Appearance of superconductivity in the tetragonal ceramic NdBa2Cu3O6.67 as a result of oxygen ordering under pressure

The appearance of superconductivity and the relaxation of T _c to the equilibrium value T _c ≈30 K in a period of five days were observed in the tetragonal ceramic NdBa₂Cu₃O_6.67 under a pressure of 1 GPa. The superconducting phase vanishes 1.3 h after the pressure is released. This behavior is explained by the charge redistribution occurring as a result of pressure-induced ordering of oxygen in the CuO_x planes. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 10, 784–787 (25 May 1996)     

Pressure-induced superconductivity in tetragonal NdBa2Cu3O6+x

The appearance of superconductivity and relaxation of the transition temperature to its equilibrium value T _c≈30 K over the course of five days have been observed in a tetragonal sample of NdBa₂Cu₃O_6.67 under 1 GPa pressure. The time dependence T _c(t) correlates with a decrease of the room-temperature electrical resistance R(t). The superconducting phase disappears 1.3 h after the pressure is removed. This behavior is explained by a redistribution of charge as a result of pressure-induced oxygen reordering in the CuO_x planes. A large effect of oxygen ordering on the transition temperature under pressure has been observed near the metal-insulator transition (the largest of all those measured in the 1-2-3 system), along with a nonlinear temperature dependence of T _c. Fiz. Tverd. Tela (St. Petersburg) 39, 1328–1334 (August 1997)     

On the investigation of magnetic critical phenomena in ferromagnets by μSR and PAC

On the basis of current theoretical views on the critical phenomena in isotropic Heisenberg ferromagnets the power temperature behavior Λ=c(τ)λ₀τ^-w has been derived for the muon spin relaxation rate Λ as π-T _c ⁻¹ (T-T _c ) → 0⁺. It is shown that the crossover from an exchange critical regime to a dipolar one is accompanied not only with the change in the critical exponentw in the above law, but also with the reduction of the coefficientc(π). A comparison with the temperature behaviour of the inverse nuclear relaxation timet _R ⁻¹ measured in the PAC experiment is carried out.     

Proton NMR relaxation in albumin solutions doped with Mn(II)

The aim of this study is to obtain further information about the source of proton relaxation in the Mn(II)-human serum albumin complex. For this purpose, proton relaxation rates in albumin solutions 1/T ₁ and 1/T ₂ were measured versus increasing amounts of manganese [Mn_t]. The fractions of manganese bound to albumin [Mn_b] and free manganese [Mn_f] were then determined from proton relaxation rate enhancement data. Paramagnetic contributions of bound manganese to the observed relaxation rates (1/T _1p^*)_b and (1/T _2p^*)_b were also determined. Finally, the (1/T _2p^*)_b/(1/T _1p^*)_b ratio was used in a derived equation to estimate an effective correlation time τ. Mean τ value of the complex was found to be in the order of 3 ns, while the hydration number of bound manganese q was estimated to be about 4. The 1/τ was found to be the sum of the inverse values of rotational correlation time 1/τ _r, mean residence time of water in hydration spheres of the complex 1/τ _m, and longitudinal electronic relaxation time of manganese 1/τ _s in the complex. In conclusion, the relaxation mechanism in albumin solutions containing Mn(II) can be interpreted through dipolar and scalar interactions modulated by τ _r, τ _m and τ _s. This analysis enables one to get reasonable figures for the τ _r and q of Mn(II) in albumin solution.     

Anisotropic impurity scattering in palladium silver alloys

Measurements have been made of the Hall coefficientR of some alloys of silver in palladium over the temperature range 1°K to 120°K. The alloys contain between ∼1 and ∼10 at.-% silver. Values ofR were also obtained at room temperature and these were in good agreement with earlier published work. The values ofR are negative in all the alloys, and |R| increases both on reducing the temperature and increasing the silver concentration,c. Below ∼10°K, |R| becomes independent of temperature but shows a linear dependence onc, increasing by a factor of 2.5 over the concentration range measured. This increase is too great to be accounted for in terms of band structure changes alone, so we have examined the effects of anisotropic impurity scattering. To a first approximation it can be shown thatR is proportional to an anisotropy parameterA, defined asA=〈τ ²(k)〉/〈τ(k)〉², whereτ(k) represents the relaxation time of an electron in a statek, and 〈〉 is an average over the Fermi surface. In palladium we assume that the majority of the current is carried by the s-electrons. In the presence of silver impurities these electrons can be scattered into s-states or d-states with relaxation times given byτ _ss α1/c(1−c) andτ _sd α1/c ²(1−c) respectively. FollowingPlate we have assumed thatτ _ss is isotropic and thatτ _sd is anisotropic, leading to an overall anisotropic relaxation time for impurity scattering. We then find the parameterA increases approximately linearly with silver content, in accordance with our experimental results.     

Fluctuation-induced pseudogap in high-temperature superconductors

We study the effect of fluctuations on the ac conductivity of a layered superconductor for c-axis electromagnetic wave polarization. The fluctuation contributions of different physical nature and sign (paraconductivity, Maki-Thompson anomalous contribution, one-electron density-of-states renormalization) are found to be suppressed by the external field at different characteristic frequencies (ω _AL∼T-T _c , ω _MT∼max{T-T _c ,τ _ϕ ⁻¹ }, ω _DOS∼min{T, τ ⁻¹}). As a result, the appearance of a nonmonotonic frequency dependence (pseudogap) in the infrared optical conductivity of high-temperature superconductor is predicted. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 6, 397–401 (25 September 1996) Department of Theoretical Physics Moscow Institute of Steel and Alloys. Published in English in the original Russian journal. Edited by Steve Torstveit.     

Slow relaxation experiments in disordered charge and spin density waves: collective dynamics of randomly distributed solitons

We show that the dynamics of disordered charge density waves (CDWs) and spin density waves (SDWs) is a collective phenomenon. The very low temperature specific heat relaxation experiments are characterized by: (i) “interrupted” ageing (meaning that there is a maximal relaxation time); and (ii) a broad power-law spectrum of relaxation times which is the signature of a collective phenomenon. We propose a random energy model that can reproduce these two observations and from which it is possible to obtain an estimate of the glass cross-over temperature (typically T _g≃ 100-200 mK). The broad relaxation time spectrum can also be obtained from the solutions of two microscopic models involving randomly distributed solitons. The collective behavior is similar to domain growth dynamics in the presence of disorder and can be described by the dynamical renormalization group that was proposed recently for the one dimensional random field Ising model [D.S. Fisher, P. Le Doussal, C. Monthus, Phys. Rev. Lett. 80, 3539 (1998)]. The typical relaxation time scales like ∼τexp(T _g/T). The glass cross-over temperature T_g related to correlations among solitons is equal to the average energy barrier and scales like T _g∼ 2xξΔ. x is the concentration of defects, ξ the correlation length of the CDW or SDW and Δ the charge or spin gap. Received 12 December 2001     

Direct measurements of energy relaxation times on an AlGaAs/GaAs heterointerface in the range 4.2–50 K

The temperature dependence of the energy relaxation time τ_e (T) of a two-dimensional electron gas at an AlGaAs/GaAs heterointerface is measured under quasiequilibrium conditions in the region of the transition from scattering by acoustic phonons to scattering with the participation of optical phonons. The temperature interval of constant τ_e, where scattering by the deformation potential predominates, is determined. In the preceding, low-temperature region, where piezoacoustic and deformation-potential-induced scattering processes coexist, τ _e decreases slowly with increasing temperature. Optical phonons start to participate in the scattering processes at T∼25 K (the characteristic phonon lifetime was equal to τ_LOτ4.5 ps). The energy losses calculated from the τ_e data in a model with an effective nonequilibrium electron temperature agree with the published data obtained under strong heating conditions. Pis’ma Zh. éksp. Teor. Fiz. 64, No. 5, 371–375 (10 September 1996)     

Magnetic relaxation in a three-dimensional ferromagnet with weak quenched random-exchange disorder

Isothermal remanent magnetization decay,M _r(t), and ‘in-field’ growth of zero-field-cooled magnetization,M _ZFC(t), with time have been measured over four decades in time at temperatures ranging from 0.25T _c to 1.25T _c (whereT _c is the Curie temperature, determined previously for the same sample from static critical phenomena measurements) for a nearly ordered intermetallic compound Ni₃Al, which is an experimental realization of a three-dimensional (d = 3) ferromagnet with weak quenched random-exchange disorder. None of the functional forms ofM _r(t) predicted by the existing phenomenological models of relaxation dynamics in spin systems with quenched randomness, but only the expressions and closely reproduce such data in the present case. The most striking features of magnetic relaxation in the system in question are as follows: Aging effects are absent in bothM _r t andM _ZFC(t) at all temperatures in the temperature range covered in the present experiments. A cross-over in equilibrium dynamics from the one, characteristic of a pured = 3 ferromagnet with complete atomic ordering and prevalent at temperatures away from T_c, to that, typical of ad = 3 random-exchange ferromagnet, occurs asT → T_c. The relaxation times τ₁(T)(τ₁ ^′(T)) and τ₂(T)(τ₂ ^′(T)) exhibit logarithmic divergence at critical temperatures and ; and both increase with the external magnetic field strength,H, such that at any given field value, . The exponent characterizing the logarithmic divergence in τ ₁ ^′ (T) and τ ₂ ^′ T possesses a field-independent value of ≃16 for both relaxation times. Of all the available theoretical models, the droplet fluctuation model alone provides a qualitative explanation for some aspects of the present magnetic relaxation data     

Effects of time delay on the statistical fluctuations for a bistable system driven by cross-correlated noises

We study the effects of time delay on the normalized correlation function C(s) and the associated relaxation time T _c for a bistable system with correlations between multiplicative and additive white noises under the condition of small time delay. Using the projection operator method, the expressions of T _c and C(s) are obtained. Based on numerical computations, it is found that the delay time τ slows down the rate of fluctuation decay of dynamical variable for the presence of positive feedback intensity (∈ > 0), while speeds up the rate of fluctuation decay of dynamical variable for the presence of negative feedback intensity (∈ < 0). The effects of the delay time τ on the T _c and C(s) are entirely opposite for ∈ 〉 0 and ∈ < 0.      

Associated relaxation time and intensity correlation function of a bistable system driven by cross-correlation additive and multiplicative coloured noise sources

The associated relaxation time and the intensity correlation function of a bistable system driven by an additive and a multiplicative coloured noise with coloured cross-correlation are investigated. Using the Novikov theorem and the projection operator method, the analytic expressions of the stationary probability distribution P_st(x), the relaxation time T_c, and the normalized correlation function C(s) of the system are obtained. The effects of the noise intensity, the cross-correlation strength λ and the cross-correlation time τ are discussed. By numerical computation, it is found that the cross-correlation strength |λ| and the quantum noise intensity D decrease the relaxation of the system from unstable points. The cross-correlation time τ delays relaxation of the system from unstable points. The cross-correlation strength λ and the cross-correlation time τ can alter the effects of the pump noise intensity Q. Thus, the relaxation time T_c is a stochastic resonant phenomenon, and distribution curves exhibit a single-maximum structure.     

Effects of Self-Correlation Time and Cross-Correlation Time of Additive and Multiplicative Colored Noises for Dynamical Properties of a Bistable System

Considering a bistable system driven by additive and multiplicative colored noises with colored cross-correlation, we obtain the analytic expressions of the stationary probability distribution P _st(x), the linear relaxation time T _c , and the correlated function C(s). The effects of the noise intensity, the self-correlation time and the cross-correlation time for the bistable system are discussed. The noise intensity D speeds up relaxation of the system from unstable points, which when D < Q, the effects are the most obvious; when D > Q, the effects are damped. The self-correlation time τ₁ and τ₂ make the stationary probability distribution of the dynamical variable x be shaper and speed up the fluctuation decay of the dynamical variable x. On the contrary, the cross-correlation time τ₃ makes the stationary probability distribution of the dynamical variable x be flatter and slows down the fluctuation decay of the dynamical variable x. The effect of the self-correlation time is more projecting than the effect of the cross-correlation time. PACS number: 05.40.−a, 02.50.−r, 05.10.Gg.     

Submillimetric cyclotron resonance linewidths and electron relaxation time in copper

For the first time submillimetric microwaves (λ<1 mm) are used to observe Azbel' Kaner cyclotron resonance in metals. The very high frequency used (typicallyF≅400 GHz) gives a large value ofωτ (typically 500) and therefore very sharp peaks. The fundamental resonance fieldH _c=m ^* cω/e is rather high (typically 200 KG), so subharmonicsH _c/n can be observed at many values ofH in the field region 0–27 KG. If relatively few electrons participate in the resonance and ifω _cτ≧50 (ω _c=eH/m ^* c,τ relaxation time) thenChambers has shown that the line shapes are independent of relaxation time while the fractional linewidthΔH/H varies as l/ωτ. For the belly orbit in pure copper the conditions of Chambers' theory are satisfied forH≧20 KG parallel to [111] axis.m ^* is a minimum andτ=1.8×10⁻¹⁰ s.     

In vivo oximetry by a pulsed longitudinally detected ESR spectrometer

By using a narrow single electron spin resonance (ESR) line agent, triarylmethyl, tris(8-carboxy-2,2,6,6-tetrahydroxyethylbenzo[1,2-d:4,5-d′] bis(1,3)dithiole-4-yl)methyl sodium salt (TAM OX063), pulsed longitudinally detected ESR (LODESR) measurements of a phantom or the chest of a living mouse at the operating frequency of ca. 300 MHz were taken and the effective longitudinal relaxation time (T ₁^*) was estimated for oximetry. Under irradiation of a pair of π-pulses with a variable interval between pulses (τ), in-phase LODESR signal intensities were obtained from the phantoms containing TAM dissolved in a physiological saline solution at a concentration of 1 mM and various concentrations of oxygen. TheT ₁^* of the phantom was calculated from the plotted curve of the LODESR signal intensity against τ. It was found that the reciprocal ofT ₁^*, i.e., the longitudinal relaxation rate, increased with the concentration of oxygen. In vivo pulsed LODESR measurements of the chest of living mice that had received a TAM injection via the intraperitoneal route were made. While the LODESR measurements were being made, the mice in one group breathed normal air and those in another group breathed 100% oxygen. It was found that the longitudinal relaxation rate of the mice breathing 100% oxygen was significantly greater than that of mice breathing normal air, indicating that breathing 100% oxygen elevates the thoracic longitudinal relaxation rate.     

Superconducting transition temperature in mercury HTSC-cuprates under hydrostatic pressure

A study is made of the properties of the homologous series of mercury HTSC-cuprates HgBa₂Ca_n−1Cu_nO_2n +2+δ with n=1–8. Experiments are conducted under pressure for samples with n=1–5. The Hg-1223 and Hg-1234 phases were synthesized using a controlled high pressure chamber. The oxygen content of an initial mixture corresponding to the Hg-1234 phase was varied by changing the composition of the initial BaO/BaO₂ oxides. The dependence of the superconducting transition temperature T _c on the lattice constant a (and, therefore, on the oxygen content) and of T _c ^max and dT _c ^max /dp on n are convex upward up to n=4, 5. The maximum values always correspond to the Hg-1223 phase. Experimental T _c ^max (n) curves for the phases with n=1–6 and dT _c ^max /dp curves for n=1–5 are compared with Anderson’s theory (the so-called RVB model). A general analysis of these results indicates that the mercury cuprates have an ideal structure for HTSC. The Hg-1223 phase is the “champion” in this ideal structure and the critical temperature corresponding to this phase (T _c =135 K) is the highest at atmospheric pressure. Zh. éksp. Teor. Fiz. 113, 1474–1483 (April 1998)     

Long-term evolution of photoinduced light absorption in C60 films

It is found that photoinduced absorption in the energy range 0.6–2.1 eV in C₆₀ films grown by the same method can differ by a factor of 100. This change is attributable a 10⁶-fold increase in the relaxation time τ of electron-hole photoexcitations after working with the films for several months. It is established that the bimolecular recombination mechanism for photoexcitations (triplet excitons and polarons), which is typical of as-prepared and partially aged films, is superseded in fully aged films by thermally activated tunneling of localized photoexcitations. An investigation of the film transmission spectra in the photon energy range 0.2–5.0 eV shows that the long-time variations of the optical properties are associated with a decrease in the concentration of defects forming shallow tails of the density of states. An abrupt decrease of the relaxation time τ and the photoinduced absorption is observed in both types of films at T⩾80 K. Fiz. Tverd. Tela (St. Petersburg) 39, 1303–1309 (July 1997)     

Experimental investigation of the longitudinal relaxation time of electronic polarization of the ground state of potassium atoms in a cell with an antirelaxation coating on the walls

We report the results of an experimental investigation of the longitudinal relaxation time T ₁ of the electronic polarization of the ground state of potassium atoms in cells with an antirelaxation coating on the walls. Investigations were performed for a number of cells at temperature T=24°C. The maximum recorded relaxation times τ are 3.6, 4.3, and 5.2 s for cells with diameter D=50,75, and 100 nm, respectively. These are the longest longitudinal relaxation times ever recorded in coated cells. The transverse relaxation time was measured for these cells at the same temperature: T ₂=0.72,1.1, and 1.4 s, respectively. Pis’ma Zh. éksp. Teor. Fiz. 70, No. 3, 198–202 (10 August 1999)     

The role of the dynamic crossover temperature and the arrest in glass-forming fluids

We discuss the role of the dynamic glass-forming fragile-to-strong crossover (FSC) in supercooled liquids. In the FSC, significant dynamic changes such as the decoupling (the violation of the Stokes-Einstein relation) of homologous transport parameters, e.g., the density relaxation time τ and the viscosity η, occur at a characteristic temperature T _c . We study the FSC using a scaling law approach. In particular, we use both forms of the mode-coupling theory (MCT): the original (ideal) and the extended form, which explicitly describes energy hopping processes. We demonstrate that T _c plays the most important physical role in understanding dynamic arrest processes.     

Reciprocity relations for the effective electrical conductivity of randomly inhomogeneous media in the fractal regime

An exact relation for the realization-averaged effective conductivities in the fractal region is found for two-dimensional randomly inhomogeneous media. It has the form {σ _e (τ,L)~× {1/σ _e (−τ,L)~⁻¹=σ _e ² (τ=0, L≫ξ), where ξ is the correlation length (the self-averaging scale), L is the size of the system, τ=(p-p _c )/p _c , and p _c is the percolation threshold. For L≫ ξ, the system is self-averaged, and the relation transforms into the Dykhne reciprocity relation, A. M. Dykhne, Zh. éksp. Teor. Fiz. 59, 110 (1970) [Sov. Phys. JETP 32, 63 (1971)] σ _e (τ)σ _e (−τ])=σ _e ² (τ=0)= σ ₁ σ ₂. A similar relation is obtained for media with an exponentially broad distribution of local conductivities, as well as for individual realizations of some deterministic structures. Zh. éksp. Teor. Fiz. 113, 1484–1490 (April 1998)     

Magnetoplastic effect and spin-lattice relaxation in a dislocation-paramagnetic-center system

A magnetic induction threshold B _c above which the magnetoplastic effect — depinning of dislocations from paramagnetic pinning centers — can be observed in samples placed in a magnetic field is predicted and observed in Al, NaCl, and LiF crystals. The existence of a threshold is associated with the fact that for B<B _c the spin-lattice relaxation time τ_sl in a dislocation-paramagnetic-center system is less than the time required for spin evolution in a magnetic field resulting in the removal of the spin forbiddenness of an electronic transition that “switches off” the dislocation-pinning-center interaction. It is shown that the threshold field B _c is sensitive to temperature and x-ray irradiation of the samples. A new method for measuring the spin-lattice relaxation time in paramagnetic centers on dislocations is proposed on the basis of the data obtained. Pis’ma Zh. éksp. Teor. Fiz. 63, No. 8, 628–633 (25 April 1996)