Electrical resistivity of iron-vanadium alloys between 78 and 1200 K

Electrical resistivity (?) of FeV alloys containing 0.5, 0.9, 2.7, and 6.1 at% V has been measured as a function of temperature (T) between 78 and 1200 K. The ? vs. T curves exhibit a change in the slope at the ferromagnetic Currie temperature (T_c). The d?/dT vs. T curves in the neibhorhood of T_c are similar to the corresponding plot for pure Fe. Our studies confirm the previously observed anomalous effect of V on T_c of Fe, i.e., that T_c increase with small additions of V to Fe. The critical index λ⁺ associated with the power law of d?/dT just above T_c has been determined as a function of V concentration.     

The ferromagnetic to paramagnetic phase transition of Fe studied by x-ray photoelectron spectroscopy

Valence band x-ray photoelectron spectra from Fe(100) have been measured as a function of temperature to above the Curie temperature, T_c. The room temperature data can be reconciled with the theoretical one-particle density of states (DOS). At T = 1.034T_c, the data do not resemble the paramgnetic DOS of Fe as calculated in the disordered-local-moment limit.     

Pressure effect on the anomalous electrical conductivity of magnetite

The temperature dependence of the electrical conductivity of magnetite was measured under hydrostatic pressure up to 18.4 kbar. It is found that the temperature of the conductivity maximum in the high temperature phase is more rapidly reduced by pressure (dT_m/dP = -4.1 K/kbar) than the Verwey temperature (dT_v/dP = -0.27 K/kbar). The discontinuous change of the conductivity at T_v appears to increase with applied pressure as a result of a lowering of T_m.     

Temperature dependence of Johnson noise

Johnson noise is usually considered to measure the absolute, thermodynamic temperature. A careful analysis of data on copper to 1.7 mK suggests that a kinetic temperature T_o coth T_o/T is measured, where T_o = 1.98 mK, and so reflects a zero-point energy.     

Accuracy of speech transmission index predictions based on the reverberation time and signal-to-noise ratio

This paper examines the accuracy of the speech transmission index (STI) calculated from the reverberation time (T) and signal-to-noise ratio (L_SN) of enclosed spaces. Differences between measured and predicted STIs have been analysed in two rooms (reverberant vs. absorbent), for a wide range of absorption conditions and signal-to-noise ratios (sixteen tests). The STI was measured using maximum length sequence analysis and predictions were calculated using either measured or predicted values of T and L_SN, the latter assuming diffuse sound field conditions. The results obtained for all the conditions tested showed that STI predictions based on T and L_SN tend to underestimate the STI, with differences between measured and predicted STIs always lower than 0.1 (on a 0.0–1.0 scale), and on average lower than 0.06. According to previous research, these differences are noticeable and therefore non-negligible, as 0.03 is the just noticeable difference in STI. The use of either measured or predicted values of T and L_SN provided similar STI predictions (i.e. non-noticeable changes), with differences between predictions that are on average lower than 0.03 for the absorbent room, and lower than 0.01 for the reverberant room.     

Measurement of hydrogen- and self-broadened half-widths of ammonia at 200 and 300°K

The hydrogen- and self-broadened half-widths have been measured for the (v₁+v₂)- and (v₂+v₃)-bands of ammonia at 300 and 207°K. Measurement of hydrogen-broadened widths has been restricted to J, K ?6, but that of self-broadened widths is done for a few lines outside that range. Assuming a power-law dependence of half-width on temperature given by γ(T)=γ(T₀)(T/T₀)^α, the average value of the index α for the lines measured is found to be 0·57 for hydrogen broadening.     

Superconductivity of Li under pressure

The superconductivity of Li under pressure is studied by a density functional method. Structural and elastic properties, transition temperature (T_c), density of states (DOS), are considered for the material at ambient and at higher pressures. The calculations, particularly of T_c and DOS as a function of pressure, are compared with other available results. This is in view of the wide difference between the previously predicted maximum T_c-value and those observed by both magnetic susceptibility and electrical resistivity experiments. The present calculations yield better estimates of T_c and other parameters with respect to measured values.     

MRI of human tumor xenografts in vivo: Proton relaxation times and extracellular tumor volume

Proton T₁ and T₂ differ substantially between tumors, but the tumor properties causing heterogeneity in T₁ and T₂ have not been fully recognized. The purpose of the study reported here was to investigate whether differences in T₁ and T₂ between tumors are mainly a consequence of differences in the fractional volume of the extracellular compartment. The study was performed using a single human tumor xenograft line showing large naturally occurring intratumor heterogeneity in the size of the extracellular compartment. The size of the extracellular compartment was calculated from the volume and the density of the tumor cells. Cell volume was measured by an electronic particle counter. Cell density was determined by stereological analysis of histological preparations. T₁ and T₂ were measured by MRI in vivo both in the absence and presence of Gd-DTPA. Two spin-echo pulse sequences were used, one with a repetition time (TR) of 600 ms and echo times (TEs) of 20, 40, 60, and 80 ms and the other with a TR of 2,000 ms and TEs of 20, 40, 60, and 80 ms. Measurements of T₁ and T₂ in the presence of Gd-DTPA were performed in a state of semi-equilibrium between uptake and clearance of Gd-DTPA. MR-images and histological preparations of tumor subregions homogeneous in extracellular volume were analysed in pairs. The extracellular volume differed between tumor subregions from 5 to 70%. T₁ and T₂ measured in the absence of Gd-DTPA differed between tumor subregions by a factor of approximately 1.5 and increased with increasing extracellular volume. The relative decrease in T₁ caused by Gd-DTPA, represented by $\text{(T}{}_{\mathrm{<mtext>1\; control</mtext>}}\text{−T}{}_{\mathrm{<mtext>1\; Gd-DTPA</mtext>}}\text{)}\text{T}{}_{\mathrm{<mtext>1\; control</mtext>}}$, also increased with increasing extracellular volume. The relative decrease in T₂ did not change significantly as the extracellular volume increased. These observations strongly suggest that the size of the extra-cellular compartment is a major determinant of proton T₁s and T₂s of tumors, possibly because the ratios of free to structured and free to bound water increase with increasing extracellular tumor volume.     

In Vivo Relaxation Time Measurements in the Human Placenta Using Echo Planar Imaging at 0.5 T

This paper presents the first in vivo measurements of the nuclear magnetic resonance relaxation times T₁ and T₂ at 0.5 T in the human placenta from 20 weeks gestational age until term, in both normal and compromised pregnancies. T₁ measurements were performed by using both an inversion recovery sequence and the Look-Locher echo planar imaging (EPI) sequence on a total of 41 women with normal pregnancies and 11 women with compromised pregnancies. T₂ measurements were performed by using a spin-echo EPI sequence on 36 women with normal pregnancies and 14 women with compromised pregnancies. In normal pregnancies, both the T₁ values measured with the inversion recovery sequence and the T₂ values were found to decrease with gestational age, the linear regression results gave T₁=−9.1t+1538 r²=0.23 p=0.03 T₂=−4.0t+338 r²=0.47 p=4 10⁻⁶ where t is the gestational age in weeks, and T₁ and T₂ are the relaxation times in milliseconds. T₁ values measured very rapidly with the Look-Locher EPI sequence, but, therefore, with a much lower signal-to-noise ratio, showed no significant trends.The T₁ values measured in the abnormal group were significantly lower than those measured in the normal group. Four out of eight patients with compromised pregnancies had placental T₁ values lying outside the 90% confidence limits for the normal population based about the regression line, significantly more than expected by chance (p = 0.005). Ten out of fourteen of the T₂ measurements in the abnormal group were below the regression line established for the normal group, with 4 lying below the 90% confidence interval, although these trends were only just significant (p = 0.06 and p = 0.03).     

Ultrasonic attenuation study of erbium in a magnetic field

The ultrasonic attenuation coefficient of longitudinal waves propagating along the c-axis of a single crystal of erbium was measured over a temperature range which covers the transition temperature from the paramagnetic to the sinusiodal phase T₆ = 83.8 K and the transition temperature from the sinusoidal to elliptical phase T_⊥ = 53.9 K. These measurements were performed as a function of temperature in the presence of constant magnetic fields and at constant temperatures as a function of applied magnetic fields. A magnetic field parallel to the c-axis shifted T₆ to lower temperatures and reduced the peak attenuation. A broad new maximum emerged on the high temperature side of the field-shifted T₆. Application of H perpendicular to the c-axis produced little change in either T₆ or T_⊥. A model introduced by Tachiki and Mackawa is used to discuss the results.     

Observation of a transition from BCS to HTSC-like superconductivity in Ba1 − x KxBiO3 single crystals

The temperature dependences of the upper critical field B _c2(T) and surface impedance Z(T) = R(T) + iX(T) have been measured in Ba_{1 ? x} K_xBiO₃ single crystals with transition temperatures 6 ≤ T _c ≤ 32 K (0.6 > x > 0.4). A transition from the BCS to an unusual type of superconductivity has been revealed: B _c2(T) curves of the crystals with T _c > 20 K have positive curvature (as in some HTSCs), and those of the crystals with T _c < 15 K described by the usual Werthamer-Helfand-Hohenberg (WHH) formula. The R(T) and X(T) dependences of the crystals with T _c ≈ 32 K and T _c ≈ 11 K in the temperature range T ? T _c are linear (as in HTSCs) and exponential (BCS), respectively. The experimental results are discussed using the extended saddle point model by Abrikosov.     

A law of corresponding states for the superfluid fraction of He II

The superfluid fraction ?_s/? in He II has been accurately measured at more than 400 points throughout the P-T plane above 1.2 K and is found to be a universal function of the reduced temperature T/T_λ(P).     

Pressure dependence of the Néel temperature of f.c.c. stainless steel

The Néel temperature T_N of f.c.c. stainless steel has been measured as a function of pressure using the Mössbauer effect. A sample with approximately 74 wt.% Fe, doped with ^57Co, and having T_N = 58.4 ± 0.1 K at zero pressure, shows T_N rising with pressure with increasing slope. Our results indicate that T_N is raised to room temperature by a pressure of 175 ± 5 kbar.     

MRI rotating frame relaxation measurements for articular cartilage assessment

In the present work we introduced two MRI rotating frame relaxation methods, namely adiabatic T_1ρ and Relaxation Along a Fictitious Field (RAFF), along with an inversion-prepared Magnetization Transfer (MT) protocol for assessment of articular cartilage. Given the inherent sensitivity of rotating frame relaxation methods to slow molecular motions that are relevant in cartilage, we hypothesized that adiabatic T_1ρ and RAFF would have higher sensitivity to articular cartilage degradation as compared to laboratory frame T₂ and MT. To test this hypothesis, a proteoglycan depletion model was used. Relaxation time measurements were performed at 0 and 48 h in 10 bovine patellar specimens, 5 of which were treated with trypsin and 5 untreated controls were stored under identical conditions in isotonic saline for 48 h. Relaxation times measured at 48 h were longer than those measured at 0 h in both groups. The changes in T₂ and MT relaxation times after 48 h were approximately 3 times larger in the trypsin treated specimens as compared to the untreated group, whereas increases of adiabatic T_1ρ and RAFF were 4 to 5 fold larger. Overall, these findings demonstrate a higher sensitivity of adiabatic T_1ρ and RAFF to the trypsin-induced changes in bovine patellar cartilage as compared to the commonly used T₂ and MT. Since adiabatic T_1ρ and RAFF are advantageous for human applications as compared to standard continuous-wave T_1ρ methods, adiabatic T_1ρ and RAFF are promising tools for assessing cartilage degradation in clinical settings.     

The influence of domains on the structural phase transition of RbCaF3

The temperature dependence of the tetragonal rotational displacement below the phase transition of RbCaF₃ is described by (T₀ - T)^β with T₀ = 199 K and β = 0.25 measured with single crystal X-ray diffraction. A method was developed to study the variability of the domains as a function of the temperature. The influence of the domains on the critical behaviour of the order parameter is pointed out.     

Parametric study on excitation temperature and electron temperature in low pressure plasmas

This work aims at investigation of the validity of the electron excitation temperature (T_exc) by optical emission spectroscopy (OES) as an alternative diagnostic to the electron temperature (T_e). The excitation and the electron temperatures were measured at a wide range of gas pressures and input powers in different plasmas such as capacitively-coupled, inductively-coupled, and magnetron direct current plasmas. As a result, both temperatures were found to decrease with an increase in pressure, whereas they not very dependent on power, indicating that T_exc showed a tendency identical to that of T_e as pressure and power were varied. This result suggests that T_exc measurement can be an alternative diagnostic for T_e measurement once the ratio of the two temperatures is found in advance through a calibration experiment especially for low pressure high electron density industrial processing plasmas in which probe measurements are limited.     

Pressure dependence of the Grüneisen parameter of sodium and potassium

Temperature changes associated with adiabatic pressure changes (?T/?P)_s have been measured for sodium and potassium at room temperature (297 K) under hydrostatic pressures up to 32 kbar. For both metals a large decrease in the value of (?T/?P)_s is observed as the pressure increases. The Grüneisen parameter γ is related to (?T/?P)_s by γ = B_s(?T/?T)_s/T where B_s is the adiabatic bulk modulus. Available data for the pressure dependence of B_s and the isothermal bulk modulus B_T are used to predict the pressure and volume dependence of γ.     

Pressure dependence of the Kondo resistance anomaly and the pair breaking effect in La-Ce alloys

The pressure dependence of the parr breaking effect and of the resistance anomaly was measured in LaCe alloys. The results indicate that the maximum in the pressure dependent pair breaking effect is due to a monotonic shift of the Kondo temperatureT _k with pressure from valuesT _k > ?T _c0 toT _k ?T _c0, whereT _c0 is the superconducting transition temperature of pure lanthanum.     

Phase transition and relaxation processes by 87Rb and 39K nuclear magnetic measurements of RbKSO4 single crystals

⁸⁷Rb and ³⁹K nuclear magnetic resonance (NMR) spectra of RbKSO₄ single crystals were measured at room temperature. ⁸⁷Rb central line has the angular dependences of second-order quadrupolar shifts. From these results, the quadrupole coupling constant and the asymmetry parameter were determined at room temperature. In addition, the spin–lattice relaxation rate, 1/T₁, and the spin–spin relaxation rate, 1/T₂, were measured as a function of temperature. The values of 1/T₁ for the ⁸⁷Rb and ³⁹K nuclei were found to increase with increasing temperature, and 1/T₁ was determined to be proportional to Tⁿ. Therefore, for the ⁸⁷Rb and ³⁹K nuclei, Raman processes with n=2 are more significantly in nuclear quadrupole relaxation than direct processes.     

Effect of hydrogenation on the magnetic and magnetoelastic properties of R 2Fe14B compounds (R = Nd, Gd, Er, Lu)

The temperature dependences of the magnetization σ(T), magnetostriction λ(T), and linear thermal expansion coefficient α(T) of R ₂Fe₁₄B intermetallic compounds (R = Nd, Gd, Er, Lu) and of their hydrides R ₂Fe₁₄BH_2.5 are studied. The magnetization was measured with a pendulum magnetometer within the temperature interval 77–700 K in a magnetic field H = 500 Oe. Magnetostriction and thermal expansion were measured using the tensometric technique in the temperature interval 77–420 K. It was established that Gd₂Fe₁₄BH_2.5 undergoes a spin-reorientational (SR) transition at T _SR = 235 K. In compounds with Nd and Er, anomalies associated with the SR transition were found in the σ(T), λ(T), and α(T) curves. The SR transition temperatures were refined and magnetic phase diagrams were constructed for the compounds studied. The α(T) curves of the R ₂Fe₁₄BH_2.5 hydrides (R = Nd, Er) revealed anomalies of a nonmagnetic origin associated with hydrogen ordering in the crystal lattice of these compounds.