g-Factors of high-spin isomers in 194Hg and 196Hg

The g-factors of the 10⁺ isomeric states in ¹⁹⁴Hg and ¹⁹⁶Hg have been measured using the in beam IPAD method. The results $\text{g(}{}^{194}\text{Hg}\text{) = ?0.24(4)}$ and $\text{g(}{}^{196}\text{Hg}\text{) = ?0.18(9)}$ are in agreement with the value expected for an ($\text{i}{}_1\text{3}\text{2}$^?2) neutron satructure and clearly contradict the previous assignment as ($\text{h}{}_{\mathrm{<mtext>1</mtext><mtext>1</mtext><mtext>2</mtext>}}{}^{\mathrm{?2}}$) proton configurations. Cranking model calculations show that the neutron excitation energies in the rotating frame agree satisfactorily with the experimental energies and that the proton excitations are expected ≈2 MeV above the experimental yrast line     

Hyperfine structure of CH3OH

Hyperfine structure of the (0, 0, 1) - (1, 0, 1) transition of methanol has been investigated by beam absorption and of the (J, 1, 3?) → (J, 1, 3+) transitions for J = 2, 3, and 6 by beam-maser spectroscopy. The best-fit results for the spin-rotation and spin-spin coupling constants $\text{C}{}_{\mathrm{JK\tau \pm }}{}^{\mathrm{(i)}}$ and $\text{D}{}_{\mathrm{JK\tau \pm }}{}^{\mathrm{(i)}}$, respectively, are in kHz¹: $\text{C}{}_{101}{}^{\mathrm{(1)}}\text{= 2.4(10)}$, $\text{C}{}_{101}{}^{\mathrm{(2)}}\text{= ?0.6(10)}$, $\text{D}{}_{101}{}^{\mathrm{(1)}}\text{= ?13.8(9)}$, $\text{D}{}_{101}{}^{\mathrm{(2)}}\text{= 7.0(9)}$, $\text{C}{}_{\mathrm{213?}}{}^{\mathrm{(1)}}\text{= ?5.0(10)}$, $\text{C}{}_{\mathrm{213?}}{}^{\mathrm{(2)}}\text{= ?5.5(10)}$ and ($\text{C}{}_{\mathrm{J13?}}{}^{\mathrm{(2)}}\text{- C}{}_{\mathrm{J13+}}{}^{\mathrm{(2)}}\text{) = 0.98(9)}$.     

Lifetime measurements of the 6p2P and 6d2D levels in Hg(II)

The radiative lifetimes of the 6p²P levels in Hg(II) have been measured to be $\text{τ(6p}{}^2\text{P}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}\text{)= 3.92±0.12)}$ ns and $\text{τ(6p}{}^2\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{)=(2.3±0.3)}$ ns by the beam-gas-Hanle and the beam-foil techniques, respectively. The result for the $\text{6p}{}^2\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ level differs from recent theoretical calculations, whereas there is good agreement for the $\text{6p}{}^2\text{P}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ level.     

Quadrupole moment of the 5−2, 134 keV state in 197Hg

The quadrupole interaction for the $\text{5}{}^{\mathrm{?}}\text{2}\text{, 134}\text{keV}$ state of ¹⁹⁷Hg in solid Hg was observed by the e^?-γ time differential perturbed angular correlation method. The quadrupole coupling constant ν_Q=126 (2) MHz is derived. By comparison with experimental quadrupole coupling constants for ¹⁹⁹Hg in Hg and HgCl₂ as well as for ²⁰¹Hg in HgCl₂ the quadrupole moment of the $\text{5}{}^{\mathrm{?}}\text{2}\text{, 134}\text{keV}$ state in ¹⁹⁷Hg is related to that of the ²⁰¹Hg ground state, which is known. The value $\text{Q(}{}^{197}\text{Hg}\text{,}\text{5}{}^{\mathrm{?}}\text{2}\text{, 134}\text{keV}\text{)=0.47(6)}\text{b}$ is deduced. This value is not in agreement with the assumption of a $\text{f}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ shell-model configuration for the 134 keV state. It is consistent with an interpretation of the $\text{5}{}^{\mathrm{?}}\text{2}$ level in terms of the core coupling model of de Shalit.     

Structure of positive parity states in 29P and two-step processes in (p,t) reactions

From a study of (p,t) reactions on ³¹P and ³⁰Si it is suggested that in ²⁹P the states with $\text{J}{}^{\mathrm{\pi }}\text{=}\text{1}\text{2}{}_1{}^{\mathrm{+}}$ and $\text{1}\text{2}{}_2{}^{\mathrm{+}}$, the pair $\text{3}\text{2}{}_2{}^{\mathrm{+}}$, $\text{5}\text{2}{}_1{}^{\mathrm{+}}$, and the pair $\text{7}\text{2}{}_3{}^{\mathrm{+}}$, $\text{9}\text{2}{}_1{}^{\mathrm{+}}$ are related by weak coupling of a s${}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ proton with the states 0₁⁺, 0₂⁺, 2₁⁺ and 4₁⁺ respectively of ²⁸Si. Completely atypical L = 2 angular distributions have been obtained for the $\text{3}\text{2}{}_1{}^{\mathrm{+}}$ and $\text{5}\text{2}{}_2{}^{\mathrm{+}}$ states in ²⁹P and it is suggested that this is due to contribution by two-step processes.     

Observed and calculated interactions between valence states of the NO molecule

No perturbation between two valence states of NO has ever been identified, although many valence-Rydberg and several Rydberg-Rydberg perturbations have been extensively studied. The first valence-valence crossing to be experimentally documented for NO is reported here and occurs between the ¹⁵N¹⁸O B²Π (v = 18) and B′²Δ (v = 1) levels. No level shifts larger than the detection limit of 0.1 cm^?1 are observed at the crossings near $\text{J = 6.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_2\text{)]}$ and $\text{J = 12.5 [B}{}^2\text{Π}\text{(F}{}_1\text{) ～ B′}{}^2\text{Δ}\text{(F}{}_1\text{)]}$; two crossings involving higher rotational levels could not be examined. Semi-empirical calculations of spin-orbit and Coriolis perturbation matrix elements indicate that although the electronic part of the $\text{B}{}^2\text{Π}\text{～ B′}{}^2\text{Δ}$ interaction is large, a small vibrational factor renders the ¹⁵N¹⁸O B (v = 18) ? B′ (v = 1) perturbation unobservable. Semi-empirical estimates are given for all perturbation matrix elements of the operators $\text{Σ}{}_{\mathrm{i}}\text{a}\text{?}{}_{\mathrm{i}}\text{l}{}_{\mathrm{i}}\text{·s}{}_{\mathrm{i}}$ and $\text{B(L}{}_{\mathrm{\pm }}\text{S}{}_{\mathrm{?}}\text{? J}{}_{\mathrm{\pm }}\text{L}{}_{\mathrm{?}}\text{)}$ which connect states belonging to the configurations $\text{(σ2p)}{}^2\text{(π2p)}{}^4\text{(π}{}^1\text{2p)}$, $\text{(σ2p)(π2p)}{}^4\text{(π}{}^1\text{2p)}{}^2$, and $\text{(σ2p)}{}^2\text{(π2p)}{}^3\text{(π}{}^1\text{2p)}{}^2$.     

Coupling constants for several light nuclei from a dispersion analysis of nucleon and deuteron scattering amplitudes

A forward dispersion relation cannot be applied to charged particle scattering amplitudes unless the influence of the Coulomb interaction is explicitly considered. Earlier studies have shown how Coulomb effects can be taken into account when direct (s-channel or bound-state) poles are investigated. In this paper we extend the Coulomb modification to include I = 0 exchange (u-channel) processes as well. We then apply a forward dispersion relation to empirical d + α, p + d and n + d elastic scattering amplitudes which contain both direct and exchange poles with and without Coulomb effects. We obtain detailed and model-independent information on the following vertices: ⁶Li-α-d (S- and D-state) ⁴He-d-d, ³He-d-p, ³H-d-n and d-p-n. From the coupling constants we calculate the asymptotic normalization (spectroscopic factors) C²₁ of the corresponding cluster wave functions, which become: $\text{C}{}^2{}_0\text{(}{}^6\text{Li}\text{, α}\text{d}\text{) = 4.62 ± 0.23}$, $\text{C}{}^2{}_2\text{(}{}^6\text{Li}\text{, α}\text{d}\text{) = (1 ± 6) × 10}{}^{\mathrm{?4}}$, C²₀(α, dd) < 2, $\text{C}{}^2{}_0\text{(}{}^3\text{He, dp}\text{) = 3.5 ± 0.4}$, $\text{C}{}^2{}_0\text{(}{}^3\text{H, dn}\text{) = 2.6 ± 0.3}\text{and}\text{C}{}^2{}_0\text{(}\text{d, np}\text{) = 1.66 ± 0.1}$.     

Lifetimes and g-factors of the 6− and 7− isomers in 66Ga and 68Ga

The 6^? and 7^? isomeric states in ⁶⁶Ga and ⁶⁸Ga at 1440.9 and 1229.6 keV, respectively, have been populated with the (¹³C, 2np) and (¹⁵N, n2p) reactions on natural Fe. The half-lives of these states have been measured to be $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(6}{}^{\mathrm{?}}\text{,}{}^{66}\text{Ga}\text{) = 57.3 ± 1.2}\text{ns}$ and $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{(7}{}^{\mathrm{?}}\text{,}{}^{68}\text{Ga}\text{) = 64 ± 2}\text{ns}$. Using previous data on the hyperfine field of Ga in Fe, the g-factors of these states have been determined by means of the TDPAD method. The results are $\text{g(6}{}^{\mathrm{?}}\text{,}{}^{66}\text{Ga}\text{) = 0.129 ± 0.003}$ and $\text{g(7}{}^{\mathrm{?}}\text{,}{}^{68}\text{Ga}\text{) = 0.105 ± 0.003}$. These values are in very good agreement with the independent particle model if one assumes the and configurations and uses the empirical proton and neutron g-factors from odd-A neighboring nuclei instead of the Schmidt values. The large disagreements with experiment when Schmidt values are used show that core polarization effects are important in these nuclei.     

Study of orientation transfer by collisions of the second kind between 198Hg and 199Hg atoms

A double resonance experiment is used to detect the collisional transfer of orientation from an optically oriented ¹⁹⁸Hg (6³P₁) atom to the hyperfine levels $\text{(6}{}^3\text{P}{}_1\text{; F =}\text{1}\text{2}\text{, F =}\text{3}\text{2}\text{)}$ of a ¹⁹⁹Hg atom. The reaction of transfer is assumed to be ¹⁹⁸Hg (6³P₁) + ¹⁹⁹Hg (6¹S₀) → ¹⁹⁸Hg (6¹S₀) + ¹⁹⁹Hg (6³P₁).The theory of such a process is summarized, the experimental set-up described and the double resonance signals compared with those predicted by the theory.     

Infrared diode laser spectroscopy of the NS radical

The v = 1 ← 0 vibration-rotation bands of the NS radical in the $\text{X}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and $\text{X}{}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ electronic states were observed by using a tunable diode laser. From the least-squares analysis the band origins were determined to be 1204.2755(12) and 1204.0892(19) cm^?1, respectively, for $\text{X}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and $\text{X}{}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$. The rotational and centrifugal distortion constants and the internuclear distance in the X²Π electronic state were obtained as follows: B_e = 0.775549(10) cm^?1, D_e = 0.00000129(33) cm^?1, and $\text{r}{}_{\mathrm{e}}\text{= 1.49403(4)}\text{A}\text{?}$, with three standard deviations indicated in parentheses.     

Band contour analysis of compounds with pure isotopes: The E fundamentals of HC35Cl3

The vibration-rotation transitions for v = 1 ← 0 of NO (${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$) have been studied by using the technique of laser magnetic resonance spectroscopy. Five magnetic resonance lines are observed with three CO laser lines in the range from 1859 to 1886 cm^?1. From these, three zero-field transition frequencies, v = 1 ← 0; $\text{R(}\text{3}\text{2}\text{)}$, $\text{P(}\text{7}\text{2}\text{)}$, and $\text{P(}\text{9}\text{2}\text{)}$ are obtained with an accuracy of ±0.0007 cm^?1. The molecular constants which have been determined by borrowing centrifugal constants from a previous infrared work are $\text{B}{}_{02}{}^1\text{= 1.72004 ± 0.00006}\text{cm}{}^{\mathrm{?1}}$, $\text{B}{}_{12}{}^1\text{= 1.70212 ± 0.00010}\text{cm}{}^{\mathrm{?1}}$, and $\text{G(v = 1) ? G(v = 0) (}\text{for}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{) = 1875.8470 ± 0.0007}\text{cm}{}^{\mathrm{?1}}$.     

Infrared diode laser spectroscopy of the CF radical

The fundamental bands of the CF radical in the $\text{X}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and $\text{X}{}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ electronic states were observed by using an infrared tunable diode laser as a source. Zeeman modulation could be used in detecting lines not only in the ${}^2\text{Π}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ state, but also in ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, because the CF radical deviates considerably from Hund's case (a). From the least-squares analysis of the observed spectra, the following molecular constants were obtained: B_e = 1.416 704 (37) cm^?1, α_e = 0.018 419 (50) cm^?1, $\text{r}{}_{\mathrm{e}}\text{= 1.271 977 (17)}\text{A}\text{?}$, D_e = 6.68 (15) × 10^?6cm^?1, p₀ = 0.008 580 (21) cm^?1, p₁ = 0.008 52 (11) cm^?1, and $\text{ν}{}_0\text{= 1286.1281 (5)}\text{cm}{}^{\mathrm{?1}}$, with three standard errors in parentheses.     

The spectrum and structure of the He2 molecule: Multichannel quantum defect analyses of the triplet levels associated with (1σg)2(1σu)npλ

Emission spectra for the electronic transitions $\text{6–17pπ}{}^3\text{Π}{}_{\mathrm{g}}\text{-2s a}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ and $\text{7–16pσ}{}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{-2s a}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}$ of He₂ are reported and the electronic structures of $\text{npπ}{}^3\text{Π}{}_{\mathrm{g}}{}^{\mathrm{?}}$ and $\text{np(}{}^2\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{,}{}^3\text{Π}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{)}$ characterized. The energy levels associated with $\text{(1σ}{}_{\mathrm{g}}\text{)}{}^2\text{(1σ}{}_{\mathrm{u}}\text{)np(}{}^3\text{Σ}{}_{\mathrm{u}}{}^{\mathrm{+}}\text{,}{}^3\text{Π}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{)}$ exhibit extensive channel mixing, which leads to a breakdown of conventional band models for the higher n¹-members of these Rydberg “series.” However, a model based on multichannel quantum defect theory quantitatively correlates the observed level structures. The higher-energy ($\text{n}{}^1\text{> ～5}$) portions of the $\text{np(}{}^3\text{Σ}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{,}{}^3\text{Π}{}_{\mathrm{g}}{}^{\mathrm{+}}\text{)}$ channels can be represented by two eigen-quantum defects μ₁ = 0.225 and μ₂ = 0.930 and the close- to loose-coupling matrix elements $\text{U}{}_{11}\text{= U}{}_{22}\text{= [N(2N + 1)}{}^{\mathrm{?1}}\text{]}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and $\text{U}{}_{12}\text{= ?U}{}_{21}\text{= [(N + 1)(2N + 1)}{}^{\mathrm{?1}}\text{]}{}^{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$. The inclusion of energy dependence in the μ_α's leads to quantitative correlations for all n¹-values.     

A high-spin isomer in 204Bi

By making use of heavy-ion and α-particle induced reactions an isomeric state has been found in ²⁰⁴Bi, with a half-life of $\text{T}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{= 1.07 ± 0.03}\text{ms}$ and the quantum characteristics I^π = 16⁺. The four-quasiparticle configuration $\text{ν(}\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}\text{)}{}^{\mathrm{?2}}\text{ν(}\text{f}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}\text{)}{}^1\text{π(}\text{h}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}^1$ has been ascribed to this state.     

Rotation-vibration analysis of the Coriolis-coupled ν5g, ν6g, ν8g and ν9 bands of H2CCO

Medium resolution infrared grating spectra of gaseous ketene, H₂CCO were recorded between 1000 and 400 cm^?1, both at instrument temperature (40°C) and with cooling (?40°C). Interferometric Fourier spectra were also measured at ?70°C with resolution 0.22 cm^?1 between 450 and 330 cm^?1. The K structure of the fundamentals ν₅, ν₆, ν₈, and ν₉ was assigned. These fundamentals are coupled by a-axis Coriolis interactions. These couplings were analysed on the symmetric top basis for setting up the perturbation matrix and by utilizing the K-dependent Coriolis shifts of levels. A preliminary analysis of the Coriolis intensity anomalies was also undertaken.Band center values from combination differences are $\text{ν}{}_5{}^0\text{= 587.30 (27)}$ and $\text{ν}{}_6{}^0\text{= 528.36 (39)}\text{cm}{}^{\mathrm{?1}}$. Synthetic spectra indicate the band origins of ν₈ and ν₉ to be close to 977.8 and 439.0 cm^?1, respectively. Estimates of Coriolis coupling constants obtained from synthetic spectra are $\text{ζ}{}_{58}{}^{\mathrm{a}}\text{= + 0.33 (5)}$, $\text{ζ}{}_{68}{}^{\mathrm{a}}\text{= + 0.714 (20)}$, $\text{ζ}{}_{59}{}^{\mathrm{a}}\text{= ? 0.774 (20)}$, and $\text{ζ}{}_{69}{}^{\mathrm{a}}\text{= ? 0.30 (2)}$. Approximate ratios of unperturbed vibrational transition moments obtained from spectral simulations are $\text{M}{}_8{}^0\text{:±iM}{}_5{}^0\text{:±iM}{}_6{}^0\text{:M}{}_9{}^0\text{≈ +2:?9:+10:+0.5}$.     

Core polarization effects in the πh92 shell and g-factors of the 8+ states in 204Po and 206Po

The $\text{g-}\text{values of}\text{[(π}\text{h}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}^2\text{, 8}{}^{\mathrm{+}}\text{]}$ isomeric levels in ²⁰⁴Po and ²⁰⁶Po have been measured with the stroboscopic method. The results obtained are: $\text{g(}{}^{204}\text{Po}\text{) = 0.923±0.013}\text{and}\text{g(}{}^{206}\text{Po}\text{) = 0.919±0.013}$. These and other known $\text{g-}\text{factors of}\text{(π}\text{h}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}\text{)}{}^{\mathrm{n}}$ states in the ²⁰⁸Pb region are compared with theoretical predictions in order to analyze the dependence of the $\text{h}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ proton g-value on the core constitution. The variation of the g-values is systematically smaller than expected from first-order configuration mixing theory, if pure shell-model wave functions are assumed.     

The ã3A2 ← X̃1A1 absorption spectrum of thioformaldehyde: A vibrational and rotational analysis

The results of a vibrational and rotational analysis of the banded $\text{a}\text{?}{}^3\text{A}{}_2\text{←}\text{X}\text{?}{}^1\text{A}{}_1$ transition in $\text{CH}{}_2\text{S}\text{CD}{}_2\text{S}$ are presented. Only three of the six vibrational modes are active in the spectrum with $\text{ν′}{}_2\text{=}\text{1320}\text{1012}$, $\text{ν′}{}_3\text{=}\text{859}\text{798}$, and $\text{2ν′}{}_4\text{=}\text{711}\text{516}\text{cm}{}^{\mathrm{?1}}$. The spin forbidden transition gains intensity primarily by a mixing of the ${}^1\text{A}{}_1\text{(π}{}^1\text{,π)}$ and ${}^3\text{A}{}_2\text{(π}{}^1\text{,n)}$ states. This is confirmed by a rotational analysis of the 0₀⁰ band of both isotopes. The rotational analysis shows that the coupling in the $\text{a}\text{?}{}^3\text{A}{}_2$ state is near Hund's case b and that the spin constants are nearly 10 times greater than those observed for CH₂O. A $\text{CNDO}\text{2}$ calculation shows that this difference is due to the greater spin orbit coupling of S in CH₂S and to the smaller energy differences between the $\text{B}\text{?}{}^1\text{A}{}_1\text{(π}{}^1\text{,π)}$, $\text{b}\text{?}{}^3\text{A}{}_1\text{(π}{}^1\text{,π)}$, $\text{X}\text{?}{}^1\text{A}{}_1$, and the $\text{a}\text{?}{}^3\text{A}{}_2\text{(π}{}^1\text{,n)}$ states. The r₀ structure calculated from the rotational constants is $\text{r}{}_{\mathrm{<mtext>CS</mtext>}}\text{= 1.683}\text{A}\text{?}$, $\text{r}{}_{\mathrm{<mtext>CH</mtext>}}\text{= 1.082}\text{A}\text{?}$, β_HCH = 119.6°, and α (out of plane) = 16.0°. A simultaneous fit of the vibrational levels in ν′₄ of CH₂S and CD₂S to a double minimum potential function yielded a barrier to molecular inversion of 13 cm^?1 and an equilibrium out-of-plane angle of 15°.     

Rotational bands in 195, 197Tl

High-spin states in ^{195, 197}Tl have been populated with (α, xn) reactions and studied by means of in-beam γ-ray and e^? spectroscopic methods. Complementary studies of the decay of ^{195, 197}Pb to ^{195, 197}Tl have been carried out. Several new features have been observed in these nuclei. The $\text{9}\text{2}{}^{\mathrm{?}}$ bands of ^{195, 197}T1. extended to $\text{27}\text{2}{}^{\mathrm{(?)}}$ and $\text{29}\text{2}{}^{\mathrm{(?)}}$, respectively, show a quenching of energy spacings between the $\text{23}\text{2}{}^{\mathrm{?}}$, $\text{25}\text{2}{}^{\mathrm{?}}$, $\text{27}\text{2}{}^{\mathrm{(?}}$ and $\text{29}\text{2}{}^{\mathrm{(?}}$ states. This has been interpreted as resulting from the coupling of a $\text{h}{}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ proton to the ($\text{π}\text{h}{}^{\mathrm{?2}}{}_{\mathrm{<mtext>11</mtext><mtext>2</mtext>}}\text{)}{}_{\mathrm{8+,\; 10+}}$ configurations in the core nuclei ^{194, 196}Hg. Furthermore, positive-parity bands based on $\text{15}\text{2}{}^{\mathrm{+}}$ states were established up to the $\text{35}\text{2}{}^{\mathrm{(+)}}$ and $\text{29}\text{2}{}^{\mathrm{(+)}}$ states in ^{195, 197}Tl respectively. Probably these bands originate from the coupling of a h${}_{\mathrm{<mtext>9</mtext><mtext>2</mtext>}}$ proton to a broken neutron pair. This pair consists of a rotation-aligned $\text{i}{}_{\mathrm{<mtext>13</mtext><mtext>2</mtext>}}$ neutron and a low-j neutron in the $\text{P}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, $\text{P}{}_{\mathrm{<mtext>3</mtext><mtext>2</mtext>}}$ or $\text{f}{}_{\mathrm{<mtext>5</mtext><mtext>2</mtext>}}$ shell. It is known to constitute the 5^? bands in ^{194, 196}Hg.     

Measurement and interpretation of the 1-0 band of 14N16O at 1900 cm−1

The wavenumbers of the vibration rotation band lines of ¹⁴N¹⁶O are reported for the ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{-}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$, ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{-}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ and ${}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}\text{-}{}^2\text{Π}{}_{\mathrm{<mtext>1</mtext><mtext>2</mtext>}}$ subbands of the 1-0 transition in the infrared. The full set of spectroscopic constants for this band has been determined by direct approach using the analysis of Zare, Schmeltekopf, Harrop, and Albritton. In addition to the band origin ν₀ and the B, D, H constants for the lower and upper vibrational levels, the following spin-orbit coupling constants have been derived: $\text{A}\text{?}{}_0\text{= 123.02772 ± 0.00011}$ and $\text{A}\text{?}{}_1\text{= 122.78248 ± 0.00011}$ (in cm^?1). Apparent centrifugal corrections to these constants have been determined and the values obtained for them are $\text{A}\text{?}{}_{\mathrm{<mtext>D</mtext><mtext>0</mtext>}}\text{= (0.347573 ± 0.00051) × 10}{}^{\mathrm{?3}}$ and $\text{A}\text{?}{}_{\mathrm{<mtext>D</mtext><mtext>1</mtext>}}\text{= (0.337135 ± 0.00050) × 10}{}^{\mathrm{?3}}\text{cm}{}^{\mathrm{?1}}$. Λ-Type doubling constants evaluated by using both grating and tunable laser data are also reported.