The hydrodynamic limit of a one-dimensional nearest neighbor gradient system

We study the hydrodynamic behavior of a one-dimensional nearest neighbor gradient system with respect to a positive convex potential . In the hydrodynamic limit the density distribution is shown to evolve according to the nonlinear diffusion equation ,(q)/t= (²/dq²){F([1/₁(q)]), with F= –.     

On the domains of generalized operators

The domains of generalized operatorsT: _–+ on rigged Hilbert spaces _– H ₊ are investigated. We introduce an equivalence relation for operators with different domains. Arguments are given for taking ₊ to be the weak quasi-completion of _– and for _– to be Mackey quasi-complete. For domains of closed symmetric Hilbert space operators we give a representation for ₊ and provide certain elements in the equivalence class of the corresponding operator.     

Hermiticity of Quantum Observables Versus Commutation Relations

In order to obtain sum rules and spectral representations the Hermiticity property , A = A, of observables is used. It is shown that for certain and the property turns out to be inconsistent with the commutation relations that contain A. The known Schwinger paradox is explained by this inconsistency.     

Parametric dependence of the properties of pulsed-laser-deposited diamond-like carbon films

The properties of Pulsed-Laser-Deposited Diamond-Like Carbon (PLD DLC) films are studied as functions of the power density and the wavelength of the laser beam, and the incident angle of the beam relative to the normal of the target surface. All the films have a similar structure consisting of graphite particulates embedded in a continuous matrix, so the macroscopic performance of the films is determined by the overall contributions of the particulates and the matrix. The use of higher, shorter, or larger leads to an enhancement of the diamond-like characteristics and a simultaneous increase of the particulate density. These two effects give opposite contributions to the electrical conductivity _R, leading to the following results. (i) _R drops with increasing in the low range (region I) due to the stronger diamond-like nature of the matrix, but increases sharply after has exceeded a threshold _min as a result of the rapid increase in particulate density. (ii) In region I, the use of shorter or larger leads to a more diamond-like matrix, and this overwhelms the degradation effect caused by the slight increase in particulate density. The samples thus become more insulating. In the high region (region II), however, the use of shorter or larger gives rise to higher particulate density, thereby increasing the electrical conductivity.     

The translation-rotation paradox in the nucleation theory

The factor of 10¹⁷ proposed by Lothe and Pound in the theory of nucleation of droplets from the vapor phase is studied using classical statistical mechanics. The controversial factor is derived from partition functions for an isolatedn-mer and for ann-molecular cluster imbedded in the bulk liquid phase. The rotational degrees of freedom have no place in, in agreement with Reiss, Katz, and Cohen's treatment. It is proved that the surface free energy of a cluster is proportional to the surface area. The estimate of what Lothe and Pound called the replacement term is different from those of previous authors. It is concluded that is written as a ratio = _g/_l, where _g and _l , are the volumes per molecule in the gas phase and in the liquid phase, respectively. For water at 300K, is approximately equal to 10₄.     

Electronic absorption and emission spectral data and fluorescence quantum yields of bridgedp-oligophenylenes,bi- to deciphenyls,and related furans and carbazoles

Absorption and fluorescence emission spectral data, as well as fluorescence quantum yields (_f), were determined for 41p-oligophenylene compounds containing 2–6, 8, and 10 benzene rings. Of 29 compounds containing carbon-bridged rings (fluorenes), 28 were dialkylated on each bridge for improved solubility and photostability. Absorption maxima for oligophenylenes were observed at wavelengths as long as 366 nm, emission maxima to 437 nm, and molar extinction coefficients () as large as 153,000 L/mol-cm; all three exceeded predicted maximum values for the corresponding unbridged oligophenylenes. The substitution of furan for benzene or carbazole for a fluorene (two examples each) bathochromically shifted absorption and emission maxima. Dialkylated carbon bridges bathochromically shifted absorption and emission maxima, and lowered _f in biphenyl and in one terphenyl analogue, but appeared to cause no diminution of _f in higher oligophenylenes. Bis(2-methoxyethyl) substitution on the bridges, incorporated to provide solubility in polar solvents, lowered _f in all examples. Tertiary alkyl substituents on terminal rings bathochromically shifted the absorption and emission maxima and generally increased _f. The loose bolt effect, which lowers _f in mononuclear substituted benzenes, may operate in 9,9-dialkylfluorenes, but not in 2,7-di-t-butylfluorene or in higher oligophenylenes. Cyclic ether and methoxy substituents as auxofluors on terminal rings generally bathochromically shifted absorption and emission maxima and increased and _f. Cyano substituents bathochromically shifted absorption and emission maxima, and increased , but lowered _f slightly.     

A complete proof of the Feigenbaum conjectures

The Feigenbaum phenomenon is studied by analyzing an extended renormalization group map . This map acts on functions that are jointly analytic in a position variable (t) and in the parameter () that controls the period doubling phenomenon. A fixed point ^* for this map is found. The usual renormalization group doubling operatorN acts on this function ^* simply by multiplication of with the universal Feigenbaum ratio ^*= 4.669201..., i.e., (N ^*(,t)= ^*( ^* ,t). Therefore, the one-parameter family of functions, ^* , ^* (t)=( ^*(,t), is invariant underN. In particular, the function ₀ ^* is the Feigenbaum fixed point ofN, while ^* represents the unstable manifold ofN. It is proven that this unstable manifold crosses the manifold of functions with superstable period two transversally.     

Treatment of droplike clusters in nucleation theory using Reiss's method

The expression of the correction factor in nucleation theory is derived by extending the method Reiss used recently. is the factor appearing in the number of critical nuclei (formed as a vapor condenses into liquid drops) as a correction to the conventional theory. It is shown that=p _l / _g /kT, wherep _l is the pressure of the liquid phase inside the drop, _g , is the volume per molecule in the vapor phase,k is the Boltzmann constant, andT is the absolute temperature. The difference between this and Reiss's expression isp _l , which replaces hisp _g (the vapor pressure in equilibrium with the drop). The derived in this paper is compatible with the expression= _g / _l ( _l is the molecular volume in the liquid phase) previously proposed by the present author.     

Interacting spinor and scalar fields: Exact self-consistent solutions in Bianci I space

Exact self-consistent solutions of the equations that describe a system of interacting spinor and massless scalar fields with the interaction Lagrangian L_int=_,^,(S), where (S) is an arbitrary function of the invariant S=, are obtained in Bianci I space. The possibility of excluding the initial singularity is studied for the case of a power-law function (S), and isotropic expansion of the space as t is established.Russian University of International Amity. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 7, pp. 53–58, July, 1995.     

Concept of time in the general law of thermodynamics as the basis of the thermodynamics of the nonequilibrium state

A mathematical formulation is proposed for the general law of thermodynamics in the form of relations defining the concept of thermodynamic time and the criterion of stable equilibrium. It is hypothesized that an implicit function F(, , , , ... ⁽ⁿ⁾)=0 associates the thermodynamic time and the potential of the nonequilibrium state. Partial solutions of a general form are also obtained for the trajectories of a nonequilibrium process, characterized by the presence of only one independent variable, i.e., =(⁽ⁿ⁾).Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 49–54, August, 1989.     

Currents and Super-Operator Product Expansionsof N = 4 Super-W Algebra

The currents and the super-operators product expansions of theN = 4 super-Walgebra are obtained. The generators of this extended conformal algebra consistof the stress-tensor superfield J and the primary superfields _±v ^q of integer orhalf-integer conformal weight and Cartan–Weylcharge q. The algorithm forderiving the N = 4 super-W algebra is given for particular cases. Explicit formsof the operator product algebra for different values of are given.     

Five-dimensional null-cone structure of big bang singularity

Firedmann model of positive space curvature, vanishing pressure and cosmological constant when isometrically imbedded as a hypersurface in five dimensional Minkowski spaceM ⁵ is globally rigid: if F() and F() are isometric imbeddings inM ⁵ there is a motion of M⁵ such that F= °f. The big bang singularity is the vertex of a null half-cone inM ⁵. Global rigidity leads to an invariant characterization of the singularity. The structure of matter at the singularity is governed by the de Sitter group.     

Ergodic properties of infinite-dimensional stochastic systems

The ergodic properties of two stochastic models _I and _II are investigated. Each model is described by a fieldx(t),t > 0, on the lattice =Z ^d,d < . For _I,x(t) evolves according to the equations wherex _s (t) R for eachs eF. Here the {w_s(t): s } are independent, one-dimensional Wiener processes, ₂ is a bounded interaction between adjacent lattice sites, and the potentials ₁ and ₂ satisfy appropriate regularity conditions. It is shown that for each model,x(t) is a Markov process on an infinite-dimensional phase spaceX. The probability measures onX that satisfy the Dobrushin-Lanford-Ruelle (DLR) conditions are stationary for this process and have a mixing property. Moreover, for _I any stationary, time-reversal-invariant probability measure that has certain regularity properties must satisfy the DLR conditions.This paper is based on a portion of the author's Ph.D. thesis.⁽²⁾     

More surprises in the general theory of lattice systems

I use Israel's methods to prove new theorems of ubiquitous pathology for classical and quantum lattice systems. The main result is the following: Let be any interaction and be any translation-invariant equilibrium state for (extremal or not). Then there exists a sequence { _k } of interactions converging to , having extremal (or even unique) translation-invariant equilibrium states _k , such that { _k } converges to . In certain situations the perturbations _k – can be chosen to lie in a cone of antiferromagnetic pair interactions. I discuss the connection with results of Daniëls and van Enter, and point out an application to the one-dimensional ferromagnetic Ising model with 1/r ² interaction (Thouless effect).     

The contrast gain in a guest-host nematic display due to a periodic boundary condition

The mean square tilt angle of a nematic slab with finite anchoring energy and periodic boundary conditions has been theoretically investigated, as a function of the slab geometry and of the reduced extrapolation length. If the anchoring strength is free-surfacelike, the contrast is affected by a loss 10% at room temperature if the ratio between the anchoring pitch and the cell thickness is 0.5.Glossary anchoring pitch - h cell thickness - /h - ( = x/, = y/h) reduced coordinates - (, ) local tilt angle - elastic constant - w_a anchoring energy anisotropy - b=/w _a de Gennes-Kleman extrapolation length - B=b/h reduced extrapolation length - T _NI nematic-isotropic transition temperature - :=(T/T _NI ) – 1 reduced temperature - easy axis direction - _MAX - _± ² mean square tilt angle along the boundary - () absorbance coefficients of the p-dye - r /: dichroic ratio - c contrast - G contrast gain - S order parameter     

Streuung spinpolarisierter Elektronen an Au(110)

Using the the spin modulated polarized electron gun based on photoemission from positive affinity GaAs the intensityI(E, , ) and asymmetry (E, , ) are measured in LEED from Au(110). The asymmetry is compared with the polarizationS(E, , ) which N. Müller obtained with a Mott detector after scattering an unpolarized electron beam from the same crystal. There is excellent agreement for the (00) beams, if the scattering plane is a mirror symmetry plane of the crystal (=0°, =90°). From the differences for the (00) and (11) beams at =35° and the (01/2) beam at =90° conditions for possible models for the reconstructed Au(110)–(1×2) surface may be derived.

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Die vorliegende Arbeit ist ein Auszug aus [1]

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Neue Addresse ab 1. Oktober 1980: B. Reihl, IBM Thomas J. Watson Research Center, Yorktown Heights, NY 10598, USA     

gl q (n) and quantum monodromy

A generalized Toda lattice based on gl(n) is considered. The Poisson brackets are expressed in terms of a Lax connection, L=–() and a classical r-matrix, {₁,₂}=[r,₁+₂}. The essential point is that the local lattice transfer matrix is taken to be the ordinary exponential, T=e; this assures the intepretation of the local and the global transfer matrices in terms of monodromy, which is not true of the T-matrix used for the sl(n) Toda lattice. To relate this exponential transfer matrix to the more manageable and traditional factorized form, it is necessary to make specific assumptions about the equal time operator product expansions. The simplest possible assumptions lead to an equivalent, factorized expression for T, in terms of operators in (an extension of) the enveloping algebra of gl(n). Restricted to sl(n), and to multiplicity-free representations, these operators satisfy the commutation relations of sl _q (n), which provides a very simple injection of sl _q (n) into the enveloping algebra of sl(n). A deformed coproduct, similar in form to the familiar coproduct on sl _q (n), turns gl(n) into a deformed Hopf algebra gl _q (n). It contains sl _q (n) as a subalgebra, but not as a sub-Hopf algebra.     

On the correlation for Kac-like models in the convex case

The aim of this paper is to stu the behavior asm tends to of a family of measures exp[- ^(m)(x)]dx ^(m) on ^m , where ^(m) is a potential on ^m which is a perturbation in a suitable sense of the harmonic potential _j x _j ² .     

Central decomposition of invariant states applications to the groups of time translations and of euclidean transformations in algebraic field theory

With aC*-algebra with unit andgG _g a homomorphic map of a groupG into the automorphism group ofG, the central measure of a state of is invariant under the action ofG (in the state space of ) iff is -invariant. Furthermore if the pair { ,G} is asymptotically abelian, is ergodic iff is ergodic. Transitive ergodic states (corresponding to transitive central measures) are centrally decomposed into primary states whose isotropy groups form a conjugacy class of subgroups. IfG is locally compact and acts continuously on , the associated covariant representations of { , } are those induced by such subgroups. Transitive states under time-translations must be primary if required to be stable. The last section offers a complete classification of the isotropy groups of the primary states occurring in the central decomposition of euclidean transitive ergodic invariant states.     

Bosons in thermal contact: AC*-algebraic model

A gas of two Boson systems coexisting inR ³, and interacting only mutually, is analyzed. The interaction is quadratic, so that the dynamical problem may be solved completely and exactly.The initial state is taken to be the mutually uncorrelated Gibbs states: ^{(1) (2)} = . We find the time evolved state, and its projections onto the separate species and the subvolumes.The principle consequences of this model are discussed. In particular we examine the possible occurrence of harmonic oscillations between the species.On Study Leave at the Department of Physics and Astronomy, The University of Rochester.This research was partially supported by the National Science Foundation under Contract No. 5-28501.