共查询到20条相似文献,搜索用时 15 毫秒
1.
2.
3.
T. Rüffer H. Lang S. Nawaz A. A. Isab S. Ahmad M. M. Athar 《Journal of Structural Chemistry》2011,52(5):1025-1029
A mixed-ligand silver(I) complex of triphenylphosphine and N,N′-dibutylthiourea (Dbtu), [Ag(Ph3P)2(Dbtu)2]NO3, is prepared and its structure in the solid state is determined by X-ray crystallography. X-ray structure of this complex
shows that it is mononuclear with the silver atom coordinated by two PPh3 and two dibutylthiourea ligands adopting a distorted tetrahedral geometry. The crystal structure shows the formation of 1-D
chains through intermolecular hydrogen bonding interactions between N-H of Dbtu and nitrate ions. The new complex is also
characterized by IR and NMR (1H and 31P) spectroscopy. The spectroscopic data are discussed in terms of the nature of bonding. A similar mixedligand complex is
also prepared for tetramethylthiourea (Tmtu), but the structure of the resulting compound shows that it is a bis(phosphine)
complex, [Ag(PPh3)2NO3] rather than a mixed-ligand complex. 相似文献
4.
5.
6.
7.
Mariana Dennehy Sandra D. Mandolesi Oscar V. Quinzani Dr. Michael Jennings 《无机化学与普通化学杂志》2007,633(15):2746-2752
The reaction of Ag6(tsac)6 ( 1 ) (tsac = thiosaccharinate anion) with triphenylphosphine gives rise to the already reported [Ag(tsac)(PPh3)3] complex ( 2 ) and to two new silver‐thiosaccharinate‐phosphine complexes, [Ag(tsac)(PPh3)2] ( 3 ) and [Ag4(tsac)4(PPh3)4] ( 4 ) (PPh3= triphenylphosphine). Spectroscopic characterization was carried out using IR, UV‐Visible and NMR techniques and confirmed by single crystal X‐ray diffraction. In each complex a singular coordination mode for the thiosaccharinate ligand is observed. The most important features of the different coordination modes of the thionates are discussed. Compound 3 crystallizes in monoclinic system, space group Pn, with a = 11.2293(3) Å, b = 12.7282(3) Å, c = 13.6056(4) Å, β = 94.985(2)°, Z = 2; while crystals of compound 4 are monoclinic, space group P21/n, a = 15.024(3) Å, b = 14.681(3) Å, c = 21.914(4) Å, β = 95.31(3)°, Z = 2. The coordination around the silver atoms in both complexes consists of almost trigonal‐planar arrangements, AgP2S in 3 and AgS2P in 4 . 相似文献
8.
9.
10.
J. V. Hanna S. W. Ng 《Acta Crystallographica. Section C, Structural Chemistry》1999,55(4):IUC9900029-IUC9900029
11.
12.
13.
14.
15.
16.
17.
18.
19.