Rheological Study of Loosened Bulk Granular Materials

Loosened bulk materials occur, for example, during grinding in a tube mill. Thus, a rheological study of bulk granular materials which are loosened by fluidisation should lead to a better characterization of the flow and conveying properties of the material when ground in the mill. For this measurement of fluidised bulk materials an agitating device and a rotary viscosimeter have been developed, designed and tested. First results are presented and discussed showing the fluidisation behaviour and density of the bulk material as a function of grain size as well as the flow properties as a function of the grain size and degree of fluidisation. Finally, a projection of further research work is given.     

Simulation of triaxial response of granular materials by modified DEM

A modified discrete element method(DEM)with rolling effect taken into consideration is developed to examine macroscopic behavior of granular materials in this study.Dimensional analysis is firstly performed to establish the relationship between macroscopic mechanical behavior,mesoscale contact parameters at particle level and external loading rate.It is found that only four dimensionless parameters may govern the macroscopic mechanical behavior in bulk.The numerical triaxial apparatus was used to study their influence on the mechanical behavior of granular materials.The parametric study indicates that Poisson’s ratio only varies with stiffness ratio,while Young’s modulus is proportional to contact modulus and grows with stiffness ratio,both of which agree with the micromechanical model.The peak friction angle is dependent on both inter-particle friction angle and rolling resistance.The dilatancy angle relies on inter-particle friction angle if rolling stiffness coefficient is sufficiently large.Finally,we have recommended a calibration procedure for cohesionless soil,which was at once applied to the simulation of Chende sand using a series of triaxial compression tests.The responses of DEM model are shown in quantitative agreement with experiments.In addition,stress-strain response of triaxial extension was also obtained by numerical triaxial extension tests.     

Jamming, yielding, and rheology of weakly vibrated granular media

We establish that the rheological curve of dry granular media is nonmonotonic, both in the presence and absence of external mechanical agitations. In the presence of weak vibrations, the nonmonotonic flow curves govern a hysteretic transition between slow but steady and fast, inertial flows. In the absence of vibrations, the nonmonotonic flow curve governs the yielding behavior of granular media. Finally, we show that nonmonotonic flow curves can be seen in at least two different flow geometries and for several granular materials.     

Modeling of stress distribution in granular piles: Comparison with centrifuge experiments

The classical method to compute stress and strain distributions in granular materials is recalled using continuum mechanics approach, and different rheological laws described. It is recalled that granular materials exhibit highly nonlinear response such as nonlinear elasticity, dilatancy and plastic flow. Finite element technique is used to predict the stress field distribution below a conic and a triangular pile. The dependence of the stress distribution on the rheological law, the bottom boundary condition and the building process (horizontal or inclined strata) is demonstrated. These results are compared to experimental data obtained in centrifuge. (c) 1999 American Institute of Physics.     

密集斜槽流颗粒靶的流动性

研究了中子辐照装置密集斜槽流颗粒靶设计的流动性,该靶设计能够提供适用于聚变反应堆材料研究的高能中子。本文通过数值模拟和理论分析的方法描述了流动的稳定性和稳固性,这在其他文献中很少被提及。结果发现,25°对于稳定的流动是可以接受的,这种颗粒流有潜力成为热介质的选择。     

Granular Leidenfrost effect in vibrated beds with bumpy surfaces

The effects of subjecting a bed of granular materials to horizontal vibrations by a bumpy oscillating surface have been investigated computationally in this study. The behaviour of the granular bed is determined by the vibration conditions applied which include the vibrating frequency and amplitude as well as the bumpiness of the oscillating surface. Under sufficiently vigorous vibration conditions, the granular Leidenfrost effect whereby the entire granular bed is levitated above the vibrating base by a layer of highly energetic particles may be observed. Granular temperature profiles of systems that exhibit the granular Leidenfrost effect indicate an unequal distribution of energy between particles near the vibrating base and those in the bulk. A bumpy oscillating surface was also observed to be more effective at introducing perturbations and transferring energy into a granular bed. The granular Leidenfrost effect can be induced by the application of larger grain sizes of particles constituting the bumpy vibrating base under vibration conditions that are normally insufficient for the onset of the effect. Lastly, a phase diagram which can be utilized for predicting the behaviours of granular beds that are subjected to oscillations by various types of bumpy surfaces has been constructed based on the simulation results obtained.     

Jamming and flow of random-close-packed spherical bubbles: an analogy with granular materials

Wet foams are random-close-packed assemblies of approximately spherical gas bubbles in a liquid. We report rheological experiments with this material, showing that even though the stiffness and frictional interactions of bubbles strongly distinguish them from solid spherical grains, jamming and flow of wet foams and granular materials are governed by closely analogous laws.     

Influence of ultrasonication and Fenton oxidation pre-treatment on rheological characteristics of wastewater sludge

The effect of ultrasonication and Fenton oxidation as physico-chemical pre-treatment processes on the change of rheology of wastewater sludge was investigated in this study. Pre-treated and raw sludges displayed non-Newtonian rheological behaviour with shear thinning as well as thixotropic properties for total solids ranging from 10 g/L to 40 g/L. The rheological models, namely, Bingham plastic, Casson law, NCA/CMA Casson, IPC Paste, and power law were also studied to characterize flow of raw and pre-treated sludges. Among all rheological models, the power law was more prominent in describing the rheology of the sludges. Pre-treatment processes resulted in a decrease in pseudoplasticity of sludge due to the decrease in consistency index K varying from 42.4 to 1188, 25.6 to 620.4 and 52.5 to 317.9; and increase in flow behaviour index n changing from 0.5 to 0.35, 0.62 to 0.55 and 0.63 to 0.58, for RS, UlS and FS, respectively at solids concentration 10–40 g/L. The correlation between improvement of biodegradability and dewaterability, decrease in viscosity, and change in particle size as a function of sludge pre-treatment process was also investigated. Fenton oxidation facilitated sludge filterability resulting in capillary suction time values which were approximately 50% of the raw sludges, whereas ultrasonication with high input energy deteriorated the filterability. Biodegradability was also enhanced by the pre-treatment processes and the maximum value was obtained (64%, 77% and 73% for raw, ultrasonicated and Fenton oxidized sludges, respectively) at total solids concentration of 25 g/L. Hence, pre-treatment of wastewater sludge modified the rheological properties so that: (1) the flowability of sludge was improved for transport through the treatment train (via pipes and pumps); (2) the dewaterability of wastewater sludge was enhanced for eventual disposal and; (3) the assimilation of nutrients by microorganisms for further value-addition was increased.     

In-Line Monitoring of Rheological Parameters with an Electromagnetic Flowmeter

Tomographic signal processing has been added to a conventional electromagnetic flowmeter. The result is a new method for measuring rheological parameters of viscous, non-Newtonian fluids. The practical realization requires only minor changes to existing instruments. Hence their main advantages are maintained, such as non-invasive, in-line measurement without pressure drop. The basic idea is to generate two different magnetic fields with the flowmeter by switching the current direction in one of the magnetic coils. The flowmeter measures two signals depending on the flow profile. Using simple parametric models for both the flow profile and the rheology, the flow profile can be calculated from the flowmeter signals, and from the flow profile the rheological behaviour is determined. The theory and experimental results with a slightly modified industrial flowmeter are presented.     

颗粒介质弹性的弛豫

颗粒介质是复杂的多体相互作用体系, 其弹性源自内部的力链结构, 弹性能量处在亚稳态, 具有复杂的弛豫行为. 在常规作用下, 颗粒介质往往呈现明显的弹性弛豫. 应力松弛是应变恒定时应力的衰减现象, 弹性弛豫是应力松弛的主要原因. 在前期工作基础上, 从弹性势能面和双颗粒温度热力学角度分析了弹性弛豫的机理, 量化了弹性应力演化不可逆过程; 基于双颗粒温度热力学计算得到了弹性能、颗粒温度和应力的演化, 其中应力松弛的计算结果与实验结果基本一致, 讨论了颗粒温度初值和输运系数的影响. 指出, 开展力链结构及其动力学研究是揭示宏观弹性弛豫机理的关键.     

Avalanche behavior in yield stress fluids

We show that, above a critical stress, typical yield stress fluids (gels and clay suspensions) and soft glassy materials (colloidal glasses) start flowing abruptly and subsequently accelerate, leading to avalanches that are remarkably similar to those of granular materials. Rheometrical tests reveal that this is associated with a bifurcation in rheological behavior: for small stresses, the viscosity increases in time; the material eventually stops flowing. For slightly larger stresses the viscosity decreases continuously in time; the flow accelerates. Thus the viscosity jumps discontinuously to infinity at the critical stress. We propose a simple physical model capable of reproducing these effects.     

The Use of an Antistatic Agent to Improve Powder Flowability

Small quantities of Larostat 519, an anti-static agent, were added to four samples of a commercial organic powder which was giving flowability problems believed to be caused by electrostatics. The effects on standardised bulk densities, on the Hausner Ratio, and on the behaviour of the samples when exposed to various controlled relative humidities in an experimental rotating inclined pan, were significant, and are reported and interpreted.     

Rheology of dense granular mixtures: boundary pressures

Models for dense sheared granular materials indicate that their rheological properties depend on particle size, but the representative size for mixtures is not obvious. Here, we computationally study pressure on a boundary due to sheared granular mixtures to determine its dependence on particle size distribution. We find that the pressure does not depend monotonically on average particle size. Instead it has an additional dependence on a measure of the effective free volume per particle we adapt from an expression for packing of monosized particles near the jammed state.     

da Vinci fluids,catch-up dynamics and dense granular flow

We introduce and study a da Vinci fluid, a fluid whose dissipation is dominated by solid friction. We analyse the flow rheology of a discrete model and then coarse-grain it to the continuum. We find that the model gives rise to behaviour that is characteristic of dense granular fluids. In particular, it leads to plug flow. We analyse the nucleation mechanism of plugs and their development. We find that plug boundaries generically expand and we calculate the growth rate of plug regions. In systems whose internal effective dynamic and static friction coefficients are relatively uniform we find that the linear size of plug regions grows as (time)^1/3 . The suitability of the model to granular materials is discussed.     

Two-point microrheology of inhomogeneous soft materials

We demonstrate a novel method for measuring the microrheology of soft viscoelastic media, based on cross correlating the thermal motion of pairs of embedded tracer particles. The method does not depend on the exact nature of the coupling between the tracers and the medium, and yields accurate rheological data for highly inhomogeneous materials. We demonstrate the accuracy of this method with a guar solution, for which other microscopic methods fail due to the polymer's mesoscopic inhomogeneity. Measurements in an F-actin solution suggest conventional microrheology measurements may not reflect the true bulk behavior.     

Some remarks on the rheology of dense granular flows

The paper reviews some peculiar properties exhibited by granular flows. We emphasize the inability of kinetic theory and of Bagnolds heuristic approach to describe the rapid regime of densely packed flows, characterized by the breakdown of the binary collision picture and by multibody long-lasting contacts. We suggest that deformation waves through the continuous paths of contacts can be effective to transport momentum and energy through the bulk, in a time very short compared to the inverse of the shear rate. This mechanism could explain some key rheological features encountered in dense granular materials.Received: 25 June 2004, Published online: 31 August 2004PACS: 45.70.-n Granular systemsJ. Rajchenbach: On leave from LMDH (CNRS-UMR 7603), Université P. et M. Curie, 75005 Paris, France.     

Preparation of Super Soft Granules from Nanosized Ceramic Powders by Spray Freezing

Owing to their extremely high specific surfaces and their high surface-to-volume ratios nanosized ceramic powders show a strong tendency to agglomeration and poor flowability. For improved properties of these powders during storage, transport and shaping a granulation step is necessary. However, the granules must be completely destroyed during dry pressing or redispersion; otherwise, the advantages of nanoparticles in comparison to conventional powders will not be realized. Spray freezing is a new granulation technique which combines the advantages of a conventional granulation by spray drying and a sublimation drying process. Different suspensions of nanosized oxide powders were rapidly frozen by spray freezing and subsequently dried by freeze drying. Thus, capillary forces can be excluded by this process. The achieved granulates show spheric granules with very low strength, improved flowability and increased bulk density. They were redispersible and can be destroyed under very low pressures.     

Creep motion in a granular pile exhibiting steady surface flow

We investigate experimentally granular piles exhibiting steady surface flow. Below the surface flow, it has been believed that a "frozen" bulk region exists, but our results show no such frozen bulk. We report here that even the particles in layers deep in the bulk exhibit very slow flow and that such motion can be detected at an arbitrary depth. The mean velocity of the creep motion decays exponentially with depth, and the characteristic decay length is approximately equal to the particle size and is independent of the flow rate. It is expected that the creep motion we have seen is observable in all sheared granular systems.     

Novel experimentally observed phenomena in soft matter

Soft materials such as colloidal suspensions, polymer solutions and liquid crystals are constituted by mesoscopic entities held together by weak forces. Their mechanical moduli are several orders of magnitude lower than those of atomic solids. The application of small to moderate stresses to these materials results in the disruption of their microstructures. The resulting flow is non-Newtonian and is characterized by features such as shear rate-dependent viscosities and non-zero normal stresses. This article begins with an introduction to some unusual flow properties displayed by soft matter. Experiments that report a spectrum of novel phenomena exhibited by these materials, such as turbulent drag reduction, elastic turbulence, the formation of shear bands and the existence of rheological chaos, flow-induced birefringence and the unusual rheology of soft glassy materials, are reviewed. The focus then shifts to observations of the liquid-like response of granular media that have been subjected to external forces. The article concludes with examples of the patterns that emerge when certain soft materials are vibrated, or when they are displaced with Newtonian fluids of lower viscosities.     

Capillary cohesion and mechanical strength of polydisperse granular materials

We investigate the macroscopic mechanical behaviour of wet polydisperse granular media. Capillary bonding between two grains of unequal diameters is described by a realistic force law implemented in a molecular-dynamics algorithm together with a protocol for the distribution of water in the bulk. Axial-compression tests are simulated for granular samples at different levels of water content, and compared to experiments performed in similar conditions. We find good agreement between numerical and experimental data in terms of the rupture strength as a function of water content. Our results show the importance of the distribution of water for the mechanical behaviour.