ZnO纳米棒阵列在TiO2介孔薄膜上的生长及其表征

通过低温水热法成功地将ZnO纳米棒阵列定向生长在了介孔锐钛矿TiO2纳米晶薄膜上,并主要利用X射线衍射、场发射扫描电子显微镜和光致发光光谱等对其进行了表征。所制备的纳米棒具有六边形的端面,纳米棒的尺寸及端面边长分布范围窄,并且沿c轴方向(002)表现出了明显的择优化生长。此外,相比于玻璃基底或TiO2纳米颗粒薄膜,生长在介孔TiO2薄膜上的ZnO纳米棒阵列表现出了较好的取向生长,表明基底的表面结构和组成对ZnO纳米棒阵列的生长有显著的影响。根据基底有序的多孔结构,讨论了纳米棒阵列可能的生长机理。所得到的ZnO纳米棒阵列在室温下分别表现出了以370 nm为中心的强近紫外光和以530 nm为中心的弱绿光两条荧光谱带。     

醇热法制备ZnO纳米棒及其发光性能

在常压条件下,以油酸为分散剂一步反应醇热法制备ZnO纳米棒,利用XRD、SEM、TEM、HRTEM和FTIR等分析技术对产物进行了表征,对产物退火前后的光致发光性能进行了测试,并对ZnO纳米棒生长机理进行讨论. 结果表明,ZnO纳米棒沿[001]方向择优取向生长,直径为10～15 nm,长度为150～200 nm,油酸与ZnO表面Zn(Ⅱ)以螯合键形式相结合,具有良好的近紫外发光性能. 随着退火温度升高,产物深能级发光强度先降低后增加.     

氧化锌薄膜的电化学沉积和表征

以透明导电玻璃(TCO)为衬底，用硝酸锌水溶液作为电解液，研究了阴极还原沉积ZnO薄膜的反应机理和电化学行为. 通过改变工艺条件来控制ZnO的生长速率， 得到了粒径为10～15 nm的纳米ZnO薄膜. XRD分析显示纳米ZnO薄膜纯度高， 呈纤锌矿结构. 光学测试结果表明，在可见光区其透光度高达90%，禁带宽度为3.37 eV.     

特定条件下的定向ZnO纳米棒的制备及表征

采用改进的溶胶凝胶和化学溶液生长两步法, 并控制特定条件在镀银载玻片上制备出定向ZnO纳米棒. 利用X射线衍射(XRD)、扫描电镜(SEM)、透射电镜(TEM)、选区电子衍射(SAED)、能谱(EDS)及傅里叶红外吸收光谱(FTIR)对纳米棒的表面形貌、结构、组分进行分析. XRD和SEM结果表明该ZnO纳米棒具有六角纤锌矿结构, 结晶质量良好, 垂直衬底生长. TEM和SAED结果表明该ZnO纳米棒形状规则, 为单晶结构. FTIR谱中的位于418 和541 cm^－1的吸收峰对应于棒状ZnO结构的伸缩振动吸收峰, 1384 和1636 cm^－1对应于六方纤锌矿ZnO晶体的Zn—O伸缩振动吸收峰. 利用负离子配位四面体生长理论初步解释ZnO纳米棒的生长过程.     

脉冲激光沉积纳米TiO2薄膜电极的现场光电化学

在O3 /O2 气氛中采用 35 5nm激光烧蚀金属钛靶的反应性沉积薄膜方法 ,成功地在镀ITO膜的玻璃基片上制备了纳米锐钛矿相TiO2 薄膜电极 .用循环伏安法研究了在Li/TiO2 电池中TiO2 薄膜电极的电化学嵌入Li离子的行为 .由现场快速紫外可见吸收光谱实时监测TiO2 薄膜电极的显色特性 ,在波长 42 0和 6 5 0nm附近出现 2个明显的吸收峰 ,并发现TiO2 薄膜电极的吸收谱的涨落过程与Li离子的嵌入和脱嵌过程具有相关性与可逆性 ,表明该纳米TiO2 薄膜电极具有高质量的光电化学性能 .     

ITO和ZnO基底对电化学沉积氧化亚铜薄膜的形貌、结构的影响及作用机制

采用电化学恒电位沉积方法在ITO导电玻璃上和在ZnO薄膜上沉积氧化亚铜(Cu₂O),并通过X射线衍射(XRD)和扫描电镜(SEM)对晶体的微观结构和表面形貌进行了分析.在ZnO基底上沉积得到了纳米级的Cu₂O粒子并且具有明显择优取向,而在ITO导电玻璃上仅得到粒径为2—5μm的Cu₂O粒子,没有明显的择优取向.对薄膜的生长机理进行了讨论.     

电化学沉积制备半导体CuInSe2薄膜

本文报道恒电位法在pH为1.35的Cu₂SO₄、SeO₂、In₂(SO₄)₃溶液中,在Ti电极上电化学沉积制备CuInSe₂纳米薄膜.研究络合剂柠檬酸和酒石酸对制备CuInSe₂纳米薄膜的影响.扫描电子显微镜(SEM)结果表明,加入络合剂后,电化学沉积的薄膜表面颗粒分布更均匀、致密.X射线衍射(XRD)分析显示,制备的CuInSe₂薄膜是黄铜矿和闪锌矿相的混和物,添加柠檬酸和酒石酸后,衍射峰增强,晶形变好.制备的薄膜颗粒尺寸大小在250nm左右,造成粒度增大的原因是由于颗粒的团聚作用.     

电沉积ZnO纳米棒阵列膜制备及其透光性能研究

应用阴极恒电流电沉积法,以ZnC l2水溶液为电解液,在经预处理的ITO导电玻璃上制备ZnO纳米棒阵列,扫描电子显微镜(SEM)、X射线衍射(XRD)及透射光谱等测试表明,ZnO纳米棒阵列具有c轴高度择优取向,呈六方纤锌矿结构.当入射光波长大于380 nm时,ZnO纳米棒阵列的透光率大于95%,并且禁带宽度变窄.     

基底对电沉积制备ZnO纳米棒阵列的影响

采用恒电位电沉积方法, 在未经修饰的ITO导电玻璃基底上通过控制实验条件制备出不同形貌的纳米ZnO结构, 而在经过ZnO纳米粒子膜修饰后的ITO导电玻璃基底上, 制备出透明、高取向、粒径小于30 nm的ZnO纳米棒阵列. 用扫描电子显微镜(SEM)、X射线衍射(XRD)以及透射光谱对制备出的ZnO纳米棒阵列的结构、形貌和透明性进行了表征. 测试结果表明, ZnO纳米棒阵列的平均直径为21 nm, 粒径分布窄, 约18～25 nm, 择优生长取向为[001]方向, 垂直于基底生长. 当入射光波长大于400 nm时, ZnO纳米棒阵列的透光率大于95%.     

电沉积多晶CuInSe_2薄膜的光电化学——Ⅰ.CuInSe_2薄膜的电沉积

研究了含Cu~(2+),In~(3+),HSeO_2~+等离子的酸性电解液中CuInSe_2的电沉积过程.对电沉积条件进行了优化选择,对电沉积机理进行了探讨.对钛基底上的沉积膜的物性和结构分析表明,沉积膜的结晶性良好,颗粒均匀而连续,为多晶黄铜矿型结构.在多硫氧化还原电对液中,用这种沉积膜制成的光电化学电池具有明显的光响应.     

Electrochemical deposition of nano-structured ZnO on the nanocrystalline TiO2 film and its characterization

One-dimensional structure of ZnO nanorod arrays on nanocrystalline TiO₂/ITO conductive glass substrates has been fabricated by cathodic reduction electrochemical deposition methods in the three-electrode system, with zinc nitrate aqueous solution as the electrolyte, and were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray (EDX) and photoluminescence (PL) spectra. The effects of film substrates, electrolyte concentration, deposition time, and methenamine (HMT) addition on ZnO deposition and its luminescent property were investigated in detail. The results show that, compared with on the ITO glass substrate, ZnO is much easily achieved by electrochemical deposition on the TiO₂ nanoparticle thin films. ZnO is hexagonally structured wurtzite with the c-axis preferred growth, and further forms nanorod arrays vertically on the substrates. It is favorable to the growth of ZnO to extend the deposition time, to increase the electrolyte concentration, and to add a certain amount of HMT in the system, consequently improving the crystallinity and orientation of ZnO arrays. It is demonstrated that the obtained ZnO arrays with high crystallinity and good orientation display strong band-edge UV (375 nm) and weak surface-state-related green (520 nm) emission peaks.     

Au/ZnO/TiO_2复合薄膜的制备及光电转换性质

以含有Au和ZnO纳米颗粒的氢氧化钛溶胶作为成膜液,通过浸渍-提拉及灼烧处理在导电玻璃表面制备Au/ZnO/TiO2复合薄膜.利用X射线衍射仪(XRD)、扫描电子显微镜(SEM)等方法对所得产物进行表征.结果表明,Au和ZnO纳米颗粒均匀地分布在多孔TiO2薄膜上,通过TiO2、ZnO和Au三组分的协同效应促进了光吸收和电荷分离,使Au/ZnO/TiO2复合薄膜具有较好的光电转换性质,可用作太阳能电池材料.     

Electrochemical impedance spectra of CdSe quantume dots sensitized nanocrystalline TiO_2 solar cells

Quantum dots sensitized nanocrystalline TiO2 solar cells (QDSSCs) are promising third-generation photovoltaic devices.In comparison with conventional dye-sensitized solar cells (DSSCs),the efficiency of QDSSCs is still very low (about 3%).In this paper,the electrochemical impedance spectroscopy technology has been adopted to investigate the quasi-Fermi level and the carrier dynamics of the colloidal CdSe QDs sensitized TiO2 eletrode with S2-/Sxredox electrolytes and the series resistance of the QDSSCs.In co...     

Electrochemical Impedance Spectroscopy of Oxide Layers on the Titanium Surface

The method of electrochemical impedance spectroscopy is used to study oxide layers formed at the titanium surface by a variety of methods. The sample’s polarization permitted the isolation, in an impedance spectrum, of the response caused by the capacitance of the space-charge region, which obeys the Mott-Schottky dependence. It is established that the high-frequency portion of an impedance spectrum is defined by morphological peculiarities of the porous portion of coatings. Assumptions, concerning the nature of a time constant, which reveals itself in the region of low frequencies at polarizing biases, are made. Equivalent circuits, intended for modeling impedance spectra, are proposed. The circuits take into consideration the effect of the space-charge region, as well as the peculiarities of the structure and morphology of the oxide film formed at the titanium surface.__________Translated from Elektrokhimiya, Vol. 41, No. 8, 2005, pp. 963–971.Original Russian Text Copyright © 2005 by Gnedenkov, Sinebryukhov.     

CdSe量子点敏化纳米二氧化钛太阳电池的电化学交流阻抗谱

量子点敏化纳米TiO2太阳电池(QDSSCs)具有诱人的发展前景,但是与传统的染料敏化太阳电池(DSSCs)相比,其目前的光电转换效率还非常低(仅为3%左右).为了寻找QDSSCs光电转换效率低的原因,本文主要采用外加偏压下的交流阻抗谱技术对通常以S2-/S-x离子对为电解质的CdSe胶体量子点敏化纳米TiO2电极的准...     

TiO2纳米管阵列负载MnOx复合催化剂的脱硝性能

研究了TiO2纳米管阵列负载的MnOx复合物选择性催化还原NOx的性能.结果显示,在150～250℃下该催化剂脱除NOx的效率达90%以上(200℃下为99%以上),表现出优异的中低温脱硝性能.当反应温度更高时,有可能使反应进入努森扩散控制状态,从而在一定程度上抑制了催化反应的进行.     

氧化锌和氧化钛纳米树热液合成的研究进展

本文简要介绍了近年来多枝纳米结构材料的研究进展,概述了氧化锌和氧化钛纳米树阵列的热液合成和反应机理,探讨性地展望了多枝纳米树阵列的研究和应用前景.     

Photoactive Thin-Film Structures of Curcumin,TiO2 and ZnO

Curcumin is known as a biologically active compound and a possible antimicrobial agent. Here, we combine it with TiO₂ and ZnO semiconductors, known for their photocatalytic properties, with an eye towards synergistic photo-harvesting and/or antimicrobial effects. We deposit different nanoscale multi-layer structures of curcumin, TiO₂ and ZnO, by combining the solution-based spin-coating (S-C) technique and the gas-phase atomic layer deposition (ALD) and molecular layer deposition (MLD) thin-film techniques. As one of the highlights, we demonstrate for these multi-layer structures a red-shift in the absorbance maximum and an expansion of the absorbance edge as far as the longest visible wavelength region, which activates them for the visible light harvesting. The novel fabrication approaches introduced here should be compatible with, e.g., textile substrates, opening up new horizons for novel applications such as new types of protective masks with thin conformal antimicrobial coatings.     

水热法制备ZnO纳米棒及其光催化性能研究

以Zn(acac)2.H2O为单源前驱体,采用水热法在140℃条件下制备了ZnO纳米棒,并用XRD、SEM、TEM等测试手段对其进行了表征。利用紫外—可见分光光度计测试了其光吸收性能,发现ZnO纳米棒对200-400 nm波长范围的光有很强的吸收性,在可见光范围内,也有较强的吸收。以ZnO纳米棒为光催化剂对有机染料酸性红4B进行了光催化降解实验,并研究了光源、污水浓度对ZnO纳米棒光催化氧化效果的影响。研究结果表明,在日光照射180 min后,对酸性红4B的降解率接近100%。