Low-frequency noise characteristics of InGaAs quantum-dot infrared photodetector structures grown by atomic layer molecular-beam epitaxy

Optical and electrical characteristics of n–i–n InGaAs/GaAs quantum-dot (QD) infrared photodetectors are reported. In particular, the low-frequency excess electrical noise is measured at room temperature and analyzed in conjunction with the optical properties of the structure. The three stackings of QD were formed by atomic layer molecular-beam epitaxy and highly Si-doped, and AlGaAs current-blocking layer was also included to reduce the dark current. The power-dependent photoluminescence (PL) spectra at 300 K indicates that there are at least three confined states in the QD. The photo-current was observed only at low temperatures (10 K) at wavelengths between 3 and 9 μm with three peaks. The dark current was relatively large and asymmetric at low temperatures. At room temperature the dark current was symmetric and ohmic. The 1/f-like low-frequency noise spectral density exhibited an almost quadratic current dependence giving a large value of the Hooge parameter of the order of unity. The relatively low-growth temperature for the AlGaAs current blocking layer and the high doping at the quantum dots seem to generate a considerable amount of defects and result in low-temperature photodetection and a large low-frequency noise density.     

Simulation studies of current transport in metal–insulator–semiconductor Schottky barrier diodes

The current–voltage characteristics of Schottky diodes with an interfacial insulator layer are analysed by numerical simulation. The current–voltage data of the metal–insulator–semiconductor Schottky diode are simulated using thermionic emission diffusion (TED) equation taking into account an interfacial layer parameter. The calculated current–voltage data are fitted into ideal TED equation to see the apparent effect of interfacial layer parameters on current transport. Results obtained from the simulation studies shows that with mere presence of an interfacial layer at the metal–semiconductor interface the Schottky contact behave as an ideal diode of apparently high barrier height (BH), but with same ideality factor and series resistance as considered for a pure Schottky contact without an interfacial layer. This apparent BH decreases linearly with decreasing temperature. The effects giving rise to high ideality factor in metal–insulator–semiconductor diode are analysed. Reasons for observed temperature dependence of ideality factor in experimentally fabricated metal–insulator–semiconductor diodes are analysed and possible mechanisms are discussed.     

Quantum-dot superluminescent diode: A proposal for an ultra-wide output spectrum

We propose a novel superluminescent diode (SLD) with a quantum dot (QD) active layer, which should give a wider output spectrum than a conventional quantum well SLD. The device makes use of inhomogeneous broadness of gain spectrum resulting from size inhomogeneity of self-assembled quantum dots grown by Stranski– Krastanow mode. Taking a design made out in the In_xGa_1-xAs/GaAs system for example, the spectrum characteristics of the device are simulated realistically, 100–200 nm full width of half maximum of output spectrum can be obtained. The dependence of the output spectrum on In composition, size distribution and injection current of the dots active region is also elaborated.     

Experimental and theoretical study of the quantum-confined Stark effect in a single InGaN/GaN quantum dot under applied vertical electric field

We present a study of the effect of externally applied vertical electric field on the optical properties of single InGaN/GaN quantum dots via microphotoluminescence spectroscopy. This is achieved by incorporating the quantum dot layer in the intrinsic region of a p–i–n diode structure. We observe a large blue energy shift of 60 meV, which is explained by the partial compensation of the internal piezoelectric field. The energy shift dependence on the applied field allows the determination of the vertical component of the permanent dipole and the polarizability. We also present theoretical modelling of our results based on atomistic semi-empirical tight-binding simulations. A good quantitative agreement between the experiment and the theory is found.     

AC shot noise through a vibrating quantum dot

In this paper we investigate the joint effects of the electron-phonon interaction and an external alternating (ac) gate voltage on the spectral density of shot noise through a vibrating quantum dot system, by applying the Lang-Firsov canonical transformation and the Keldysh nonequilibrium Green's function (NGF) technique. We find that the effects of the electron-phonon and electron-photon interaction on the differential shot noise are different. The main resonant peak of the differential shot noise is decreased only when a time-dependent gate voltage is imposed on quantum dot. With the ac field amplitude increasing, the main resonant peak of the differential shot noise decreases. The Fano factor of the system, which exhibits the deviation of shot noise from the Schottky formula, is also studied. Super-Poissonian shot noise appears due to the photon absorption (emission) processes in the low bias voltage region.     

Optical line-shape and the time-domain photon echo measurement in semiconductor quantum dots

It is shown theoretically that, because of the characteristic line-shape of the electronic spectral density, the experimental photon-echo signal, giving the dephasing of the electronic state of a quantum dot, should be modulated in time quasi-periodically. This suggestion is demonstrated numerically for the case of InAs quantum dots for several temperatures of the sample. A comparison with the recent experiments on CdSe nanocrystals is presented. The theoretical argumentation is based on the recent theoretical calculation of the homogeneous optical line-shape based on the multiple electron–LO–phonon scattering in quantum dots.     

Polarization spectroscopy of positive and negative trions in an InAs quantum dot

Using polarization-sensitive photoluminescence and photoluminescence excitation spectroscopy, we study single InAs/GaAs self-assembled quantum dots. The dots were embedded in an n-type, Schottky diode structure allowing for control of the charge state. We present here the exciton, singly charged exciton (positive and negative trions), and the twice negatively charged exciton. For non-resonant excitation below the wetting layer, we observed a large degree of polarization memory from the radiative recombination of both the positive and negative trions. In excitation spectra, through the p-shell, we have found several sharp resonances in the emission from the s-shell recombination of the dot in all charged states. Some of these excitation resonances exhibit strong coulomb shifts upon addition of charges into the quantum dot. One particular resonance of the negatively charged trion was found to exhibit a fine structure doublet under circular polarization. This observation is explained in terms of resonant absorption into the triplet states of the negative trion.     

Spectral response of the intrinsic region of a GaAs–InAs quantum dot solar cell considering the absorption spectra of ideal cubic dots

Recently, attempts have been made by some researchers to improve the efficiency of quantum dot solar cells by incorporating different types of quantum dots. In this paper, the photocurrent density has been obtained considering the absorption spectra of ideal cubic dots. The effects of quantum dot size dispersion on the spectral response of the intrinsic region of a GaAs–InAs quantum dot solar cell have been studied. The dependence of the spectral response of this region on the size of quantum dots of such solar cell has also been investigated. The investigation shows that for smaller quantum dot size dispersion, the spectral response of the intrinsic region of the cell increases significantly. It is further observed that by enlarging the quantum dot size it is possible to enhance the spectral response of such solar cells as it causes better match between absorption spectra of the quantum dots and the solar spectrum. These facts indicate the significant role of quantum dot size and size dispersion on the performance of such devices. Also, the power conversion efficiency of such solar cell has been studied under 1 sun, AM 1.5 condition.     

Spin-flip shot noise in a quantum dot coupled to carbon nanotube terminals responded by a rotating magnetic field

We have investigated the spectral density of shot noise of the system with a quantum dot (QD) coupled to two single-wall carbon nanotube terminals, where a rotating magnetic field is applied to the QD. The carbon nanotube (CN) terminals act as quantum wires which open quantum channels for electrons to transport through. The shot noise and differential shot noise exhibit novel behaviors originated from the quantum nature of CNs. The shot noise is sensitively dependent on the rotating magnetic field, and the differential shot noise exhibits asymmetric behavior versus source-drain bias and gate voltage. The Fano factor of the system exhibits the deviation of shot noise from the Schottky formula. The super-Poissonian and sub-Poissonian shot noise can be achieved in different regime of source-drain bias.     

InAs–GaAs self-assembled quantum dot lasers: physical processes and device characteristics

The gain characteristics of InAs–GaAs self-assembled quantum dot lasers are studied using two complementary techniques. The modal gain is derived from a measurement of the normal incidence, inter-band photoconductivity. For a device containing a single layer of dots the maximum modal gain of the ground state transition is found to be insufficient for lasing action. As a consequence lasing occurs for excited state transitions, which have a larger oscillator strength, with the precise transition being dependent upon the device cavity length. The second technique uses the Hakki–Paoli method to determine the spectral and current dependence of the gain. A quasi-periodic modulation of the below threshold gain is observed. This modulation is shown to be responsible for the form of the lasing spectra, which consist of groups of lasing modes separated by non-lasing spectral regions. Possible mechanisms for this behaviour are discussed.     

Optimization of a schottky barrier mixer diode in the submillimeter wave region

We have designed a mixer Schottky barrier diode (SBD) for use in the submillimeter wave region with a structure optimized for minimum noise temperature. The dependence of mixer noise temperature upon thickness and doping density of the epitaxial layer and diode diameter of SBDs was simulated within the framework of existing theories. Special care was taken to formulate the SBD current-voltage and capacitance-voltage relations in a way that correctly describes the behavior of real SBDs.     

Millisecond fluorescence in InAs quantum dots embedded in AlAs

The temperature dependence of steady-state and time-resolved photoluminescence from self-assembled InAs quantum dots embedded in AlAs has been studied. Millisecond-long nonexponential photoluminescence decay is observed in the temperature range of 4.2–50 K. At higher temperatures, the decay time decreases to a few nanoseconds. The experimental results are interpreted using a model of singlet–triplet splitting of exciton levels in small dots in a dense quantum dot system with local carrier transfer between dots.     

Dynamical control of electron states in double quantum dot

Controllable electron dynamics in a double quantum dot has been investigated theoretically in the presence of strong sinusoidal electric field and monotonically varied bias voltage, applied to the structure. It is shown that the possibility to create controllable electron states strongly depends on the relation between Rabi frequency and typical reciprocal time of bias change. As follows from theoretical analysis, when time of bias change is the biggest temporal parameter of the problem, electron density can be fully relocated from one quantum dot to another under the action of both resonant sinusoidal field and slowly varied voltage. When the period of Rabi oscillations is much greater than the time of bias change, electron tunneling between two neighboring quantum dots becomes suppressed. In this case electron density stays in the quantum dot that was initially occupied.     

Experimental demonstration of coherent coupling of two quantum dots

During the recent years semiconductor nanostructures have attracted considerable interest with respect to potential applications in quantum information processing. In particular, quantum dot molecules have been suggested to provide the building block of a quantum computer: forming quantum gates due to coherent coupling of two dots. The characteristic dependence of the splitting of ‘bonding’ and ‘anti-bonding’ states suggests coherent coupling of two InAs/GaAs quantum dots. Anti-crossings in the fine structure of excitons due to mixing of optically bright and dark states have been observed in Faraday configuration. In Voigt configuration the diamagnetic shift of the quantum dot molecule is enhanced compared to a single quantum dot. These findings altogether demonstrate the coherent coupling of exciton states in quantum dot molecules.     

Resonant photocurrent-spectroscopy of individual CdSe quantum dots

Here we report on investigations on CdSe quantum dots incorporated in ZnSe based Schottky photodiodes with near-field shadow masks. Photoluminescence and photocurrent of individual quantum dots were studied as a function of the applied bias voltage. The exciton energy of the quantum dot ground state transition was shifted to the excitation energy by using the Stark effect tuning via an external bias voltage. Under the condition of resonance with the laser excitation energy we observed a resonant photocurrent signal due to the tunnelling of carriers out of the quantum dots at electric fields above 500 kV/cm.     

Splitting and storing excitons in strained coupled self-assembled quantum dots

We present a novel self-assembled quantum dot structure designed to spatially separate and store photo-generated electrons and holes in pairs of strain coupled quantum dots. The spatial separation of electron–hole pairs into quantum dots and strain-induced quantum dots has been investigated and verified by photoluminescence experiments. Results from time-resolved PL demonstrates that at low temperatures (3 K) the electron–hole pair can be stored for several seconds.     

Temperature dependence of the electron distribution in a GaAs matrix with embedded InAs quantum dots

We report on the effect of the Debye averaging process on the CV characteristics of a sample containing four coupled planes of InAs self-assembled quantum dots. The observed electron distribution presented a dynamical dependence of the temperature during the C–V measurements which was explained in terms of the screening length dependence on the temperature. In addition, using the C–V data, we calculated the electron density at the planes containing the InAs dots and we have observed a high-temperature stability: the electron density at the quantum dots remained constant over a large range of temperature.     

Electroluminescence of CdSe/CdS quantum dots and the transfer of the exciton excitation energy in an organic light-emitting diode

A light emitting diode has been developed on the basis of multilayer nanostructures in which CdSe/CdS semiconductor colloidal quantum dots serve as emitters. Their absorption, photo-, and electroluminescence spectra have been obtained. The strong influence of the size effect and the density of particles in the layer on the spectral and electrophysical characteristics of the diode has been demonstrated. It has been shown that the rates of the transfer of the exciton excitation energy from organic molecules to quantum dots increase strongly even at a small increase in the radius of the core (CdSe) of a particle and depend strongly on the thickness of the shell (CdS) of the particle. The optimal arrangement of the layer of quantum dots with respect to the p-n junction has been estimated from the experimental data. The results demonstrate that the spectral characteristics and rates of the electron processes in light-emitting devices based on quantum dots incorporated into an organic matrix can be efficiently controlled.     

混合量子点QLED结构性能研究

为研究基于混合量子点的QLED结构与性能,利用红光量子点以及绿光量子点两种材料制备了橙光QLED器件,并对其性能进行了表征。实验制备的器件结构为ITO/PEDOT∶PSS/poly-TPD/混合QDs/Zn O/Al,其中发光层采用了3种混合量子点的混合结构方案。方案一先旋涂红光量子点层,后旋涂绿光量子点层;方案二先旋涂绿光量子点层,后旋涂红光量子点层;方案三将红光、绿光量子点1∶1混合后制备为发光层。实验结果表明:方案一制备的器件电流密度最大,发光亮度最低,且只有红光谱;方案二制备的器件具有最小的电流密度,同时具有红、绿光谱,在8 V电压下,电流效率约为4.69 cd/A;方案三制备的器件同时具有红、绿光谱,电流密度与发光特性介于方案一与方案二之间。实测数据与理论分析是一致的,方案二制备的器件存在双能量陷阱,能够将注入的空穴以及电子同时限制在红光量子点层内。通过调节各功能层厚度使得载流子注入平衡,可进一步增大发光电流,提高器件效率。     

Charged magneto-exciton states in semiconductor quantum dots

By embedding a layer of self-assembled quantum dots into a field-effect structure, we are able to control the exciton charge in a single dot. We present the results of photoluminescence experiments as a function of both charge and magnetic field. The results demonstrate a hierarchy of energy scales determined by quantization, the direct Coulomb interaction, the electron–electron exchange interaction, and the electron–hole exchange interaction. For excitons up to the triply charged exciton, the behavior can be understood from a model assuming discrete levels within the quantum dot. For the triply charged exciton, this is no longer the case. In a magnetic field, we discover a coherent interaction with the continuum states, the Landau levels associated with the wetting layer.