The dynamic properties of polyethylene and an acrylonitrile — Butadiene — Styrene material in a broad range of temperature and strain-rate variation

Conclusions The mechanical properties of an acrylonitrile-butadiene-styrene material and polyethylenes of densities =0.92 and 0.96 g/cm³ are studied within the temperature range of from 100 to –196°C and at strain rates of from 10^–3 to 1.3 · 10³ sec^–1. It is observed that under low-temperature and high-strain-rate conditions, the laws governing the mechanical properties of the acrylonitrile-butadiene-styrene material and polyethylenes are similar. Regions of strain rates and temperatures are found for which the behavior of the test materials is in good agreement with the Ree-Eyring equation, and, consequently, conforms to a temperature-time analogy. No embrittlement of the polyethylene is observed during tests at strain rates to 1.3 · 10³ sec^–1 and temperatures down to –196°C. In approximating these values of and T, the mechanical properties of polyethylenes will cease to be dependent on initial density.Institute of Polymer Mechanics, Academy of Sciences of the Latvian SSR, Riga. Translated from Mekhanika Polimerov, No. 6, 1027–1033, November–December, 1978.     

A study of the special features of stress relaxation in irradiated polytetrafluoroethylene

As a result of experimental studies of stress relaxation in polytetrafluoroethylene irradiated with various doses (from 2×10⁴ to 1×10⁶ rads), data have been obtained which make it possible to judge the rate of occurrence of relaxation processes in the polymer. A number of special features have been revealed which distinguish the character of occurrence of relaxation processes in the irradiated and nonirradiated material.Plastics Scientific-Research Institute, Moscow. Translated from Mekhanika Polimerov, No. 1, pp. 148–150, January–February, 1972.     

Experimental study of young's modulus of glass-plastics

The results of study of Young's modulus of glass-plastics in the 10^–1–10⁵-Hz frequency range are presented. A stepwise variation in the modulus, which governs the relaxation process corresponding to a low-temperature internal-friction peak in the filler, is obtained.Rybinsk Institute of Aircraft Technology. Translated from Mekhanika Polimerov, No. 6, pp. 1089–1091, November–December, 1975.     

Creep of fluoroplastic under the joint action of tension and hydrostatic pressure

Conclusions 1. The effect of hydrostatic pressure on the creep of Teflon has been investigated under isothermal conditions. The applicability of the principle of reduced variables for reduction of creep curves with respect to pressure has been shown.2. It has been ascertained that in the pressure region from atmospheric to 1600 kgf/cm² there are two subregions, which are separated by a transition at a pressure of 700–800 kgf/cm². It has been shown that in these subregions the occurrence of relaxation processes has different characters.3. A direct measurement of the free volume of Teflon has been made in the temperature range from 40 to 120°C. A sharp increase in free volume in the region of the temperature transition has been shown.Leningrad Technological Institute of the Refrigeration Industry. Okhtinsk Scientific and Industrial Union "Plastpolimer," Leningrad. Translated from Mekhanika Polimerov, No. 3, pp. 434–438, May–June, 1977.     

Exact analysis of asymmetric random polling systems with single buffers and correlated input process

We introduce a simple approach for modeling and analyzing asymmetric random polling systems with single buffers and correlated input process. We consider two variations of single buffers system: the conventional system and the buffer relaxation system. In the conventional system, at most one customer may be resided in any queue at any time. In the buffer relaxation system, a buffer becomes available to new customers as soon as the current customer is being served. Previous studies concentrate on conventional single buffer system with independent Poisson process input process. It has been shown that the asymmetric system requires the solution ofm 2 ^m –1) linear equations; and the symmetric system requires the solution of 2 ^m–1–1 linear equations, wherem is the number of stations in the system. For both the conventional system and the buffer relaxation system, we give the exact solution to the more general case and show that our analysis requires the solution of 2 ^m –1 linear equations. For the symmetric case, we obtain explicit expressions for several performance measures of the system. These performance measures include the mean and second moment of the cycle time, loss probability, throughput, and the expected delay observed by a customer.     

Study of mechanical relaxation processes in ladder organosilicon polymers

Dynamic viscoelastic properties of ladder polyorganosiloxanes have been studied by the method of induced resonance oscillations in the temperature range from –150 to 300°C and in the frequency range from 8 to 300 Hz. Two broad maxima of mechanical losses were observed for all the polymers studied independently of their chemical structure, a low-temperature maximum in the –150 to 0°C region and a high-temperature maximum in the 0 to 250°C region. It was found that the introduction of alkyl groups into polyphenylsilsesquioxanes does not noticeably affect the position and nature of the low-temperature relaxation peaks but in certain cases leads to an increase in the dynamic modulus in polyphenylalkylsilsesquioxanes, compared with the modulus of polyphenylsilsesquioxane in the same temperature region. In the high-temperature region, a distinct dependence is observed of the relaxation peak on the length and the content of alkyl groups in the polymer. It has been found that increase in the length and the content of alkyl groups is accompanied by a shift in the peak in the direction of low temperatures and a decrease in the value of the modulus. Hypotheses have been suggested on the nature of the shifts which lead to the relaxation peaks observed in the ladder polyorganosiloxanes.Institute of Heteroorganic Compounds, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 5, pp. 804–809, September–October, 1973.     

Effect of the type of state of stress on the characteristics of the mechanical glass transition process in polymers

The effect of the type of state of stress on the activation energy and relaxation time is investigated with reference to the mechanical glass transition (softening) process in polymers. An expression relating the mechanical glass transition temperature with the structural glass transition temperature, the mean stress, and the stress intensity is obtained for isotropic homogeneous polymers. Experimental data obtained for polymethyl methacrylate in uniaxial tension and compression, pure bending, and shear are presented.All-Union Scientific Research Institute of Aviation Materials, Moscow. Translated from Mekhanika Polimerov, No. 2, pp. 195–199, March–April, 1971.     

Investigation of the mechanical properties of acrylics under conditions of creep,stress relaxation,and harmonic vibration

The dynamic and static (creep, stress relaxation) mechanical properties of various acrylics have been investigated. A relation is established between the structure and the macroscopic mechanical properties. The previous thermal history and the characteristics of the state of stress are shown to affect the nature of the relaxation processes and the mechanical properties of the acrylics. Generalized stress relaxation curves are constructed. The mechanical glass transition temperatures of the acrylics investigated are determined.Lenin Moscow State Pedagogic Institute. Translated from Mekhanika Polimerov, No. 1, pp. 157–159, January–February, 1973.     

Study on the impact-shear viscosity of block polymers

The temperature dependence of the specific impact viscosity of several amorphous and amorphous-crystalline polymers as measured in tests by means of the authors' impact-cutting method is discussed. It is shown that this dependence agrees fairly well with the mechanical losses determined at the same interaction frequencies and, hence, is sensitive to the relaxation transitions in polymers (an enhanced impact stability corresponds to the transition regions). The similarity mentioned above and the correspondence between the temperature dependences of the density, the Poisson coefficient, and the elasticity modulus suggests that mechanical energy supplied is dissipated by a molecular-motion type including segment motion and relating to melting of the crystallites.S. M. Kirov Leningrad Institute of Textile and Light Industry. Translated from Mekhanika Polimerov, No. 2, pp. 226–230, March–April, 1972.     

Impact strength of high-density polyethylene with various molecular weight distributions

The Charpy impact strength of high-density polyethylene specimens prepared under low pressure with average molecular weight from 60·10³ to 1.5·10⁶ and differing substantially in molecular weight distributions has been studied at room temperature and at –190°C. It is shown that, both at room temperature and at temperature considerably below the glass-formation temperature, the impact strength of polyethylene in the range of molecular weights mentioned is determined mainly by the content of fractions with molecular weights about 10⁵ and more and does not depend on the width of the molecular weight distribution."Plastpolimer" Scientific-Research Association, Leningrad. Translated from Mekhanika Polimerov, No. 5, pp. 919–921, September–October, 1973.     

Polymer fractography and fracture kinetics

The fractographic method makes it possible to determine the test temperature and time at which anomalies appear in the temperature-time dependence of the strength of polymethyl methacrylate and polycaprolactam by finding the conditions of disappearance of specular zones from the fracture surfaces of these polymers. For PMMA these values are –40°C and 10^–2 sec, for PCL –120°C and 10^–7 sec, respectively.For communication 1 see [2].Ioffe Physicotechnical Institute, Academy of Sciences of the USSR, Leningrad. Translated from Mekhanika Polimerov, No. 2, pp. 232–237, March–April, 1971.     

Properties of multicomponent polymers systems

In order to design materials having different mechanical properties combined with a permittivity of 2.2–2.6 and tg =2·10^–4-4.10^–4 at 20±1° C and 10⁶ Hz, it is possible to use compositions consisting of polystyrene, polyisobutylene and polyethylene. Projections of the three-dimensional triangular composition-property diagrams are presented for selecting the composition corresponding to spcified properties (hardness at 20 and 50° C and breaking stress and elongation).Central Scientific-Research Institute of Communications, Moscow. Moscow Krupskaya Regional Pedagogical Institute. Translated from Mekhanika Polimerov, Vol. 4, No. 6, pp. 133–1135, November–December, 1968.     

Mechanical relaxation processes in polymers

The various kinetic processes are classified and the place of relaxation effects among them is established. The theoretical basis of mechanical relaxation phenomena in polymers is outlined. The characteristics of relaxation processes associated with molecular mobility are examined with reference to various classes of polymers, in particular, amorphous and crystalline polymers, copolymers, and mechanical mixtures. The characteristics of relaxation processes associated with rearrangement of the supermolecular structures in amorphous and crystalline polymers are considered.This article is a review of mechanical relaxation effects in polymers with particular attention to research conducted in the Problem Laboratory of Polymer Physics of the Moscow Lenin State Pedagogical Institute.Problem Laboratory of Polymer Physics, Lenin Moscow State Pedagogical Institute. Translated from Mekhanika Polimerov, Vol. 5, No. 1, pp. 30–53, January–February, 1969.     

Use of the results of auxiliary experiments in solving problems in the linear theory of viscoelasticity

The approximate method of solving problems of the theory of linear viscoelasticity with arbitrary creep and relaxation kernels, proposed in [2], is substantiated and generalized. The essence of this method consists in the approximation of the functions depending on the Laplace — Carson transforms of the mechanical characteristics of a viscoelastic body by means of certain combinations of the transforms of the creep and relaxation kernels. The expressions obtained as a result of the approximation enable the inverse transforms of the unknown functions to be found without difficulty.Moscow Lomonosov State University. Translated from Mekhanika Polimerov, Vol. 4, No. 6, pp. 963–969, November–December, 1968.     

Effect of the molecular weight of polystyrene on the viscosity of concentrated solutions

The viscosity of solutions of polystyrene of various molecular weights (from 1.04 · 10² to 3.8 · 10⁵) in a poor solvent (decalin) and a good solvent (ethylbenzene) has been measured at temperatures from 15 to 70°C over a broad range of shear stresses from 10² to 10⁶ dyne/cm². The nature of the solvent has a considerable influence on the critical molecular weight and the absolute value of the viscosities of the solutions over the entire range of molecular weights and on the form of the flow curves of decalin solutions of polystyrene as a function of temperature. The heat of activation of viscous flow increases with increase in molecular weight and shear stress on the interval 20–80°C. The results obtained are explained in terms of the effect of the molecular weight of the polymer, the nature of the solvent, stress and temperature on structure formation in the solution and on the orientation of the macromolecules and structures in the flow process.Ural Gor'kii State University, Sverdlovsk. Translated from Mekhanika Polimerov, No. 5, pp. 920–926, September–October, 1970.     

A new method of measuring the viscoelastic properties of polymer systems in fluid and highly elastic states using forced vibrations in the ultralow-frequency region

A method is considered for measuring the dynamic mechanical characteristics of polyer systems using forced vibrations in the ultralow-frequency region down to 10^–6 Hz. The essence of this method lies in the fact that during the measurement process the motion of the polymer sample is controlled with a set amplitude and frequency, and the dynamic characteristics of the polymer are determined from the controlling mechanical stress. The method is illustrated using the results of measurements of the components of the complex modulus for polybutadiene over a wide range of temperatures and frequencies without making use of superimposition.The Central Constructional Bureau for Prototype Instrument Construction, Academy of Sciences of the USSR, Moscow. Translated from Mekhanika Polimerov, No. 2, pp. 344–347, March–April, 1976.     

Relaxation of polyvinylchloride compositions

The relaxation of polyvinyl chloride, stabilized by dibasic lead carbonate or lead stearate and plasticized by a small amount of diisooctyl phthalate, was investigated. It was found that the lead stabilizers and diisooctyl phthalate accelerate the relaxation processes in the polymer. There is a correlation between the rate of the relaxation processes and the glass-transition temperature.Higher Chemicotechnological Institute, Sofia. Translated from Mekhanika Polimerov, No. 5, pp. 916–919, September–October, 1972.     

The effect of rate of deformation on the mechanical characteristics of plastics

An experimental investigation of the effect of the rate of deformation on the strength and modulus of elasticity of vinyl plastic and glass-reinforced laminate is described. It is established that when the rate of relative tensile deformation of vinyl plastic at 25°C is reduced from 2000×10^–6 sec^–1 to 5×10^–6 sec^–1, and that for glass-reinforced laminate from 1000×10^–6 sec^–1 to 1.3×10^–6 sec^–1, the decrease in the modulus of elasticity is about 40% and the decrease in ultimate strength 30 and 48%, as the case may be.Mekhanika polimerov, Vol. 1, No. 1, pp. 76–81, 1965     

Effect of temperature on the chemical relaxation process in rubbers

The effect of temperature on the chemical relaxation of rubbers has been investigated. With reference to nine industrial rubbers it has been shown that during storage in the stressed state (at =const) chemical relaxation is chiefly determined by two processes proceeding at different rates. Furthermore, the chemical relaxation of rubbers is determined not only by the rate constants of these two processes but also by the pre-exponential constants C_0i, the relationship between which varies with increase in temperature. It is possible to extrapolate the rate constants (k_i) and pre-exponential constants (C_0i) from elevated temperatures (110–50° C) to temperatures in the range 20–25° C. An equation is proposed that makes it possible to calculate the change in the elastic properties of rubbers in the stressed state at storage temperatures (20–25° C) by means of results obtained at elevated temperatures.Mekhanika Polimerov, Vol. 3, No. 3, pp. 448–454, 1967     

Effect of long-term storage of polycarbonates on stress relaxation

The effect of long-term storage (three-five years) on the mechanical properties of polycarbonates and Makrolon has been experimentally investigated under conditions of stress relaxation at normal and elevated temperatures.Scientific-Research Institute of Mechanics, Lomonosov Moscow State University. Translated from Mekhanika Polimerov, No. 1, pp. 149–151, January–February, 1973.