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1.
The Prigogine-Flory-Patterson theory of liquid mixtures has been qpplied to the H
m
E
and V
m
E
for binary mixtures of a bicyclic compound, benzene, cyclohexane and n-hexane with a cycloalkane, cyclohexene, a cycloalkadiene and benzene. Furthermore the Prigogine-Flory theory has been used to predict activity coefficients at infinite dilution from the experimentally determined H
m
E
at 25°C for the mixtures cyclohexane, cyclohexene, 1,3-cyclohexadiene, 1,4-cyclohexadiene and benzene with a bicyclic compound. The predictions are compared to experimental results. 相似文献
2.
The Prigogine-Flory-Patterson theory of liquid mixtures has been applied to the H
m
E
and V
m
E
for binary mixtures of an n-alkane with decalin, bicyclohexyl, tetralin, cyclohexylbenzene, benzene, cyclohexane and n-hexane. Furthermore the Prigogine-Flory theory has been used to predict activity coefficients at infinite dilution from the experimentally determined H
m
E
at 25°C and at finite concentrations for n-hexane and n-heptane with decalin, bicyclohexyl, tetralin and cyclohexylbenzene. 相似文献
3.
The V
m
E
and H
m
E
for solutions of benzene in decahydronaphthalene, in bicyclohexyl, in cyclohexylbezene and in 1,2,3,4-tetrahydronaphthalene have been measured over the complete composition range at 25°C. The results have been fitted to the Flory theory of liquid mixtures. 相似文献
4.
The activity coefficients at infinite dilution have been measured at 25°C for cyclohexane, cyclohexene, 1,3-cyclohexadiene, 1,4-cyclohexadiene, benzene, n-hexane, 1-hexene, 1-hexyne, n-heptane, 1-heptene and 1-heptyne in decahydronaphthalene, bicyclohexyl, 1,2,3,4-tetrahydronaphthalene and cyclohexylbenzene. These results, together with previously determined H
m
E
and V
m
E
have been used to calculate the partial molar excess thermodynamic properties of mixing at infinite dilution. 相似文献