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用超高压透射电子显微镜原位加热动态观察的方法研究从非晶氢氧化镧转变为纳米级氧化镧超细粉过程中显微组织和结构的变化。电子衍射花样证实在试样被加热到400℃以上时转变为氧化镧纳米粉,其颗粒尺寸为20 ̄50nm。 相似文献
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纳米Sm2O3掺杂CeO2粉末的制备和性能表征 总被引:2,自引:1,他引:2
以Ce2(CO3)3和Sm2O3为原料, 用改进的氨水-双氧水沉淀法制备了CeO2和(CeO2)0.8为基质(Sm2O3)0.2的纳米粉末.对干燥后的氢氧化物进行了TG/DSC热分析, 约650 ℃时Ce(OH)4完全转变为CeO2.XRD分析表明, 650 ℃焙烧的粉末为萤石结构, 说明Sm2O3已固溶到CeO2中.经TEM测试, 粉体颗粒大小在5~10 nm之间, BET测试的平均颗粒尺寸为11.2 nm.由TEM照片还可以看出粉体具有良好的分散性, 且无硬团聚体存在. 相似文献
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通过本体氧化物在常压沸腾水中的水化处理制备了具有棒状外型的氢氧化镧。XRD衍射图显示在短时间内可以得到六方相氢氧化镧,表明其水化过程是相当快的。所得氢氧化镧几乎完全呈针状和棒状外型,其宽度为2-3μm,长为5-8μm。对棒状氢氧化镧的形成机制作了适当解释,并通过煅烧该氢氧化镧微米棒得到了类似外形的氧化镧。该方法比水热法更易于实现工业化应用。 相似文献
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La2(C2O4)3纳米微粒的摩擦学行为研究 总被引:14,自引:0,他引:14
纳米摩擦学是90年代摩擦学研究最活跃的领域之一[1]。稀土元素由于具有4f电子特性,使其元素及其化合物具有许多特殊的性能[2~8]。本研究采用吸附共沉淀表面修饰法制备了烷基磷酸盐修饰的La2(C2O4)3纳米微粒,并将其分散于润滑基础油中考察其摩擦学行为。利用有机脂肪链的减摩、纳米微粒的抗磨以及稀土元素的特殊作用,提高润滑油的摩擦学性能,拓宽稀土化合物在润滑材料领域的应用。1 实验部分11 表面修饰La2(C2O4)3纳米微粒的制备在醇水混合溶剂中,加入一定量的烷基磷酸吡啶盐(自制)和草酸盐… 相似文献
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以硝酸铒和席夫碱为原料,制备席夫碱盐络合物。使用燃烧合成的方法制备了Er2O3纳米晶体。采用傅立叶变换红外光谱(FT—IR)分析了反应历程。使用x射线衍射分析仪(XRD)进行了物相分析及粒径计算。使用透射电镜(TEM)观察了粉体的形貌。结果表明,生成相为单一的立方晶系。纳米晶体晶粒分布不均匀,没有明显的硬团聚现象发生。荧光试验表明,其发射谱在1.54μm处出现发射峰,同时在1.54μm两侧出现肩峰。 相似文献
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Nanocrystalline ZnO was prepared with ZnCl2·2H2O and (NH4)2CO3 as raw materials by direct precipitation method. The precursor was proved to be [Zn5(OH)6(CO3)2] by TG-DTG-DTA and IR analysis. This precursor was calcined at 300°C for 1, 2 and 3 hours respectively, and then the nanocrystalline
ZnO of different grain size were obtained. The nanocrystalline ZnO was characterized using X-ray diffraction (XRD), TEM and
Brunner-Emmett-Teller method (BET). Experimental results for nanocrystalline ZnO showed that the minimum size was about 8nm,
the maximum was about 15 nm and the mean grain size was 12 nm, the surface area was 80.56 m2/g and the purity was 99.9% when the precursor was calcined at 300°C for 2 h.
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Translated from Journal of Inner Mongolia Normal University (Natural Science Edition), 2006, 35(1) (in Chinese) 相似文献
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La2NiO4/Al2O3催化剂上CH4/CO2的重整 总被引:8,自引:1,他引:8
通过溶胶-凝胶方法制备了尖晶石结构的La2NiO4/Al2O3催化剂,采用BET,XRD和TG表征了催化剂的孔分布、比表面积、体相组成以及凝胶样品的热失重和热分解过程.将催化剂应用于CH4/CO2重整反应制合成气,考察了惰性气体和反应温度对转化率、选择性以及积碳的影响.结果表明,在高空速(GHSV=4.8×104ml/(g·h))下,CH4和CO2转化率分别为51%和60%,CO和H2的选择性约为98%和92%,惰性气体He的引入明显地提高了CH4和CO2的转化率. 相似文献
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Xiong Bi-Tao Zhou Bao-Xue Li Long-Hai Cai Jun Liu Yan-Biao Cai Wei-Min 《Chemical Papers》2008,62(4):382-387
Nanocrystalline titanium dioxide particles with anatase structure and high thermal stability have been synthesized using the
basic sol-gel method. The particle size and morphology were refined under hydrothermal conditions in the presence of different
concentrations of tetramethylammonium hydroxide (TMAH) at 210°C and 230°C. XRD and TEM analysis showed that the TiO2 particles obtained were homogeneous and monodispersive at low contents of TMAH. All intense peaks, clearly observed in the
XRD patterns, were assigned to the anatase phase and no rutile phase was observed. At high contents of TMAH, nanoscale small
(10–30 nm) and larger (>100 nm) TiO2 particles were one-pot synthesized. The nanocrystalline TiO2 particles synthesized by this method have good thermal stability. With the sintering temperature of up to 650°C, all the
XRD peaks maintained good agreement with the anatase reference data. 相似文献
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碳酸氢铵沉淀法制备氧化钇粉体时反应条件对产物粒度的影响 总被引:7,自引:1,他引:7
研究了碳酸氢铵沉淀法的反应条件对氧化钇粒度的影响,探讨了粒度变化规律。发现在沉淀反应中,晶型碳酸钇铵的形成与否是影响氧化钇粒度的关键因素。在较低的反应温度下,当碳酸氢铵和氯化钇的浓度大于0.25mol·L-1,摩尔比大于5,陈化时间大于60min时得到碳酸钇铵沉淀,经煅烧可获得粒度(D50)大于1μm的氧化钇。当反应物浓度较低、摩尔比小,陈化时间较短时得到无定型碳酸钇沉淀,煅烧沉淀可获得粒度(D50)小于0.5μm的氧化钇。实验证明选择适当的沉淀反应条件,可制备D50在0.3~10μm范围内的不同粒度级别的氧化钇粉体。 相似文献
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Preparation and characterization of highly photoactive nanocrystalline TiO_2 powders by solvent evaporation- induced crystallization method 总被引:1,自引:0,他引:1
Highly photoactive bi-phase nanocrystalline TiO2 photocatalyst was prepared by a solvent evaporation-induced crystallization (SEIC) method, and calcined at different temperatures. The obtained TiO2 photocatalyst was characterized with X-ray diffraction (XRD), transmission electron microscopy (TEM) and BET surface areas. The photocatalytic activity was evaluated by the photocatalytic oxidation of acetone in air. The results show that solvent evaporation can promote the crystallization and phase transformation of TiO2 at 100℃. When calcination temperatures are below 600℃, the prepared TiO2 powders show bimodal pore size distributions in the mesoporous region. At 700℃, the pore size distributions exhibit monomodal distribution of the inter-aggregated pores due to the collapse of the intra-aggregated pores. At 100℃, the obtained TiO2 photocatalyst by this method shows good photocatalytic activity, and at 400℃, its photocatalytic activity exceeds that of Degussa P25. This may be attributed to the fact t 相似文献
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Using La2(SO4)3 and the active carbon powder as reactants,
La2O2S∶Mn2+ red phosphor was synthesized by microwave radiation method. The phosphor was characterized by means of X-ray diffraction (XRD), scanning electron microscopy (SEM), laser-diffraction size analyzer and fluorospectrophotometer. The XRD analysis showed that the phosphor was pure phase
La2O2S. The phosphor of La2O2S∶Mn2+ showed hexagonal crystal structure with diverse shapes, such as spherical and rod, with average particle size of 10.22 μm. The emission and excitation spectra of the phosphor were determined by fluorospectrophotometer and the results showed that the excitation spectrum of the phosphor under 600 nm emission wavelength was excitation bands between 250 nm and 350 nm with a peak value of 303 nm. Then ,when exicited under UV 303 nm, the phosphor showed broad band emission of 550~700 nm with a peak at 607 nm. In addition, the optimal effects were obtained for the phosphor preparation when the concentration of the activator
Mn2+ was xMn=0.01, the ratio of C and O (nC / nO) in the reactants was 0.6∶1, and the time of reaction was about 1 h.
La2O2S∶Mn2+ has strong absorption of UV spectrum and can emit bright red light. 相似文献
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液相沉淀法制备纳米ZnO粉体的研究 总被引:1,自引:0,他引:1
现有制备纳米ZnO的方法大多需要较特殊的设备和严格的反应条件[1 4] 。笔者采用液相沉淀法,首先以草酸为沉淀剂直接从硫酸锌水溶液中沉淀出前驱体ZnC2 O4·2H2 O ,然后经过滤、洗涤、干燥和焙烧分解,制得了平均晶体粒径为2 5nm的ZnO粉体。此方法操作简单、反应条件温和、易于控制。但沉淀在洗涤过滤和干燥时易产生团聚现象[7] 。为此采取以稀草酸溶液对制得的前驱体进行超声洗涤和1 2 0℃真空干燥的措施,明显提高了粉体的分散性能。1 实验部分1 1 主要仪器及试剂Zn(SO4) 2 和H2 C2 O4·2H2 O(A .R .)。KS 2 5 0E型超声波清洗仪… 相似文献
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Sergio L. González-Cortés José Orozco Delfin Moronta Bernardo Fontal Freddy E. Imbert 《Reaction Kinetics and Catalysis Letters》2000,69(1):145-152
Methane transformation over Ni and Cu modified Sr2+/La2O3 catalysts has been studied. These species favor formation of reducible mixed oxides and change the surface reactivity of the Sr2+/La2O3 system, modifying the reaction mechanism, since Sr2+/La2O3 favors methane oxidative coupling but with copper methane combustion is favored and nickel favors partial oxidation. 相似文献
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将Al(NO3)3-Ce(NO3)3混合溶液滴入到NH4HCO3-NH3.H2O混合溶液中,采用共沉淀法制备了CeO2-Al2O3复合载体.采用等体积浸渍法分别浸渍助剂La和活性组分Cu,制备了Cu/La/CeO2-Al2O3催化剂.考察了催化剂在富氧条件下对丙烯选择性还原NO反应的催化活性,并借助扫描电镜、原子力显微镜、X射线衍射、比表面积测定、红外光谱、热重分析、X射线光电子能谱和程序升温还原等方法研究了催化剂活性与结构之间的关系.结果表明,CeO2-Al2O3复合载体能显著增大催化剂的比表面积和孔径,增加表面Lewis酸酸量,改善催化剂的还原性能;助剂La能进一步增大催化剂的比表面积和孔径,增加表面Br nsted酸酸量,显著提高催化剂的热稳定性;催化剂的粒径较小,对丙烯选择性还原NO反应具有较高的催化活性,最高催化活性时的温度较低. 相似文献