Electrochemical extraction of alkaloids of the tropane group from plant raw material

Summary 1. In a study of the carbohydrates ofEremurus regeli Vved., according to the period of development of the plant, it has been found that in the leaves the maximum amount of pectin substances is present in the period of the ripening of the seeds. In the tuber roots, water-soluble polysaccharides form the main component and they are present in maximum amount after the withering of the epigeal part.2. A preliminary investigation of the pectin substances from the leaves has shown that they belong to the heteropolysaccharides consisting of galacturonic acid and the neutral monosaccharides xylose, rhamnose, arabinose, and galactose.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR. Translated from Khimiya Prirodnykh Soedinenii, No. 4, pp. 429–432, July–August, 1974.     

O-methylcyclovirobuxine-D — A new alkaloid fromBuxus sempervirens

The amounts and compositions of the essential oils in the leaves and fruit of Meyer's lemon in the various vegetation periods have been studied. It has been established that as the fruit ripens the amount of essential oils and of monoterpene hydrocarbons in its peel and in the leaves increases.Institute of Plant Biochemistry, Academy of Sciences of the Georgian SSR. Sukhumi Zonal Experimental Station of Essential-Oil Crops. Sukhumi Experimental Station of Subtropical Crops, All-Union Institute of Plant Growing. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 784–787, November–December, 1985.     

Polysaccharides ofPolygonatum II. A study of the dynamics of the accumulation of the polysaccharides ofPolygonatum sewerzowii

Summary The amounts of water-soluble polysaccharides in various organs ofPolygonatum sewerzowii in different vegetation periods have been determined and their polysaccharide compositions have been established.The maximum amount of water-soluble polysaccharides is present in the leaves and stems in the fruit-bearing period, in the roots at the time of budding, and in the rhizomes at the time of flowering. The quantitatively predominating component in the polysaccharides of the stems is galactose, and in the leaves, roots, and rhizomes, mannose. D-Mannose has been isolated from the rhizomes and leaves.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 11, pp. 3–5, January–February, 1979.     

The protopectin of the leaves and petioles of Sosnovskii's cowparsnip and heartleaf colewort

Summary 1. The protopectins of the petioles and leaves of Sosnovskii's cowparsnip and heartleaf colewort have been studied. It has been shown that the protopectins of wild-growing herbs are similar to the pectins of fruit and vegetables.2. The heterogeneity of the pectins isolated has been shown by the fractionation method. Two main fractions were obtained — neutral (weakly acidic) and acidic.M. V. Lomonosov Odessa Technological Institute of the Food Industry. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 760–763, November–December, 1977.     

Carbohydrates and lipids ofBrassica oleracea

Lipids and polysaccharides have been obtained from the leaves ofBrassica oleracea. The qualitative and quantitative compositions of the lipid complex have been studied. The fatty acid compositions of the total neutral lipids and of the phospho- and glycolipids have been determined. The carbohydrate complex of cabbage includes water-soluble polysaccharides, low-methoxyl pectins, hemicelluloses, and free monosugars. The polypeptides have been characterized by their mannoside compositions.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, fax (3712) 89 14 75. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 612–615, September–October, 1994.     

Polysaccharides of saponin-bearing plants. IV. Structure of glucans A,B, and C of Biebersteinia multifida

The neutral polysaccharides of the tuberous roots ofBiebersteinia multifida consist of three weakly branched glucans, A, B, and C. It has been established by periodate and chromic acid oxidation, methylation, and mass spectrometry that in the chains of glucans A, B, and C the monosaccharides are linked to one another by -1 6 bonds and there is branching at the C-3 atoms of the glucopyranose residues.Institute of Chemistry of Plant Substances, Uzbekistan Republic Academy of Sciences, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 188–191, March–April, 1993.     

Preliminary investigation of the water-soluble polysaccharides from the leaves of the bambooSasamorpha chiisanensis

It has been shown that the water-soluble polysaccharides of the leaves of the bambooSasamorpha chiisanensis Nak., after the removal of starch, contain residues of D-galactose, D-glucose, mannose, arabinose, D-xylose, rhamnose, and glucuronic and galacturonic acids and form an involved polysaccharide complex. Eight polysaccharide fractions differing in their uronic acid contents and in the ratio of neutral sugars have been isolated with the aid of chromatography on DEAE-cellulose.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 44–48, January–February, 1987.     

Chemical investigation of the polysaccharides of the leaves ofPlantago major L.

Summary 1. A polysaccharide has been isolated from the leaves ofPlantage major L. and its monosaccharide composition has been studied.2. It has been established that the polysaccharide investigated contains D-galacturonic acid, D-galactose, D-glucose, D-xylose, L-rhamnose, L-arabinose, a partially methylated galactose, and two unidentified monosaccharides.3. The high content of galacturonic residues (68%) in the polysaccharide enables it to be classified as a pectin.Khimiya Prirodnykh Soedinenii, Vol. 1, No. 5, pp. 297–302, 1965     

Large-Scale Purification of Water-Soluble Polysaccharides from Flaxseed Mucilage, and Isolation of a New Anionic Polymer

Summary Viscous flaxseed mucilage has previously been described as a mixture of two polysaccharides (acidic and neutral). In this study, we have shown that a combination of ion exchange and size exclusion chromatography enables purification of three distinct polysaccharides. Molecular weight (Mw) analysis, performed by size-exclusion chromatography on line with a multi-angle laser light-scattering detector, revealed that the main polysaccharide (75%) was a neutral polymer with a Mw of approximately 1.2 × 10⁶ g mol^–1. The two others were acidic polysaccharides denoted AF₁ (3.75%, 6.5 × 10⁵ g mol^–1) and AF₂ (21.25%, 1.7 × 10⁴ g mol^–1).Presented at: International Symposium on Separation and Characterization of Natural and Synthetic Macromolecules, Amsterdam, The Netherlands, February 5–7, 2003     

Asparagus polysaccharides. I. Isolation and characterization of polysaccharides ofA. neglectus: Glucomannans of the roots

Water-soluble polysaccharides and pectin substances have been isolated from various organs ofA. neglectus and their quantitative amounts and monosacchardie compositions have been determined. Native acetylated glucomannans (A, B, and C) containing 13, 15, and 20% of acetyl groups and being homogeneous according to the results of gel chromatography have been isolated from the roots. On the basis of the results of periodate oxidation, methylation, and IR spectroscopy it has been established that the neutral polysaccharides of the roots ofA. neglectus is a mixture of three glucomannans consisting of -14 linear-bound D-gluco- and D-mannopyranose residues.Deceased.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 702–706, November–December, 1981.     

Chemical and immunochemical investigation of the lipopolysaccharides ofVibrio alginolyticus

A chemical and immunochemical study of the LPSs of the microorganismsVibrio alginolyticus (strains 1385–80, 945–80, and 2076–80) has been made. A difference in the monosaccharide composition of the LPSs of the strains studied has been shown. It had been established that the LPSs of strains 945–80 and 2076–80 possess a high serological specificity, while the LPS of strain 1385–80 differ serologically from them. A suggestion is made of the role of different monosaccharides in the formation of the immunochemical determinants of the LPSs of the strains studied.Pacific Ocean Institute of Bioorganic Chemistry of the Far-Eastern Scientific Center of the USSR Academy of Sciences, Vladivostok. Translated from Khimiya Priorodnykh Soedinenii, No. 5, pp. 652–657, September–October, 1987.     

Carbohydrates ofSymphytum asperum

It has been shown that the carbohydrates ofSymphytum asperum L. — a promising fodder plant — include water-soluble polysaccharides, pectin substances, protopectin, hemicelluloses, a glucomannan, and cellulose. The quantitative amounts of the polysaccharide fractions in the raw material have been established and their characteristics are given. The protopectins of the leaves and stems ofSymphytum asperum L. have been characterized. Their macromolecules are based on a fragment constructed of D-galacturonic acid residues linked by -glycosidic bonds.M. V. Lomonosov Odessa Technological Institute of the Food Industry. Translated from Khimiya Prirodnykh Soedinenii, No. 1, pp. 15–20, January–February, 1984.     

Polysaccharides ofEremurus. X. Characteristics of the polysaccharides ofEremurus lactiflorus andE. luteus

Water-soluble polysaccharides have been isolated from two species ofEremurus — E. lactiflorus andE. luteus — with yields of 13.5% and 20.5%, respectively. They contained mainly glucose and mannose in ratios of 1:5 and 1:3.1. The polysaccharides ofE. lactiflorus were separated from a column of DEAE-cellulose. The yield of neutral fraction was 10.3%. Gel filtration of the polysaccharides on Sephadex G-200 showed their polydispersity. Homogeneous fractions were obtained by fractional precipitation with ethanol. They have been characterized with respect to monosaccharide composition, molecular weight, and IR spectra.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 5, pp. 604–608, September–October, 1979.     

Polyphenolic compounds ofPersica vulgaris

The results are given of a chemical study of the polyphenol composition of various organs ofPersica vulgaris Mill. The material of investigation consisted of the dried leaves, flowers, the bark of the roots and of the stems, the fruit, and the skin of the fruit of the peach collected from the experimental plots of the R. R. Shreder Scientific-Research Institute of Horticulture and Viniculture of the Uzbek SSR. Seventeen polyphenols have been isolated, of which 14 have been characterized completely. The amounts of total polyphenols in the skin of the fruit of 10 varieties have been determined. Kaempferol 3-O--D-diglucopyranoside and quercetin 3-O--D-diglucopyranoside have been isolated from peach leaves for the first time, and (—)-epicatechin gallate from the bark of the stems. The position of the sugar substituent in persicoside has been established: it is hesperitin 5-O--D-glucopyranoside.Institute of Bioorganic Chemistry, Academy of Sciences of the Uzbek SSR, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 316–321, May–June. 1979.     

Plant polysaccharides VII. Polysaccharides ofMorus and their hypoglycemic activity

Water-soluble polysaccharides, pectin substances, and hemicelluloses have been isolated fromMorus leaves, and their qualitative and quantitative compositions have been determined. The polysaccharides obtained by extraction with hot water have been investigated for hypoglycemic activity. A polysaccharide fromMorus alba proved to have the highest sugar-lowering activity.Materials presented at the IInd International Symposium of the Chemistry of Natural Compounds.Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 789–791, November–December, 1997.     

Polysaccharides ofAconitum zaravschanicum

The dynamics of the accumulation of water-soluble polysaccharides and pectin substances of Aconitum zaravschanicum Steinb over the vegetation periods have been studied. The maximum amounts of polysaccharides have been established and their comparative physicohemical characteristics have been determined.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Uzbekistan Republic, Tashkent. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 357–359, May–June, 1993.     

Lipids of microalgae. III. Lipids of the biomass ofMonocrysis lutheri grown under the conditons of an accumulation culture

The class composition of the lipids of the biomass of the microalgaMonochrysis lutheri grown under the accumulation regime of cultivation has been investigated for the first time. A predominance of triacylglycerols in the neutral lipids, of phosphatidylcholine in the phospholipids, and of digalactosyldiacylglycerols in the glycolipids has been established. New natural alkan-8-ones of the C₃₆-C₅₀ series have been detected.Institute of the Chemistry of Plant Substances. Academy of Sciences, of the Republic of Uzbekistan, Tashkent. FAX (3712) 62 73 48. Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 325–330, May–June, 1994.     

Composition of the lipids and carbohydrates of the seeds ofAmaranthus caudatus

The chemical composition of the seed lipids ofAmaranthus caudatus L. has been investigated. The fatty acid compositions of the neutral lipids and of the phospho- and glycolipids have been determined. The hydrocarbon components ofA. caudatus have been identified and its alcohol-soluble carbohydrates, water-soluble polysaccharides, and pectin substances have been characterized.Institute of the Chemistry of Plant Substances, Academy of Sciences of the Republic of Uzbekistan, Tashkent, fax (3712) 40 64 75. Translated from Khimiya Prirodnykh Soedinenii, No. 6, pp. 797–799, November–December, 1997.     

Polysaccharide from the leaves ofPhytolacca americana

A polysaccharide has been isolated from the leaves ofPhytolacca americana and has been characterized. It has been established that it contains residues of galactose, arabinose, xylose, and rhamnose, in a ratio of 3:4:1:3 and also D-galacturonic acid (85–90%). The results obtained permit the polysaccharide to be assigned to the class of pectin substances.All-Union Oncologic Scientific Center, Academy of Medical Sciences of the USSR, Moscow. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 166–169, March–April, 1982.     

Carbohydrate compositions of preparations of fungal origin

The fractional composition of the polysaccharides formed by some local strains of basidial fungi (Panus tigrinus, Pleurotus ostreatus, Fomes formentarius, andPhanarechaeta chrysosporium) in a submerged medium on various plant wastes (spent cottonseed pulp and cottonplant stems) has been investigated. Water-soluble polysaccharides, pectin substances, and hemicelluloses have been isolated from the products synthesized by the fungi, and their qualitative and quantitative monosaccharide compositions have been determined.Materials presented at the Second International Symposium of the Chemistry of Natural Compounds (SCNC, Eskiehir, Turkey, October 22–24, 1996).Translated from Khimiya Prirodnykh Soedinenii, No. 3, pp. 352–357, May–June, 1977.