Nuclear structure study of 96Tc and multiplet structure in doubly odd Tc and Nb isotopes

Low-lying states in ⁹⁶Tc excited through the ⁹⁶Mo(d, 2nγ) reaction have been investigated by means of on-line internal conversion electron and γ-ray spectroscopy. Measured singles spectra and relative excitation functions together with particle-γ and γ-γ coincidences were used to identify and fit the transitions in a level scheme. The low-lying positive-parity states 2⁺–7⁺and negative-parity states 2^? and 3^? are compared with those appearing systematically in doubly odd ^{94, 98}Tc and ^92–96Nb isotopes. Comparison is also made with simple shell-model calculations for those nuclei based on the configuration space and the tendency of the multiplet structure of the wave functions is discussed.     

The (g92)2 residual interaction from 87Sr(d,t)86Sr

Differential cross sections for ⁸⁷Sr(d, t)⁸⁶Sr transitions to the $\text{(1}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}^{\mathrm{?2}}$ states of ⁸⁶Sr were obtained with the Pittsburgh 18 MeV deuteron beam and the Enge split-pole spectrograph. States of ⁸⁶Sr up to 3.82 MeV in excitation were studied with a total resolution of 12 keV. Successful distorted-wave Born approximation (DWBA) predictions for ⁸⁷Sr(d, t) ⁸⁶Sr angular distributions permitted the extraction of l-values and spectroscopic strengths. The sum-rule value agrees with the observed value for the $\text{(1}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}^{\mathrm{?2}}$ configuration. The observed $\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ strength is spread over 13 states. Contrary to an earlier interpretation, the 0⁺ ground state is found to contain only 65% of the strength. Similarly, the full 4⁺ strength is not located in a single state. The new data change the interpretation of the $\text{(}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}^{\mathrm{?2}}$ spectrum of ⁸⁶Sr. They significantly alter the deduced low-spin matrix elements and bring them into much closer agreement with those derived from ⁸⁸Y. Several new negative-parity states dominated by l = 1 orbital angular momentum transfer have also been identified.     

Low-lying states in 95Tc studied with the 93Nb(α, 2nγ)95Tc reaction

Low-lying states in ⁹⁵Tc were studied with the ⁹³Nb(α, 2nγ)⁹⁵Tc reaction. The level scheme was obtained from the γ-γ coincidence measurement. The spin assignment was made on the basis of the observed γ-ray angular distributions and the excitation functions. The $\text{337}\text{keV}\text{7}\text{2}{}^{\mathrm{+}}\text{, 627}\text{keV}\text{(}\text{5}\text{2}{}^{\mathrm{+}}\text{), 882}\text{keV}\text{13}\text{2}{}^{\mathrm{+}}\text{and}\text{957}\text{keV}\text{11}\text{2}{}^{\mathrm{+}}$ states, and possibly state, are found to be strong candidates for the core multiplet states $\text{[(1}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}_{\mathrm{<mtext>p</mtext>}}\text{?2}{}^{\mathrm{+}}\text{]}{}_{\mathrm{J}}$. These states are discussed in term of a weak coupling model and the dressed three-quasiparticle model. The observed γ-ray angular distributions are compared with expectations based on a simple deexcitation model of the (α, 2nγ) reaction.     

Negative-parity states in Pb isotopes: g-factor of the 480 ns,if Jπ = 9− isomer in 200Pb

The g-factor of the 480 ns, 9^? isomer at 2.237 MeV in ²⁰⁰Pb was measured by the time-differential perturbed angular distribution method. The result, g = ?0.0285±0.0011 confirms the rather pure $\text{(}\text{f}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}{}^{\mathrm{?1}}\text{)}$ quasiparticle structure of this state. Half-lives of 480±20 ns, 43±3 ns and 42±4 ns have been measured for the 2237 keV 9^?, 2154 keV 7^? states in ²⁰⁰Pb and the 2208 keV state in ²⁰²Pb, respectively; E2 transitions and g-factors of negative-parity states in even, neutron-deficient Pb isotopes are discussed.     

Energies and orbital sizes for some Rydberg and valence states of the nitrogen molecule

Accurate SCF computations are reported on the Rydberg states of N₂ of electron configurations $\text{---1π}{}_{\mathrm{u}}{}^3\text{2π}{}_{\mathrm{u}}$, $\text{---1π}{}_{\mathrm{u}}{}^3\text{3σ}{}_{\mathrm{u}}$, and ---3σ_g2π_g, also on the valence states of the configuration $\text{---1π}{}_{\mathrm{u}}{}^3\text{1π}{}_{\mathrm{g}}$. The Rydberg state calculations supplement those of Lefebvre-Brion and Moser. A comparison is made between the $\text{---1π}{}_{\mathrm{u}}{}^3\text{2π}{}_{\mathrm{u}}$ states and the parallel set of states of the $\text{1π}{}_{\mathrm{u}}{}^3\text{1π}{}_{\mathrm{g}}$ configuration. This comparison shows a sharp difference in the ¹Σ⁺ states of the two configurations, the ¹Σ⁺ state being very high in the latter but relatively low in the former configuration. Recknagel coefficients are given for the several states of the two configurations; as expected, these are much smaller for the $\text{1π}{}_{\mathrm{u}}{}^3\text{2π}{}_{\mathrm{u}}$ configuration. Also, the ¹Δ state is relatively lower for the latter configuration.     

Energy levels of low lying triplet states of N2 from infrared emission studies

A theoretical model used to describe the $\text{B′}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}$ and B³Π_g states of N₂ is presented. Using recently acquired high resolution spectra of the $\text{B′}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{?}}\text{→ B}{}^3\text{Π}{}_{\mathrm{g}}$ (0-0) band, rotational energy levels of the v = 0 vibrational levels of these two states are generated with this model. These levels are in excellent agreement with those obtained using a combination differences technique. The precision of the model generated levels is 0.01 cm^?1. The previously unpublished rotational levels of Dieke and Heath for the $\text{A}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$, B³Π_g and C³Π_u states are referenced to the $\text{N}{}_2\text{X}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ (v = 0, J = 0) ground level and tabulated here. Estimates of the precision of their work are made.     

Lifetimes and g-factors of the 6− and 7− isomers in 66Ga and 68Ga

The 6^? and 7^? isomeric states in ⁶⁶Ga and ⁶⁸Ga at 1440.9 and 1229.6 keV, respectively, have been populated with the (¹³C, 2np) and (¹⁵N, n2p) reactions on natural Fe. The half-lives of these states have been measured to be $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(6}{}^{\mathrm{?}}\text{,}{}^{66}\text{Ga}\text{) = 57.3 ± 1.2}\text{ns}$ and $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(7}{}^{\mathrm{?}}\text{,}{}^{68}\text{Ga}\text{) = 64 ± 2}\text{ns}$. Using previous data on the hyperfine field of Ga in Fe, the g-factors of these states have been determined by means of the TDPAD method. The results are $\text{g(6}{}^{\mathrm{?}}\text{,}{}^{66}\text{Ga}\text{) = 0.129 ± 0.003}$ and $\text{g(7}{}^{\mathrm{?}}\text{,}{}^{68}\text{Ga}\text{) = 0.105 ± 0.003}$. These values are in very good agreement with the independent particle model if one assumes the and configurations and uses the empirical proton and neutron g-factors from odd-A neighboring nuclei instead of the Schmidt values. The large disagreements with experiment when Schmidt values are used show that core polarization effects are important in these nuclei.     

Multipolarities of γ-rays from 92, 94Nb and 94,95,96,97,98Tc

^{92, 94}Nb and ^{94, 96, 98}Tc have been produced by the (p, n) reaction at proton energies on and near the $\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ isobaric analog resonance. ^95,97Tc have been produced by the (p, γ) reaction below the (p, n) threshold. Internal conversion electrons due to the decay of their excited states were detected on-line with a mini-orange spectrometer which is optimized for the energy range 50 to 500 keV. Gamma rays from these nuclei were detected with a thin Ge(Li) detector. Isomeric-delayed internal conversion electrons and γ-rays were observed, using a nanosecond-pulsed beam. The internal conversion coefficients for 55 transitions in these nuclei have been determined and their multipolarities deduced. The multipolarity of the transitions in these nuclei is predominantly M1. Negative parities have been assigned through use of the $\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ isobaric analog resonance enhancements of the population of negative-parity final states. The systematic behavior of the 2^?, 3^? doublet and of the $\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{?}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ multiplet in these nuclei is discussed.     

High spin states in 93mo populated in the (p,n) reaction

High spin states in the $\text{ν}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{(π}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}{}^2$) multiplet in ⁹³Mo were investigated with the ⁹³Nb(p, n) ⁹³Mo reaction. A new isomeric state at 2430 keV with a half-life of 3.53±0.18 ns is interpreted as the lower $\text{17}\text{2}{}^{\mathrm{+}}$ member of the multiplet. A number of further states have been identified. The results are compared to previous experiments and shell model calculations.     

Study of low-lying states in 92Tc with the 92Mo(3He,t) reaction

States in ⁹²Tc have been studied by means of the ⁹²Mo(³He, t) reaction at 27.5 MeV. The Q-value for this reaction and the excitation energy of the isobaric ground state analogue of ⁹²Mo were determined to be ?7.882 ± 0.030 MeV and 3.813 ± 0.030 MeV respectively. Strongly populated levels in ⁹²Tc appear to belong to configurations arising from the $\text{(1g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}_{\mathrm{\pi }}\text{(1g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}_{\mathrm{\nu }}{}^{\mathrm{?1}}$ multiplet.     

g-Factors of high-spin isomers in 194Hg and 196Hg

The g-factors of the 10⁺ isomeric states in ¹⁹⁴Hg and ¹⁹⁶Hg have been measured using the in beam IPAD method. The results $\text{g(}{}^{194}\text{Hg}\text{) = ?0.24(4)}$ and $\text{g(}{}^{196}\text{Hg}\text{) = ?0.18(9)}$ are in agreement with the value expected for an ($\text{i}{}_1\text{3}\text{2}$^?2) neutron satructure and clearly contradict the previous assignment as ($\text{h}{}_{\mathrm{<mtext>1</mtext><mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{?2}}$) proton configurations. Cranking model calculations show that the neutron excitation energies in the rotating frame agree satisfactorily with the experimental energies and that the proton excitations are expected ≈2 MeV above the experimental yrast line     

Predissociation and Λ-doubling in the even-parity Rydberg states of the nitrogen molecule

Predissociations in the y¹Π_g and $\text{x}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ Rydberg states of N₂ (configurations $\text{1π}{}_{\mathrm{u}}{}^{\mathrm{?1}}\text{4pσ}$ and $\text{1π}{}_{\mathrm{u}}{}^{\mathrm{?1}}\text{3pπ}$, respectively) and their likely causes, are discussed. Peaking of rotational intensity at unusually low J values, without sharp breaking off, is interpreted as due to case c^? or case cⁱ predissociation. Λ doubling in the y state, attributed to interactions with the $\text{x}{}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ state and with another, ¹Σ⁺, state of the same electron configuration as x, is analyzed. From this analysis the location of the (unobserved) ${}^1\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}$ state, here labeled x′, is obtained. It is concluded that the predissociation in the Π⁺ levels of the y state is an indirect one mediated by the interaction with x′ coupled with predissociation of x′ by a ${}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{?}}$ state dissociating to ${}^4\text{S +}{}^2\text{P}$ atoms: combined, however, with perturbation of the y state by the k¹Π_g Rydberg state (configuration $\text{3σ}{}_{\mathrm{g}}{}^{\mathrm{?1}}\text{4dπ}$), whose Π⁺ levels are completely predissociated.     

Magnetic moments of (νi132)−n isomers in neutron-deficient lead isotopes

The magnetic moments of the 12⁺ isomers in ^{192, 196, 198, 200, 206}Pb and of the $\text{33}\text{2}{}^{\mathrm{+}}$ isomer in ²⁰⁵Pb have been measured using the PAD technique. The results for the g-factors are: g(192) = ?0.173(2), g(196) = ?0.1600(15), g(198) = ?0.1552(15), g(200) = ?0.1512(15), g(206) = ?0.1496(18), and g(205) = ?0.148(5). As all states have a rather pure $\text{(νi}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}\text{)}{}^{\mathrm{?n}}$ configuration, the values reflect directly the $\text{νi}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ orbital. They show a decrease towards the more neutron-deficient isotopes attributed to the reduced core polarisation as a result of decreasing occupation of the $\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ neutron shell. The measured systematics are discussed regarding core polarisation, mesonic corrections, and small admixtures of core-excited states to the $\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ wave function.     

Level structure of 100Tc

Gamma and electron spectra following thermal neutron capture on ⁹⁹Tc have been studied with a bent-crystal spectrometer, Ge(Li) and Si(Li) detectors and a magnetic spectrometer. Prompt and delayed γ-γ coincidences with Ge(Li) detectors have been performed. A level scheme is proposed for ¹⁰⁰Tc comprising 21 excited states up to 640 keV. The binding energy of the last neutron in ¹⁰⁰Tc was deduced. For most levels, spin and parity values were assigned. Two isometric transitions of respective half-lives 10.2 and 4.6 μs have been identified using the ¹⁰⁰Mo(d, 2n)¹⁰⁰Tc reaction with a pulsed beam of deuterons. From the comparison of the present (n, γ) study and the collaborative study of the ⁹⁹Tc(d, p) reaction, several members of the multiplets $\text{π}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{ν}\text{g}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}$, $\text{π}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{ν}\text{g}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$, $\text{π}\text{g}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{ν}\text{s}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and $\text{π}\text{p}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{ν}\text{d}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ have been identified.     

The 46, 48, 50Ti(p, α) 43, 45, 47Sc reactions at 40.35 MeV

The ^{46, 48, 50}Ti(p, α) ^{43, 45, 47}Sc reactions have been studied at a proton energy of 40.35 MeV with an overall energy resolution of about 80 keV FWHM. Angular distributions for states with excitation energies up to about 7 MeV in ⁴³Sc and ⁴⁵Sc and up to 8.4 MeV in ⁴⁷Sc are presented. Both positive- and negative-parity states were observed. A microscopic form factor formalism for the three-nucleon transfer reaction was applied to extract quantitative information. Zeroth order calculations have been performed assuming the simplest possible configuration for the transferred nucleons. Subsequently, the ($\text{1}\text{f}{}_{\mathrm{<mtext>7</mtext><mtext>2</mtext>}}\text{)}{}^{\mathrm{n}}$ shell-model wave functions of Kutschera et al. have been used in a more detailed test, considering the components with different neutron angular momentum couplings. Reasonable agreement was obtained for most of the states considered. The effect on the calculated analyzing power of including different configurations for the $\text{7}\text{2}{}^{\mathrm{?}}$ g.s. transition in ⁴⁷Sc was found to be small.     

Magnetic circular dichroism of transition metal ions in solids—II K2NaGaF6: Cr3+

The absorption and MCD spectra of the ${}^4\text{A}{}_{\mathrm{2g}}\text{→}{}^4\text{T}{}_{\mathrm{2g}}$, ${}^4\text{A}{}_{\mathrm{2g}}$, ${}^4\text{A}{}_{\mathrm{2g}}\text{→}{}^4\text{T}{}_{\mathrm{1g}}{}^{\mathrm{a}}$ and ${}^4\text{A}{}_{\mathrm{2g}}\text{→}{}^4\text{T}{}_{\mathrm{1g}}{}^{\mathrm{b}}$ spin-allowed transitions of Cr³⁺ in K₂NaGaF₆ are reported. It is shown that transitions to the ${}^4\text{T}{}_{\mathrm{1g}}$. states are induced by T_1u vibratio the other spin-allowed transition, ${}^4\text{A}{}_{\mathrm{2g}}\text{→}{}^4\text{T}{}_{\mathrm{2g}}$, there are three competing intensity mechanisms: electric dipole induced by T_1u vibrations, electric dipole induced by T_2u vibrations and magnetic dipole, and an estimate is made of the relative importance of these. The magnetic dipole ${}^4\text{A}{}_{\mathrm{2g}}\text{→}{}^2\text{E}{}_{\mathrm{g}}$ zero-phonon line is observed to be accompanied by a vibrational sideband for which the coupling is predominantly with T_2u vibrations. Other weak transitions are observed in MCD spectra and their origin briefly discussed.     

The g-factor difference for the 61+ and 88+ states in 210Po

The difference in g-factors for the 6₁⁺ and 8₁⁺$\text{(πh}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}{}^2\text{)}$ states in ²¹⁰Po has been measured as $\text{(g}{}_6\text{? g}{}_8\text{)}\text{g}{}_8\text{= 2.0 ± 0.7\%}$. This result represents a small violation of additivity. A value of g₈ = 0.909 ± 0.011, independent of g₆, was also obtained.