共查询到20条相似文献,搜索用时 156 毫秒
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利用457.5nm固体激光器作为激发光源,得到了在不同功率激发下的多孔硅样品的拉曼光谱以及一些谱峰参数随功率的变化关系. 在从前的理论研究中,认为是由于激光功率的增大导致样品局域温度升高,从而使样品局域粒径变小,并由此引起了一系列谱峰参数的变化. 分别由520cm-1和300cm-1附近得到的随功率变化的拉曼谱图,详细讨论并计算了激光功率对多孔硅样品局域温度的定量影响,为拉曼光谱用于样品温度的定量测量奠定了实验基础.
关键词:
拉曼光谱
多孔硅
激光功率
样品温度 相似文献
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《光学学报》2015,(5)
提出了多孔硅表面缺陷光子晶体结构,引入多孔硅敏感层及吸收介质层形成表面缺陷腔,利用多孔硅高效的承载机制,将其作为待测样本的传感区域;由于吸收介质Zn S对谐振波长的吸收,可在反射光谱中获得与谐振波长对应的缺陷峰。以多孔硅的厚度为被优化变量,利用反向传播神经网络进行结构参数优化获得多孔硅的厚度最优值。由Goos-H?nchen位移建立待测样本浓度与缺陷峰波长的关系模型,进而对该结构进行传感特性分析。结果表明,优化结构参数后,缺陷峰对应的反射率由31.23%下降到0.00129%,其Q值可达1537.37。在传感特性研究中,每1%质量分数的灵敏度为2.5 nm。该表面缺陷光子晶体传感结构可为样本浓度、组分等信息的监测提供一定的理论参考。 相似文献
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理论上,采用Bruggeman有效介质近似,研究了有机吸附物对多孔硅微腔的折射率及其光致发光谱的影响.实验上,采用计算机控制的电化学腐蚀法制备了多孔硅微腔样品,并利用机械泵油的蒸气分子与该微腔样品进行相互作用.研究发现,多孔硅微腔发射的窄化光致发光谱对泵油蒸气分子的吸附与脱附很敏感,与之伴随的是该窄化光致发光谱发生明显的峰位移动(可达71nm)和强度变化.结合Bruggeman近似和表面态对多孔硅发光的影响,对实验结果进行了定性解释.实验结果与理论模拟结果符合较好.
关键词:
Bruggeman近似
吸附物
多孔硅微腔
光致发光谱 相似文献
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In this paper, a method based on transmission-speckle correlation is proposed for measuring static and dynamic deformation of liquid surface. In the method, a high-speed camera placed vertically above the tested liquid surface is used to observe and record a special speckle pattern put in advance at the bottom of liquid. According to the Snell׳s law, the deformation of liquid surface will lead to the movement of the transmission-speckles. In terms of this, the quantitative relationship between height changes of liquid surface and the in-plane displacement of transmission-speckles can be deduced. Combining with multi-directional Newton iteration algorithm, the dynamic deformation field of liquid surface can be calculated from the in-plane displacement vector field of transmission-speckle images in different moment using speckle correlation method. The sensitivity of the method in measuring height changes of liquid surface is discussed. In this paper, a validation test to measure the surface morphology of a plano-convex lens demonstrates the feasibility and the effectiveness of the method. In addition, the dynamic deformation and propagation process of ripples in the water surface caused by a droplet were investigated. 相似文献
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为了精密检测靶丸壳层厚度及其分布数据,开展了靶丸壳层厚度及其分布的白光反射光谱测量技术研究。介绍了靶丸壳层的白光反射光谱及其光谱数据处理方法(极值法、峰值拟合法、干涉级次校正法等)的基本原理,搭建了基于白光反射光谱的精密回转轴系测量装置;开展了GDP靶丸壳层厚度及其分布的白光反射光谱测量、数据处理和可靠性验证实验,获得了靶丸壳层厚度圆周分布曲线。结果表明,基于峰值拟合法和干涉级次校正的白光反射光谱技术可实现靶丸壳层厚度及其分布的准确测量,其测量误差小于0.1 μm。 相似文献
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现实中很多场景都需要精确的颜色表示,如纺织、印刷、艺术品扫描存档、在线商品展示等。光谱反射率是决定物体颜色的本质属性,如果知道了光谱反射率,就可以重现物体在任何光照和观测条件下的颜色。采用专业仪器测量光谱反射率有成本高、分辨率低、测量时间慢等问题。随着数码成像设备的普及,基于相机RGB响应值的光谱反射率重建算法具有重要现实意义。光谱反射率重建的目的是建立低维RGB响应值到高维光谱反射率向量的映射关系,回归方法在这一领域已取得广泛应用。由于光谱反射率向量所处的空间是嵌在高维欧氏空间中的一个低维子流形,在训练样本有限的条件下,传统的全局回归方法不能有效地学习该流形结构,往往导致过拟合,使得学习出来的模型泛化能力较差。局部线性回归方法虽然可以改善全局回归过拟合的问题,但是局部学习方法易受例外点的影响,导致拟合不足。针对这一问题,提出一种基于局部加权线性回归的光谱反射率重建方法,这种方法在一个k最近邻范围约束内,给每个局部训练样本赋予不同的权重,从而有所侧重地利用局部训练样本来估计光谱反射率。实验结果表明,基于局部k最近邻加权线性回归的方法能更有效地利用局部信息,缓解过拟合和拟合不足,更准确地重建光谱反射率。 相似文献
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针对皮肤胆固醇无创检测的迫切需求,设计了一种基于微型光谱仪的便携式和智能化的皮肤漫反射光谱实时测量系统。配制毛地黄皂苷—辣根过氧化物酶共聚物溶液,利用毛地黄皂苷可与皮肤胆固醇分子中的羟基特异性结合和辣根过氧化物酶能与TMB试剂(主要成分为3,3’,5,5’-四甲基联苯胺)反应显色的特性,实现皮肤胆固醇的高灵敏和高特异的识别与指示,并通过测量反应后颜色的变化程度来定量皮肤胆固醇的浓度。以与人体皮肤结构相近的猪皮肤为实验对象,采用萃取法获得梯度浓度的胆固醇样本,利用上述光谱测量系统检测样本内的胆固醇浓度来验证该方法的可行性。实验结果显示,相对漫反射率能够区分不同浓度的胆固醇样本,在特征单波长(442,450和463 nm)处和特征波段442~500 nm内,漫反射率强度因子均可以定量反映样本内的胆固醇浓度,经线性拟合,判定系数R2分别为0.960,0.959,0.958和0.958。研究结果表明,使用漫反射光谱技术可以实现皮肤胆固醇的快速无创检测,将其应用于动脉粥样硬化性疾病风险评估,对于该类疾病的防控具有重要意义。 相似文献
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鲜肉水分近红外漫反射方法及实验研究 总被引:2,自引:0,他引:2
研究鲜肉深层水分的快速、无损检测方法,并用于鲜肉深层水分检测仪器的研制,具有很重要的现实意义,也是市场迫切的需求。以猪鲜肉为样品,采用近红外离散式光源,应用基于稳态空间分辨方法的漫反射方式解决了检测深度问题,测量鲜肉水分含量,得到了比较好的实验结果,r均达到0.90以上。用变异系数calculation of coefficient of variability(CV)和组内相关系数intra class correlation(ICC)检验测量的可靠性,CV≤5%,ICC达到0.83,表明方法稳定可靠。 相似文献
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One of the important factors through food manufacturing is hygienic management. Thus, food manufactures prove their hygienic activities by taking certifications like a Hazard Analysis and Critical Control Point (HACCP). This concept also applies to food monitoring. Acoustical measurements have advantage for other measurement in food monitoring because they make it possible to measure with noncontact and nondestructive. We tried to monitor lactic fermentation of yogurt by a probing sensor using a pair of acoustic transducers. Temperature of the solution changes by the reaction heat of fermentation. Consequently the sound velocity propagated through the solution also changes depending on the temperature. At the same time, the solution change its phase from liquid to gel. The transducers usage in the solution indicates the change of the temperature as the change of the phase difference between two transducers. The acoustic method has advantages of nondestructive measurement that reduces contamination of food product by measuring instrument. The sensor was inserted into milk with lactic acid bacterial stain of 19 degrees C and monitored phase retardation of propagated acoustic wave and its temperature with thermocouples in the mild. The monitoring result of fermentation from milk to Caspian Sea yogurt by the acoustic transducers with the frequency of 3.7 MHz started to show gradient change in temperature caused by reaction heat of fermentation but stop the gradient change at the end although the temperature still change. The gradient change stopped its change because of phase change from liquid to gel. The present method will be able to measure indirectly by setting transducers outside of the measuring object. This noncontact sensing method will have great advantage of reduces risk of food contamination from measuring instrument because the measurement probes are set out of fermentation reactor or food containers. Our proposed method will contribute to the hygienization for the food manufacture industry. 相似文献
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A new method is proposed here for measuring the optical constants of solids. The method is based on measuring the change of the derivative of reflectance with the angle of incidence Θ of p-polarized light for different Θ around the pseudo-Brewster angle. The accuracy of the method has been checked by determining the optical constants of some transparent and opaque materials. The method seems very sensitive to the presence of thin oxide layers and it is also expected to be useful in determining oxide thicknesses. 相似文献
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文物壁画在自然环境下产生褪色现象具有复杂性,严格意义上讲,人们无法重现自然环境下这种褪色发生的条件,但这并不妨碍人们研究其褪色原因的可能性和途径。通过实验来验证所提出机制的合理性,这也符合自然科学普遍采用的研究方法。提出颜料层微观形貌变化是引起壁画褪色的一种重要原因。胶料作为颜料层的连续相,当胶料分解时,颜料层微观形貌必然产生变化,为证明这种变化会引起颜料层褪色,而非颜料变化所致。建立了以具有较高热稳定性的赭石为颜料,以明胶作为粘接剂制成模拟的壁画颜料层。然后通过加热处理使胶料发生氧化分解,从而造成颜料层微观形貌发生变化,但赭石颜料依然稳定,期望证明在颜料赭石不发生变化时,由于颜料层微观形貌变化也可引起颜料褪色。实验通过煅烧壁画颜料层模拟样获得胶料降解的壁画模型,分别以SEM及多角度反射率光谱等技术,考察模拟样胶料降解前后表面微观形貌和光学性质变化。结果表明:壁画模拟样煅烧后,颜料层表面产生空隙结构,样品表面多角度反射率光谱表明煅烧后样品颜料层对可见光的反射增加而吸收降低,并观察到模拟样颜色淡化。以无色,难挥发,且不与颜料层发生化学反应的离子液体涂覆褪色样品表面,以上述技术表征涂覆处理前后颜料层表面微观形貌和表面光学性质变化,结果表明:离子液体填充了褪色样品表面颗粒间空隙,检测到样品表面对可见光的反射降低而吸收增加,观察到褪色样品的颜色加深。以上实验结果证明了推测合理性,即微观形貌变化确实会引起颜色变化。依据此原理以唐代墓室褪色壁画为例,进行了显现修复应用研究,其颜色显现效果显著。 相似文献