Collinear and noncollinear emission of anti-stokes and second order stokes Raman radiation

Generating higher order stimulated Raman scattering in benzene, apart from phase-matched anti-Stokes radiation a collinear anti-Stokes emission is observed, which is explained by parametric four-photon processes under mismatch condition.     

Optical emission spectrum of rubidium atoms isolated in solid krypton

Saturation induced minima of the output power of a He/Ne-laser appear if Zeeman splitting equals the frequency separation. These minima have been investigated as a function of pressure. The results show pressure broadening caused by velocity changing and alignment destroying collisions. In contrast to Lamb-dip measurements the effect of phase changing collisions on collision broadening is negligible.     

Observation of collective-emission-induced cooling of atoms in an optical cavity

We report the observation of collective-emission-induced, velocity-dependent light forces. One-third of a falling sample containing 3 x 10(6) cesium atoms illuminated by a horizontal standing wave is stopped by cooperatively emitting light into a vertically oriented, confocal resonator. We observe decelerations up to 1500 m/s(2) and cooling to temperatures as low as 7 microK, well below the free-space Doppler limit. The measured forces substantially exceed those predicted for a single two-level atom.     

Theoretical study of the X-ray Kβ emission spectrum of an argon atom

The influence of many-particle effects on absolute values and the shape of the doubly differential cross section of resonant inelastic scattering of a linearly polarized X-ray photon by a free Ar atom close to the K- and KM ₂₃-ionization thresholds is studied theoretically. The evolution of the spatially extended profile of the scattering cross section to the principal Kβ_1,3 and satellite Kβ₅ structures of the Ar X-ray Kβ emission spectrum is demonstrated. The calculations are performed in the nonrelativistic Hartree-Fock approximation for the wave functions of one-electron states and in the dipole approximation for the anomalous-dispersion amplitude of the scattering probability. The effects of the radial relaxation of electron shells, the correlation loosening, vacuum correlations, the spin-orbit and multiplet splitting, as well as the Auger and radiative decays of the vacancies produced are taken into account. The calculation results have a predictive character and, for the case of the incident photon energies of 3199.2 and 3245.9 eV, they are in good agreement with the results of the synchrotron experiment on measuring the X-ray Kβ emission spectrum of a free Ar atom.     

The emission and absorption spectra of chromyl chloride in an argon matrix at 4 K

The emission and absorption spectra of chromyl chloride (and the pure ³⁵Cl isotopic species) have been obtained in an argon matrix at 4 K. In emission, two systems are obtained and these correlate with the two systems previously found in the absorption spectrum of the pure crystal and which were analyzed as the lowest singlet and triplet systems. The emission systems have, therefore, been assigned as phosphorescence and fluorescence.     

Observation of intense stokes and anti-stokes lines in CH4 pumped by 355 nm of a Nd:YAG laser

The stimulated Raman scattering (SRS) and four-wave mixing (FWM) processes have been studied in detail in CH₄ gas pumped by the third-harmonic of Nd:YAG laser at =355 nm. The conversion efficiency and average output energy have been measured for the various Stokes and anti-Stokes lines at different experimental conditions. The threshold input energy at various CH₄ pressures has been calculated for the unguided and capillary waveguide Raman cells. The calculated values for the capillary case have been compared with the measured values at different CH₄ pressures and the two results are in good agreement.     

原子间的偶极相互作用对其在腔场中辐射谱的影响

研究了两个通过偶极-偶极力关联的两能级原子在单模腔场中的辐射谱,发现原子间偶极-偶极力的贡献;使辐射谱偏离关于中心频率的对称性.对真空场和强场情况作了细致的讨论.     

Resonant stokes and anti-stokes Raman scattering of light in CdSe/ZnSe nanostructures

Raman scattering spectra of CdSe/ZnSe multilayer nanostructures with a CdSe insert of a nominal thickness of 2.1 monolayers were studied. A heavy dependence of the intensity and of the frequency position of the multiphonon Stokes and anti-Stokes LO bands on the exciting photon energy was detected. The results obtained are interpreted as a resonance with various exciton transitions in the CdSe insert and barrier ZnSe layers. A difference between the Stokes and anti-Stokes frequencies of LO bands observed as the resonance conditions are varied confirms the inhomogeneous nature of the photoluminescence band of CdSe quantum dots.     

Energy spectrum of fermionized bosonic atoms in optical lattices

We investigate the energy spectrum of fermionized bosonic atoms, which behave very much like spinless noninteracting fermions, in optical lattices by means of the perturbation expansion and the retarded Green's function method. The results show that the energy spectrum splits into two energy bands with single-occupation; the fermionized bosonic atom occupies nonvanishing energy state and left hole has a vanishing energy at any given momentum, and the system is in Mott-insulating state with a energy gap.Using the characteristic of energy spectra we obtained a criterion with which one can judge whether the Tonks-Girardeau (TG) gas is achieved or not.     

Test of an optical parametric oscillator (OPO) as a compact and fast tunable stokes source in coherent anti-stokes raman spectroscopy (CARS)

An optical parametric oscillator (OPO), as a novel kind of broadband Stokes source, is employed for coherent anti-Stokes Raman spectroscopy (CARS). Compared to the conventional dye laser configuration OPO-CARS offers practical advantages. The tunable OPO allows a fast and comfortable frequency tuning. The excitation bandwidth of about 35 cm^–1 (FWHM) limits the spectral range of effective and stable single pulse CARS generation but can be used to enhance selected spectral structures.     

The reaction of F atoms with CO in an argon matrix. Vibrational and electronic spectra of FCO

Upon codeposition at 14 K of an Ar:CO sample with an Ar:NF₃ sample that had been passed through a low-power microwave discharge in an Al₂O₃ tube, very prominent infrared absorptions of FCO and F₂CO were observed. Overtone bands of FCO were identified at 2032 and 3690 cm⁻¹, and their assignment was confirmed by both carbon-13 and oxygen-18 isotopic substitution. Further data were also obtained on the vibrational fundamentals of isotopically substituted F₂CO. A six-constant valence force potential has been derived for FCO using a least-squares force constant adjustment to the isotopic data and assuming a recently calculated structure. The photodissociation of FCO into F + CO was observed with a threshold near 2800 Å. The assignment of two overlapping electronic transitions of FCO between 3400 and 2300 Å is discussed.     

Annealing studies on the absorption spectrum of 41K-atoms trapped in an argon matrix

Argon crystals were doped with 0.2 ppm of ⁴¹K through the nuclear reaction ⁴⁰Ar (n, β^-) ⁴¹K. The absorption spectrum from 300 nm to 800 nm was measured as a function of the annealing temperature. Absorption ← 4²s_{$\text{1}\text{2}$} transition of the free atom could be bands corresponding to the 4²p_{$\text{1}\text{2}$}, _{$\text{3}\text{2}$} ← 4²s_{$\text{1}\text{2}$} and 5²p_{$\text{1}\text{2}$}, _{$\text{3}\text{2}$} ← 4²s_{$\text{1}\text{2}$} transition of the free atom could be observed. The absorption bands depend strongly on the annealing temperature. An increase in the annealing temperature results in a blue shift of the absorption bands.     

The UV absorption spectrum of the phenyl radical isolated in solid argon

Phenyl radicals have been generated by photodecomposition of nitrosobenzene isolated in solid argon at 12 K. In this medium the origin of the first UV absorption band of nitrosobenzene corresponding to theS ₀ S ₂ transition is found at 30260 cm^–1. Excitation with an excess energy of 2200 cm^–1 results in very efficient photodissociation. The fragments NO and phenyl are stable for many hours. Annealing of the sample above 35 K led to partial recombination and recovery of the absorption spectrum of nitrosobenzene. The UV spectrum of the phenyl radical was obtained in the wavenumber range 25000–45000 cm^–1, apparently without contamination by other species. It shows sharp lines at 25220, 33880, and 34820 cm^–1 and two broader maxima at 38360 and 41060 cm^–1. Of these only the line at 34820 cm^–1 had been assigned to the phenyl radical in earlier work. These data are compared to recent molecular orbital calculations.Dedicated to Prof. F. P. Schäfer on the occasion of his 65th birthday.     

Manifestation of outgoing resonance in stokes and anti-stokes spectra of ZnTe and ZnMgTe quantum wires

The spectra of resonant light scattering by ZnTe quantum wires have been measured at excitation energies of 2.18–2.72 eV. The quantum wires have been grown on Si(100) and GaAs(100) substrates by molecular beam epitaxy. The effect of outgoing resonance with the electron transition energy E ₀ on the intensity of phonon lines of the Stokes spectrum and on the intensity ratio of the Stokes and anti-Stokes spectral lines has been studied. The energy E ₀ has been determined in ZnTe and ZnMgTe quantum wires from the edge luminescence spectra.     

Splitting of vibrational mode of CO isotopic species in the unstable trapping site in argon matrix

FTIR spectra of the antisymmetric stretch and symmetric bending vibrational modes of isotopic species of CO₂ trapped in argon matrix are recorded at 5 K with a resolution of . A splitting of the mode is observed for the different species in the trapping site termed unstable. Considering this splitting and the width of the line observed for this unstable site, one expects this site to be larger than the stable one. A theoretical model is elaborated to interpret this splitting. Calculations performed at harmonic level of approximation for vibrational modes in a single substitutional site (S1) and a double substitutional one (S2) in a fcc distorted argon lattice to minimize the free energy of the molecule-matrix system, show the splitting to occur in the larger site. The latter result leads us to invert former attribution of the sites: the stable site is a single substitutional one, whereas the unstable site is a double substitutional one. Received: 27 January 1998 / Revised: 30 July 1998 / Accepted: 17 August 1998     

Manifestation of the van der Waals surface interaction in the spontaneous emission of atoms into an optical nanofiber

We study the spontaneous emission of atoms near an optical nanofiber and analyze the coupling efficiency of the spontaneous emission into a nanofiber. We also investigate the influence of the van der Waals interaction of atoms with the surface of the optical nanofiber on the spectrum of coupled light. Using, as an example, ⁸⁵Rb atoms we show that the van der Waals interaction may considerably extend the red wing of the spontaneous emission line and, accordingly, produce a well-defined asymmetry of the spontaneous emission spectrum coupled into an optical nanofiber.