Electro-optic behavior of lithium niobate at cryogenic temperatures

The unclamped relative permittivity, , and the Pockels coefficient, , of congruent lithium niobate at a frequency f = 5760 Hz have been determined at low temperatures (7 K < T < 300 K). A He cryostat setup mounted to one arm of an electronically phase-stabilized Michelson interferometer was utilized for the measurement of . A continuous decrease in both parameters was observed as T → 0 K with limiting values of and , respectively.     

Lower hybrid current drive experiments with graphite limiters in the HT-7 superconducting tokamak

Recent progress of lower hybrid (LH) experiments with new graphite limiters configuration in the HT-7 tokamak is presented. The lower hybrid current drive (LHCD) efficiency can be determined by fitting based on experimental data. Improved particle confinement was observed via LHCD (P_LHW>300 kW) characterized by the particle confinement time τ_p increased about 1.56 times. It is found that runaways are suppressed during loop voltage is decreasing at the flat-top phase of LH discharges. The main limitations of pulse length are presented in long-pulse experiments with new limiter configuration.     

First-principles study on the electronic structures and absorption spectra for the PbWO4 crystal with lead vacancy

The electronic structures and absorption spectra for the perfect PbWO₄ (PWO) crystal and the crystal containing lead vacancy have been calculated using density functional theory code CASTEP with the lattice structure optimized. The calculated absorption spectra of the PWO crystal containing exhibit seven absorption bands peaking at 1.72 eV (720 nm), 2.16 eV (570 nm), 2.81 eV (440 nm), 3.01 eV (410 nm), 3.36 eV (365 nm), 3.70 eV (335 nm) and 4.0 eV (310 nm), which are very close to the experimental values. It predicts that the 330, 360, 420, 500-750 nm absorption bands are related to the existence of in the PWO crystal.     

Modelling of phase transitions and reaction at CO adsorption on oxygen precovered Pd(1 1 1)

Using the interaction parameters up to the third neighbors and activated form of O and CO diffusion and their reaction, the model has been proposed for Monte-Carlo simulations describing the catalytic O + CO → CO₂ reaction and occurring phase transitions on Pd(1 1 1) surface. Upon adsorption of CO the pre-adsorbed oxygen transforms from p(2 × 2)_O phase into and phases in the limit of room and moderate temperatures, respectively. We demonstrate that the kinetic effects determine both the occurrence of the p(2 × 1)_O and disappearance of the phases at moderate and low temperatures, respectively. Using reaction rate as a fit parameter, we show that at room temperature the start of the reaction can be synchronized with the occurrence of phase.     

Ion formation in laser-irradiated cesium vapor

We study theoretically the formation of Cs⁺ and during cw laser radiation resonant with 6s-7p transition of Cs atomic vapor. This is done by numerically solving rate equations for the evolution of atomic state and electron populations. The results of calculations for the atomic and molecular ions density at different values of laser power clarified that the associative ionization and Penning ionization process play an important role for producing the and Cs⁺, respectively, during the plasma formation. Also, the results showed that laser power of the order of 150 mW and 40-50 ns irradiation time are optimal in producing a fully ionized plasma.     

Adsorption structure of germanium on the Ru(0 0 0 1) surface

Coverage-dependent adsorption energy of the Ge/Ru(0 0 0 1) growth system and the geometrical distortions of the most stable adsorption structure are investigated through first-principles calculations within density functional theory. A local minimum in adsorption energy is found to be at a Ge coverage of 1/7 monolayer with a Ru(0 0 0 1)- symmetry. Based on this stale superstructure, the scanning tunneling microscopy (STM) and scanning tunneling spectroscopy (STS) images are simulated by means of surface local-density of states (LDOS). The results are consistent well with the STM measurements on the phase for Ge overlayer on Ru(0 0 0 1). From this stimulation, the relations between the STM images and the lattice distortion are also clarified.     

Study of Density Behavior During LHCD and IBW Heating in the HT-7 Superconducting Tokamak

A new method using special shape parameters has been introduced to study density behavior with synergy of lower hybrid current drive (LHCD) and ion Bernstein wave (IBW) heating in the HT-7 superconducting tokamak. During the synergy of the LHCD and IBW heating an improved confinement plasma was achieved, and the electron density was increased and peaked.     

ψ″ Decays to charmless final states

The importance of measuring the decays of the ψ″ = ψ (3770) resonance is discussed. These decays can shed light on a possible discrepancy between the total and cross-sections at the ψ″, and on a proposed mechanism for enhancement of penguin amplitudes in B meson decays through charm-anticharm annihilation. Measurements (including the ψ″ line shape) in states of definite G-parity and in inclusive charmless final states such as η′ + X are found to be particularly important.     

Surface phase diagram and temperature induced phase transitions of Sn/Cu(1 0 0)

Room temperature deposition of Sn on Cu(1 0 0) gives rise to a rich variety of surface reconstructions in the submonolayer coverage range. In this work, we report a detailed investigation on the phases appearing and their temperature stability range by using low-energy electron diffraction and surface X-ray diffraction. Previously reported reconstructions in the submonolayer range are p(2 × 2) (for 0.2 ML), p(2 × 6) (for 0.33 ML), ()R45° (for 0.5 ML), and c(4 × 4) (for 0.65 ML). We find a new phase with a structure for a coverage of 0.45 ML. Furthermore, we analyze the temperature stability of all phases. We find that two phases exhibit a temperature induced reversible phase transition: the ()R45° phase becomes ()R45° phase above 360 K, and the new phase becomes p(2 × 2) also above 360 K. The origin of these two-phase transitions is discussed.     

Formation mechanisms of GaN nanorods grown on Si(1 1 1) substrates

Scanning electron microscopy (SEM) images, transmission electron microscopy (TEM) images, and selected-area electron diffraction (SAED) patterns showed that vertically well aligned GaN nanorods with c-axis-oriented crystalline wurzite structures were grown on Si(1 1 1) substrates by using hydride vapor phase epitaxy. The high-resolution TEM (HRTEM) images showed that the crystallized GaN nanorods contained very few defects and that they were consisted of , {0 0 0 1}, and { } facets. The formation mechanisms for the GaN nanorods grown on Si(1 1 1) substrates are described on the basis of the SEM, TEM, SAED pattern, and HRTEM results.     

Fabrication of well ordered Zn nanorod arrays by ion irradiation method at room temperature and effect on crystal orientations

Highly oriented and densely packed one-dimensional (1D) polycrystalline Zn nanorods were fabricated on zinc plate without any catalyst at room temperature by bombardment with obliquely incident Ar⁺ ion via ion irradiation method. The sputtered surfaces were fully covered with Zn nanostructures with diameter and the length around 60 nm and 1.3 μm, respectively, confirmed by scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The crystal orientation of the Zn plate was investigated by electron back scattering pattern method (EBSP). The numerical density and morphology of Zn nanostructures (nanoneedle or nanorods) were found to be 2.1 × 10⁶ to 9 × 10⁶/mm² depending upon the crystal orientation and the atomic density on different crystallographic faces. () faces of Zn polycrystal tended to form more dense nanostructures compared to () faces. This is because of lower atomic density on () faces in comparison with () faces. This indicates that lower atomic density on any crystallographic faces is favorable to form nanostructure of higher density. The outstanding feature of this growth technique is that it provides a new direction for the controllable growth of desired nanostructures of variable density at room temperature without any catalyst. These well-aligned arrays of Zn nanorods/nanoneedle might be a promising material for the future application in nanodevices.     

The second hyperpolarizability of CdTe nanocrystals using polarization-resolved degenerate four-wave mixing

Polarization-resolved forward degenerate four-wave mixing (DFWM) in a nonresonant region revealed the effective third-order nonlinear susceptibility of colloidal CdTe nanocrystals (NCs) with the size near the Bohr radius and various concentrations. The second hyperpolarizabilities, and , of the CdTe NCs were ∼1.15 × 10⁻⁴¹ m⁵/V² and ∼3.01 × 10⁻⁴² m⁵/V² from the measurement of the concentration-dependent third-order nonlinear susceptibility of CdTe NCs, respectively. The ratio (/) of the hyperpolarizabilities was ∼0.26, which indicated a large contribution of an electronic polarization process to the third-order nonlinearity of CdTe NCs.     

Microstructure of epitaxial scandium nitride films grown on silicon

Epitaxial scandium nitride films (225 nm thick) were grown on (1 1 1)-oriented silicon substrates by molecular beam epitaxy (MBE), using ammonia as a reactive nitrogen source. Film microstructure was investigated using X-ray diffraction (XRD). The (1 1 1) ω-scan FWHM of 0.551° obtained for films grown at 850 °C is the lowest reported so far for ScN thin films. The principal orientation of ScN with respect to Si is (1 1 1)_ScN//(1 1 1)_Si and []_ScN//[]_Si, representing a 60° in-plane rotation of the ScN layer with respect to the Si substrate. However, some twinning is also present in the films; the orientation of the twinned component is (1 1 1)_ScN//(1 1 1)_Si and []_ScN//[]_Si, representing a ‘cube-on-cube’ orientation. The volume percentage of these twins in the films decreases with increasing film growth temperature.     

Low-temperature measurements of magnetic susceptibility and specific heat of Eu2Ti2O7—An XY pyrochlore

Magnetic susceptibility obtained from magnetization measurement (for fields H=0.1 and 1.0 T) of polycrystalline Eu₂Ti₂O₇ shows two distinct features. Firstly, increases on cooling below 300 K and attains a temperature-independent constant value at 68 K (T_max). Secondly, shows an antiferromagnetic increase below 4.9±0.1 K. The former behavior is explained by crystal field (CF) theory. CF levels and wave functions of ground and excited states are determined accurately from analyses of and earlier reported Mössbauer and optical spectra. Analysis of vs. 1/T curve at low temperatures gives the classical nearest-neighbor exchange interaction J^cl=−0.76 K and a weak dipolar interaction D_nn=0.0056 K. C_P of polycrystalline sample of Eu₂Ti₂O₇ and Y₂Ti₂O₇ are measured between 1.8-35 and 1.8-120 K respectively and θ_D vs. T (K) curves are calculated. At 4 K, θ_D of Eu₂Ti₂O₇ shows a kink and dC_P/dT curve show a maximum. Optical results show energy exchange between Eu³⁺ ions at intrinsic and extrinsic (defect) sites via super-exchange interaction at low temperature which may account for the observed anomalous behavior of and C_P.     

NaCl islands decorated with 2D or 3D 3,4,9,10-perylene-tetracarboxylic-dianhydride nanostructures

The formation of PTCDA (3,4,9,10-perylene-tetracarboxylic-dianhydride) nanostrutures on Au(1 1 1)-() covered with NaCl islands has been studied using scanning tunneling microscopy (STM). Atomically resolved STM images show that NaCl grows as (1 0 0)-terminated layers on Au(1 1 1)-(). Local atomic hexagonal packing has also been observed in the NaCl(1 0 0) layer. At submonolayer NaCl coverage, PTCDA forms two-dimensional islands on the Au(1 1 1) surface and nucleate preferentially at the NaCl island step edges. When the Au surface is fully covered with NaCl layers, PTCDA molecules form three-dimensional molecular clusters decorating the step edges of NaCl layers.     

Problems with power content beam parameter product

The M² beam propagation factor is widely used to characterize the quality of laser radiation and its propagation. When M² is defined by the second-moments, M² ? 1 holds in the paraxial approach. For many applications it is more convenient to use the power content values (normally η = 86.5%), also proposed by ISO. For the corresponding power content factor, it is often assumed that also holds. We have demonstrated previously that for a superposition of two coherent Gauss-Laguerre modes with radial symmetry, the 86.5% value of [6]. In recent years, has also been presented experimentally for a superposition of axially shifted Gaussian beams [7]. The problems with power content for axial superposition of Gaussian beams are discussed. In this paper it is shown that the 86.5% power content value can not be smaller than one for a coherent superposition of axially shifted Gaussian beams with radial symmetry presented in Ref. [7]. A superposition of two Gaussian beams with different waists and without shift is also discussed, and the corresponding of such beam can be smaller than one, depending strongly on the power content value η. For low power content values η and a large (or very small) ratio of the two different waists approaches zero. These investigations demonstrate that is not a suitable parameter to characterize laser radiation.     

X-ray initiated molecular photochemistry of Cl-containing adsorbates on a Si(1 0 0) surface using synchrotron radiation

X-ray initiated molecular photochemistry for SiCl₄ and CCl₄ adsorbed on Si(1 0 0) at ∼90 K following Cl 2p core-level excitation is investigated by photon stimulated ion desorption and ion kinetic energy distribution measurements. The Cl excitation of solid SiCl₄ induces the significant enhancement (∼900%) of the Cl⁺ yield, while the Cl excitation of condensed CCl₄ leads to a moderate enhancement (∼500%) of the Cl⁺ yield. The enhancement of Cl⁺ yield at the specific core-excited states is strongly correlated to the ion escaped energy. Upon X-ray exposure for CCl₄ adsorbed on Si(1 0 0) (20-L exposure), the Cl⁺ yields at resonances decrease and new structures at higher photon energies are observed. Cl⁺ yields at these new resonances are significantly enhanced compared to those at other resonances. These changes are the results of desorption and surface reaction of the CCl₄-Si surface complex due to X-ray irradiation. We have demonstrated that state-specific enhancement of ion desorption can be successfully applied to characterize the reaction dynamics of adsorbates adsorbed on surfaces by X-ray irradiation.