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1.
Aryltellurenyl iodides react with Reformatsky reagents in dry THF at room temperature rapidly to produce α-aryltelluro esters in good yields. 相似文献
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α-Functionalized chlorophosphonic monoesters were easily prepared by a selective chlorination of the corresponding phosphonic diesters with phosphorus oxychloride. 相似文献
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A New Convenient Synthesis of Pyridine-N-oxides 总被引:2,自引:0,他引:2
《中国化学快报》1996,(10)
ANewConvenientSynthesisofPyridine-N-oxidesTaoLU;XinZhongSHI;YiMingWU(Dept.ofOrganicChemistry,ChinaPharmaceuticalUniversity,Na... 相似文献
5.
We have reported the reductive cleavage of azlactones1 and phenylhydrazones2 of carbonyl compounds in the presence of a suitable catalyst. In this paper a general method involving a one step synthesis of β-amino acid3,4, in good yield, through catalytic reduction of oximes of α-β-unsaturated acid is reported. This method involves the reaction of α, β-unsaturated acid with hydroxylamine hydrochloride in the presence of sodium acetate. Markovnikov's rule is followed in the synthesis of oximes of α, β-unsaturated acids. 相似文献
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A series of vinydiazomethanes were readily prepared by sodium borohydride reduction of a-diazo-p-ketoesters followed by phosphorus oxychloride induced dehydration of the resulting a-diazo-p-hydroxyesters. 相似文献
7.
Starting from 2, 3-O-isopropylideneglycerol (1), a general procedure for the preparation of protected α-hydroxyacetaldehydes has been developed. 相似文献
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Glycidic esters, upon isomerisation with BF3.Et2O yield α-hydroxy-β,γ-unsaturated esters. These are then reduced with LiAlH4 to vicinal diols which are converted to vinyl epoxides in two steps. 相似文献
9.
Hua Fang Weizhu Chen Bihong Hong Yufen Zhao Meijuan Fang 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2182-2193
This article describes the synthesis of α-hydroxyphosphonic acid esters using the Pudovik reaction. IR, 1H NMR, 13C NMR, 31P NMR, MS, and elemental analysis were employed to confirm their structures. X-ray structure analysis is reported for six compounds. The antibacterial activities of these compounds are also reported. Supplemental materials are available for this article. Go to the publisher's online edition of Phosphorus, Sulfur, and Silicon and the Related Elements to view the free supplemental file. 相似文献
10.
Aromatic α-hydroxyiminoacetonitriles can be conveniently prepared by a facile one-pot procedure in high yields involving chlorination of the corresponding aldoximes with tert-butyl hypochlorite followed by reaction with alkali cyanide. 相似文献
11.
Aromatic α-hydroxyiminoacetonitriles can be conveniently prepared by a facile one-pot procedure in high yields involving chlorination of the corresponding aldoximes with tert-butyl hypochlorite followed by reaction with alkali cyanide. 相似文献
12.
During a study of synthetic approaches to various naturally-occurring sesquiterpenes lactones, we developed a new synthesis of the α-methylene-γ-butyrolactone group.1 This new sequence suggested that it might be applicable to the general synthesis of α-methylenecarbonyl compounds.2 This report describes the application to a general synthesis of α-substituted acrylic esters. 相似文献
13.
Reaction of 2-functional alkyl-1,3-diketones with 30% aqueous formaldehyde using aqueous 6-10M potassium carbonate solution as base, afforded a-functional alkyl vinyl ketones in good yields. 相似文献
14.
A synthesis of α-bromo-α,β-unsaturated esters 2 from tert-butyl α-(trimethylsilyl)-α-bromoacetate (1) and carbonyl compounds is described. 相似文献
15.
Diego Colombo Fiamma Ronchetti Antonio Scala Ida M. Taino Piera A. Taino 《Journal of carbohydrate chemistry》2013,32(4):611-617
Abstract An efficient chemoenzymatic synthesis of methyl α-d-allopyranoside and methyl 3-deoxy-α-d-ribo-hexopyranoside starting from methyl 4,6-O-benzylidene-α-d-glucopyranoside is described. 相似文献
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α,β-unsaturated nitriles were synthesized by the reaction of aldehydes with bromoacetonitrile promoted by tri-n-butylphosphine and zinc. 相似文献
18.
Raisa Kalyanova Pavel Petrovskii Tatyana Mastryukova 《Phosphorus, sulfur, and silicon and the related elements》2013,188(8-9):2225-2226
y -Haloalkyl dithiophosphorus acid esters undergo the thermal rearrangement resulting in the corresponding 2-oxo-1,3,2-dithiaphosphacyclanes. 相似文献
19.
The synthetic utility of α-methylene carbinols has prompted considerable recent preparative interest. However, many of the reported methods1 lack scope and require reagents or reaction conditions which are incompatible with sensitive functional groups. We report below two closely related methods for the synthesis of α-methylene carbinols which are based on the reductive elimination of β,γ-epoxysulfones. Both methods give the desired products in moderate overall yield in a four-step sequence which is mild and experimentally facile. 相似文献
20.
The tert‐butyl esters of indole‐5‐carboxylic acid and related compounds such as benzofuran‐ and benzothiophene‐5‐carboxylic acid were readily accessed by reacting the appropriate carboxylic acids with tert‐butyl trichloroacetimidate. To obtain the tert‐butyl esters of the 5‐carboxylic acids of 1H‐benzotriazole and 1H‐benzimidazole, position 1 of these heterocycles had to be protected by acetylation prior to reaction with tert‐butyl trichloroacetimidate. Cleavage of the acetyl residue of the obtained intermediates by dilute aqueous NaOH in ethanol led to the desired tert‐butyl 1H‐benzotriazole‐and 1H‐benzimidazole‐5‐carboxylates. 相似文献