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不同Ba含量的Y-Ba-Cu-O体系多晶材料的相组成及其超导电性 总被引:1,自引:0,他引:1
本文采用Raman光谱分析方法对名义组分为YBaxCu3O(x=2.0,1.8,1.6,1.2,0.6)的系列样品的相组成和超导转变温度的关系进行了分析.结果表明:1)在制备Y(123)相材料过程中,Ba元素的含量对样品的成相有着重要影响.在高Ba含量的Y(123)相样品中,容易产生BaCuO2相杂质,在低Ba含量的样品中则容易产生Y(211)、(Y2BaCuO5)相杂质,而Ba含量适当低于标准化学剂量配比时有利于Y(123)相的生成2)样品的相组成对超导转变温度Tc值影响不大,但与超导转变温度宽度△Tc密切相关.当x=1.6时,其△Tc最小,说明样品中适量的Y(211)相杂质的存在对超导转变特性的改善是有利的. 相似文献
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本文采用Raman光谱分析方法对名义组分为YBaxCu3O7-y(x=2.0,1.8,1.6,1.2,0.6)的系列样品的相组成和超导转变温度的关系进行了分析,结果表明:1)在制备Y(123)相材料过程中,Ba元素的含量对样品的成相有着重要影响,在高Ba含量的Y(123)相样品中,容易产生BaCuO2相杂质,在低Ba含量的样品中则容易产生Y(211)、(Y2BaCuO5)相杂质,而Ba含量适当低于 相似文献
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我们用Schilling等人的方法制备出了Hg-Ba-Ca-Cu-O超导化合物系,并用X-ray衍射、TEM、磁化率及电阻等实验测量对它们进行了初步研究.由TEM观察,证实了在HBCCO系中存在Hg-1201相,Hg-1212相和Hg-1223相.用高-Q振动子技术,对HgBa2CuO4+y样品作了磁通点阵融化的力学测量,从而估计出该样品的不可逆线的形状.我们还对Hg-1223样品作了事后退火处理研究,在氧气中退火可使该样品的Tc略有增高,这些结果表明Hg-1223样品的超导相可能处在微弱的“under-doped”态. 相似文献
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用H_2~+束流光谱研究YBa_2Cu_(3-x)Ag_xO_y(x=0.5、1.0、1.5、2.0、3.0)体系的发光特性。 相似文献
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用Sn分别部分替代Y-Ba-Cu-O系超导体中的Y或Cu,制备了Y-Ba-Cu-Sn-O系超导体,实验结果表明,在相当大的替代范围(30%的 Y,40%的 Cu)内,超导体仍保持正交结构,其零电阻转变温度基本上稳定在90K左右. 相似文献
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TIAN Nailiang 《Chinese Journal of Lasers》1999,8(4):372-376
Introduction TheinvestigationofdirectcrystallizationofYBa2Cu3O7superconductorbylaserirradiationYBaCuOmaterialofstoichiometrical123compositionisinterested.Thedirectlasersynthesisofhightemperaturesuperconductorhasspecificdominace[1].Itisthefinestru… 相似文献
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K. Sreedhar R. A. Mohan Ram A. K. Raychaudhuri P. Ganguly C. N. R. Rao 《Phase Transitions》2013,86(1-2):3-15
High-temperature superconductivity in the Y-Ba-Cu-O system has been discussed with special reference to the identification and characterization of the pure monophasic compound responsible for the superconductivity. The crucial role of oxygen has been examined in the light of the structure and thermogravimetric analysis. 相似文献
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Superconductivity of Y-Ba-Cu-O system is studied in the composition 2:2:3 and 1:2:3 of Y:Ba:Cu. The effect of replacement of Y or Ba by divalent Sr and Ca, trivalent Ce and tetravalent Zr is studied. X-ray diffraction, SEM and TEM techniques are used for materials characterization. Superconducting transition temperatures are measured resistively. Rapid resistance drop observed above 230 K in Y-Ba-Sr-Cu-O and Y-Ba-Ca-Cu-O systems indicate the possible existence of superconductivity above 230 K. Substitution of Ce in place of Y is found to reduce the onset Tc from 95 K to 80 K. For the first time, replacement of Cu by Zr in Y-Ba-Cu-O has yielded the onset Tc of about 105 K. 相似文献
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C. Hohn M. Galffy A. Dascoulidou A. Freimuth H. Soltner U. Poppe 《Zeitschrift für Physik B Condensed Matter》1991,85(2):161-168
We report on measurements of the Seebeck-effect, the Nernst-effect, and the magnetoresistance in the mixed state of ac-axis oriented expitaxial film of Y–Ba–Cu–O. In contrast to conventional superconductors we find a large Seebeck-coefficientS, which is comparable in magnitude to the Nernst-effect. The broadening of the super-conducting transitions of magnetoresistance and Seebeck-effect are rather similar with respect to (1) the temperature dependence, (2) the dependence on the direction between magnetic field and crystal axis and (3) the dependence on the direction between magnetic field and driving forces. The large Seebeck-effect has to be attributed to dissipation due to normal quasiparticle-excitations, since the vortex-contribution to the Seebeck-effect is by far too small to account for the observed magnitude ofS. It is argued that such a quasiparticle contribution to the dissipation is large in the high-T
c superconductors because of the small coherence lengths and thus the small vortex cores. Another possibility is that granularity leads to dissipation proportional to the normal state transport properties. The Seebeck-voltage depends on all dissipative processes other than vortex motion, whereas the Nernst-effect depends only on the vortex motion. Therefore by measurements of thermomagnetic effects the various dissipative properties may be separated. 相似文献
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C. Politis J. Geerk M. Dietrich B. Obst H. L. Luo 《Zeitschrift für Physik B Condensed Matter》1987,66(3):279-282
We report the synthesis, characterization and superconducting temperature of high-temperature superconducting Y0.3Ba0.7CuO3, Y0.4Ba0.6CuO3 and Y1.2Ba0.8CuO4. The volume fraction of the superconducting phase is estimated to be of the order of 10%.HighT
c
superconductivity withT
c
-onsets up to 125 K (midpoint 102 K, zero resistance: 90 K) is observed in multi-phase Y–Ba–Cu–O oxygen defect compounds with the nominal composition of Y1.2Ba0.8CuO4–y
(0y0.4). 相似文献
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S. Umakoshi Y. Ikeda A. Wongsatanawarid C.-J. Kim M. Murakami 《Physica C: Superconductivity and its Applications》2011,471(21-22):843-845
A top-seeded melt-growth (TSMG) process is widely used to fabricate single domain YBa2Cu3Oy (Y–Ba–Cu–O) bulk superconductors. Pores are often found in the TSMG-processed Y–Ba–Cu–O samples due to the oxygen gas evolution during the molten stage. Recently developed liquid infiltration growth (LIG) process is known to be effective in suppressing the pore evolution and in refining the size of Y2BaCuO5 (Y211) particles dispersed in YBa2Cu3Oy matrix. The LIG process utilizes the liquid (Ba3Cu5O8) infiltration into a pre- sintered Y211 contact and slow cooling through a peritectic temperature. In this study, we fabricated bulk Y–Ba–Cu–O superconductors by the LIG process combined with top-seeding with SmBa2Cu3Oy seed and confirmed that a single-domain bulk can be produced. Trapped field measurements however showed that some distortion in the field distribution was observed in the region near the seed crystal, which was attributed to Y211 density and its relatively large size. 相似文献
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《Physics letters. A》1987,126(1):55-57
A small amount of Pd addition increases Tc for the YBa2Cu3O7−y oxide. The maximum offset, midpoint and onset temperatures of the YBa2(Cu0.999Pd0.001)3O7−y oxide are 92.1, 95.0 and 105 K, respectively. Excess addition of Pd decreases Tc. The Tc change is consistent with the results of the lattice constants. 相似文献
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P. Steiner V. Kinsinger I. Sander B. Siegwart S. Hüfner C. Politis 《Zeitschrift für Physik B Condensed Matter》1987,67(1):19-23
XPS and UPS photoemission experiments on the highT c superconductors (T c ≈90 K) with nominal composition YBa2Cu3O9-y (y≈2) show the following:
- The density of electronic states at the Fermi energy is very small, much smaller than in pure Cu.
- The Cu 2p spectra show only a Cu2+ contribution.
- The Ba core levels show a structure with two components of nearly equal magnitude, which leads to the suggestion that these compounds have large O2? vacancies coordinated to Ba2+ sites.
- Annealing at 400°C under UHV conditions leads possibly to a partial reduction of Cu2+ to lower Cu valence states and to a small increase of the O2? vacancy component of the Ba2+ line.