The magnetic hyperfine field of bromine in iron by NMR/ON

Nuclear magnetic resonance of⁸²Br oriented at low temperature in iron has been observed with a sample prepared by ion implantation atT<0.2 K. The asymmetric resonance signal can be decomposed in a broad background signal and a narrow line of FWHM=1.8 (4) MHz which can be attributed to⁸²Br in undisturbed substitutional sites of Fe. From the center frequency of this narrow line (B _ext=0)=201.86(13) MHz we derive the magnetic hyperfine field asB _hf(BrFe)=81.38(6) T. This value is considerably larger than the result of theoretical calculations.     

Magnetic hyperfine field of arsenic in nickel by NMR/ON of71,72As

The magnetic hyperfine splitting frequencies of⁷¹AsNi and⁷²AsNi in a 0.11 Tesla external magnetic field have been determined by NMR/ON method as 66.00(6) MHz and 106.17(13) MHz respectively. Using the known magnetic moments of μ(⁷¹As)=1.6735(18) and μ(⁷²As)=−2.1566(3), the hyperfine fields were deduced asB _hf(⁷¹AsNi)=12.824(19) Tesla andB _hf(⁷²AsNi)=12.807(16) Tesla.     

The hyperfine field of sodium in iron

The hyperfine field of NaFe has been measured using Low Temperature Nuclear Orientation of cold implanted²⁴Na. The combination of both the γ-and β-anisotropies yields information on the implantation fraction of Na in Fe. Furthermore, an, upper limit for the relaxation time of Na in Fe could be deduced.     

The hyperfine field of oxygen in iron

From an on-line nuclear orientation measurement on¹⁵O implanted in iron, the hyperfine field of oxygen in iron was deduced as +12.2(16) T. This experiment, together with two measurements on¹⁷F, which was implanted in the same foil, also yielded information on the relaxation and implantation behaviour of light impurities when implanted at low dose and at low temperature.     

The hyperfine field of krypton in iron

The hyperfine field of krypton nuclei at lattice sites in iron has been determined using nuclear orientation. From the anisotropy of the electrons emitted in the decay of⁸⁵Kr implanted in iron, a hyperfine field value of +31.2(8) T was deduced for a substitutional fraction of approximately 37%. Also, a relaxation time of the order of 900 see was observed at temperatures between 7 and 11 mK.     

The hyperfine field on carbon in iron

Integral perturbed angular correlation experiments have been carried out on recoilimplanted¹⁵C nuclei in iron. The 739 keV5/2⁺ level of¹⁵C was populated via the¹⁴C(d, p)¹⁵C^* reaction. Using the known g-factor and lifetime of the state, effective internal fields of –12.4±1.1 kG and –10.9±1.5 kG were determined at room temperature and 77 K, respectively. A conduction electron polarization hyperfine field of about –20 kG was deduced from the data.Work supported in part by the National Science Foundation.     

The hyperfine field of99Tc in iron

The magnetic hyperfine field at⁹⁹Tc impurities in Fe has been measured to be ¦H _hf¦=325 (7) kGauss at 298 °K. The technique of time-differential perturbed angular correlations on the 181 keV state of⁹⁹Tc was used.     

Local magnetic moment and hyperfine field in hydrogenated iron and iron-vanadium alloy

The local magnetic moment and hyperfine fieldB _hf at Fe and V sites in hydrogenated iron and iron-vanadium were calculated using the discrete variational method. The variations in andB _hf with H occupation of the octahedral (O) site were considered. It was found that when H occupies the O site neighbouring an Fe atom, both local moment and hyperfine field at this atom decrease linearly with increasing number of H atoms. The rate of decrease is larger for Fe in iron as compared to iron in vanadium. On the other hand, when H resides at an O site next neighbouring an Fe atom, whether in iron metal or in iron-vanadium, the Fe magnetic moment increases slowly, while the hyperfine field remains almost constant. The V moment in iron, which is negative (–0.83 _B ), becomes less negative (–0.30 _B) as H occupies the neighboring O sites, whereas slight changes occur (–0.88 _B) when H is at the next neighbouring O site. The net effect of H on Fe in iron is to decrease the average magnetic moment at a rate of 1.2 _B per H/Fe for low H content. On the other hand, the average Fe moment in an iron-vanadium alloy increases if H resides at O sites which are immediate neigbours of V and next neighbours of Fe. This may explain the development of a magnetic state on hydrogenation of Fe-V alloys, which is exhibited by the specific heat and susceptibility measurements. The changes in the isomer shift were found to agree with experimental trends.     

The supertransferred magnetic hyperfine field in chromium-iron tellurates

The broadening of the¹²⁵Te Mössbauer spectral absorption with decreasing temperature in compounds of the type Cr_2?x Fe _x Te _x TeO₆ (x=0.4, 0.8, 1.0, 1.5) is attributed to the presence of a supertransferred magnetic hyperfine field. The origin of the supertransferred magnetic hyperfine field, which is not observed in antiferromagnetically ordered Cr₂TeO₆ or Fe₂TeO₆, is associated with an imbalance in the magnetic exchange interaction at tellurium which results from the replacement of chromium by iron.     

The magnetic and hyperfine properties of iron in silicon carbide

The magnetic and hyperfine properties of iron impurities in 3C- and 6H- silicon-carbide are calculated using the abinitio method of full-potential linear-augmented-plane-waves. The iron atoms are introduced at substitutional carbon, Fe _C , and silicon, Fe _Si , sites as well as at the tetrahedral interstitial sites with four nearest neighbours carbon atoms, Fe _I (C), and four nearest neighbours silicon atoms, Fe _I (Si). The effect of introducing vacancies at the neighbours of these sites is also studied. Fe atoms with complete neighbors substituted at Si or C sites are found to be nonmagnetic, while Fe atoms at interstitial sites are magnetic. Introduction of a vacancy at a neighboring site reverse the picture.     

Magnetic hyperfine field at caesium in iron

We report temperature dependence of nuclear orientation (NO), and the first observation of NMR/ON on Cs in iron.^{132, 136}Cs were implanted at room temperature into polycrystalline and single crystal iron. NO values for the (average) magnetic hyperfine field B_hf (CsFe) are close to 34T, intermediate between the value of 40.7T found in on-line samples made at mK temperatures and the NMR/ON value of 27.8 (2)T. The latter studies. The site/field distribution is briefly discussed. ISOLDE Collaboration, CERN     

Magnetic hyperfine field for zinc in iron

The magnetic hyperfine field for zinc in iron has been measured by the DPAD method following the reaction ⁶⁴Ni(α, n)⁶⁷Zn^m. Measurements performed with a sandwich target and with ⁶⁴Ni($\text{Fe}$) alloy targets containing 3% and 6% nickel yielded similar results: H_hf(0) = -191 ± 3 kG.     

The magnetic hyperfine interaction of iron atoms isolated in a xenon matrix in the presence of an external magnetic field

The Mössbauer effect has been used to measure the magnetic hyperfine interaction of isolated ⁵⁷Fe atoms in solid xenon with an applied external magnetic field. A field dependent Mössbauer absorption spectrum is observed. The ground state of these iron atoms is a triplet, which is split in the external field. The Mössbauer spectrum was analyzed taking into consideration relaxation effects. For an applied external field of 28 kOe an internal magnetic field at the ⁵⁷Fe nucleus of 700± 15 kOe was observed (external field included).     

The magnetic hyperfine field at140Ce in nickel

The hyperfine interaction of¹⁴⁰Ce in nickel has been investigated by the time-differential perturbed-angular-correlation technique (TDPAC). The probe was produced by isotope separator implantation of the fission product¹⁴⁰Xe, the ^- decay chain of which finally populates excited states of¹⁴⁰Ce.Different spin rotation spectra were observed before and after an 8 h annealing at 415°C. The analysis of the spectra led to the conclusion that the Ce ions were in the diamagnetic 4⁺ state. The dominant contributions to the hyperfine interaction are two different magnetic hyperfine fields: |H _hf ¹|=385±7 kOe and |H _hf ²|=276±12 kOe.H _hf ¹ disappears after annealing. The fraction of nuclei which observeH _hf ² is increased by the annealing procedure from 16% to 75%. It is assumed thatH _hf ¹ is the hyperfine field of CeNi in an unperturbed substitutional site andH _hf ² is attributed to Ce ions which have trapped a single vacancy.     

The magnetic hyperfine field at Hg impurities in ferromagnetic Gd

The magnetic hyperfine field at dilute Hg impurities in Gd has been investigated by the conversion electron (e ^–)--time differential perturbed angular correlation (TDPAC) technique. The radioactivities^197m Hg and¹⁹⁹Tl were implanted into Gd foils by means of an isotope separator. TDPAC measurements were performed with the 165 keV-L-conversion electron—134 keV--cascade of¹⁹⁷Hg at different temperatures and with the 334 keV--158 keV-K-conversion electron cascade of¹⁹⁹Hg at 200 K.The regular site occupation probabilities were found to be 15(3)% for an annealed^197m HgGd sample and 29(5)% in unannealed¹⁹⁹TlGd samples.From the magnetic hyperfine interaction frequencies measured for the regular sites at 200 K the magnetic hyperfine fields |H _hf(¹⁹⁷HgGd; 200 K)|=256(13) kG and |H _hf(¹⁹⁹HgGd; 200 K)|=267(7) kG were deduced.On leave from the University of Lisboa, Portugal     

The hyperfine magnetic field of172Yb in Fe and Ni

Time-differential perturbed angular correlation measurements have been performed on the 91–1095 keV -ray cascade emitted by¹⁷²Yb nuclei in the capture decay of¹⁷²Lu, using implanted sources of¹⁷²Lu in Fe and Ni. From these measurements hyperfine field valuesB(YbFe)=–1253±83 kG andB(YbNi)=–143±12 kG follow at room temperature. From the modulation amplitude of the spectra it follows that only about 20% of the ytterbium nuclei participate in the precession.