined by the initial conditions. The experimental evidence is generally consistent with the theory.     

The Gibbs-Thompson relation within the gradient theory of phase transitions

This paper discusses the asymptotic behavior as 0+ of the chemical potentials associated with solutions of variational problems within the Van der Waals-Cahn-Hilliard theory of phase transitions in a fluid with free energy, per unit volume, given by ²¦¦²+ W(), where is the density. The main result is that is asymptotically equal to E/d+o(), with E the interfacial energy, per unit surface area, of the interface between phases, the (constant) sum of principal curvatures of the interface, and d the density jump across the interface. This result is in agreement with a formula conjectured by M. Gurtin and corresponds to the Gibbs-Thompson relation for surface tension, proved by G. Caginalp within the context of the phase field model of free boundaries arising from phase transitions.     

Experimental and numerical analysis of oscillatory tube flow of viscoelastic fluids represented at the example of human blood

Summary The 4 constant parameters of an Oldroyd type constitutive equation for normal human blood of 45% haematocrit were determined by means of the steady flow curve and the material functions () and (), measured at 2 Hz in an oscillatory capillary viscometer. It was found, as other authors did before, that the phenomenological behaviour of blood flow can be reproduced qualitatively thereby. The quantitative behaviour, however, cannot be described by thus developed parameters. The parameters of the constitutive equationµ ₀, ₁ and ₂ were therefore generalized to become dependent of shear rate and frequency respectively.In itself this is nothing but a transformation of the material functions ( ),() and (), but these can be used as parameters in a constitutive equation though having lost the property of constancy.In this way the linear region of viscoelasticity and the steady flow curve can be reproduced quantitatively. A computer simulation of oscillatory flow for large amplitudes shows another tendency for the phase shift between pressure and flow than the experiment in the oscillatory capillary rheometer does.The applicability of a constitutive equation modified in this manner for other than oscillatory flow should be further examined especially for pulsatile flow.

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Zusammenfassung Mit Hilfe der Fließkurve für die stationäre Strömung und Messungen der Materialfunktion () im Oszillations-Kapillarrheometer bei 2 Hz wurden die Konstanten der 4-Konstanten-Oldroyd-Stoffgleichung für gesundes Humanblut von 45% Hämatokrit bestimmt. Es zeigte sich, daß sich — wie auch schon von anderen Autoren mitgeteilt wurde — mit den so ermittelten Modellkonstanten die Phänomenologie des Fließverhaltens des Blutes qualitativ gut beschreiben läßt. Zur quantitativen Beschreibung reicht dieses Modell jedoch nicht aus, wie man an der Wiedergabe der stationären Fließkurve und der Materialfunktionen der linearen Viskoelastizität erkennt. Aus diesem Grund wurden die Parameterµ ₀, ₁ und ₂ in Abhängigkeit der Schergeschwindigkeit bzw. der Frequenz angesetzt.Dies bedeutet zunächst nichts anderes als eine Transformation der Materialfunktionen, jedoch in einer Art, daß letztere als Parameter in einer Stoffgleichung verwendet werden können, was allerdings mit dem Verlust der Konstanz der Parameter verbunden ist. Mit einer derart modifizierten Stoffgleichung lassen sich der Bereich der linearen Viskoelastizität und die stationäre Fließkurve quantitativ beschreiben. Eine Computersimulation der oszillierenden Rohrströmung zeigt für große Amplituden eine andere Tendenz für die Phasenverschiebung zwischen Druck und Volumenstrom, als sie sich bei Messungen am Oszillations-Kapillarrheometer ergibt.Die Anwendbarkeit der modifizierten Stoffgleichung für andere Strömungsformen, wie z.B. pulsierende Rohrströmungen, muß noch geprüft werden.

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Paper, presented at the Annual Conference of the Deutsche Rheologische Gesellschaft in Berlin, May 8–10, 1978.

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With 8 figures     

Rheo-NMR study of a non-flow-aligning side-chain liquid crystal polymer in nematic solution

The flow behavior of a highly concentrated solution of a nematic side-chain liquid crystal polymer in a low molecular mass nematic solvent is investigated by deuterium nuclear magnetic resonance with simultaneous measurement of the shear viscosity in a cone-and-plate NMR viscometer. The director orientation under shear in the magnetic field is determined from the quadrupole splitting of the NMR spectra. The orientation as a function of shear rate is analyzed in terms of the Ericksen-Leslie-Parodi theory, yielding the Leslie coefficients ₂ and ₃ and thus the flow alignment parameter . From the combined analysis of orientation and viscosity as a function of shear rate a total of four independent viscosity parameters is obtained for the nematic solution. The value determined for the flow-alignment parameter, 0.2, and the analysis of the data based on Brochard's theory show that the polymer is of the non-flow-aligning type and has a slightly prolate shape.     

Injection of ideal fluid from a slot into a free stream

A cold gas is injected from a slot into a free stream of hot gas. In a simple model this leads to a two-fluid free boundary problem with the jump relation |u^-|²–|u⁺|² = ( constant) on the free boundary {u=0}, where u is the stream function. We prove that for any (–1, ) there exists a unique solution (Q, u) where Q is the flux of the injected fluid. Various properties of the solution u and of the free boundary are established.     

Axisymmetric spreading of a heavy liquid over a plane

A study is made of the steady flow over a horizontal plane of a heavy inviscid incompressible liquid which flows through the side surface of a circular cylinder which rises above the plane to height h and has a base radius ofa. The motion of the liquid is assumed to be symmetric with respect to the axis of the cylinder; the pressure p is constant (equal to the atmospheric pressure) on the free surface of the liquid. Fora/h = 1, this problem can be regarded as a problem of perturbation of the flow from a flat source by a free surface. Investigation showed that this perturbation problem is essentially nonlinear, and a solution of it in the complete region occupied by the liquid can be obtained only in variables of the boundary layer type. The problem admits linearization under the additional assumption that the parameter = Q²/(8²ga³) is small; here, Q is the constant volume flow rate of the liquid per unit height of the cylinder, and g is the acceleration of free fall. For the case 1, 1 the problem is solved by the method of integral transformations. A noteworthy feature of the solution is the slow damping of the perturbations of the velocity with the depth (inversely proportional to the square of the distance from the free surface), in contrast to the similar problem of the wave motions of a heavy liquid, for which the velocity perturbations are damped exponentially.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 2, pp. 3–7, March–April, 1984.     

Necessary and sufficient conditions for isotropic rank-one convex functions in dimension 2

We provide some new necessary and sufficient conditions for regular isotropic rank-one convex functions on M ₂ ⁺={2×2 matrices such that det M0}. It is well known that isotropic functions W (M) can be written as W (M)=G(₁, ₂) where _i are the singular values of M. One of these conditions allows us to understand better the gap between the rank-one convexity and the quasiconvexity.     

The relaxation time spectrum of nearly monodisperse polybutadiene melts

The relaxation behavior of polymers with long linear flexible chains of uniform length has been investigated by means of dynamic mechanical analysis. The relaxation time spectrum (H()) follows a scaling relationship with two self-similar regions, one for the entanglement and terminal zone, and a second one for the transition to the glass. This can be described in its most general form (termed BSW spectrum) as H() = H _e ^ne + H _g ^– n _g for < _max and H() = 0 for _max < , where H _e , H _g , n _e , n _g are material constants and _max is the molecular weight dependent cut-off of the self-similar behavior. In this study, the dynamic mechanical response has been measured and analyzed for four highly entangled, nearly monodisperse polybutadienes with molecular weights from 20000 to 200000. The data are well represented by the BSW spectrum with scaling exponents of n _e = 0.23 and n _g = 0.67. The values of the exponents obtained in this work are about the same as those found for polystyrene samples in a previous study. This suggests that the two types of polymers have a similar relaxation pattern. However, at this point further refinement of the experiments is needed before being able to draw definite conclusions about the universality of the exponents.Dedicated to Professor Arthur S. Lodge on the occasion of his 70th birthday and his retirement from the University of Wisconsin.     

A regularity theorem for certain fourth-order differential operator

ＡＲＥＧＵＬＡＲＩＴＹＴＨＥＯＲＥＭＦＯＲＣＥＲＴＡＩＮＦＯＵＲＴＨ－ＯＲＤＥＲＤＩＦＦＥＲＥＮＴＩＡＬＯＰＥＲＡＴＯＲ￥ＬｉｕＹｉｎｇｒａｎ（刘颖范）（ＮａｎｊｉｎｇＵｎｉｖｅｒｓｉｔｙｏｆＡｅｒｏｎａｕｔｉｃｓａｎｄＡｓｔｒｏｎａｕｔｉｃｓ．Ｎａ...     

Constitutive equations applied to dispersed systems

Summary It has been investigated whether constitutive equations, which have been proposed originally to describe the rheological behaviour of polymerlike materials, can be used to represent the rheology of dispersions. Such equations generally predict stresses that depend on both the shear () and a quantity ( ) which is the product of the shear rate ( ) and the time constant of the material ().The behaviour of dispersions depends in general on the concentration of the dispersed particles. The dissipative aspect of the rheological behaviour is almostNewtonian for very dilute dispersions while it becomes plastic for more densely packet dispersions. In the latter case the shear stress is practically independent of the shear rate at low shear rates. Such behaviour may be accounted for in the constitutive equations by assuming to be almost constant. This motivated us to choose the equation ofBogue where the relaxation time () depends on the shear rate ( ), according to 1/ = (1/ ₀) + a , where 1/ ₀ accounts for the viscous behaviour and a for the plastic behaviour.Comparing the actual rheological behaviour of dispersions of fat crystals in paraffin oil with the behaviour predicted by theBogue equation, it turns out that theBogue equation has some success in representing the stress overshoot in steady shear experiments. However, the predicted value of the normal stress for the concentrated dispersions is too low in comparison with the measured value. It is suggested that this discrepancy is due to the dilatant behaviour of these dispersions.Moreover, the values of the dynamic moduli measured in oscillatory shear are predicted incorrectly, due to considerable changes in particle network which already occur at very small deformations.With 10 figures     

The dynamic and steady shear properties of synovial fluid and of the components making up synovial fluid

Steady-shear and dynamic properties of a pooled sample of cattle synovial fluid have been measured using techniques developed for low viscosity fluids. The rheological properties of synovial fluid were found to exhibit typical viscoelastic behaviour and can be described by the Carreau type A rheological model. Typical model parameters for the fluid are given; these may be useful for the analysis of the complex flow problems of joint lubrication.The two major constituents, hyaluronic acid and proteins, have been successfully separated from the pooled sample of synovial fluid. The rheological properties of the hyaluronic acid and the recombined hyaluronic acid-protein solutions of both equal and half the concentration of the constituents found in the original synovial fluid have been measured. These properties, when compared to those of the original synovial fluid, show an undeniable contribution of proteins to the flow behaviour of synovial fluid in joints. The effect of protein was found to be more prominent in hyaluronic acid of half the normal concentration found in synovial fluid, thus providing a possible explanation for the differences in flow behaviour observed between synovial fluid from certain diseased joints compared to normal joint fluid.Nomenclature A Ratio of angular amplitude of torsion head to oscillation input signal - G Storage modulus - G Loss modulus - I Moment of inertia of upper platen — torsion head assembly - K Restoring constant of torsion bar - N ₁ First normal-stress difference - R Platen radius - S ⁽ⁱ⁾ Geometric factor in the dynamic property analysis - t ₁ Characteristic time parameter of the Carreau model - X, Y Carreau model parameters - Z () Reimann Zeta function of - Carreau model parameter - Shear rate - Apparent steady-shear viscosity - ^* Complex dynamic viscosity - Dynamic viscosity - Imaginary part of the complex dynamic viscosity - ₀ Zero-shear viscosity - ₀ Cone angle - Carreau model characteristic time - Density of fluid - Shear stress - Phase difference between torsion head and oscillation input signals - ₀ Zero-shear rate first normal-stress coefficient - Oscillatory frequency     

Thermal conductivity of partially ionized hydrogen

The effect of ionizing collisions on thermal conductivity is studied. A formal expression is obtained for with additional terms considering the presence of ionizing collisions in the gas. Calculations performed at p=1 atm and a temperature range of 10,000–25,000 °K show that the effect of ionizing collisions on translational heat capacity is not great. On the other hand, the presence of such collisions in the gas leads to a retardation of diffusion processes, which in turn leads to a significant reduction in the chemical component of the coefficient , with this reduction being strongly dependent on the choice of number of excited atomic levels realized in the gas.Translated from Izvestiya Akademii Nauk SSSR, Mekhanika Zhidkosti i Gaza, No. 1, pp. 98–103, January–February, 1978.     

The effect of non-steady wall shear on pressure surges in conduits carrying viscous liquids

Summary A study is made of the attenuation of pressure surges in a two-dimension a channel carrying a viscous liquid when a valve at the downstream end is suddenly closed. The analysis differs from previous work in this area by taking into account the transient nature of the wall shear, which in the past has been assumed as equivalent to that existing in steady flow. For large values of the frictional resistance parameter the transient wall shear analysis results in less attenuation than given by the steady wall shear assumption.Nomenclature c /, ft/sec - e base of natural logarithms - F(x, y) integration function, equation (38) - (x) mean value of F(x, y) - g local acceleration of gravity, ft/sec² - h width of conduit, ft - k (2m–1)^{2 2} L/h ² c, equation (35) - k* 12L/h ² c, frictional resistance parameter, equation (46) - L length of conduit, ft - m positive integer - n positive integer - p pressure, lb/ft² - p ₀ constant pressure at inlet of conduit, lb/ft² - P pressure plus elevation head, p+gz, equation (4) - mean value of P over the conduit width h - P ₀ p ₀+gz ₀, lbs/ft² - R frictional resistance coefficient for steady state wall shear, lb sec/ft⁴ - s positive integer; also, condensation, equation (6) - t time, sec - t ct/L, dimensionless time - u x component of fluid velocity, ft/sec - u _m mean velocity in conduit, equation (12), ft/sec - u ₀(y) velocity profile in Poiseuille flow, equation (19), ft/sec - transformed velocity - U initial mean velocity in conduit - x distance along conduit, measured from valve (fig. 1), ft - x x/L, dimensionless distance - y distance normal to conduit wall (fig. 1), ft - y y/h, equation (25) - z elevation, measured from arbitrary datum, ft - z ₀ elevation of constant pressure source, ft - isothermal bulk compression modulus, lbs/ft² - _n , equation (37) - _n (2n–1)/2, equation (36) - viscosity, slugs/ft sec - / = kinematic viscosity, ft²/sec - density of fluid, slugs/ft³ - ₀ density of undisturbed fluid, slugs/ft³ - ø angle between conduit and vertical (fig. 1) The research upon which this paper is based was supported by a grant from the National Science Foundation.     

Steady flow of a liquid metal in a rectangular MHD channel

The known experimental studies of steady flows of a liquid metal in magnetohydrodynamic (MHD) channels of rectangular section [1–4] were performed only for a few values of the Reynolds number, which does not permit a clear delineation of the fundamental governing laws of the flow in the zone of transition from laminar to turbulent flow. In addition, the study of turbulent MHD flows has been limited to two-dimensional channels.Below we present some results of experimental studies of the effect of a transverse magnetic field on the resistance coefficient for mercury flow in an MHD channel with side ratio 1 to 2.5. The choice of a channel with this side ratio was dictated by the need for studies of the intermediate case between flows in two-dimensional and square channels, which differ significantly from one another because of the different effect of the walls parallel to the magnetic field. In our studies, for each value of the Hartmann number the investigations were made for 30–50 values of the Reynolds number.Notation B₀ flux density of the applied magnetic field - M Hartmann number - R Reynolds number - _tm resistance factor of turbulent MHD flow - _* critical value of the resistance factor - geometric parameter of channel - the component of resistance factor in ordinary hydrodynamics due to pulsations - normed function - electric conductivity of metal - viscosity of metal - R₀ shydraulic radius - N smagnetic field parameter     

Asymptotic theory for calculating heat fluxes near the corner of a body

A method is presented for calculating the distribution of the thermal fluxes, friction stresses, and pressure near the corner point of a body contour in whose vicinity the outer supersonic flow passes through an expansion wave. The method is based on a study of the asymptotic solutions of the Navier-Stokes equations as the Reynolds number R approaches infinity for the flow region in which the longitudinal gradients of the flow functions are large, invalidating conventional boundary layer theory. This problem was examined in part in [1], in which the distribution of the friction and pressure in a region with length on the order of a few thicknesses of the approaching boundary layer was obtained in the first approximation. The leading term of the expansion for the thermal flux to the surface of the body vanishes for a value of the Prandtl number equal to unity and for other values of the Prandtl number does not match directly with its value in the undisturbed boundary layer.The thermal-flux distribution is obtained for values of the Prandtl number approaching unity. For this purpose it was necessary to consider a more general double passage to the limit as 1 and 0 for a finite value of the parameter B=[(–1)/] [–ln ^1/4/]^1/4 characterizing the ratio of the effects of thermal conduction, viscous dissipation, and convection. The solution obtained previously [1] corresponds to the particular case B and therefore for actual values of R=10⁴–10⁶, ~ 0.7 overestimates considerably the effect of the dissipative term on heat transfer, although even in first approximation it describes the pressure distribution well and the friction distribution satisfactorily. For smooth matching of the solutions with the corresponding flow functions in the undisturbed boundary layer it was necessary to introduce a flow region with free interaction for the expansion flow. Equations and boundary conditions which describe the flow as a whole are presented. Examples are given of numerical calculations and comparison with experiment.     

The relaxation of polymers with linear flexible chains of uniform length

The analysis of dynamic mechanical data indicates that linear flexible polymer chains of uniform length follow a scaling relation during their relaxation, having a linear viscoelastic relaxation spectrum of the formH() = n ₁ G _N ⁰ × (/ _max) ⁿ¹ for _max. Data are well represented with a scaling exponent of about 0.22 for polystyrene and 0.42 for polybutadiene. The plateau modulusG _N ⁰ is a material-specific constant and the longest relaxation time depends on the molecular weight in the expected way. At high frequencies, the scaling behavior is masked by the transition to the glassy response. Surprisingly, this transition seems to follow a Chambon-Winter spectrumH() = C^–n2, which was previously adopted for describing other liquid/solid transitions. The analysis shows that the Rouse spectrum is most suitable for low molecular-weight polymersM M _c , and that the de Gennes-Doi-Edwards spectrum clearly predicts terminal relaxation, but deviates from the observed behavior in the plateau region.Dedicated to Prof. Richard S. Stein on the occasion of his 65th birthday.On sabbatical leave from the University of Linz, Austria.