Supersolid bose-fermi mixtures in optical lattices

We study a mixture of strongly interacting bosons and spinless fermions with on-site repulsion in a three-dimensional optical lattice. For this purpose we develop and apply a generalized dynamical mean-field theory, which is exact in infinite dimensions and reliably describes the full range from weak to strong coupling. We restrict ourselves to half filling. For weak Bose-Fermi repulsion a supersolid forms, in which bosonic superfluidity coexists with charge-density wave order. For stronger interspecies repulsion the bosons become localized while the charge-density wave order persists. The system is unstable against phase separation for weak repulsion among the bosons.     

Supersymmetry and the Goldstino-like mode in bose-fermi mixtures

Supersymmetry is assumed to be a basic symmetry of the world in many high-energy theories, but none of the superpartners of any known elementary particle have been observed yet. We argue that supersymmetry can also be realized and studied in ultracold atomic systems with a mixture of bosons and fermions, with properly tuned interactions and single particle dispersion. We further show that in such nonrelativistic systems supersymmetry is either spontaneously broken or explicitly broken by a chemical potential difference between the bosons and fermions. In both cases the system supports a sharp fermionic collective mode similar to the Goldstino mode in high-energy physics, due to supersymmetry. We also discuss possible ways to detect this mode experimentally.     

Competing types of order in two-dimensional bose-fermi mixtures

Using a functional renormalization group approach we study the zero temperature phase diagram of two-dimensional Bose-Fermi mixtures of ultracold atoms in optical lattices, in the limit when the velocity of bosonic condensate fluctuations is much larger than the Fermi velocity. For spin-1/2 fermions we obtain a phase diagram, which shows a competition of pairing phases of various orbital symmetry (s, p, and d) and antiferromagnetic order. We determine the value of the gaps of various phases close to half filling, and identify subdominant orders as well as short-range fluctuations from the renormalization group flow. For spinless fermions we find that p-wave pairing dominates the phase diagram.     

Kinetics of phase separation in polymer mixtures

Characteristic features of the liquid-liquid phase separation process in polymer systems are presented, followed by a concise review of existing studies on phase-separation kinetics in polymer solutions and mixtures. Brief discussions have been made on two selective topics in this field, i.e., applicability of Cahn's linearized theory for spinodal decomposition to polymer mixtures and the scaling law in the late stage of phase separation.     

Superfluidity near phase separation in Bose-Fermi mixtures

We study the transition to fermion pair superfluidity in a mixture of interacting bosonic and fermionic atoms. The fermion interaction induced by the bosons and the dynamical screening of the condensate phonons due to fermions are included using the nonperturbative Hamiltonian flow equations. We determine the bosonic spectrum near the transition towards phase separation and find that the superfluid transition temperature may be increased substantially due to phonon damping.     

Micellization and phase separation in binary amphiphile mixtures

Grand canonical Monte Carlo simulations with histogram reweighting are used to examine the micellization and phase separation of a lattice model for binary amphiphile mixtures in an implicit solvent. The model amphiphiles consist of a neutral, rigid head group that occupies seven lattice sites and solvophobic tail chains of varying length and number. It is found that the critical micelle concentration of the mixtures closely matches theoretical values obtained by assuming that the components form an ideal mixture. The solubility of amphiphiles which undergo a first-order transition to form a disordered liquid phase can be increased by adding an amphiphile that forms micelles, and the phase transitions in these mixtures are between a dense liquid state and a low concentration phase that contains aggregates. In both micelles and dense liquids, the amphiphiles mix indiscriminately and the micelle size and shape depends on the concentration ratio of the two species.     

Mixing and phase separation in molecular fluid mixtures

The equation of state for a hard convex body (HCB) fluid mixture, which is based on the scaled particle theory, is utilized to derive the Helmholtz free energy, F, and the concentration fluctuations, S.,(O), to investigate the thermodynamic stability of athermal and not athermal molecular fluid mixtures. The role of the size and the non-sphericity geometrical factor of the molecule on the stability of the mixture is critically examined. The energetics of long-range attractive forces for not athermal mixtures have been introduced through the double Yukawa potential in conjunction with a realistic distribution function. The formalism allows one to investigate the properties of molecular mixtures under induced conditions of extreme temperature and pressure. The results suggest that geometrical factors coupled with energetics play a dominant role in phase separation.     

Crystallization and phase separation in nonadditive binary hard-sphere mixtures

We calculate for the first time the full phase diagram of an asymmetric nonadditivehard-sphere mixture. The nonadditivity strongly affects the crystallization and the fluid-fluid phase separation. The global topology of the phase diagram is controlled by an effective size ratio y(eff), while the fluid-solid coexistence scales with the depth of the effective potential well.     

Supersolids versus phase separation in two-dimensional lattice bosons

We study the nature of the ground state of the two-dimensional extended boson Hubbard model on a square lattice by quantum Monte Carlo methods. We demonstrate that strong but finite on-site interaction U along with a comparable nearest-neighbor repulsion V result in a thermodynamically stable supersolid ground state for densities larger than 1/2, in contrast to fillings less than 1/2 or for very large U, where the checkerboard supersolid is unstable towards phase separation. We discuss the relevance of our results to realizations of supersolids using cold bosonic atoms in optical lattices.     

Early stages of phase separation from polydisperse polymer mixtures

We study the early stages of phase separation in a mixture of a polydisperse and a monodisperse polymer within the Cahn-Hilliard framework. We model the polydisperse component using a finite, but arbitrarily large, number of components, and show that the number of components required for convergent behaviour to be achieved is computationally undemanding. We study the growth rate of fluctuations following a quench into the two-phase region of the phase diagram. The q-dependence of the growth rate is shown to be commensurate with the behaviour of a monodisperse-monodisperse mixture, with the major difference being an effective mobility that is dependent on the quench depth. We also study the deviation of the time dependence of the scattering function from single exponential behaviour. Received 29 June 2000 and Received in final form 20 November 2000     

Modes selection in polymer mixtures undergoing phase separation by photochemical reactions

Phase separation kinetics and morphology of binary polymer mixtures (A/B) in the presence of photochemical reactions were investigated by using phase-contrast optical microscopy combined with digital image analysis. The polymers were chemically designed in such a way that two types of chemical reactions, intermolecular photodimerization and intramolecular photoisomerization, of polymer segments can be induced and controled by irradiation with ultraviolet light. Unlike the conventional case, the phase separation in the presence of these reactions is spontaneously frozen due to the suppression of the long-wavelength instabilities, resulting in stationary spatial structures with intrinsic periodicities. These characteristic length scales are determined by the competition between the two antagonistic interactions: phase separation as a relatively short-range activation and the photochemical reaction as a long-range inhibition. Furthermore, it was found that the spatial symmetry breaking of concentration fluctuations can emerge from the elastic stress associated with the nonhomogeneous kinetics of the reactions. Experimental data obtained with three types of reactions: A-A only cross-link, A-A and B-B simultaneous cross-links and the reversible A<-->B photoisomerization are described. These results do not only indicate that combination of chemical reactions and phase separation could provide a novel method to control the morphology of multiphase polymer materials, but also suggest that photoreactive polymers can be used as a chemical system to study the mode-selection process in polymers far from thermodynamic equilibrium. (c) 1999 American Institute of Physics.     

Supersolid phase in spin dimer XXZ systems under a magnetic field

Using the quantum Monte Carlo method, we study, under external magnetic fields, the ground state phase diagram of the two-dimensional spin S=1/2 dimer model with an anisotropic intraplane antiferromagnetic coupling. With the anisotropy 4 greater/approximately Delta greater/approximately 3, a supersolid phase characterized by a nonuniform Bose condensate density that breaks translational symmetry is found. The rich phase diagram also contains a checkerboard solid, an antiferromagnet in the z axis, and a superfluid phase formed by S(z)= +1 spin triplets which has a finite staggered magnetization in the in-plane direction. As we show, the model can be realized as a consequence of including the next nearest neighbor coupling among dimers and our results suggest that spin dimer systems may be an ideal model system to study the supersolid phase.     

Supersolid phase of hard-core bosons on a triangular lattice

We study properties of the supersolid phase observed for hard-core bosons on the triangular lattice near half-integer filling factor, and the phase diagram of the system at finite temperature. We find that the solid order is always of the (2m, -m, -m) with m changing discontinuously from positive to negative values at half filling, in contrast with phases observed for Ising spins in a transverse magnetic field. At finite temperature we find two intersecting second-order transition lines: one in the 3-state Potts universality class and the other of the Kosterlitz-Thouless type.     

Double-exchange model: phase separation versus canted spins

We study the competition between different possible ground states of the double-exchange model with strong ferromagnetic exchange interaction between itinerant electrons and local spins. Both for classical and quantum treatment of the local spins the homogeneous canted state is shown to be unstable against a phase separation. The conditions for the phase separation into the mixture of the antiferromagnetic and ferromagnetic/canted states are given. We also discuss another possible realization of the phase-separated state: ferromagnetic polarons embedded into an antiferromagnetic surrounding. The general picture of a percolated state, which emerges from these considerations, is discussed and compared with results of recent experiments on doped manganaties. Received 17 March 1999     

外噪声场对二元混合物相分离的驱动作用

采用蒙特卡罗法研究了外高斯噪声场对二元混合物体系相分离的驱动作用.研究发现，高斯噪声场的引入可以加快体系畴的生长，驱动体系形成沿着［1,1］取向的条状畴结构.在噪声强度一定、噪声作用的概率小于0.015时，高斯噪声场消除了深度淬火引起的体系畴的冻结，畴的生长因子随噪声作用概率线性增加.对足够强的高斯噪声场，存在一个最佳的作用概率区域，其间体系能形成取向性好的条状畴结构. 关键词： 高斯噪声 二元混合物 相分离