Element‐selective X‐ray detected magnetic resonance: a novel application of synchrotron radiation

X‐ray detected magnetic resonance (XDMR) is a new element‐selective spectroscopy in which X‐ray magnetic circular dichroism is used to probe the resonant precession of spin and orbital magnetization components when a strong microwave pump field is applied perpendicularly to the static bias field. Experimental configurations suitable for detecting the very weak XDMR signal are compared. XDMR signatures were measured in yttrium iron garnet and related thin films on exciting not only the iron K‐edge but also the yttrium at diamagnetic sites. These measurements are shown to yield unique information regarding the wide‐angle precession of induced magnetization components involving either orbital p‐projected densities of states at the iron sites, or spin polarized d‐projected densities of states at the yttrium sites. Extending XDMR measurements into the millimeter wave range would make it possible to study paramagnetic systems routinely and investigate optical modes as well as acoustic modes in ferrimagnetic/antiferromagnetic systems.     

X-ray detected magnetic resonance at the Fe K-edge in YIG: Forced precession of magnetically polarized orbital components

X-ray detected magnetic resonance (XDMR) has been measured for the first time on exciting the Fe K-edge in a high-quality yttrium iron garnet film epitaxially grown on a gadolinium gallium garnet substrate. This challenging experiment required resonant pumping of yttrium iron garnet at high microwave power, i.e., in the foldover regime. X-ray magnetic circular dichroism (XMCD) was used to probe the change in the longitudinal component of the magnetization M _Z induced by the precession of magnetic moments located at the iron sites. Since XMCD at the Fe K-edge refers mostly to the equilibrium contribution of magnetically polarized 4p orbital components, XDMR at the Fe K-edge should reflect the precessional dynamics of the latter orbital moments. From the measured precession angle, we show that there is no dynamical quenching of the polarized orbital components at the iron sites in yttrium iron garnet.     

Two-magnon relaxation reversal in ferrite spheres

The reversal of two-magnon relaxation associated with linear scattering of oscillations of uniform magnetization precession from sample nonuniformities is studied theoretically and experimentally in ferrite spheres of yttrium iron garnet (YIG). Relaxation reversal is performed by parametric phase conjugation of dipole-exchange spin waves formed as a result of scattering of uniform precession from inhomogeneities. As a result of two-magnon backward scattering of dipole-exchange spin waves with a certain time delay, magnetization oscillations are renewed with an amplitude that could exceed the initial amplitude of uniform precession. The relaxation reversal is due to crystallographic anisotropy of the sample and is manifested most strongly when a YIG sphere is magnetized along the intermediate axis [110]. Experiments were carried out on YIG spheres of diameter 0.65–1.05 mm for a parallel pumping frequency ω _p /2π ≈ 9.4 GHz, which is about twice the uniform precession frequency. The maximal delay time for the restored signal of uniform precession was about 2 μs, while the maximal amplitude exceeded the initial uniform precession amplitude by a factor of about 5. The “latent” relaxation parameters of ferrites, e.g., the natural ferromagnetic resonance linewidth associated with many-particle processes and the linewidth associated with two-magnon scattering at bulk nonuniformities, are determined experimentally.     

Element selective X-ray magnetic circular and linear dichroisms in ferrimagnetic yttrium iron garnet films

X-ray magnetic circular dichroism (XMCD) was used to probe the existence of induced magnetic moments in yttrium iron garnet (YIG) films in which yttrium is partly substituted with lanthanum, lutetium or bismuth. Spin polarization of the 4d states of yttrium and of the 5d states of lanthanum or lutetium was clearly demonstrated. Angular momentum resolved d-DOS of yttrium and lanthanun was shown to be split by the crystal field, the two resolved substructures having opposite magnetic polarization. The existence of a weak orbital moment involving the 6p states of bismuth was definitely established with the detection of a small XMCD signal at the Bi M₁-edge. Difference spectra also enhanced the visibility of subtle changes in the Fe K-edge XMCD spectra of YIG and {Y, Bi}IG films. Weak natural X-ray linear dichroism signatures were systematically observed with all iron garnet films and with a bulk YIG single crystal cut parallel to the (1 1 1) plane: this proved that, at room temperature, the crystal cannot satisfy all requirements of perfect cubic symmetry (space group: ), crystal distortions preserving at best trigonal symmetry ( or R3m). For the first time, a very weak X-ray magnetic linear dichroism (XMLD) was also measured in the iron K-edge pre-peak of YIG and revealed the presence of a tiny electric quadrupole moment in the ground-state charge distribution of iron atoms. Band-structure calculations carried out with fully relativistic LMTO-LSDA methods support our interpretation that ferrimagnetically coupled spins at the iron sites induce a spin polarization of the yttrium d-DOS and reproduce the observed crystal field splitting of the XMCD signal.     

X-ray detected ferromagnetic resonance in thin films

We discuss the physical content of X-ray Detected Magnetic Resonance (XDMR), i.e. a novel spectroscopy which uses XMCD to probe the resonant precession of the local magnetization in a strong microwave pump field. We focus on the simplest case of a steady-state precession of elemental moments in the non-linear regime of angular foldover. Like XMCD, XDMR is element and edge selective and could become a unique tool to investigate how precessional dynamics can locally affect the spin and orbital magnetization of p- or d-projected DOS. This should be possible only in the limit where there is no overdamping due to ultrafast orbit-lattice relaxation.     

Optical characterization of thermal-stress induced by spin waves in thin-film ferrimagnetic structures

It is shown that intense spin-dipole waves (SDWs) excited in thin yttrium iron garnet (YIG) films induce an in-plane thermal stress (σ) of 1-2 MPa in a YIG/GGG structure (where GGG is gadolinium gallium garnet). In YIG/GGG with normal magnetization, σ shifts its ferromagnetic resonance frequency by ≈1 MHz, which is comparable to the linewidth of the absorption curve of YIG/GGG resonators. The effect was characterized by an optical technique that detects σ in the GGG substrate. It was also demonstrated that this effect can be used for the optical-microwave spectroscopy of spin waves in thin ferromagnetic films, by using thermal mapping of SDWs in the substrate. We have shown that this opens up the possibility of determining the contribution of the two-particle magneto-elastic interaction to the microwave heating of the sample.     

外延YIG膜中激发磁模的精细结构

用激发磁波的方式在面内磁化的外延YIG膜上得到了一组等间距、慢衰减的磁模。考虑到磁化强度在模内不均匀性及进动为椭圆进动,导出了模式间距和磁性参数间的关系。和实验比较可以推算出表征不均匀的参数。对于我们的样品,该不均匀性约为2.6—5.8％。 关键词：     

Magnetoelastic Waves in Submicron Yttrium–Iron Garnet Films Manufactured by Means of Ion-Beam Sputtering onto Gadolinium–Gallium Garnet Substrates

A series of equidistant oscillations have been revealed in the transmission spectrum and dispersion law of Damon–Eshbach surface magnetostatic waves (SMSWs) propagating in submicron (200-nm) yttrium–iron garnet (YIG) films manufactured by means of ion-beam sputtering onto gadolinium–gallium garnet (GGG) substrates. These oscillations correspond to the excitation of magnetoelastic waves in the YIG–GGG structure at frequencies of resonant interaction between the surface magnetostatic waves and the elastic shear modes of the wave-guiding YIG–GGG structure. The obtained results show that the studied YIG films are characterized by an efficient magnetoelastic coupling between their spin and elastic subsystems and the matching of acoustic impedances at the YIG–GGG interface, thus providing the possibility to consider the ion-beam sputtering of YIG films onto GGG substrates as a promising technology for the creation of magnonic and straintronic devices.     

Control of spin waves in a thin film ferromagnetic insulator through interfacial spin scattering

Control of spin waves in a ferrite thin film via interfacial spin scattering was demonstrated. The experiments used a 4.6 μm-thick yttrium iron garnet (YIG) film strip with a 20-nm thick Pt capping layer. A dc current pulse was applied to the Pt layer and produced a spin current across the Pt thickness. As the spin current scatters off the YIG surface, it can either amplify or attenuate spin-wave pulses that travel in the YIG strip, depending on the current or field configuration. The spin scattering also affects the saturation behavior of high-power spin waves.     

Nonreciprocity engineering in magnetostatic spin waves

Magnetostatic surface spin waves (MSSW) excited from a coplanar waveguide antenna travel in different directions with different amplitudes. This effect, called nonreciprocity of MSSW, has been investigated by micromagnetic simulations. The ratio of amplitude of two counter propagating spin waves, the nonreciprocity parameter κ, is obtained for different ferromagnetic materials, such as NiFe (Py), CoFeAl, yttrium iron garnet (YIG), and GaMnAs. A device schematic has been proposed in which κ can be tuned to a large value by varying simple geometrical parameters of the device.     

Brillouin spectroscopy of nonlinear magnetoacoustic resonances in a layered YIG/GGG structure

Brillouin light scattering spectroscopy is used to visualize the spatial structure of magnetoacoustic resonances in an yttrium iron garnet (YIG) film on a gadolinium–gallium garnet (GGG) substrate under the strong influence of nonlinear processes of three magnon decay. It is shown that the decay processes result in the simultaneous excitation of magnetoacoustic resonances at two frequencies: those of the input signal and its half frequency. The distribution of coupled magnetic and elastic waves becomes much more complicated and the excitation threshold of magnetoacoustic resonances arises.     

Conversion-electron Mössbauer study of sputtered Bi3Fe5O12

Temperature dependence of the magnetization measurements and Conversion Electron Mössbauer Spectroscopy (CEMS) have been performed on sputtered Bi₃Fe₅O₁₂ (BiIG), Y₃Fe₅O₁₂ (YIG) and (Bi, Y)IG films. Under the effect of the diamagnetic dilution of the diamagnetic yttrium sublattice the magnetization of BiIG is decreased with respect to YIG. The hyperfine field at the tetrahedral iron sites is increased, indicating a decrease in the intra-sublattice exchange interaction rather than the decrease of the tetrahedral iron moment.     

Temperature and field dependences of photo-induced changes in the magnetization in yttrium iron garnet

The changes in the magnetization of yttrium iron garnet (YIG) when irradiated by a pulsed neodymium laser beam with wavelength λ=1.06 μm are investigated. Measurements are performed in the temperature range from 100 K to 600 K in various external magnetic fields. YIG single crystals grown along the crystallographic (100), (110), and (111) directions are chosen so that the external anisotropy of the indicated processes can be determined. Characteristic temperature intervals dominated by different mechanisms of variation of the magnetization under the influence of a laser pulse are discussed. Fiz. Tverd. Tela (St. Petersburg) 39, 1263–1266 (July 1997)     

Inverse spin Hall effect in ITO/YIG exited by spin pumping and spin Seebeck experiments

Spin currents, which are excited in indium tin oxide(ITO)/yttrium iron garnet(YIG) by the methods of spin pumping and spin Seebeck effect, are investigated through the inverse spin Hall effect(ISHE). It is demonstrated that the ISHE voltage can be generated in ITO by spin pumping under both in-plane and out-of-plane magnetization configurations.Moreover, it is observed that the enhancement of spin Hall angle and interfacial spin mixing conductance can be achieved by an appropriate annealing process. However, the ISHE voltage is hardly seen in the presence of a longitudinal temperature gradient. The absence of the longitudinal spin Seebeck effect can be ascribed to the almost equal thermal conductivity of ITO and YIG and specific interface structure, or to the large negative temperature dependent spin mixing conductance.     

Negative Magnetoresistance in the n-InSb/YIG Structure

Physics of the Solid State - In this paper, it is shown that in the n-InSb/YIG/GGG (YIG is yttrium iron garnet, GGG is gadolinium gallium garnet) structure, when the geometry of magnetization is...     

The origin of spin current in YIG/nonmagnetic metal multilayers at ferromagnetic resonance

Spin pumping in yttrium-iron-garnet(YIG)/nonmagnetic-metal(NM) layer systems under ferromagnetic resonance(FMR) conditions is a popular method of generating spin current in the NM layer.A good understanding of the spin current source is essential in extracting spin Hall angle of the NM and in potential spintronics applications.It is widely believed that spin current is pumped from precessing YIG magnetization into NM layer.Here,by combining microwave absorption and DC-voltage measurements on thin YIG/Pt and YIG/NM_1/NM_2(NM_1 =Cu or Al,NM_2 =Pt or Ta),we unambiguously showed that spin current in NM,instead of from the precessing YIG magnetization,came from the magnetized NM surface(in contact with thin YIG),either due to the magnetic proximity effect(MPE) or from the inevitable diffused Fe ions from YIG to NM.This conclusion is reached through analyzing the FMR microwave absorption peaks with the DC-voltage peak from the inverse spin Hall effect(ISHE).The voltage signal is attributed to the magnetized NM surface,hardly observed in the conventional FMR experiments,and was greatly amplified when the electrical detection circuit was switched on.     

Structure dependence of magnetic properties in yttrium iron garnet by metal-organic decomposition method

The yttrium iron garnet(YIG) samples are prepared at different temperatures from 900?C to 1300?C by the metalorganic decomposition(MOD) method. The chemical composition and crystal structure of the samples are studied by scanning electron microscope(SEM), XRD, and M ¨ossbauer spectrometer. It is shown that the ratio of ferric ions on two types of sites, the octahedral and the tetrahedral, is increased with the sintering temperature. At 1300?C, the pure garnet phase has been obtained, in which the ferric ions ratio is 2:3 leading to the minimum magnetic coercivity and maximum saturation magnetization. These results provide a route to synthesize pure YIG materials as the basic materials used in various spintronics applications.     

Polarized neutron study of covalency effects in yttrium iron garnet

Magnetic structure amplitudes of 170 reflections up to sin $\text{θ}\text{λ}\text{= 1.0}\text{A}\text{?}{}^{\mathrm{?1}}$ were measured by polarized neutron diffraction at T = 295K on yttrium iron garnet. The data set was completed by model calculations and the magnetization density was determined. The magnetic moments obtained by integration and refinement are considerably reduced on both iron sites due to charge density transferred from intervening ligand ions. A residual moment of uncancelled spin of (0.032 ±0.004) μ_B is observed on the oxygen ion. Evidence for magnetization density on the oxygen atom and between oxygen and tetrahedral iron was found. A qualitative discussion in terms of a molecular orbital model is given. A further data set collected at 4.2K showed equally a magnetic moment lower than expected for the free ion.     

Optimization of MO Bragg diffraction of guided optical waves by MSW in YIG films by using inclined magnetic bias field

We describe a new scheme of noncollinear interaction geometry for magneto-optical (MO) Bragg cells based on inelastic scattering of guided optical wave beams by magnetostatic waves in yttrium–iron–garnet (YIG) films. A great increase of the diffracted light intensity was obtained when using an inclined magnetization of the film, in the case when static in-plane magnetization component is directed along the light propagation direction. It is shown that the diffraction efficiency can be increased more than two times, at a specific value of the angle (≈35°) between the saturation magnetization vector and the normal to the film surface. The effect can be explained through a four-wave model of the diffraction process, which can take place in optical waveguides with MO gyrotropy. The results obtained by a simple analytical solution of the diffraction problem are found to be in good qualitative agreement with the experimental observations.     

Four-magnon decay of magnetostatic surface waves in yttrium iron garnet films

The four-magnon instability of magnetostatic surface waves (MSSWs) in yttrium iron garnet epitaxial films is investigated experimentally. It is shown that four-magnon instability for MSSWs with wave numbers 30–600 cm⁻¹ is a decay instability and develops for values of the wave magnetization close to the threshold level for second-order parametric instability of a homogeneous transverse pump wave. When the supercriticality of the MSSW power is 15–20 dB, the generated parametric spin waves themselves become unstable with respect to the four-magnon interaction, so that kinetic instability develops in the film. It is shown that the pump signal transmitted through the signal and the length of the “nonlinear” part of the film, where a MSSW is capable of exciting parametric spin waves, increase as the pump power is increased. Fiz. Tverd. Tela (St. Petersburg) 38, 330–338 (February 1997)