共查询到20条相似文献,搜索用时 31 毫秒
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Novakov I. A. Orlinson B. S. Navrotskii M. B. 《Russian Journal of Organic Chemistry》2009,45(2):316-317
Russian Journal of Organic Chemistry - 相似文献
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The reaction of 6-methyl-2-methylthio-3-(2-thioxo-1,3,4-oxadiazol-5-yl)methyl-4(3H)-pyrimidinone with butyland benzylamine and also with piperidine and morpholine has been studied. It was found that the primary amines not only open the 1,3,4-oxadiazole ring to form the corresponding thiosemicarbazides but also substitute the methylthio group at position 2 in the pyrimidine ring. Morpholine can only open the 1,3,4-oxadiazole ring but piperidine can also substitute the methythio group to give an oxadiazolethione piperidinium salt.Vilnius University, Vilnius 2734, Lithuania. Translated from Khimiya Geterotsiklicheskikh Soedinenii, No. 8, pp. 1125–1129, August, 1998. 相似文献
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G. Zigeuner R. Hopmann Ch. Knopp A. Fuchsgruber 《Monatshefte für Chemie / Chemical Monthly》1970,101(6):1829-1830
Dihydro-6-styryl-2(1H)-pyrimidinones react with dienophiles such as maleic anhydride in form of aDiels—Alder reaction. 相似文献
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Preparation of a number of derivatives of 2-amino-5-bromo-6-phenyl-4(3H)-pyrimidinone (ABPP) including the 2-dialkylaminoalkylamino-, 2-hydroxyalkylamino-, 2-ethoxycarbonylamino- and 2-alkylaminocarbonyl-amino- groups substituted on the pyrimidine ring as well as preparation of 1-(alkylaminoalkyl)-4,6-dioxo-8-phenyl-2,3,4,6-tetrahydro-1H-pyrimido[1,2-α]pyrimidines and 3,5-dioxo-7-phenyl-1,2,3,5-tetrahydroimidazo-[1,2-α]pyrimidines with or without the bromo-substitution are reported. 相似文献
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Two lithium sulfenamides were prepared by reaction of (CH(3))(3)C-N(H)-S-C(6)H(4)CH(3)-4 (1) and 4-CH(3)C(6)H(4)-N(H)-S-C(6)H(4)CH(3)-4 (2) with an alkyllithium. The unsolvated sulfenamide Li[(CH(3))(3)C-NS-C(6)H(4)CH(3)-4] (3) was soluble enough for variable-temperature (VT) (7)Li NMR to provide evidence of a dynamic exchange of oligomers in solution. The crystal structures of the solvated sulfenamides of [Li(2)(eta(2)-(CH(3))(3)C-NS-C(6)H(4)CH(3)-4)(2)(THF)(2)] (4) and of [Li(2)(eta(1)-4-CH(3)C(6)H(4)-NS-C(6)H(4)CH(3)-4)(2)(THF)(4)] (6) consisted of dimers in which the anions display different hapticities. The VT (7)Li NMR spectra of 4 suggest that the two different structures exist in equilibrium in toluene-THF mixtures. These compounds are easily oxidized to the neutral thioaminyl radicals as identified by EPR spectroscopy. 相似文献
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Oscar L. Acevedo Robert S. Andrews Martin Dunkel P. Dan Cook 《Journal of heterocyclic chemistry》1994,31(4):989-995
A series of 4-(1-alkynyl)-2(1H)-pyrimidinone ribonucleosides were synthesized from the Pd-catalyzed coupling of terminal alkynes to the 4-chloropyrimidin-2-one ribonucleoside ( 2 ). These compounds were hydrated, using three different methods, to afford the 4-(2-oxoalkylidene)-2(1H)-pyrimidinones. The 4-enol-pyrimidin-2-one structure of the title compounds offers functional groups with the potential for Watson-Crick hydrogen bonding. 相似文献
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A novel compound N-(4-methylbenzyl)-4-(3-fluorophenyl)-4-piperidinol hydrochloride has been synthesized and its structure (C19H23ClFNO, Mr = 335.83) was characterized by elemental analysis, IR, ^1H NMR, MS and single-crystal X-ray diffraction analyses. The crystal belongs to the triclinic system, space group P1 with a = 7.2163(6), b = 10.7905(9), c = 12.2651(10) A, α = 109.576(2),β = 98.407(2),γ= 95.956(2)°, V= 878.14(13)A3, Z = 2, Dc = 1.270 g/cm^3,μ = 0.231 mm^-1, F(000) = 356, S = 1.100, the final R = 0.0525 and wR = 0.1425 for 3206 unique reflections (Rint = 0.0140) with 2736 observed ones (I 〉 2σ(I)). The piperidine ring exhibits a chair conformation. The dihedral angle made by the methyl- and fluoro-substituted benzene rings is 66.84(7)°. There are some intra- and intermolecular hydrogen bonding interactions among the molecules, which stabilize the whole crystal structure. The preliminary biological activity tests indicate good herbicidal activity for the title compound, in particular against the roots of some tested plants (such as Brassica campestris L. and Echinochloa crusgallis L.). 相似文献