共查询到20条相似文献,搜索用时 62 毫秒
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《化学物理学报》2020,(2)
本文通过反应力场来研究中性双甘氨肽与高取向热解石墨的碰撞动力学过程,分别模拟初始入射角度为0°、20°、45°和70°以及入射能量为481.5 kJ/mol和表面温度为677 K的情况,并且确定和分析了散射产物的角度分布、平动能分布、内能分布和表面滞留时间分布.双甘氨肽是一种多原子分子,具有较多的低频振动模式和较强的表面吸附相互作用,这些使得碰撞过程的表面滞留时间较长和容易造成能量损失,尤其是表面法线方向.由于碰撞分子的动量沿表面法线方向上明显地发生损失,而沿表面平行方向上的动量则会大部分保留,因此,其散射角通常会呈现出超镜面反射分布,并且末态的平动能要远小于所谓硬立方模型的预测值.本文加深了多肽分子与高取向热解石墨碰撞及其能量转移过程的认识和理解,有助于设计在稀薄大气中收集这类大分子的中性气体浓缩器. 相似文献
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提出了一种利用总积分散射(TIS)测量K9玻璃基片表面散射和体散射的实验方法。首先采用磁控溅射技术在基片表面沉积厚度为几十nm的金属Ag薄膜,然后将基片的表面和体区分开考虑,通过TIS测得了基片上下表面的均方根粗糙度, 进而求得基片的总散射和表面散射,最后计算得到了体散射。分别利用TIS和原子力显微镜(AFM)测量了3个样品上表面所镀Ag膜的均方根粗糙度,两种方法所得的均方根粗糙度的数值相差不明显,差值分别为0.08,0.11和0.09 nm, 表明TIS和AFM的测量结果相一致。利用该方法测得3块K9玻璃基片的总散射分别为6.06×10-4,5.84×10-4和6.48×10-4,表面散射介于1.25×10-4~1.56×10-4之间,由此计算得到的体散射分别为3.10×10-4,3.30×10-4和3.61×10-4。 相似文献
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提出了一种利用总积分散射(TIS)测量K9玻璃基片表面散射和体散射的实验方法。首先采用磁控溅射技术在基片表面沉积厚度为几十nm的金属Ag薄膜,然后将基片的表面和体区分开考虑,通过TIS测得了基片上下表面的均方根粗糙度, 进而求得基片的总散射和表面散射,最后计算得到了体散射。分别利用TIS和原子力显微镜(AFM)测量了3个样品上表面所镀Ag膜的均方根粗糙度,两种方法所得的均方根粗糙度的数值相差不明显,差值分别为0.08,0.11和0.09 nm, 表明TIS和AFM的测量结果相一致。利用该方法测得3块K9玻璃基片的总散射分别为6.06×10-4,5.84×10-4和6.48×10-4,表面散射介于1.25×10-4~1.56×10-4之间,由此计算得到的体散射分别为3.10×10-4,3.30×10-4和3.61×10-4。 相似文献
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提出一种新型的激光放大技术, 高效地实现冲击点火所需的102 ps级高功率激光脉冲. 该技术耦合了传统的激光驱动器放大技术和受激布里渊散射(SBS) 脉冲压缩技术, 在不改变现有激光装置主体结构的前提下, 使用长脉冲(数 ns) 充分提取主放大器储能, 然后在系统输出端通过SBS进行脉冲自抽运的能量转移, 将长脉冲能量转移给102 ps级的冲击脉冲, 实现高效放大的目的. 该技术在主动控制下实现能量转移, 将克服传统SBS压缩时间特性不可控的缺点, 输出满足冲击点火时域特性要求的精密控制激光脉冲. 相似文献
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金属中表面和界面散射的量子力学处理 总被引:1,自引:0,他引:1
通过建立量子力学散射模型,运用格林函数的解析方法,分别研究电子在两种金属模型中的传播机制,并相应得到电子在粗糙界面处的透射系数、镜面反射系数及在粗糙表面处的镜面反射系数. 相似文献
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表面增强能量转移效应的研究 总被引:1,自引:4,他引:1
通过分析2、2′菁染料水溶液、银胶体以及2、2′菁染料吸附于银胶表面时的吸收光谱得知,2、2′菁染料吸附于银胶表面时,有J聚集体出现,通过分析基频及高阶线性Raman光谱,证实了一些低波数的Raman信号是由J聚集体产生的,从而进一步证实了吸附于银胶表面的2、2′菁染料以单体和J聚集体形式共存.同时,由吸收光谱还可以看出,2、2′菁染料分子及其J聚集体分子的吸收带都处于银胶吸收带的半高宽范围内,满足共振条件,当用不同激发波长(514.5 nm和488 nm)的光激发吸附于银胶表面的2、2′菁染料时,观察到了J聚集体的敏化荧光,而用此激发光激发2、2′菁染料水溶液时,就没有观察到J聚集体的敏化荧光,从而说明了银胶表面的存在,加速了单体2、2′菁染料分子与其J聚集体分子之间的能量转移速率. 相似文献
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同时测量了碳纳米管(D-CNT)和高取向热解石墨(HOPG)的拉曼光谱,第一次分别在HOPG和D-CNT中观察到了位于4265cm-1和4248cm-1的(G+D*)三级模的拉曼散射;拉曼谱的研究显示,D-CNT的结构比HOPG的无序,同时也进一步表明此无序程度主要来源于结构的缺陷,而非石墨层卷曲成筒状之故 相似文献
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Komolov A. S. Lazneva E. F. Gerasimova N. B. Sobolev V. S. Pshenichnyuk S. A. Asfandiarov N. L. Kraikin V. A. Handke B. 《Physics of the Solid State》2019,61(10):1922-1926
Physics of the Solid State - The results of diagnostics of the atomic composition of a diphenylphthalide (DPP) film thermally precipitated in vacuum by the of X-ray photoelectric spectroscopy (XPS)... 相似文献
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Magnetic-Field-Induced Semimetal-Insulator-like Transition in Highly Oriented Pyrolitic Graphite 下载免费PDF全文
We report the extraordinarily large positive magnetoresistances (MR, 69400% at 4.5K under a magnetic field of 8.15 T), de Hass-van Alphen oscillations effect at 10 K and the semimetal-Jnsulator-like transition in a wide range of temperature in highly oriented pyrolitic graphite (HOPG). Besides a dominating ordinary MR (OMR) mechanism in the free-electron mode, it is realized from qualitative analysis that the Coulomb interacting quasiparticles within graphite layers play some roles. However it is difficult to associate the transition with the simple OMR theory. In order to investigate the possible origins of the transition, further analysis is carried out. It is revealed that the magnetic-field-induced behaviour is responsible for the semimetal-insulator-like transitions in HOPG. 相似文献
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Polarized neutron reflectivity has been used to investigate the peak pattern and the magnetization reversal process of laterally structured Fe- and CoFe-films. The peak pattern of the wire arrays was analyzed in the specular as well as in the off-specular regime. The intensities of the different cross-sections at the off-specular first-order peak were investigated as a function of external magnetic field. Magnetization reversals are discussed and compared to MOKE studies of the same system. 相似文献
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Pierpaolo Mastrolia Edoardo Mirabella Giovanni Ossola Tiziano Peraro 《Physics letters. [Part B]》2012
We show that the evaluation of scattering amplitudes can be formulated as a problem of multivariate polynomial division, with the components of the integration-momenta as indeterminates. We present a recurrence relation which, independently of the number of loops, leads to the multi-particle pole decomposition of the integrands of the scattering amplitudes. The recursive algorithm is based on the weak Nullstellensatz theorem and on the division modulo the Gröbner basis associated to all possible multi-particle cuts. We apply it to dimensionally regulated one-loop amplitudes, recovering the well-known integrand-decomposition formula. Finally, we focus on the maximum-cut, defined as a system of on-shell conditions constraining the components of all the integration-momenta. By means of the Finiteness Theorem and of the Shape Lemma, we prove that the residue at the maximum-cut is parametrized by a number of coefficients equal to the number of solutions of the cut itself. 相似文献
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利用了氢原子飞渡时间谱实验方法对处于高n主量子数里德堡态的氢原子与氦原子的分子束散射过程进行了高分辨研究.测量了H(n)+He→H(n′)+He散射过程的散射微分截面.实验结果表明,产物主要分布在前向散射方向,在侧向也有一定的分布.在前向和侧向存在大量的振荡结构.同时详细的研究也表明,在上述的散射过程中往前散射的方向上,氢原子里德堡态主量子数n的变化并不是很大.实验结果得到了为理论上精确研究高n主量子数里德堡态的氢原子与氦原子的散射动力学的一套精细的实验数据. 相似文献
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Xin Bao Wu 《International Journal of Infrared and Millimeter Waves》1994,15(10):1733-1744
The electromagnetic scattering from an anisotropic cylindrical dielectric shell is formulated by using the wave functions for anisotropic media and the boundary-value method. The cylindrical shell is assumed to be infinite in length, and it is illuminated by a plane wave or a cylindrical wave from a line source. The problem is two-dimensional and the solutions to both types of polarization (TE and TM) are presented. Numerical results for the effects of various geometrical and electrical parameters on the bistatic radar cross section are presented. 相似文献