低气压条件下的铁电体离子发射特性研究

以低气压条件下的铁电体离子发射特性为研究对象,通过结合高速相机、光谱的光学诊断和二维网格质点法耦合蒙特卡洛碰撞模型(PIC-MCC)的仿真模拟获得了锆钛酸铅(PZT)铁电体离子发射的主要成分、表面放电的发光及等离子体演化过程、离子的产生及离子电流形成机制,为进一步研究铁电体离子源奠定了基础。     

Photoluminescence properties of porous InP filled with ferroelectric polymers

Photoluminescence properties of porous InP are found to be strongly affected by infilling ferroelectric polymers. Based on the temperature- and excitation-power-dependent photoluminescence, the intensity suppression and blue shift of the near-band-edge emission are supposed to result from the passivation of surface states by introducing ferroelectric polymers. On the other hand, the significant enhancement of deep-level emission is caused by the increased concentration of phosphorus vacancies due to ion exchange when infilling the ferroelectric polymers into porous InP. The surface passivation of porous InP by ferroelectric polymers is useful for improving the performances of InP-based electronic and optoelectronic devices.     

Coulomb microexplosions of ferroelectric ceramics

Energetic neutral and extreme ultraviolet emission initiated by the dense plasma propagation along a ferroelectric surface has been found. It was shown that the emission of neutrals is characterized by a large divergence and velocities up to 7 x 10(7) cm/s. This phenomenon is explained by an extremely large electric field with amplitude > or =10(6) V/cm and rise time approximately 10(-10) s which appears at the plasma front due to the fast fall in the driving pulse. This electric field causes microexplosions of the ferroelectric surface due to inertia in the ion polarization response.     

Potential relief on the surface of polarized ferroelectric electrets from an analysis of the anomalous electron emission spectra

A technique is proposed for determining the specific features in the potential distribution over a free surface of polarized ferroelectric electrets from analyzing the anomalous electron emission spectra. This technique is applied to examine the potential distribution over the surface of a lead magnoniobate single crystal and ferroelectric ceramics. Reasoning from the results obtained for the lead magnoniobate crystal, the inference is drawn that the degree of perfection of surface layers of ferroelectric single crystals can be controlled using the anomalous electron emission spectra.     

Energetic electron emission from a ferroelectric sample during incomplete surface discharge

In this paper, the results of simplified analytical modeling and particle-in-cell numerical simulations of plasma formation and propagation along the surface of a ferroelectric sample under the application of a negative driving pulse to the rear solid electrode are presented. These models allow one to reproduce the main characteristics of the incomplete discharge. In particular, it is shown that the experimentally observed energetic electrons are related to the secondary emission electron acceleration in the sheath between the plasma and the ferroelectric surface. Also, simulation results show that secondary electron emission significantly decreases the surface plasma density while increasing its propagation velocity and that high desorption rate of the neutrals is required to sustain surface plasma formation.     

Electron emission from charged surfaces of ferroelectrics-electrets: Part 1. Properties of the electron emission

The present paper describes properties of the electron emission from negatively charged surfaces of poled ferroelectrics-electrets. This emission results from the irradiation of the surface with X-rays of weak intensity. It has been shown both experimentally and theoretically that the mechanism of its emergence differs from the photoemission mechanism, it rather roots in the ferroelectric state of the surface layer.     

Thermostimulated electron emission from polar cleavage of a triglycine sulfate crystal

This paper reports the results of experimental investigations into thermostimulated electron emission from the positive and negative cleavage surfaces of a ferroelectric triglycine sulfate crystal. It is shown that the current density j of emission from the negative surface is universally higher than that from the positive surface over the entire range from room temperature to the Curie point. The shape of the j(T) curves substantially depends on the degree of natural unipolarity of the studied samples. The results obtained are discussed in the framework of the mechanism of field electron emission from the surface electronic states.     

掺镧锆锡钛酸铅陶瓷极化强度变化量对电子发射电流强度的影响

铁电阴极因其优异的电子发射性能在高功率微波管的电子束源、平板显示技术以及宇航推进器等领域 有着广阔应用前景而日益受到人们的重视.大量研究表明,铁电阴极电子发射性能受阴极材料性能的影响. 在激励电场作用下,铁电阴极材料会产生表面非屏蔽电荷而引起极化强度的变化, 这表明铁电阴极电子发射性能可能与阴极材料的极化强度变化量存在着某种关系. 为研究阴极材料极化强度变化量对铁电阴极电子发射性能的影响,以掺镧锆锡钛酸铅铁电和反铁电陶瓷样品 作为阴极材料,通过正半周电滞回线测试得到阴极材料在不同电场强度下的极化强度变化量, 测量得到电子发射电流强度随激励电场的变化曲线,并分析了电子发射电流强度与极化强度变化量的关系. 结果表明,两种样品电子发射电流强度与极化强度变化量正相关.     

Mechanism of negative ion emission from surfaces of ferroelectrics

Experimental studies of the mechanism of negative ion and cluster ion emission from surfaces of ferroelectrics are described. The emission was produced by negative voltage pulses with the amplitude of about 400 V, with a rapid rise-time (below 10 ns) and a slow decay‐time (several μs). The pulses were applied between the back side of the ferroelectric sample and the metal tip touching the front emitting side. The surface of the ferroelectrics could be cleaned in situ by 1 keV Ar⁺ bombardment. The morphologic changes around the tip were observed with an atomic force microscope (AFM). Mostly negative ions and cluster ions were emitted and studied in our experiments. Positive ions were detected with much lower probability and are produced by an entirely different microscopic process than negative ions. Masses as well as energies of emitted ions were measured with a time-of-flight (TOF) spectrometer and compared with available spontaneous desorption (SD) spectra and Cs‐SIMS spectra in order to clarify the mechanism of the emission. The trajectory of ions emitted from the sample was studied by computer simulation. The conclusion of these studies is that the negative ion emission is caused by the Coulomb explosion of a polarization cloud rapidly formed at the front edge of the pulse. The explosion takes place in the vicinity of the tip-sample contact at distances several tens of μm from the contact where the stabilizing effect of the positively charged tip is already small.     

Low-voltage pulse exciting electron emission from ferroelectric copolymer film cathode: Role of film thickness and emission stability

Ferroelectric copolymer thin films P(VDF-TrFE) are used as a ferroelectric cathode for investigation of their electron emission properties. This ferroelectric copolymer films with different thicknesses are deposited by spin-coating method, and then the annealing process is carried out to improve the crystallinities of as-deposited copolymer films. The measurement results of ferroelectric electron emission showed that the copolymer P(VDF-TrFE) films had a desired ferroelectric electron emission ability excited at low-voltage pulse, and its peak emission current can reach to be ∼1.3 μA when the pulse voltage is 280 V. In addition, the effect of film thickness on electron emission property and emission stability of copolymer thin film P(VDF-TrFE) are discussed.