共查询到20条相似文献,搜索用时 390 毫秒
1.
Frank J. Berry Xiaolin Ren Peter Slater 《Journal of Physics and Chemistry of Solids》2008,69(8):2032-2036
We report here on the fluorination of the perovskite-related phases La1−xSrxFe1−yCoyO3−δ. The introduction of fluorine in place of oxygen is achieved through a low-temperature (400 °C) reaction with poly(vinylidene fluoride). X-ray powder diffraction data show that in all cases the fluorination leads to an expansion in the unit cell, which is consistent with partial replacement of oxygen by fluorine and consequent reduction in the oxidation state of iron and/or cobalt. This reduction in oxidation state is confirmed by X-ray absorption- and Mössbauer-spectroscopy. The Mössbauer spectra show complex magnetically split hyperfine patterns for the fluorinated samples, reflecting the interactions between Fe3+ ions, which are not possible in oxides containing Fe4+. 相似文献
2.
本文在多通道量子数亏损理论(MQDT)框架下,利用相对论多通道理论(RMCT),分别在冻结实近似、 考虑Δl=-1的偶极极化效应、Δl=+1的偶极极化效应、Δl=± 1的偶极极化效应、伸缩模效应以及同时考虑偶极极化效应和伸缩模效应等不同层次近似下,系统地计算了碱金属Li, Na, K, Rb, Cs和Fr七个里德伯系列的能级,即ns2S1/2, np2P1/2, np2P3/2, nd2D3/2, nd2D5/2, nf2F5/2 和nf2F7/2.计算结果表明,电子关联效应对碱金属原子的里德伯能级的影响很大.总的来说,偶极极化效应比伸缩模效应重要,而在偶极极化效应中, Δl = + 1的偶极极化效应比Δl = - 1的偶极极化效应重要.但对于Na的ns2S1/2,(nd2D3/2,nd2D5/2)里德伯系列的能级,和Li的(np2P1/2,np2P3/2)里德伯系列的能级,是伸缩模效应比较重要. 相似文献
3.
介绍了一种基于新型非线性晶体Ba1-xB2-y-zO4SixAlyGaz 的可调谐深紫外飞秒激光光源. 从理论上分析了基频光和倍频光在通过非线性晶体时所造成的空间走离和群速度失配, 为了补偿空间走离以及波长调谐过程中晶体折射造成的光束偏离现象, 将两块相同的倍频晶体成镜像放置来产生二次谐波. 并调节延迟线的长度来补偿基频光和倍频光之间的群速度失配, 从而提高和频转换效率. 然后通过和频方式进行三倍频和四倍频来突破晶体相位匹配条件的限制, 产生了波长低于200 nm的深紫外飞秒激光. 利用钛宝石激光器提供基频光光源, 最终在250–300 nm, 192.5–210 nm 范围内获得了高重频、可调谐超短脉冲紫外和深紫外激光. 并在基频光波长为800 nm时, 得到的二倍频、三倍频和四倍频的功率分别为1.28 W, 194 mW和5.8 mW, 相对于前一级的转换效率依次为46.14%, 15.16%和3%. 采用互相关法测量得到266.7 nm紫外激光的脉冲宽度约为640.4 fs. 相似文献
4.
采用磁控溅射,紫外线光刻和离子束刻蚀制备了La2/3Ca1/3MnO3/Eu2CuO4/La2/3Ca1/3MnO3磁性隧道结.通过对获得的磁性隧道结的I-V特性测量,发现非线性的I-V特性,显示结样品的隧穿特性.有趣的是发现在电极材料La2/3Ca1/3MnO3的金属-绝缘体转变温度(Tp)以下,I-V曲线出现一个跳变.随着温度降低,开始出现跳变的临界电流增大,但是跳变都发生在同样的电压下~209mV.当电流增大或减小在跳变点附近出现回滞.这一跳变只发生在铁磁金属态,表明这是一个磁性相关联的效应,可能对应一种新的磁性开关过程.虽然,目前对这一现象背后的物理机理还不清楚,但是,这一现象有可能在未来自旋电子学器件方面具有潜在的应用价值.
关键词:
庞磁电阻
磁性隧道结
开关效应 相似文献
5.
I. A. Starkov A. S. Kozhemyachenko S. F. Bychkov A. P. Nemudry N. Z. Lyakhov 《Bulletin of the Russian Academy of Sciences: Physics》2010,74(8):1059-1061
The oxygen permeability of ceramic SrCo0.8 − y
Fe0.2Nb
y
O3 − z
(0 ≤ y ≤ 0.2) and La0.3Sr0.7Co0.6Fe0.2Nb0.2O3 − z
disc membranes as a function of temperature and oxygen partial pressure was studied. Kinetic analysis was performed based
on the experimental data on oxygen permeability as a function of oxygen partial pressure. 相似文献
6.
7.
在有效质量近似下利用打靶法求出Ga1-xInxNyAs1-y/GaAs量子阱中的本征能级En, 并通过费米黄金规则计算电子-LO声子由第一激发态到基态的散射率和平均散射率随温度、阱宽以及氮(N)和铟(In)组分变化的规律. 计算结果表明: 在In 组分恒定的情况下, 随着N组分的增加, 散射率和平均散射率增加; 在N组分恒定的情况下, 随着In组分的增加, 散射率和平均散射率减小; 随着温度的增加, 在温度较低时散射率和平均散射率随温度的增加变化不大, 在温度较高时随温度的增加而增加; 随着阱宽的增加, 散射率和平均散射率都是先增加到一个最大值, 然后再减小, 最大值出现在阱宽200 Å附近. 计算结果对Ga1-xInxNyAs1-y/GaAs量子阱在光电子器件应用方面有一定的指导意义.
关键词:
费米黄金规则
1-xInxNyAs1-y/GaAs量子阱')" href="#">Ga1-xInxNyAs1-y/GaAs量子阱
LO声子
散射率 相似文献
8.
Guo-Yu Lan Yang-Wei Lin Zong-Hong Lin Huan-Tsung Chang 《Journal of nanoparticle research》2010,12(4):1377-1388
This article describes the synthesis of highly water-soluble Zn
x
Hg1−x
Se
y
S1−y
quantum dots (QDs) in aqueous solution through a simple photo-assisted reaction between ZnSe QDs and mercury(I) nitrate dihydrate
[Hg2(NO3)2·2H2O]. In order to deduce the optimal synthesis conditions, we varied several parameters, including the concentrations of mercaptosuccinic
acid (MSA) and Hg2(NO3)2·2H2O, the illumination time, and the reaction temperature. When irradiated at temperatures below 80 °C, the ZnSe QDs reacted
with the S2− ions formed rapidly from MSA and the Hg2+ ions formed from Hg2
2+ ions to form Zn
x
Hg1−x
Se
y
S1−y
QDs through a process of photo-etching and surface combination. Under different conditions, we prepared a series of Zn
x
Hg1−x
Se
y
S1−y
QDs that emit fluorescence at the maximum wavelengths ranging from 405 to 760 nm. Inductively coupled plasma-mass spectrometry
and transmission electron microscopy/energy dispersive spectrometry revealed that the content of Hg in the Zn
x
Hg1−x
Se
y
S1−y
QDs was greater when the synthesis was conducted at higher temperature. The Zn0.88Hg0.12Se0.44S0.56 QDs exhibit improved photostability than crude ZnSe QDs and possess long lifetimes (τ1 ~ 38 ns and τ2 ~ 158 ns). 相似文献
9.
S. V. Grigoriev V. A. Dyadkin S. V. Maleyev D. Menzel J. Schoenes D. Lamago E. V. Moskvin H. Eckerlebe 《Physics of the Solid State》2010,52(5):907-913
Two systems of noncentrosymmetric cubic helical magnets Mn1 − y
Fe
y
Si (y = 0.06, 0.08, 0.10) and Fe1 − x
Co
x
Si (x = 0.10, 0.15, 0.20, 0.25, 0.30, 0.35, 0.50) have been compared. The concentration dependences of the critical temperature
and magnetic field have been obtained using small-angle polarized-neutron scattering and analyzed in the framework of the
Bak-Jensen model. It has been established that, among the two interactions that play the main role in these systems, i.e.,
the isotropic symmetric ferromagnetic exchange and the Dzyaloshinskii-Moriya isotropic antisymmetric interaction, the former
interaction determines the critical temperature in the Mn1 − y
Fe
y
Si system and the latter interaction determines this temperature in the Fe1 − x
Co
x
Si system. 相似文献
10.
利用金辅助金属有机化学气相沉淀法(MOCVD)在GaAs(111)B衬底上分别制备了InAs/GaAs和InAs/In x Ga1-xAs/GaAs(0≤x≤1)纳米线异质结构.实验结果显示,直接生长在GaAs纳米线上的InAs纳米线生长方向杂乱或者沿着GaAs纳米线侧壁向衬底方向生长,生长的含有In x Ga1-xAs组分渐变缓冲段的InAs/In x Ga1-x关键词:
纳米线异质结构
xGa1-xAs')" href="#">InxGa1-xAs
组分渐变缓冲层
金属有机化学气相沉淀法 相似文献
11.
基于k·p微扰理论, 通过引入应变哈密顿量作为微扰, 建立了双轴应变Ge/Si1-xGex价带色散关系模型. 模型适于任意晶向弛豫Si1-xGex虚衬底上的应变Ge价带结构, 通过该模型可获得任意k方向应变Ge的价带结构和空穴有效质量. 模型的Matlab模拟结果显示, 应变Ge/Si1-xGex价带带边空穴有效质量随Ge组分的增加而减小, 其各向异性比弛豫Ge更加显著. 本文研究成果对Si基应变Ge MOS器件及集成电路的沟道应力与晶向的设计有参考价值. 相似文献
12.
In natural and social science, many events happened at different space–times may be closely correlated. Two events, A (Alice) and B (Bob) are defined as correlated if one event is determined by another, say, for suitable operators. A nonlocal AB–KdV system with shifted-parity (, parity with a shift), delayed time reversal (, time reversal with a delay) symmetry where is constructed directly from the normal KdV equation to describe two-area physical event. The exact solutions of the AB–KdV system, including invariant and symmetric breaking solutions are shown by different methods. The invariant solution show that the event happened at A will happen also at B. These solutions, such as single soliton solutions, infinitely many singular soliton solutions, soliton–cnoidal wave interaction solutions, and symmetry reduction solutions etc., show the AB–KdV system possesses rich structures. Also, a special Bäcklund transformation related to residual symmetry is presented via the localization of the residual symmetry to find interaction solutions between the solitons and other types of the AB–KdV system. 相似文献
13.
采用柠檬酸溶胶凝胶和放电等离子烧结制备了Ca位双掺杂型的BaxAgyCa3-x-yCo4O9烧结体,利用X射线衍射仪、扫描电子显微镜、电阻率测试仪等研究了烧结体相组成、取向度、织构及电性能.结果表明:含Ag的掺杂试样中出现了偏离化学计量比分布的Ag单质,掺杂试样取向度随Ba与Ag掺杂量之比x/y的增大而提高,含Ag的掺杂试样取向度低于未掺杂试样,不含Ag的掺杂试样取向度高于未掺杂试样.x=y=01的试样导电机理发生变化.Ba,Ag掺杂量相等的试样保持较低取向度的同时具有较低的电阻率,在973 K时达到最低值(73 mΩcm),而取向度最低的Ag单掺杂试样电阻率在所有试样中最低,在973 K时为63 mΩcm.
关键词:
3Co4O9')" href="#">Ca3Co4O9
双掺杂
织构
电输运性能 相似文献
14.
P. A. Popov P. P. Fedorov V. M. Reiterov E. A. Garibin A. A. Demidenko I. A. Mironov V. V. Osiko 《Doklady Physics》2012,57(3):97-99
The thermal conductivity of single crystals of Ca1 − x
Er
x
F2 + x
(x = 0.01, 0.05, 0.07, and 0.10) and Ca1 − x
Tm
x
F2 + x
(x = 0.02, 0.04, and 0.06) solid solutions is studied in the temperature ranges 50–300 and 298–673 K. With increasing content
of rare-earth elements, the behavior of thermal conductivity in these solid solutions changes from the characteristic of defect
single crystals to glasslike. The concentration dependences of thermal conductivity for the two systems differ insignificantly. 相似文献
15.
16.
17.
基于对制作在n-GaN上的肖特基二极管的变温I-V测试和C-V测试,采用表面势垒减薄模型对肖特基二极管的电流输运特性进行了研究.试验结果表明,肖特基接触的电流输运机理非常复杂,在不同的温度条件和偏压条件下有着不同的电流输运机理.在此基础上对肖特基接触I-V特性方程进行了修正,得到了很好的拟合曲线.试验表明,高温I-V法提取的势垒高度与常温C-V法提取的势垒高度接近于根据金属功函数得出的理论势垒高度值.
关键词:
氮化镓
肖特基二极管
表面势垒减薄模型
热电子场发射 相似文献
18.
A. D. Smirnov 《Optics and Spectroscopy》2010,109(5):680-686
Vibrational, rotational, and centrifugal spectroscopic constants and radiative parameters, i.e., the Einstein coefficients,
oscillator strengths, and wave numbers for vibrational transitions in electronic systems of bands A
1Σ
u
+-X
1Σ
g
+ (0 ≤ v′ ≤ 25; 0 ≤ v″ ≤ 44), B
1Π
u
-X
1Σ
g
+ (0 ≤ v′ ≤ 29; 0 ≤ v″ ≤ 47), and the radiative lifetimes for the vibrational levels of excited states of the sodium dimer,
are calculated. The calculations are carried out based on semiempirical potential curves constructed in this study. The calculated
spectroscopic constants and radiative lifetimes are compared to the experimental values. 相似文献
19.
M. A. Melkozerova E. V. Zabolotskaya D. G. Kellerman A. S. Semenova E. Yu. Medvedev G. V. Bazuev 《Physics of the Solid State》2011,53(2):323-328
The magnetic interactions in the quasi-one-dimensional complex oxides Ba6NiMn4O15, Ba6Ni2Mn3O15, and Ba6Ni3Mn2O15 have been investigated using electron paramagnetic resonance and magnetic susceptibility measurements. It has been revealed
that, for the Ba6Ni2Mn3O15 and Ba6Ni3Mn2O15 compounds, the magnetic moments are considerably smaller than the theoretical values and depend on the temperature. The results
obtained have been interpreted under the assumption that the structure contains Ni3+ ions in which the energy level structure can lead to the above anomalies. 相似文献
20.
Perovskites BaTi1−xFexO3 has been synthesized with the concentration x ranging from 0.01 to 0.02. Their transformation point of ferroelectric to paraelectric and the corresponding latent heat of the phase transformation were observed to decrease with increasing the doping level of Fe3+. Bonded layered composites BaTi1−xFexO3–Tb1−yDyyFe2−z have been fabricated and their magnetoelectric effect has been investigated. The sample containing a layer of perovskite BaTi0.985Fe0.015O3 was found to show the maximum transverse ME voltage coefficient, which is about 1422 mV Oe−1 cm−1 under a magnetic field of 1580 Oe, in these bilayers. Analysis shows that the Fe-doped BaTiO3 with doping level at about 1.5% should have largest piezoelectric coefficient in these ceramics BaTi1−xFexO3. 相似文献