The physics behind the fizz in champagne and sparkling wines

Bubbles in a glass of champagne may seem like the acme of frivolity to most of people, but in fact they may rather be considered as a fantastic playground for any physicist. Actually, the so-called effervescence process, which enlivens champagne and sparkling wines tasting, is the result of the fine interplay between CO₂ dissolved gas molecules, tiny air pockets trapped within microscopic particles during the pouring process, and some both glass and liquid properties. Results obtained concerning the various steps where the CO₂ molecule plays a role (from its ingestion in the liquid phase during the fermentation process to its progressive release in the headspace above the tasting glass as bubbles collapse) are gathered and synthesized to propose a self-consistent and global overview of how gaseous and dissolved CO₂ impact champagne and sparkling wine science. Physicochemical processes behind the nucleation, rise, and burst of gaseous CO₂ bubbles found in glasses poured with champagne and sparkling wines are depicted. Those phenomena observed in close-up through high-speed photography are often visually appealing. I hope that your enjoyment of champagne will be enhanced after reading this fully illustrated review dedicated to the science hidden right under your nose each time you enjoy a glass of champagne.     

快速降压下Tween20 液滴真空闪蒸特性

为探究闪蒸喷雾冷却的微观机理, 设计并搭建了液滴悬挂式真空闪蒸实验装置, 利用可视化窗口探究Tween20 液滴闪蒸过程中的闪蒸特性及气泡生长机理. 液滴在快速降压过程中形态会经历气泡成核、气泡生长、伴随气泡生长、爆裂这四个阶段的变化, 并反复循环这一过程直至液滴稳定蒸发. 对于液滴温度的变化, 闪蒸室的终态压力起到了决定性的作用, 并且其终态温度随压力的升高明显上升. 同时通过液滴闪蒸过程形态图分析发现, 液滴在剧烈爆炸阶段其温度也发生明显下降; 在稳定蒸发阶段, 其温度也将开始稳定不变. 因此可知液滴的剧烈爆炸会带走其自身的大量热量. 而 Tween20 浓度对液滴温度的影响微乎其微, 但其会使液滴内气泡的初始成核时间发生明显滞后, 并抑制液滴内的气泡发生破裂.     

Flower-shaped structures around bubbles collapsing in a bubble monolayer

In this paper, high-speed macro-photography is used to investigate the dynamics of small bubbles collapsing at the free surface of a glass when filled with champagne. Immediately after the rupture of a bubble cap, adjoining bubbles are stretched toward the lowest part of the cavity left by the bursting bubble, leading to unexpected and short-lived flower-shaped structures. Our results strongly suggest stresses in the bubble cap of adjacent bubbles much higher than those observed around an isolated single collapsing cavity.     

Development of a compact CO2 sensor based on near-infrared laser technology for enological applications

This paper reports the development of an infrared laser spectrometer using commercial diode laser emitting at 2.68 μm. The instrument is designed to measure CO₂ concentrations above a glass poured with a sparkling liquid, such as beer or champagne in the present case. This spectrometer was developed in order to realize the cartography of CO₂ outgassing in the headspace above various glasses. We provide details of the instrument design and data processing. Absorption lines were carefully selected to minimize interferences from neighboring water vapor transitions. The instrument performance allows to measure ambient CO₂ concentrations so that one can be very confident in the CO₂ concentrations measurements above the glass. Some preliminary results on sparkling liquids such as beer and champagne are presented and compared to a model describing the flux of CO₂ discharging from glasses due to the contribution of bubbles.     

Effervescence in champagne and sparkling wines: From grape harvest to bubble rise

Bubbles in a glass of champagne may seem like the acme of frivolity to most of people, but in fact they may rather be considered as a fantastic playground for any fluid physicist. Under standard tasting conditions, about a million bubbles will nucleate and rise if you resist drinking from your flute. The so-called effervescence process, which enlivens champagne and sparkling wines tasting, is the result of the complex interplay between carbon dioxide (CO₂) dissolved in the liquid phase, tiny air pockets trapped within microscopic particles during the pouring process, and some both glass and liquid properties. In this tutorial review, the journey of yeast-fermented CO₂ is reviewed (from its progressive dissolution in the liquid phase during the fermentation process, to its progressive release in the headspace above glasses). The most recent advances about the physicochemical processes behind the nucleation, and rise of gaseous CO₂ bubbles, under standard tasting conditions, have been gathered hereafter. Let’s hope that your enjoyment of champagne will be enhanced after reading this tutorial review dedicated to the unsuspected physics hidden right under your nose each time you enjoy a glass of bubbly.     

High-speed imaging of ultrasonic emulsification using a water-gallium system

Aiming at elucidating ultrasonic emulsification mechanisms, the interaction between a single or multiple acoustic cavitation bubbles and gallium droplet interface was investigated using an high-speed imaging technique. To our best knowledge, the moment of emulsification and formation of fine droplets during ultrasound irradiation were observed for the first time. It was found that the detachment of fine gallium droplets occurs from the water-gallium interface during collapse of big cavitation bubbles. The results suggest that the maximum size of cavitation bubble before collapsing is of prime importance for emulsification phenomena. Previous numerical simulation revealed that the collapse of big cavitation bubble is followed by generation of high-velocity liquid jet directed toward the water-gallium interface. Such a jet is assumed to be the prime cause of liquid emulsification. The distance between cavitation bubbles and water-gallium interface was found to slightly affect the emulsification onset. The droplet fragmentation conditions are also discussed in terms of the balance between (1) interfacial and kinetic energies and (2) dynamic and Laplace pressure during droplet formation.     

Acoustic characteristics of bubble bursting at the surface of a high-viscosity liquid

An acoustic pressure model of bubble bursting is proposed.An experiment studying the acoustic characteristics of the bursting bubble at the surface of a high-viscosity liquid is reported.It is found that the sudden bursting of a bubble at the high-viscosity liquid surface generates N-shape wave at first,then it transforms into a jet wave.The fundamental frequency of the acoustic signal caused by the bursting bubble decreases linearly as the bubble size increases.The results of the investigation can be used to understand the acoustic characteristics of bubble bursting.     

Acoustic cavitation in 1-butyl-3-methylimidazolium bis(triflluoromethyl-sulfonyl)imide based ionic liquid

In this work, a comparison between the temperatures/pressures within acoustic cavitation bubble in an imidazolium-based room-temperature ionic liquid (RTIL), 1-butyl-3-methylimidazolium bis(triflluoromethyl-sulfonyl)imide ([BMIM][NTf₂]), and in water has been made for a wide range of cavitation parameters including frequency (140–1000 kHz), acoustic intensity (0.5–1 W cm⁻²), liquid temperature (20–50 °C) and external static pressure (0.7–1.5 atm). The used cavitation model takes into account the liquid compressibility as well as the surface tension and the viscosity of the medium. It was found that the bubble temperatures and pressures were always much higher in the ionic liquid compared to those predicted in water. The valuable effect of [BMIM][NTf₂] on the bubble temperature was more pronounced at higher acoustic intensity and liquid temperature and lower frequency and external static pressure. However, confrontation between the predicted and the experimental estimated temperatures in ionic liquids showed an opposite trend as the temperatures measured in some pure ionic liquids are of the same order as those observed in water. The injection of liquid droplets into cavitation bubbles, the pyrolysis of ionic liquids at the bubble-solution interface as well as the lower number of collapsing bubbles in the ionic liquid may be the responsible for the lower measured bubble temperatures in ionic liquids, as compared with water.     

Sonoluminescence and dynamics of cavitation bubble populations in sulfuric acid

The detailed link of liquid phase sonochemical reactions and bubble dynamics is still not sufficiently known. To further clarify this issue, we image sonoluminescence and bubble oscillations, translations, and shapes in an acoustic cavitation setup at 23 kHz in sulfuric acid with dissolved sodium sulfate and xenon gas saturation. The colour of sonoluminescence varies in a way that emissions from excited non-volatile sodium atoms are prominently observed far from the acoustic horn emitter (“red region”), while such emissions are nearly absent close to the horn tip (“blue region”). High-speed images reveal the dynamics of distinct bubble populations that can partly be linked to the different emission regions. In particular, we see smaller strongly collapsing spherical bubbles within the blue region, while larger bubbles with a liquid jet during collapse dominate the red region. The jetting is induced by the fast bubble translation, which is a consequence of acoustic (Bjerknes) forces in the ultrasonic field. Numerical simulations with a spherical single bubble model reproduce quantitatively the volume oscillations and fast translation of the sodium emitting bubbles. Additionally, their intermittent stopping is explained by multistability in a hysteretic parameter range. The findings confirm the assumption that bubble deformations are responsible for pronounced sodium sonoluminescence. Notably the observed translation induced jetting appears to serve as efficient mixing mechanism of liquid into the heated gas phase of collapsing bubbles, thus potentially promoting liquid phase sonochemistry in general.     

An alternative technique for determining the number density of acoustic cavitation bubbles in sonochemical reactors

The present paper introduces a novel semi-empirical technique for the determination of active bubbles’ number in sonicated solutions. This method links the chemistry of a single bubble to that taking place over the whole sonochemical reactor (solution). The probe compound is CCl₄, where its eliminated amount within a single bubble (though pyrolysis) is determined via a cavitation model which takes into account the non-equilibrium condensation/evaporation of water vapor and heat exchange across the bubble wall, reactions heats and liquid compressibility and viscosity, all along the bubble oscillation under the temporal perturbation of the ultrasonic wave. The CCl₄ degradation data in aqueous solution (available in literature) are used to determine the number density through dividing the degradation yield of CCl₄ to that predicted by a single bubble model (at the same experimental condition of the aqueous data). The impact of ultrasonic frequency on the number density of bubbles is shown and compared with data from the literature, where a high level of consistency is found.     

New insights into the mechanisms of ultrasonic emulsification in the oil–water system and the role of gas bubbles

Ultrasonic emulsification (USE) assisted by cavitation is an effective method to produce emulsion droplets. However, the role of gas bubbles in the USE process still remains unclear. Hence, in the present paper, high-speed camera observations of bubble evolution and emulsion droplets formation in oil and water were used to capture in real-time the emulsification process, while experiments with different gas concentrations were carried out to investigate the effect of gas bubbles on droplet size. The results show that at the interface of oil and water, gas bubbles with a radius larger than the resonance radius collapse and sink into the water phase, inducing (oil–water) blended liquid jets across bubbles to generate oil-in-water-in-oil (O/W/O) and water-in-oil (W/O) droplets in the oil phase and oil-in-water (O/W) droplets in the water phase, respectively. Gas bubbles with a radius smaller than the resonance radius at the interface always move towards the oil phase, accompanied with the generation of water droplets in the oil phase. In the oil phase, gas bubbles, which can attract bubbles nearby the interface, migrate to the interface of oil and water due to acoustic streaming, and generate numerous droplets. As for the gas bubbles in the water phase, those can break neighboring droplets into numerous finer ones during bubble oscillation. With the increase in gas content, more bubbles undergo chaotic oscillation, leading to smaller and more stable emulsion droplets, which explains the beneficial role of gas bubbles in USE. Violently oscillating microbubbles are, therefore, found to be the governing cavitation regime for emulsification process. These results provide new insights to the mechanisms of gas bubbles in oil–water emulsions, which may be useful towards the optimization of USE process in industry.     

Cavitation bubble behavior and bubble–shock wave interaction near a gelatin surface as a study of in vivo bubble dynamics

The collapse of a single cavitation bubble near a gelatin surface, and the interaction of an air bubble attached to a gelatin surface with a shock wave, were investigated. These events permitted the study of the behavior of in vivo cavitation bubbles and the subsequent tissue damage mechanism during intraocular surgery, intracorporeal and extracorporeal shock wave lithotripsy. Results were obtained with high-speed framing photography. The cavitation bubbles near the gelatin surface did not produce significant liquid jets directed at the surface, and tended to migrate away from it. The period of the motion of a cavitation bubble near the gelatin surface was longer than that of twice the Rayleigh's collapse time for a wide range of relative distance, L/R_max, excepting for very small L/R_max values (L was the stand-off distance between the gelatin surface and the laser focus position, and R_max was the maximum bubble radius). The interaction of an air bubble with a shock wave yielded a liquid jet inside the bubble, penetrating into the gelatin surface. The liquid jet had the potential to damage the gelatin. The results predicted that cavitation-bubble-induced tissue damage was closely related to the oscillatory bubble motion, the subsequent mechanical tissue displacement, and the liquid jet penetration generated by the interaction of the remaining gas bubbles with subsequent shock waves. The characteristic bubble motion and liquid jet formation depended on the tissue's mechanical properties, resulting in different damage mechanisms from those observed on hard materials.     

Universal scaling law for jets of collapsing bubbles

Cavitation bubbles collapsing and rebounding in a pressure gradient ?p form a "microjet" enveloped by a "vapor jet." This Letter presents unprecedented observations of the vapor jets formed in a uniform gravity-induced ?p, modulated aboard parabolic flights. The data uncover that the normalized jet volume is independent of the liquid density and viscosity and proportional to ζ ≡ |?p|R(0)/Δp, where R(0) the maximal bubble radius and Δp is the driving pressure. A derivation inspired by "Kelvin-Blake" considerations confirms this law and reveals its negligible dependence of surface tension. We further conjecture that the jet only pierces the bubble boundary if ζ ? 4 × 10(-4).     

过冷沸腾中的局域气泡和射流的动态行为

本文以10 mm直径加热钢管为研究对象,通过大量可视化的实验研究,对核态过冷沸腾中的气泡动力学行为以及射流现象进行了描述和分析。在实验中我们观察到泡顶射流和核态射流的竞争,双射流,“液洞”现象等一些特殊的沸腾现象。射流的泵吸作用、汽泡表面相变换热、Marangoni效应等是导致射流和气泡结构演化的根本原因。     

气泡在自由液面破碎后的射流断裂现象研究

在势流假设下, 考虑表面张力以及黏性修正, 建立自由液面在气泡破碎后全非线性运动的数值模型, 给出射流断裂和水滴撕裂的数值处理方法. 同时进行上浮气泡在自由液面破裂的实验研究, 数值解与实验值符合良好.为了研究自由液面在气泡破碎后的运动学机理和规律, 运用开发的程序研究了不同尺寸气泡破碎后的动态特性, 包括从气泡底部顶起的射流、射流断裂以及水滴分裂等复杂的物理现象, 总结了从射流上撕裂出的第一个水滴尺寸、撕裂时间以及最大射流速度的变化规律. 最后讨论了雷诺数与韦伯数对气泡破碎后自由液面运动的影响. 关键词： 气泡 自由液面 破碎 断裂     

Numerical simulations of the aspherical collapse of laser and acoustically generated bubbles

The details of nonlinear axisymmetric oscillations and collapse of bubbles subject to large internal or external pressure disturbances, are studied via a boundary integral method. Weak viscous effects on the liquid side are accounted for by integrating the equations of motion across the boundary layer that is formed adjacent to the interface. Simulations of single-cavitation bubble luminescence (SCBL) and single-bubble sonoluminescence (SBSL) are performed under conditions similar to reported experimental observations, aiming at capturing the details of bubble collapse. It is shown that any small initial deviation from sphericity, modeled through a small initial elongation along the axis of symmetry, may result in the formation and impact of two counter-propagating jets during collapse of the bubble, provided the amplitude of the initial disturbance is large enough and the viscosity of the surrounding fluid is small enough. Comparison between simulations and experimental observations show that this is the case for bubbles induced via a nano-second laser pulse (SCBL) during a luminescence event. In a similar fashion, simulations show that loss of sphericity accompanied with jet formation and impact during collapse is also possible with acoustically trapped bubbles in a standing pressure wave (SBSL), due to the many afterbounces of the bubble during its collapse phase. In both cases jet impact occurs as a result of P(2) growth in the form of an afterbounce instability. When the sound amplitude is decreased or liquid viscosity is increased the intensity of the afterbounce is decreased and jet impact is suppressed. When the sound amplitude is increased jet formation is superceded by Rayleigh-Taylor instability. In the same context stable luminescence is quenched in experimental observations. In both SCBL and SBSL simulations the severity of jet impact during collapse is quite large, and its local nature quite distinct. This attests to the fact that it is an energy focusing mechanism whose importance in generating the conditions under which a luminescence event is observed should be further investigated.     

流体黏性及表面张力对气泡运动特性的影响

基于气泡边界层理论,引入黏性修正,采用边界积分法,考虑黏性效应和表面张力在单气泡以及双气泡耦合作用过程中的影响.首先将建立的数值模型与Rayleigh-Plesset的解析解进行对比,发现二者符合良好,验证了数值模型的有效性;在此基础上,建立考虑流体弱黏性效应的双气泡耦合模型,研究流体黏性和表面张力作用下,气泡表面变形、射流速度、流场能量转换等物理量的变化规律;最后研究雷诺数和韦伯数对于气泡脉动特性的影响规律.结果表明,流体黏性会抑制气泡脉动和气泡射流发展,降低气泡半径和射流速度;表面张力不改变气泡脉动幅值,但缩短了脉动周期,提升气泡势能.     

Comparative visualized investigation of impact-driven high-speed liquid jets injected in submerged water and in ambient air

This paper is a comparative study on the characteristics of high-speed liquid jets injected in surrounding water and air using shadowgraph technique. One of the main objectives is to investigate the effects of liquid’s physical properties, used to generate the high-speed liquid jets, on jet generation’s characteristics. Moreover, comparative investigations on effects of those liquid jets after injected in water and air are reported. The high-speed liquid jets were generated by the impact of a projectile launched by a horizontal single-stage power gun. The impact-driven high-speed liquid jets were visualized by shadowgraph technique and images were recorded by a high-speed digital video camera. The process of impact-driven high-speed liquid jet injection in air and water, oblique shock waves, jet-induced shock waves, shock waves propagation, the bubble behavior, bubble collapse-induced rebound shock waves and bubble cloud regeneration were clearly observed. It was found that different properties of liquid (surface tension and kinematic viscosity) affect the jet maximum velocity and shape of the jet. Bubble behaviors were only found for the jet injected in water. From the shadowgraph images, it is found that the maximum average jet velocity, expansion and contraction velocities of bubble in axial direction increase when the value of the multiplied result of surface tension by kinematic viscosity increases. Therefore, surface tension and kinematic viscosity are the significant physical properties that affect characteristics of high-speed liquid jets.     

Dynamics of laser-induced cavitation bubble during expansion over sharp-edge geometry submerged in liquid – an inside view by diffuse illumination

Laser ablation in liquids is growing in popularity for various applications including nanoparticle production, breakdown spectroscopy, and surface functionalization. When laser pulse ablates the solid target submerged in liquid, a cavitation bubble develops. In case of “finite” geometries of ablated solids, liquid dynamical phenomena can occur inside the bubble when the bubble overflows the surface edge. To observe this dynamics, we use diffuse illumination of a flashlamp in combination with a high-speed videography by exposure times down to 250 ns. The developed theoretical modelling and its comparison with the experimental observations clearly prove that this approach widens the observable area inside the bubble. We thereby use it to study the dynamics of laser-induced cavitation bubble during its expansion over a sharp-edge (“cliff-like” 90°) geometry submerged in water, ethanol, and polyethylene glycol 300. The samples are 17 mm wide stainless steel plates with thickness in the range of 0.025–2 mm. Bubbles are induced on the samples by 1064-nm laser pulses with pulse durations of 7–60 ns and pulse energies of 10–55 mJ. We observe formation of a fixed-type secondary cavity behind the edge where low-pressure area develops due to bubble-driven flow of the liquid. This occurs when the velocity of liquid overflow exceeds ~20 m s⁻¹. A re-entrant liquid injection with up to ~40 m s⁻¹ velocity may occur inside the bubble when the bubble overflows the edge of the sample. Formation and characteristics of the jet evidently depend on the relation between the breakdown-edge offset and the bubble energy, as well as the properties of the surrounding liquid. Higher viscosity of the liquid prevents the generation of the jet.