激光热诱导PbS纳米微粒的自陷、衍射和自散焦现象

用波长为488nm的氩离子激光与聚乙烯吡咯烷酮(PVP)修饰的PbS纳米微粒水溶胶作用,观察到了样品的自陷、衍射和自散焦现象,样品的折射率为负。测量了自陷阈值功率,计算了样品的非线性折射率n2。样品响应时间为11.86ms,且对488nm波长的光有吸收,说明样品的上述现象主要是由激光热诱导折射率的改变所引起的。     

激光器件 激光安全与防护

TN24 2005053373 激光防护塑料材料的研制=Study of laster protective mate- rials[刊,中]／王庭慰(南京工业大学材料科学与工程学院． 江苏,南京(210009)),花超…∥激光杂志．-2005,26 (2)．-75-76 对激光吸收剂IR1060、530、580的激光吸收进行了比 较,并确定其在材料中的比例。以聚碳酸酯为基材,掺杂 激光吸收剂IR1060、530、580制备了防波长为,530nm和1060 nm激光、眩光的激光防护材料,并对其光学密度、抗激光     

防激光、防眩光PMMA材料的研制

以聚甲基丙烯酸甲酯为基材,分别以激光吸收剂A和激光吸收剂B作为功能添加剂,制备了能有效地吸收530nm、1060nm波长激光和500～580nm波长眩光的防激光、防眩光PMMA材料。对其防激光、防眩光的性能、可见光透过率和力学性能进行了测试和分析。研究结果表明,实验所制得的防激光、防眩光PMMA材料在530nm波长处的透过率为0.01%,在1060nm波长处的透过率为0.02%,在500～580nm波长范围内该PMMA材料的平均透过率为0.1%左右。     

C60高聚物复合固体材料的反饱和吸收过程研究

本文报导了新型材料C_(60)α-甲基苯乙烯/苯乙烯共聚物薄板的制作,并利用530nm,10ns激光研究此固体材料的激光透过特性.观测到反饱和吸收过程,即实现了光限制效应.     

偶氮接枝的聚氨酯薄膜光谱响应特性的实验研究

利用旋涂法，通过接枝共聚的方法制备了具有偶氮侧基的聚氮酯高分子聚合物薄膜。并利用二倍频YAG激光（532nm）作为激发光，白光光源作为参考光，在室温下测试了该薄膜在激发光作用前后的吸收光谱，发现该薄膜在430nm-530nm内有较强的吸收。以及随着激光能量的增大和撤去激发光后，随着无光照时间的延长，360nm与500nm波长处吸收强度的变化趋势。     

偶氮接枝的聚氨酯薄膜作为光存储介质的实验研究

利用旋涂法，通过接枝共聚方法制备具有偶氮侧基的聚氨酯高分子聚合物薄膜。利用二倍频YAG激光(532nm)作为激发光，白光光源作为参考光，在室温下测试了该薄膜在激发光作用前后的吸收光谱，发现该薄膜在430一530nm内有较强的吸收。最后给出激发光强度的增大和撤去激发光后，随着无光照时间的延长，380nm与520nm波长处吸收强度的变化趋势。     

激光防护材料注塑加工工艺的研究

采用聚碳酸酯为基材,掺杂激光吸收剂制备了防530nm和1060nm波长激光的防护材料,通过对加工温度和混合料在料筒中停留时间的研究,确定了材料的加工温度为280℃,混合料在料筒中的时间为3min,确定了防护材料的加工工艺条件,并对其光学密度、激光防护能量、可见光透过率和抗冲击强度进行了测试。结果表明防护材料在530nm和1060nm波长的光密度大于4,其防激光能量达150mJ,可见光透过率为17%,抗冲击强度高,完全可以满足一般激光防护材料的要求。     

金复合纳米微粒的消光特性

基于Mie光散射理论,研究了金壳介质芯的金复合纳米球壳微粒在光散射与吸收中的消光特性.对微粒增大时的多极子特性以及内半径变动时共振峰的移动作了计算和分析,证实了共振峰位置随内外半径比增大而增大的规律.还对纯金纳米微粒的多极子特性作了计算,并讨论了总消光效率中散射和吸收各自的贡献.     

激光对PbS破坏作用的实验研究

PbS是一种重要的红外探测器材料。激光对PbS破坏作用的研究在军事和商业领域都有着重要的意义。利用反射光能量法对半导体材料PbS进行了激光损伤实验。通过对损伤过程的实时监测,分析激光辐照PbS的热学过程,并得到1064nm激光对半导体材料PbS的激光损伤阈值。     

通过飞秒泵浦探测技术研究PbS纳米颗粒的激发态瞬态动力学过程

利用飞秒泵浦探测技术研究了PbS半导体纳米颗粒复合的SiO₂溶胶凝胶薄膜的瞬态动力学过程。通过改变激发探测波长和激发光强度,研究引起PbS半导体纳米颗粒的非线性吸收的两种机制。当激发探测波长选在激子吸收峰附近(620nm)时,由于激子的饱和吸收引起的光致漂白,当激发波长选在激子能态的低能侧(753,800nm),同时观察到激子的饱和吸收和双激子效应引起的光致吸收。研究了激子的饱和吸收和双激子效应引起的激发态吸收随激发态电子-空穴对浓度的变化关系,表明双激子效应与载流子浓度有很大关系。在高激发强度下,双激子效应引起的诱导吸收远远大于激子跃迁引起的光致漂白,双激子效应在非线性吸收中起着决定性作用。     

稠苯芳杂环及其烷基质子化学位移的计算

本文提出了予测稠苯芳杂环及其烷基链上质子化学位移的计算方法。 将稠苯芳杂环化合物用凯库勒式表示,计算式为为需考虑的苯环内的乙烯基效应。σ_mi,ci为各苯环的环流效应。σ_1,Hc为各芳杂环的屏蔽效应,对杂环上质子它就是该单独芳杂环上相应质子的δ值,对苯环上质子要将它分解为各结构因素的效应,即:σ_1,He=(1/2)^d-1δ_x=y(或σ_z)+σ_c-c·σ_m,H. σ_x-y与σ_z为杂原子或其基团的屏蔽效应,σ_c=c为存在于芳杂环中的乙烯基的效应,σ_m,Hc为芳杂环的环流效应,d为对不同质子所考虑的键数。有取代基时需考虑取代基的效应。计算环上烷基质子的公式为:δ=σ_p,CH3+ασ_c,CH3+βσ_t,CH3+σ_l,G σ_l,G为稠苯芳杂环基的某级效应。     

Structural phase transitions at clean and metal-covered Si(111) surfaces investigated by RHEED spot analysis

Structural phase transitions between various kinds of superlattice structures formed on a Si(111) surface have been investigated by spot analysis of reflection high-energy electron diffraction (RHEED). Reversible transitions induced by temperature changes and irreversible ones induced by metal depositions were observed. Detailed discussions on the dynamics of the phase transitions are made by quantitative analyses of integrated spot intensity and profile. For a phase transition of 7′7  1′1 structures on a clean Si(111) surface, a hysteresis with temperature difference of 5°C. between in heating and cooling processes was found in the spot intensity change, indicating a first-order transition. Hysteresis was hardly recognized, on the other hand, for transitions of Au-induced superstructures (5×2-Au or ×-Au)  1×1-Au. The spot profiles were found to be broadened during the transition of Si(111)-×-Au  1×1-Au, which was a signature of a continuous transition, while the profiles remained unchanged during the transitions of the 7×7  1×1 and 5×2-Au  1×1-Au phases. Structural conversions induced by In adsorption on the Si(111) surface kept at constant temperatures were also analyzed. The conversions at room temperature were totally dependent on the initial substrate surface structures; the 7×7 surface did not show any structural conversion with In adsorption, while the ×-In surface successively converted to a 2×2 and a × phase with coverage increase. The structural transitions at elevated temperatures were sensitively dependent on the temperatures. Sequences of transitions among the 7×7, 4×1, ×, 1×, and ×4 were quantitatively revealed as changes in RHEED spot intensity.     

ErP5O14非晶玻璃的红外量子剪裁

研究了Er_1.0P₅O₁₄铒非晶玻璃的红外量子剪裁现象. 从吸收谱和激发光谱的计算比较中肯定了Er_1.0P₅O₁₄非晶 玻璃的1537.0 nm红外荧光为多光子量子剪裁荧光. 从Er_1.0P₅O₁₄非晶玻璃的可见和红外荧光发射光谱中发现激发²H_11/2, ⁴G_11/2和⁴G_9/2能级所导致的⁴I_13/2→⁴I_15/2量子剪裁红外荧光很强;基于自发辐射速率、无辐射弛豫速率和能量传递速率等参数的计算,对其量子剪裁机理进行了分析.发现起源于基态的强下转换能量传递{²H_11/2→⁴I_9/2,⁴I_15/2→⁴I_13/2},{⁴G_11/2→⁴I_13/2, ⁴I_15/2→²H_11/2},{⁴G_9/2→⁴F_7/2,⁴I_15/2→⁴I_13/2}和{⁴G_9/2→⁴I_13/2, ⁴I_15/2→²H_11/2}是导致Er_1.0P₅O₁₄非晶玻璃具有强的三光子和四光子量子剪裁红外荧光的原因.研究结果对改善太阳能电池效率有一定意义.     

1-forms over the moduli space of irreducible connections defined by the spectrum of Dirac operators

Let (P) be the moduli space of irreducible connections of a G-principal bundle P over a closed Riemannian spin manifold M. Let D_A be the Dirac operator of M coupled to a connection A of P and f a smooth function on M. We consider a smooth variation A(u) of A with tangent vector ω and denote T_ω:= (D_A(u)−f) (u=0. The coefficients of the asymptotic expansion of trace (T_ω · e^-t(D_A−f)2) near t=0 define 1-forms a^(k)_f, K=0, 1, 2, … on (P). In this paper we calculate aa⁽⁰⁾_f, a⁽¹⁾_f, a⁽²⁾_f and study some of their properties. For instance using the 1-form a⁽²⁾_f for suitable functions f we obtain a foliation of codimension 5 of the space of G-instantons of S⁴.     

Phase formation and magnetic properties of Nd2Fe14B-type Nd16Co76B8−xCx alloys and their hydrides

An attempt is made to synthesize Nd₂Co₁₄C compound by mechanical alloying Nd₁₆Co₇₆B_8−xC_x (0x8) alloys and subsequent annealing. Phase formation and magnetic properties of Nd₂Fe₁₄B-type Nd₁₆Co₇₆B_8−xC_x alloys and their hydrides are investigated. The Nd₂Co₁₄(B,C) phase with Nd₂Fe₁₄B-type structure is formed for Nd₁₆Co₇₆B_8−xC_x (0x7) alloys, while NdCo₇C_δ phase with TbCu₇-type structure is observed in Nd₁₆Co₇₆C₈ alloy. The lattice parameter c of the Nd₂Co₁₄(B,C) phase decreases with increasing the carbon content. A limit volume of the unit cell to form the Nd₂Fe₁₄B-type structure is estimated to be 0.870 nm³. The spin-reorientation temperature T_SR increases with increasing the carbon content, due to an enhancement of magnetocrystalline anisotropy caused by carbon substitution for boron. After hydrogenation, the lattice expansion is observed for Nd₁₆Co₇₆B_8−xC_x (0x7) alloys. The spin-reorientation temperature of Nd₁₆Co₇₆B_8−xC_xH_y (0x7) is much lower than that of the host alloys. Some structural and magnetic properties of hypothetic Nd₂Co₁₄C and Nd₂Co₁₄CH_y compounds are estimated by extrapolation.