Uncommon temperature dependence of the rotational motion of OH− centers in NaCl

Abstract

The correlation time τ_D of the rotational motion of OH^? centers in NaCl was studied for two different OH^?-concentrations (44 ppm and 220 ppm) between 0.5 K and 16 K by ²³Na nuclear spin relaxation measurements. The correlation time in the sample containing 44 ppm OH^? is given by phonon-assisted tunneling of isolated defects, whereas the OH^?-motion in the sample containing 220 ppm can be described by a coupled ensemble of quantum mechanical hindered rotators below a critical temperature which is determined by the strength of the interaction between the OH^? dipoles.     

The temperature dependence of the third-order nonlinear susceptibility χ(3) of CS2 and dodecylbenzene

The dependence of the third-order nonlinear susceptibility ⁽³⁾ of CS₂ and C₁₈H₃₀ (dodecylbenzene) on temperature was measured by the degenerate four-wave mixing method. The empirical formula of this dependence was obtained. An explanation of this relationship was also given through the application of the model of a polar molecular moving in a viscous medium under the action of a laser beam.     

Low temperature vibrational relaxation of OD in the A2Σ, state

The vibrational relaxation of the A ²Σ state of OD has been studied in the low translational temperature environment of an argon free-jet (T_trans near 5 K). Using laser induced fluorescence (LIF), the absolute vibrational relaxation rate coefficients were measured for OD A²Σ (ν′) to be 7.1 ± 2.6 × 10^?11, 5.9 ± 1.4 × 10^?11, and 2.7 ± 1.1 × 10^?11 cm³ s^?1 for the ν = 3, 2 and 1 states, respectively. State-to-state relaxation rate coefficients were also obtained for the ν= 1, ? = 1 level going to ν= 0, ? levels in the A²Σ manifold. The rotational relaxation rate coefficient for ν= 1, ?= 1 in the A state of OD was found to be 9.6 ± 1.0 × 10^?11cm³s^?1. These values are consistent with values measured for OH A²Σ, and the total loss rates are near the capture rate coefficient value. The vibrational relaxation rate coefficients k_ν appear to be governed by the vibrational energy of the molecule rather then by interaction with nearby dissociative states such as the a⁴Σ state. The relative Einstein A factors for the A²σ (ν = 3) state of OD were determined and compared with the available calculated value.     

How we can interpret the T1 dispersion of MC, HPMC and HPC polymers above glass temperature?

The chain dynamics in methyl cellulose (MC), hydroxypropylmethyl cellulose (HPMC) and hydroxypropyl cellulose (HPC) were studied with the aid of field-cycling NMR relaxometry technique in the temperature range from 300 to 480 K that is above the glass transition, but below thermal degradation. The frequency dependence of proton spin-lattice relaxation time was determined between 24 kHz and 40 MHz for selected temperatures. The experimental spin-lattice relaxation dispersion data were fitted with the power law relations of T(1) proportional variant omega(gamma) predicted by the tube/reptation model. The exponent's values found from the fitting procedure for MC, HPMC and HPC almost exactly match the ones predicted in tube/reptation model for limit II (gamma=0.75) and in MC also for limit III (gamma=0.50). Remarkably, this finding concerns the polymers in networks formed of the same polymer species.     

Nature of the temperature dependence of the absorption coefficient in the remote wing of the 4.3 μm CO2 band

The complex nature of the temperature dependence of the absorption coefficient beyond the edge of the CO₂ 4.3 m band — the change of the sign of the derivative of the absorption coefficient with respect to the temperature near the edge and in the remote wing of the band — is explained on the basis of the theory of spectrum line wings. The first change in the sign is due to the temperature dependence of the classical potential of intermolecular interaction; the second depends mainly on the difference in the quantum energies of molecule interaction. Therefore, a study of the dependence of the absorption coefficient on the temperature in the band wings provides information about the nature of the terms of the interacting molecules.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 12, pp. 42–45, December, 1987.     

Optical evidence for symmetry changes above the Néel temperature of KCuF3

We report on optical measurements of the 1D Heisenberg antiferromagnet KCuF3. The crystal-field excitations of the Cu2+ ions have been observed and their temperature dependence can be understood in terms of magnetic and exchange-induced dipole mechanisms and vibronic interactions. Above TN we observe a new temperature scale TS characterized by the emergence of narrow absorption features that correlate with changes of the orbital ordering as observed by Paolasini et al. [Phys. Rev. Lett. 88, 106403 (2002)]. The appearance of these optical transitions provides evidence for a symmetry change above the Néel temperature that affects the orbital ordering and paves the way for the antiferromagnetic ordering.     

Singular temperature dependence of the equation of state of superconductors with spin–orbit interaction in the low-temperature region

The equation of state is investigated for a thin superconducting film in a longitudinal magnetic field and with strong spin-orbit interaction at the critical point. As a first step, the state with the maximal value of the magnetic field for a given value of spin–orbit interaction at T = 0 is chosen. This state is investigated in the low-temperature region. The temperature contribution to the equation of state is weakly singular.     

Non-monotonic temperature dependence of the effective susceptibility exponent — A characteristic feature of many disordered spin systems

It is shown that a non-monotonic temperature dependence of the effective exponent γ(T) of the linear (non-linear) susceptibility is a characteristic feature of many disordered ferromagnets (spin glasses, random anisotropy magnets). The predictions of the correlated molecular field theory, Monte Carlo computer simulations, high temperature series expansions and the Sherrington-Kirkpatrick model are compared with experimental results. Implications for the determination of the critical exponent from the susceptibility data are discussed.     

Pressure and temperature dependence of the structure of liquid Sn up to 5.3 GPa and 1373 K

Pressure and temperature dependence of the structure of liquid Sn has been measured up to 5.3?GPa and 1373?K using multi-angle energy-dispersive X-ray diffraction in Paris–Edinburgh cell. Under nearly isobar condition at ～1?GPa, liquid Sn displays a normal behavior with gradual structural changes with temperature up to 1373?K. Under isothermal compressions at 850 and 1373?K, however, the structure factors of liquid Sn both show a turn-over at ～3?GPa in the height of the first diffraction peak. According to the hard sphere cluster model, the structure of liquid Sn may be viewed as two different types of clusters. Below ～3?GPa, it is shown that the packing fraction of the dominant cluster (occupying ～0.94 fraction) changes with compression, while above ～3?GPa, the packing fractions and the hard sphere diameters of both clusters start to influence the structure, causing significant changes with increasing pressure. Our results suggest that the compression behavior of liquid Sn changes from localized densification only in one cluster below ～3?GPa to homogeneous structural changes in both clusters above ～3?GPa.     

Nonlinear coefficient and temperature dependence of the refractive index of lithium niobate crystals in the terahertz regime

The effective nonlinear coefficient d _eff of lithium niobate is determined to be 94 pm/V for a process that converts infrared light to 1.35 THz radiation. This value is inferred from the performance of a continuous-wave, singly-resonant optical parametric oscillator, in which the cavity-enhanced signal wave of a primary parametric process acts as a pump wave for a cascaded process, generating terahertz waves. To quantify the nonlinear coefficient, the coupled wave equations including absorption are evaluated. Furthermore, from our measurements we also determine the temperature dependence of the refractive index to be dn _THz/dT=0.0013/K around 1.4 THz.     

Electron–phonon energy relaxation in bismuth excited by ultrashort laser pulse: temperature and fluence dependence

We present analysis of the experiments on excitation of bismuth by ultrafast laser pulses and compare with heating bismuth in equilibrium conditions. The analysis shows that the electron–phonon relaxation time is a strong function of the lattice temperature. We developed a kinetic theory, which predicts well the experimental results. We demonstrate that lattice heating and re-structuring with the temperature-dependent energy exchange rates occurs much faster than what follows from the two-temperature model with constant relaxation factor. The analytic formulae corrected by equilibrium and non-equilibrium data allowed the interpretation of various experiments without controversy. We demonstrate that all observed ultrafast transformation of bismuth are purely thermal in nature, thus excluding the conjectures about non-thermal melting.     

Thermal diffusion in binary mixtures containing molecular gases. III. The temperature dependence of αT

A recent expression for the thermal diffusion factor α_T for binary atom-molecule mixtures, which includes a full range of inelastic collisional contributions [McCourt, F. R. W., 2003, Molec. Phys., 101, 2181] has been utilized to calculate its temperature dependence for equimolar N₂-He, Ne, Ar mixtures and for an equimolar CO₂-Ar mixture. Accurate classical trajectory values for the effective cross-sections entering into the expression for α_T, obtained for the most reliable potential energy surfaces available, have been employed in the calculations. Good agreement has been attained with experiment for all four binary mixtures, including the decrease of α_T with increase in temperature observed for CO₂-Ar mixtures, heretofore considered to be anomalous.     

Nonmonotonic dependence of the work function of ytterbium nanofilms deposited on the Si(111)7 × 7 surface at room temperature on the film thickness

The dependences of the work function of ytterbium nanofilms on their thickness are studied. The films are evaporated at room temperature on the Si(111)7 × 7 surface of silicon samples doped to different levels and having different types of conduction (n and p). It is shown that these dependences exhibit a pronounced nonmonotonic behavior, which does not depend on the type of silicon used. It is established that the amplitude of the nonmonotonic variations in the work function is governed by the surface microroughness of the deposited layers, so that larger amplitudes correspond to smoother films. The variations in the work function of the films due to the deposition of electrically negative Si atoms on their surface are investigated. It is revealed that the sign of the variation depends on the film thickness. This result strange at first glance is associated with the fact that the electron density distribution at the metal-film-vacuum interface depends nonmonotonically on the amount of deposited ytterbium. This nonmonotonic behavior is a manifestation of electron density standing waves (Friedel oscillations) generated in the films by the ytterbium-silicon interface.     

Pressure–temperature dependence of thermodynamic properties of rutile (TiO2): A first-principles study

Ab-initio calculations of thermal properties of rutile (TiO₂) have been performed by using the projector augmented-wave (PAW) method within the generalized gradient approximation (GGA). Both pressure- and temperature-dependent thermodynamic properties such as the bulk modulus, thermal expansion, thermal expansion coefficient, heat capacity at constant volume and constant pressure were calculated using two different models based on the quasiharmonic approximation (QHA): the Debye–Slater and Debye–Grüneisen model with Dugdale–MacDonald (DM) approximation. Also, the empirical energy corrections were applied to the results to correct the systematic errors introduced by the functional. It is found that the Debye–Grüneisen model provides more accurate estimates than the Debye-Slater models, especially after empirical energy correction.     

Calculation of the temperature dependence of the thermal emf in amorphous alloys CaxAl1−x and AuxNi1−x

The temperature dependence of the thermal emf of Ca_xAl_1–x and Au_xNi_1–x for four different concentrations of the components of the alloys is calculated on the basis of the concept of dynamic concentrated excitations in amorphous metal systems. It is shown that increasing x from 0.15 to 0.50 in Au_xNi_1–x raises the thermal emf, and a further increase in the Au concentration from 0.50 to 0.80 lowers S(T). For Ca_xAl_1–x the dependence S(T) is calculated in the interval of Ca concentrations from 0.55 to 0.75. In this concentration interval the thermal emf decreases as x is increased. It is shown that for both types of alloys the S(T) curve bends abruptly at a temperature near 10T₀ (where T₀ is the concentration-dependent characteristic temperature of amorphous alloys separating the ranges of strong and weak scattering of electrons by dynamic concentration excitations). The so-called S(T) knee shifts toward lower temperatures when the thermal emf increases with increasing x and toward higher temperatures when S(T) decreases with increasing x. The results agree with experimental data.Institute of Physics of Strength and Materials Science, Siberian Branch, Russian Academy of Sciences. State University, Tomsk. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, No. 8, pp. 43–48, August, 1994.